CN100443564C - Composite base material sand-fixation agent and manufacture method - Google Patents
Composite base material sand-fixation agent and manufacture method Download PDFInfo
- Publication number
- CN100443564C CN100443564C CNB2005100967398A CN200510096739A CN100443564C CN 100443564 C CN100443564 C CN 100443564C CN B2005100967398 A CNB2005100967398 A CN B2005100967398A CN 200510096739 A CN200510096739 A CN 200510096739A CN 100443564 C CN100443564 C CN 100443564C
- Authority
- CN
- China
- Prior art keywords
- sand
- fixing agent
- fixation agent
- agent
- organosilicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002131 composite material Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000000034 method Methods 0.000 title abstract 3
- 239000000463 material Substances 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 16
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001110 calcium chloride Substances 0.000 claims abstract description 8
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 14
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- 229920000609 methyl cellulose Polymers 0.000 claims description 7
- 239000001923 methylcellulose Substances 0.000 claims description 7
- 235000019353 potassium silicate Nutrition 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011575 calcium Substances 0.000 abstract description 3
- 229910052791 calcium Inorganic materials 0.000 abstract description 3
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 abstract description 3
- 206010016807 Fluid retention Diseases 0.000 abstract description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910021529 ammonia Inorganic materials 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 abstract description 2
- 229920002521 macromolecule Polymers 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract description 2
- 239000010703 silicon Substances 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 abstract 2
- KCLANYCVBBTKTO-UHFFFAOYSA-N Proparacaine Chemical compound CCCOC1=CC=C(C(=O)OCCN(CC)CC)C=C1N KCLANYCVBBTKTO-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 229940087458 alcaine Drugs 0.000 abstract 1
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 239000001164 aluminium sulphate Substances 0.000 abstract 1
- 229940077746 antacid containing aluminium compound Drugs 0.000 abstract 1
- 229940043430 calcium compound Drugs 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 235000011127 sodium aluminium sulphate Nutrition 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 206010067482 No adverse event Diseases 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- -1 salt compound Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates the composite base sand-fixation agent and preparing method. The sand-fixation agent is made by mixing the plant fiber macromolecular compound with ammonia, silicon, calcium and aluminium compounds. The method comprises the following steps: putting the sodium silicate, aluminium sulphate and calcium chloride into autoclave, stirring, then adding mixture liquid of sulfuric acid and alcaine; adding cellulose methyl, aquadrate and organosilicon, controlling the temperature, stirring, cooling, filtering, and getting the product. The sand-fixation agent can make sand cure for 4 hours, compression strength of it is 0.20MPa for 7 days, and compression strength of it is 0.10MPa after soaking. The sand-fixation agent has strong fixation strength, and is not bad for plants. The agent has advantages of good penetrability, heat-durability, acid-resistivity, adhesiveness and water-retention property.
Description
1, technical field:
Composite interstitial substance sand-fixing agent of the present invention and production method belong to chemical field.
2, background technology:
In recent years, China's desert desert enlarged areas, the desertification of land aggravation, sandstorm takes place frequently, and brings serious harm to the national economic development, and defending and controlling sand becomes the problem that the NORTHWEST CHINA North China presses for solution.Both at home and abroad at present emulsified bitumen solution and calcium lignin sulphonate series solution of adopting as sand-fixing agent more, its consolidated sand strength is low, generally can only reinforce the drift-sand top layer, play and cut off wind to the effect of the grains of sand or make the grains of sand be bonded to the plate-like effect that can not be blown up, environment is had certain pollution, and Application Areas is restricted.
3, summary of the invention:
The object of the present invention is to provide a kind of consolidated sand strength height, composite interstitial substance sand-fixing agent and production method that vegetation is had no adverse effects.
The objective of the invention is to be achieved by the following technical programs: utilize inorganic and organic salt compound, the inorganic acid solution of vegetable fibre macromolecular compound and ammonia, silicon, calcium, aluminium to be mixed with out the composite interstitial substance sand-fixing agent.Raw materials used and weight is during preparation composite interstitial substance sand-fixing agent:
Methylcellulose gum: 0.1～0.3kg, organosilicon: 0.1～0.3kg, sulfuric acid: 2～4kg, hydrochloric acid: 2～4kg, Tai-Ace S 150: 2～3kg, calcium chloride: 1～2kg, urea: 3～5kg, water glass: 80～90kg.
Production method: the mixture with water glass, Tai-Ace S 150, calcium chloride joins in the reactor that has agitator earlier, adds the mixed solution of sulfuric acid and hydrochloric acid then; Add methylcellulose gum, urea and organosilicon afterwards more gradually, temperature is controlled at 60～80 ℃, and the reaction dissolving was stirred 4 hours, and naturally cooling is reduced to normal temperature, and filtration can obtain water white composite interstitial substance sand-fixing agent.
Through the check of Xinjiang building materials non-metallic products quality monitoring testing station, this composite interstitial substance sand-fixing agent can reach following effect:
1. can solidify in 4 hours, infinite compression strength was 0.20MPa in 7 days, can reach 0.1Mpa after the immersion comprehensively.The consolidated sand strength height, vegetation is had no adverse effects.
2. tasteless, nontoxic, do not have smell, colourless, have good penetration, thermotolerance, acid resistance, adhesivity and water-retention property.
4, embodiment:
Embodiment:
Raw materials used and weight is when preparing 100 kilograms of composite interstitial substance sand-fixing agents:
Methylcellulose gum: 0.1～0.3kg, organosilicon: 0.1～0.3kg, sulfuric acid: 2～4kg, hydrochloric acid: 2～4kg, Tai-Ace S 150: 2～3kg, calcium chloride: 1～2kg, urea: 3～5kg, water glass: 80～90kg.
Production method: the mixture with water glass, Tai-Ace S 150, calcium chloride joins in the reactor that has agitator earlier, adds the mixed solution of sulfuric acid and hydrochloric acid then; Add methylcellulose gum, urea and organosilicon afterwards more gradually, temperature is controlled at 60～80 ℃, and the reaction dissolving was stirred 4 hours, and naturally cooling is reduced to normal temperature, and filtration can obtain water white composite interstitial substance sand-fixing agent.
During use, the composite interstitial substance sand-fixing agent of every 100kg is added 60% water dilution, artificial or airplane spray is in husky surface, every cubic metre of husky body of the curable 3-5 cubic meter of composite interstitial substance sand-fixing agent, and husky body can solidify comprehensively in 4 hours.
Claims (2)
1, a kind of composite interstitial substance sand-fixing agent is characterized in that: raw materials used and weight is:
Methylcellulose gum 0.1～0.3kg, organosilicon 0.1～0.3kg, sulfuric acid 2～4kg, hydrochloric acid 2～4kg, Tai-Ace S 150 2～3kg, calcium chloride 1～2kg, urea 3～5kg, water glass 80～90kg;
Production method: the mixture with water glass, Tai-Ace S 150, calcium chloride joins in the reactor that has agitator earlier, adds the mixed solution of sulfuric acid and hydrochloric acid then; Add methylcellulose gum, urea and organosilicon afterwards more gradually, temperature is controlled at 60～80 ℃, and the reaction dissolving was stirred 4 hours, and naturally cooling is reduced to normal temperature, filters promptly to obtain water white composite interstitial substance sand-fixing agent.
2, the production method of composite interstitial substance sand-fixing agent as claimed in claim 1 is characterized in that: the mixture with water glass, Tai-Ace S 150, calcium chloride joins in the reactor that has agitator earlier, adds the mixed solution of sulfuric acid and hydrochloric acid then; Add methylcellulose gum, urea and organosilicon afterwards more gradually, temperature is controlled at 60～80 ℃, and the reaction dissolving was stirred 4 hours, and naturally cooling is reduced to normal temperature, filters promptly to obtain water white composite interstitial substance sand-fixing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100967398A CN100443564C (en) | 2005-08-24 | 2005-08-24 | Composite base material sand-fixation agent and manufacture method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100967398A CN100443564C (en) | 2005-08-24 | 2005-08-24 | Composite base material sand-fixation agent and manufacture method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1919969A CN1919969A (en) | 2007-02-28 |
| CN100443564C true CN100443564C (en) | 2008-12-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100967398A Expired - Fee Related CN100443564C (en) | 2005-08-24 | 2005-08-24 | Composite base material sand-fixation agent and manufacture method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100443564C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103243706B (en) * | 2013-05-28 | 2015-03-11 | 中国科学院新疆生态与地理研究所 | Method for spraying chemical sand-fixation agents |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058037A (en) * | 1991-07-23 | 1992-01-22 | 江坤 | Dune-fixing agent of peculiar composite and method for making thereof |
| JPH05339567A (en) * | 1992-06-11 | 1993-12-21 | Mitsubishi Petrochem Co Ltd | Water holding agent for soil |
| CN1118828A (en) * | 1994-05-16 | 1996-03-20 | 黄智山 | Covering material for fixing ash and its construction method |
| CN1184837A (en) * | 1996-12-13 | 1998-06-17 | 西南交通大学 | Firming agent contg. clay for construction with concrete |
| CN1243858A (en) * | 1999-06-28 | 2000-02-09 | 吉林大学 | Water-preserving agent for preventing water leakage of dry or semi-dry farmland |
| CN1408815A (en) * | 2001-09-27 | 2003-04-09 | 关启美 | Sand fixing agent and its preparing method and use |
-
2005
- 2005-08-24 CN CNB2005100967398A patent/CN100443564C/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058037A (en) * | 1991-07-23 | 1992-01-22 | 江坤 | Dune-fixing agent of peculiar composite and method for making thereof |
| JPH05339567A (en) * | 1992-06-11 | 1993-12-21 | Mitsubishi Petrochem Co Ltd | Water holding agent for soil |
| CN1118828A (en) * | 1994-05-16 | 1996-03-20 | 黄智山 | Covering material for fixing ash and its construction method |
| CN1184837A (en) * | 1996-12-13 | 1998-06-17 | 西南交通大学 | Firming agent contg. clay for construction with concrete |
| CN1243858A (en) * | 1999-06-28 | 2000-02-09 | 吉林大学 | Water-preserving agent for preventing water leakage of dry or semi-dry farmland |
| CN1408815A (en) * | 2001-09-27 | 2003-04-09 | 关启美 | Sand fixing agent and its preparing method and use |
Non-Patent Citations (2)
| Title |
|---|
| 化学固沙材料在干旱沙漠地区的应用. 王银梅，韩文峰，谌文武.中国地质灾害与防治学报，第15卷第2期. 2004 |
| 化学固沙材料在干旱沙漠地区的应用. 王银梅，韩文峰，谌文武.中国地质灾害与防治学报，第15卷第2期. 2004 * |
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| Publication number | Publication date |
|---|---|
| CN1919969A (en) | 2007-02-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: WANG YUHUI Free format text: FORMER OWNER: XINJIANG SAILISI SCIENCE AND TECHNOLOGY DEVELOPMENT CO., LTD. Effective date: 20100129 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20100129 Address after: The first highway investigation and Design Institute, No. 133, South Building Road, Nanhu South Road, the Xinjiang Uygur Autonomous Region, Xinjiang, Urumqi 16, China: 830063 Co-patentee after: Qin Mengju Patentee after: Wang Yu Hui Address before: 14, building 16, Henan East Road, Urumqi, the Xinjiang Uygur Autonomous Region: 830011 Patentee before: Xinjiang Sailisi Science & Technology Development Co., Ltd. |
|
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Xinjiang Huiyu Technology Co. Ltd. Luqiao Assignor: Wang Yuhui|Qin Mengju Contract record no.: 2011650000018 Denomination of invention: Composite base material sand-fixation agent and manufacture method Granted publication date: 20081217 License type: Exclusive License Open date: 20070228 Record date: 20110713 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081217 Termination date: 20160824 |