Background technology
Nearest CaCu
3Ti
4O
12Material has caused people's extensive concern, and it has unusual high specific inductivity, about 10 near room temperature
4~10
5, and good thermostability is arranged in the temperature range of 100~600K.Temperature is reduced to below the 100K, ε sharply is reduced to about 100, but do not observe the long-range structure phase transformation (1, Subramanian M A, Li D, Duan N, et al.Highdielectric constant ACu3Ti4O12 and ACu3Ti3FeO12 phases[J] .Solid State Chem, 2000,15:323-325; 2, Ramirez A P, Subramanian M A, Gardel M, et al.Giant dielectr constant response in acopper-titanate[J] .Solid State Commun, 2001,15:217-220; 3, Subramanian M A, Sleight A W.ACu3Ti4O12 and ACu3Ru4O perovskites:high dielectric constants and valence degeneracy[J] .Sol State Sci, 2002,4:347-351; 4, Homes C C, Vogt T, Shapiro S M, et al.Optical responsehigh-dielectric-constant perovskite-related oxide[J] .Science, 2001,12:625-629; 5, Moussa S M, Kennedy B J.Structural studies of the distorted perovski Ca0.25Cu0.75TiO3[J] .Mater Res Bull, 2001,36:2525-2529) these character make it be with a wide range of applications in electronics industry.
Different experimentations, experimental technique and preparation technology have remarkable influence to the dielectric properties of CCTO material.At present in the preparation process of the CCTO pottery of reporting in the document, many employing long-time pre-burnings (8h), perhaps pre-sinter process repeatedly, sintering time is very long, from 10h to tens hour even up to a hundred hours, make that preparation process complexity, cycle are long, energy consumption is bigger, and the short period of time sintering prepares the few of CCTO pottery.
The loss tangent of ceramic capacitor material is low more, helps production application more.But the CCTO material of preparation generally has bigger dielectric loss when having high permittivity.Room temperature lowest loss angle tangent value D is 0.05 (D.P.Cann under the 1kHz of bibliographical information at present, S.Aygun, X.Tan, Extended Abstracts of the 11th USJapan Seminar onDielectric and Piezoelectric Ceramics, Sapporo Japan, 2003:153-156) with 0.06 (Li Xuewei, the firm .CaCu of State of Zhao
3Ti
4O
12Microstructure of ceramics and dielectric properties [J]. Liaoning Project Technology University's journal, 2005,25).
Summary of the invention
The object of the present invention is to provide a kind of low-dielectric loss CaCu
3Ti
4O
12The preparation method of pottery.
Concrete steps of the present invention are:
1) earlier raw material lime carbonate, titanium dioxide and cupric oxide were mixed in 1: 4: 3 in molar ratio, wet ball grinding gets mixed powder.
2) with the mixed powder oven dry, with the mixed powder pre-burning, the temperature of pre-burning is 850~1000 ℃ after the oven dry.
3) mixed powder after the pre-burning carries out ball milling again, crosses 80 eye mesh screens, drying at least, adds polyvinyl alcohol (PVA), and grinding, granulation get the granulation powder.
4) the granulation dried bean noodles is molded, cold isostatic compaction gets base substrate again.
5) with blank sintering, furnace cooling gets target product then.
Before the test, target product is carried out surface finish, last silver electrode is done the dielectric properties test.
Wet ball grinding is crossed 80 eye mesh screens at least.Mixed powder after grinding is dried in baking oven.With powder pre-burning in the agate crucible, can be incubated 1~6h after the pre-burning then.The amount that adds polyvinyl alcohol is 7%~10% of a dry back mixed powder.The pressure that the granulation dried bean noodles is molded is preferably 100~250MPa; The pressure of cold isostatic compaction is preferably 100~250MPa.The agglomerating temperature is preferably 1020~1100 ℃, also insulation behind the sintering.
Adopt the prepared CaCu of the present invention
3Ti
4O
12Pottery, its base substrate densification, pore quantity is few, and shrinking percentage is low, can more sinter porcelain under the low temperature, and dielectric properties are improved significantly, and its loss tangent is minimum to be 0.024, is a kind of method of the effective CCTO of improvement dielectric properties.
Embodiment
Embodiment 1
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 80 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1: 1.2.Use planetary ball mill ball milling 4h, rotating speed 250 commentaries on classics/min, mixed powder after grinding is dried in baking oven.With mixed powder pre-burning in the agate crucible, 950 ℃ of pre-burnings also are incubated 2h then.Mixed powder after the pre-burning carries out ball milling, drying again.The PVA that adds 10% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 150MPa pressure, be diameter 9mm at the 200MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1020 ℃ of sintering and be incubated 2h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.Its D=0.024, ε r=3535.4.
Embodiment 2
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 100 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1.1: 1.1.Use planetary ball mill ball milling 4h, rotating speed 250 commentaries on classics/min, mixed powder after grinding is dried in baking oven.With mixed powder pre-burning in the agate crucible, 850 ℃ of pre-burnings also are incubated 6h then.Mixed powder after the pre-burning carries out ball milling, drying again.The PVA that adds 7% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 200MPa pressure, be diameter 9mm at the 150MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1050 ℃ of sintering and be incubated 2h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.Its D=0.024, ε r=3535.4.
Embodiment 3
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 120 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 0.9: 0.9.Use planetary ball mill ball milling 4h, rotating speed 250 commentaries on classics/min, mixed powder after grinding is dried in baking oven.With mixed powder pre-burning in the agate crucible, 900 ℃ of pre-burnings also are incubated 1h then.Mixed powder after the pre-burning carries out ball milling, drying again.The PVA that adds 8% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 100MPa pressure, be diameter 9mm at the 250MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1100 ℃ of sintering and be incubated 2h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 4
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 80 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1.2: 1.Use planetary ball mill ball milling 5h, rotating speed 200 commentaries on classics/min, mixed powder after grinding is dried in baking oven.With mixed powder pre-burning in the agate crucible, 1000 ℃ of pre-burnings also are incubated 3h then.Mixed powder after the pre-burning carries out ball milling, drying again.The PVA that adds 10% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 250MPa pressure, be diameter 9mm at the 100MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1060 ℃ of sintering and be incubated 2h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 5
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 120 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1: 1.2.Use planetary ball mill ball milling 4h, rotating speed 250 commentaries on classics/min, mixed powder after grinding is dried in baking oven.With mixed powder pre-burning in the agate crucible, 950 ℃ of pre-burnings also are incubated 5h then.Mixed powder after the pre-burning carries out ball milling, drying again.The PVA that adds 9% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 150MPa pressure, be diameter 9mm at the 150MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1030 ℃ of sintering and be incubated 2h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 6
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 100 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1.1: 1.3.Use planetary ball mill ball milling 6h, rotating speed 200 commentaries on classics/min.Mixed powder after grinding is dried in baking oven.Then with mixed powder pre-burning in the agate crucible, 850 ℃ of pre-burnings and be incubated the 6h. pre-burning after powder carry out ball milling, drying again.The PVA that adds 7% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 100MPa pressure, be diameter 8mm at the 250MPa cold isostatic compaction again, the disk of thickness 1.5mm.Base substrate in electric furnace in 1050 ℃ of sintering and be incubated 2h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.Its D=0.066, ε r=3554.9.
Embodiment 7
Raw material lime carbonate, titanium dioxide and cupric oxide were mixed in 1: 4: 3 in molar ratio, and wet ball grinding in agate jar is crossed 120 eye mesh screens, and ball-milling medium is a distilled water, presses mass ratio, raw material: agate ball: distilled water=1: 0.9: 1.2.Use planetary ball mill ball milling 5h, the powder behind the rotating speed 250 commentaries on classics/min. ball millings is dried in baking oven.Then with powder pre-burning in the agate crucible, 1000 ℃ of pre-burnings and be incubated the 1h. pre-burning after powder carry out ball milling, drying again.The PVA that adds 8% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 150MPa pressure, be diameter 9mm at the 200MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1020 ℃ of sintering and be incubated 2h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 8
Raw material lime carbonate, titanium dioxide and cupric oxide were mixed in 1: 4: 3 in molar ratio, and wet ball grinding in agate jar is crossed 100 eye mesh screens, and ball-milling medium is a distilled water, compares raw material by quality; Agate ball: distilled water=1: 1: 1.1.Use planetary ball mill ball milling 5h, the powder behind the rotating speed 280 commentaries on classics/min. ball millings is dried in baking oven.Then with powder pre-burning in the agate crucible, 1000 ℃ of pre-burnings and be incubated the 2h. pre-burning after powder carry out ball milling, drying again.The PVA that adds 8% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 200MPa pressure, be diameter 8mm at the 150MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1050 ℃ of sintering and be incubated 3h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 9
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 80 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1.1: 1.2.Use planetary ball mill ball milling 3h, the powder behind the rotating speed 300 commentaries on classics/min. ball millings is dried in baking oven.Then with powder pre-burning in the agate crucible, 1000 ℃ of pre-burnings and be incubated the 4h. pre-burning after powder carry out ball milling, drying again.The PVA that adds 10% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 180MPa pressure, be diameter 9mm at the 150MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1100 ℃ of sintering and be incubated 3h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 10
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 100 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1.1: 1.Use planetary ball mill ball milling 4h, the powder behind the rotating speed 250 commentaries on classics/min. ball millings is dried in baking oven.Then with powder pre-burning in the agate crucible, 950 ℃ of pre-burnings and be incubated the 5h. pre-burning after powder carry out ball milling, drying again.The PVA that adds 9% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 200MPa pressure, be diameter 9mm at the 180MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1050 ℃ of sintering and be incubated 3h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 11
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 120 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1.1: 1.Use planetary ball mill ball milling 3h, the powder behind the rotating speed 300 commentaries on classics/min. ball millings is dried in baking oven.Then with powder pre-burning in the agate crucible, 850 ℃ of pre-burnings and be incubated the 2h. pre-burning after powder carry out ball milling, drying again.The PVA that adds 10% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 150MPa pressure, be diameter 9mm at the 150MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1020 ℃ of sintering and be incubated 3h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 12
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 80 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1.1: 1.2.Use planetary ball mill ball milling 5h, the powder behind the rotating speed 250 commentaries on classics/min. ball millings is dried in baking oven.Then with powder pre-burning in the agate crucible, 960 ℃ of pre-burnings and be incubated the 5h. pre-burning after powder carry out ball milling, drying again.The PVA that adds 8% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 250MPa pressure, be diameter 9mm at the 150MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1100 ℃ of sintering and be incubated 4h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.
Embodiment 13
Raw material lime carbonate, titanium dioxide and cupric oxide 1: 4: 3 are in molar ratio mixed, and wet ball grinding in agate jar is crossed 100 eye mesh screens, and ball-milling medium is a distilled water, by quality than raw material: agate ball: distilled water=1: 1.1: 0.9.Use planetary ball mill ball milling 4h, the powder behind the rotating speed 300 commentaries on classics/min. ball millings is dried in baking oven.Then with powder pre-burning in the agate crucible, 950 ℃ of pre-burnings and be incubated the 6h. pre-burning after powder carry out ball milling, drying again.The PVA that adds 10% mass percent then, grinding, granulation in agate mortar.The granulation powder is dry-pressing formed under 150MPa pressure, be diameter 9mm at the 200MPa cold isostatic compaction again, the disk of thickness 2mm.Base substrate in electric furnace in 1020 ℃ of sintering and be incubated 4h, furnace cooling then.Surface finish, last silver electrode is carried out the dielectric properties test.