CN100497820C - Method for making paper for used in embossed and patterned gold porcelain - Google Patents
Method for making paper for used in embossed and patterned gold porcelain Download PDFInfo
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- CN100497820C CN100497820C CNB2006100358271A CN200610035827A CN100497820C CN 100497820 C CN100497820 C CN 100497820C CN B2006100358271 A CNB2006100358271 A CN B2006100358271A CN 200610035827 A CN200610035827 A CN 200610035827A CN 100497820 C CN100497820 C CN 100497820C
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Abstract
The invention discloses a manufacturing method of cameo gold-covering plaque paper, which comprises the following steps: preparing non-optical bottom-powder pigment; making gloss cameo pigment; preparing ink oil and screen; proceeding fourth print. The plaque paper can be sintered by traditional ceramics pigment and valued metal agent once, which saves artificial painting procedure.
Description
Technical field
The present invention relates to a kind of manufacture method of ceramic marble paper, particularly a kind of manufacture method of paper for used in embossed and patterned gold porcelain.
Background technology
Sticking marble paper on the porcelain blank surface, make porcelain form various colourful patterns by roasting the burning, is a kind of general using method of porcelain incrustation, is widely used in the production of household china and furnishings decorative ceramics.But, because existing ceramic paint is different with the roasting temperature of burning of noble metal preparation (as gold, platinum etc.), both are disposable burning till simultaneously, therefore if form the decorative pattern that contains noble metal on the porcelain surface, traditional way is to stick earlier marble paper on porcelain, add by hand after roasting the burning again and retouch noble metal preparation, concrete technological process is: the porcelain blank → decal paper → roasting burning → finished product of burn → manually painting in gold → bake.There is the shortcoming of two aspects in this method, and the one, technological process is long, production efficiency is low, and it is not meticulous to paint in gold by hand, the defect rate height; The 2nd, whole process flow needs the roasting burning of secondary, and energy loss is big.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, a kind of paper for used in embossed and patterned gold porcelain is provided, ceramic paint and noble metal preparation can disposablely be burnt till.
The present invention is achieved in that
A kind of manufacture method of paper for used in embossed and patterned gold porcelain comprises the steps: powder pigment prepared of the unglazed end, light embossment pigment prepared, and the varnish preparation, half tone is made, the first impression, the second impression, the third printing, the 4th printing.
Powder pigment of the described unglazed end comprises following parts by weight of component: titanium dioxide 25-50, boron oxide 15-20, zirconia 10-30, be prepared from by the following method: raw material is mixed in proportion, and 1250-1320 ℃ of calcining down, by expecting: the weight ratio of flux piece=10:3 adds flux piece ball milling, adding 10% (percentage by weight) alcohol again grinds, 30-35 ℃ of oven dry pulverized with 300 order edge mills, and be standby.
Described light embossment pigment comprises following parts by weight of component: lead oxide 5-15, and silica 1 5-30, zirconia 5-25, aluminium oxide 25-35, the preparation method is identical with powder method for preparing pigment of the unglazed end.
Described varnish comprises following parts by weight of component: pine tar 25-50, hydro-desulfurization heavy oil 10-25, acetate 2-butoxy ethyl ester 10-25, heavy aromatics camphorated oil 2.5-10, dibutyl phthalate 2.5-10, be prepared from by the following method: raw material are mixed in proportion, put reactor into and heat to 80-90 ℃ of stewing out of water 36-48 hour, standby.
It is 350 order/square inches (silk screen) that half tone order number is selected in the described first impression for use, the weight ratio adding varnish of powder pigment of the unglazed end being pressed material: oil=10:6 grinds to form ink-like, use method for printing screen, be printed on the marble paper base stock under the condition of 24 ℃ of temperature, humidity 65% dry 12-14 hour then.
It is 180 order/square inches (steel mesh) that half tone order number is selected in the described second impression for use, the weight ratio adding varnish of light embossment pigment being pressed material: oil=10:5 grinds to form ink-like, on the basis of the first impression, stamp light embossment pigment, under the condition of 24 ℃ of temperature, humidity 65% dry 14-16 hour then.
It is 300 order/square inches (silk screen) that described the third printing is selected half tone order number for use, stamps noble metal preparation on the basis of the second impression, under the condition of 24 ℃ of temperature, humidity 65% dry 6-8 hour then.
To select half tone order number for use be 80 order/square inches (silk screen) in described the 4th printing, stamps front cover oil on the basis of the third printing, under the condition of 24 ℃ of temperature, humidity 65% dry 4-6 hour then, promptly makes paper for used in embossed and patterned gold porcelain.
Described marble paper base stock is an autogtaphic printing paper.
Described noble metal preparation is light lemon gold paste or platinum cream.
The invention has the beneficial effects as follows: because the adjustment of pigment formula makes the roasting burning temperature of pigment reach consistent with the roasting burning temperature of noble metal preparation, therefore porcelain marble paper of the present invention is attached on the porcelain blank surface, only need to burn (810-830 ℃), just can form colourful decorative pattern: the pattern or the lines that form the plane at the position that is printed on powder pigment of the unglazed end through once baking; Produce anaglyph in the position projection that is printed on embossment pigment; Form noble metal pattern or lines at the position that is printed on noble metal preparation, removed the operation of manually painting in gold from, improved production efficiency and product percent of pass, saved energy consumption.The present invention is applicable to fields such as household china, display art porcelain, and with the porcelain that porcelain marble paper of the present invention is decorated, third dimension is strong, and graceful valuable, product specification obviously improves.
Description of drawings
Fig. 1 is the process chart of porcelain marble paper of the present invention.
The specific embodiment
Below by example, can do further understanding to the present invention.
Example 1: the manufacturing of porcelain marble paper of the present invention
(1) gets 40 kilograms of titanium dioxide, 18 kilograms of boron oxides, after 20 kilograms of mixing of zirconia, contain the container of making by quartz, in 1280 ℃ kiln, calcine, add 23.4 kilograms of flux piece ball millings, adding 10.1 kilograms of edible alcohols grinds, 32 ℃ of oven dry down, pulverize with 300 order edge mills, it is standby to make powder pigment of the unglazed end.
(2) get 10 kilograms in lead oxide, 22 kilograms of silica, 15 kilograms of zirconias after 30 kilograms of mixing of aluminium oxide, contain the container of being made by quartz, in 1280 ℃ kiln, calcine, add 23.1 kilograms of flux piece ball millings, add 10 kilograms of alcohol and grind, 32 ℃ of oven dry down, pulverize with 300 order edge mills, it is standby to make light embossment pigment.
(3) get 38 kilograms of pine tars, 17 kilograms in hydro-desulfurization heavy oil, 17 kilograms of acetate 2-butoxy ethyl esters, 6.2 kilograms of heavy aromatics camphorated oils are put reactor into and are heated to 85 ℃ of stewing out of waters 42 hours after 6.2 kilograms of mixing of dibutyl phthalate, and it is standby to make varnish.
(4) require to make half tone according to porcelain marble paper flower face layout and color, 350 order/square inches (silk screen), 300 order/square inches (silk screen), 80 order/square inches (silk screen) and 4 kinds of specifications of 180 order/square inches (steel mesh) are arranged respectively.
(5) first impression: selecting half tone order number for use is 350 order/square inches, it is some to get powder pigment of the unglazed end, weight ratio adding varnish by material: oil=10:6 grinds to form ink-like, use method for printing screen, be printed on the autogtaphic printing paper, 24 ℃ of temperature, drying is 13 hours under the condition of humidity 65% then.
(6) second impression: selecting half tone order number for use is 180 order/square inches (steel mesh), it is some to get light embossment pigment, weight ratio adding varnish by material: oil=10:5 grinds to form ink-like, on the basis of the first impression, stamp light embossment pigment, 24 ℃ of temperature, drying is 15 hours under the condition of humidity 65% then.
(7) the third printing: selecting half tone order number for use is 300 order/square inches, stamps light lemon gold paste (outsourcing) on the basis of the second impression, and then 24 ℃ of temperature, drying is 7 hours under the condition of humidity 65%.
(8) the 4th printings: selecting half tone order number for use is 80 order/square inches, stamps front cover oil (outsourcing) on the basis of the third printing, and then 24 ℃ of temperature, drying is 5 hours under the condition of humidity 65%, promptly makes paper for used in embossed and patterned gold porcelain of the present invention.
Example 2: the manufacturing of porcelain marble paper of the present invention
Light platinum cream in step (7) printing of example 1, other steps are identical with example 1, and promptly making noble metal preparation is the porcelain marble paper of the present invention of platinum cream.
Example 3: porcelain marble paper of the present invention is used for the decorative daily-use porcelain
(1) before the applique,, greasy dirt or dust can not be arranged earlier with domestic porcelain (biscuit) cleaning surfaces.
(2) porcelain that will post the porcelain marble paper is sent into the roasting burning of kiln, and temperature is controlled between 810-830 ℃.The kiln top cover can not close tightly before noting 300 ℃ simultaneously, guarantee oxygen abundance in the stove.
Heating up when (3) baking burning can not be too urgent, after should volatilizing fully at the solvent of front cover oil, and the high temperature section of being allowed for access.The temperature of row's film should be controlled between 500-550 ℃.
Claims (3)
1, a kind of manufacture method of paper for used in embossed and patterned gold porcelain is characterized in that, it comprises the steps: powder pigment prepared of the unglazed end, light embossment pigment prepared, and the varnish preparation, half tone is made, the first impression, the second impression, the third printing, the 4th printing; Powder pigment of the described unglazed end comprises following parts by weight of component: titanium dioxide 25-50, boron oxide 15-20, zirconia 10-30, be prepared from by the following method: raw material is mixed in proportion, 1250-1320 ℃ of down calcining, press raw material: the weight ratio of flux piece=10:3 adds flux piece ball milling, adds percentage by weight again and be 10% alcohol grinding, 30-35 ℃ of oven dry down, pulverize with 300 order edge mills; Described light embossment pigment comprises following parts by weight of component: lead oxide 5-15, and silica 1 5-30, zirconia 5-25, aluminium oxide 25-35, the preparation method is identical with powder method for preparing pigment of the unglazed end; Described varnish comprises following parts by weight of component: pine tar 25-50, hydro-desulfurization heavy oil 10-25, acetate 2-butoxy ethyl ester 10-25, heavy aromatics camphorated oil 2.5-10, dibutyl phthalate 2.5-10, be prepared from by the following method: raw material are mixed in proportion, put reactor into and heat to 80-90 ℃ of stewing out of water 36-48 hour; It is the silk screen of 350 order/square inches that half tone order number is selected in the described first impression for use, powder pigment of the unglazed end is added varnish by the weight ratio of pigment: varnish=10:6 grind to form ink-like, use method for printing screen, be printed on the marble paper base stock under the condition of 24 ℃ of temperature, humidity 65% dry 12-14 hour then; It is the steel mesh of 180 order/square inches that half tone order number is selected in the described second impression for use, light embossment pigment is added varnish by the weight ratio of pigment: varnish=10:5 grind to form ink-like, on the basis of the first impression, stamp light embossment pigment, under the condition of 24 ℃ of temperature, humidity 65% dry 14-16 hour then; It is the silk screen of 300 order/square inches that described the third printing is selected half tone order number for use, stamps noble metal preparation on the basis of the second impression, under the condition of 24 ℃ of temperature, humidity 65% dry 6-8 hour then; To select half tone order number for use be the silk screen of 80 order/square inches in described the 4th printing, stamps front cover oil on the basis of the third printing, under the condition of 24 ℃ of temperature, humidity 65% dry 4-6 hour then, promptly makes paper for used in embossed and patterned gold porcelain.
2, the manufacture method of porcelain marble paper according to claim 1 is characterized in that, described marble paper base stock is an autogtaphic printing paper.
3, the manufacture method of porcelain marble paper according to claim 1 is characterized in that, described noble metal preparation is light lemon gold paste or platinum cream.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100358271A CN100497820C (en) | 2006-06-01 | 2006-06-01 | Method for making paper for used in embossed and patterned gold porcelain |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100358271A CN100497820C (en) | 2006-06-01 | 2006-06-01 | Method for making paper for used in embossed and patterned gold porcelain |
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| Publication Number | Publication Date |
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| CN1865591A CN1865591A (en) | 2006-11-22 |
| CN100497820C true CN100497820C (en) | 2009-06-10 |
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| CNB2006100358271A Expired - Fee Related CN100497820C (en) | 2006-06-01 | 2006-06-01 | Method for making paper for used in embossed and patterned gold porcelain |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538169B (en) * | 2009-04-15 | 2012-03-14 | 深圳市祥钰精品制造有限公司 | Processing technique of genuine-golden relief sculpture of handicraft article |
| CN101531539B (en) * | 2009-04-16 | 2012-06-27 | 深圳市祥钰精品制造有限公司 | Processing technology for anaglyph red porcelain handicraft article |
| CN101992645B (en) * | 2009-08-21 | 2013-02-27 | 祥和彩瓷制造(上海)有限公司 | Method for producing composite transfer ceramic and glass colored paper using gravure |
| CN101921139B (en) * | 2010-09-21 | 2012-06-27 | 上海高诚艺术包装有限公司 | Manufacture method of ceramic wine bottle with liquid gold |
| CN102555564A (en) * | 2012-01-12 | 2012-07-11 | 宗海燕 | Ceramic decal paper printing method by directly unrolling roll paper on multicolor synchronous overprinting line |
| CN105365422B (en) * | 2015-10-09 | 2018-12-25 | 裴磊 | A kind of embossment decal paper and its production technology and application |
| CN109293396A (en) * | 2018-09-30 | 2019-02-01 | 何兴安 | A kind of Germanium enviroment protective ceramic and preparation method thereof |
| CN113773116A (en) * | 2020-06-10 | 2021-12-10 | 唐山市琨窑陶瓷有限公司 | Production process for printing on ceramic product and printed ceramic product |
| CN111646820B (en) * | 2020-06-10 | 2023-04-07 | 唐山市琨窑陶瓷有限公司 | Coating process of ceramic product and ceramic product |
| CN112479590B (en) * | 2020-12-08 | 2022-09-13 | 福建省德化云水窑陶瓷有限公司 | Preparation method of fluorescent glazing stained paper and fluorescent ceramic product prepared by same |
| CN113698233B (en) * | 2021-08-31 | 2023-06-06 | 深圳市国瓷永丰源瓷业有限公司 | Pearlescent interference color combination product and preparation method thereof, stained paper and one-time color burning process |
| CN113844189B (en) * | 2021-09-16 | 2023-06-09 | 德化县新佳兴印刷有限公司 | One-time firing relief Jin Huazhi and preparation method thereof |
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Granted publication date: 20090610 Termination date: 20140601 |