CN100425554C - 一种丙烯酸生产废水的处理方法 - Google Patents
一种丙烯酸生产废水的处理方法 Download PDFInfo
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- CN100425554C CN100425554C CNB2006100974199A CN200610097419A CN100425554C CN 100425554 C CN100425554 C CN 100425554C CN B2006100974199 A CNB2006100974199 A CN B2006100974199A CN 200610097419 A CN200610097419 A CN 200610097419A CN 100425554 C CN100425554 C CN 100425554C
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- Prior art keywords
- waste water
- reactor
- acrylic acid
- acid production
- production waste
- Prior art date
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- 239000002351 wastewater Substances 0.000 title claims abstract description 59
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 28
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 238000011282 treatment Methods 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 18
- 230000001105 regulatory effect Effects 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 238000005868 electrolysis reaction Methods 0.000 claims description 16
- 239000010802 sludge Substances 0.000 claims description 11
- 238000010790 dilution Methods 0.000 claims description 10
- 239000012895 dilution Substances 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 8
- 238000009280 upflow anaerobic sludge blanket technology Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 150000003016 phosphoric acids Chemical class 0.000 claims description 5
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 238000004065 wastewater treatment Methods 0.000 abstract description 2
- 230000001276 controlling effect Effects 0.000 abstract 3
- 238000007865 diluting Methods 0.000 abstract 1
- 239000010815 organic waste Substances 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- -1 phenyl aldehyde Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- MUZDXNQOSGWMJJ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;prop-2-enoic acid Chemical class OC(=O)C=C.CC(=C)C(O)=O MUZDXNQOSGWMJJ-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000009279 wet oxidation reaction Methods 0.000 description 2
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002894 chemical waste Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000009629 microbiological culture Methods 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 150000003384 small molecules Chemical group 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2006100974199A CN100425554C (zh) | 2006-11-07 | 2006-11-07 | 一种丙烯酸生产废水的处理方法 |
Applications Claiming Priority (1)
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CNB2006100974199A CN100425554C (zh) | 2006-11-07 | 2006-11-07 | 一种丙烯酸生产废水的处理方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1948189A CN1948189A (zh) | 2007-04-18 |
CN100425554C true CN100425554C (zh) | 2008-10-15 |
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CNB2006100974199A Expired - Fee Related CN100425554C (zh) | 2006-11-07 | 2006-11-07 | 一种丙烯酸生产废水的处理方法 |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101269899B (zh) * | 2008-05-13 | 2011-05-11 | 吉林大学 | 一种丙烯酸废水的综合处理方法 |
CN101973653B (zh) * | 2010-09-30 | 2012-07-04 | 南京大学 | 采用复合混凝法处理高浓度pam生产废水的方法 |
CN102267890B (zh) * | 2010-11-16 | 2014-06-11 | 中国环境科学研究院 | 从丙烯酸酯生产废水中萃取回收丙烯酸的方法 |
CN102225976B (zh) * | 2011-04-29 | 2012-10-10 | 张家港市德宝化工有限公司 | 以丙烯酸废水为原料制备聚丙烯酸类分散剂的方法 |
CN102491591B (zh) * | 2011-12-09 | 2014-12-03 | 宜兴市荣盛达环保有限公司 | 一种高浓度聚酯切片污水处理与循环利用***方法 |
CN103803741B (zh) * | 2012-11-14 | 2015-05-13 | 中国石油天然气股份有限公司 | 一种处理丙烯酸装置酸性废水的方法 |
CN103058418A (zh) * | 2013-01-18 | 2013-04-24 | 北京市环境保护科学研究院 | 一种丙烯酸废水生化处理的预处理装置及方法 |
CN103739170A (zh) * | 2014-01-22 | 2014-04-23 | 南京美泓环保科技有限公司 | 一种污水的处理方法 |
CN104556554A (zh) * | 2014-12-04 | 2015-04-29 | 江门谦信化工发展有限公司 | 一种丙烯酸及酯废水的深度处理工艺的方法 |
CN105152447B (zh) * | 2015-09-28 | 2017-11-03 | 博天环境集团股份有限公司 | 一种治理丙烯酸废水及回收乙酸钠的方法 |
CN105859037B (zh) * | 2016-05-13 | 2019-01-15 | 中国海洋石油集团有限公司 | 一种高浓度丙烯酸及酯废水的组合处理方法 |
CN108409044B (zh) | 2018-04-04 | 2019-04-16 | 蓝星安迪苏南京有限公司 | 用于处理丙烯醛反应器废水的方法及装置 |
CN114920489B (zh) * | 2022-05-26 | 2024-02-09 | 昌德新材科技股份有限公司 | 一种水泥生料添加剂及其应用和水泥生产工艺 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1435594A (zh) * | 2002-01-30 | 2003-08-13 | 株式会社日本触媒 | 丙烯酸和聚丙烯酸生产工艺中的废物处理方法 |
CN1600706A (zh) * | 2004-10-12 | 2005-03-30 | 北京东方石油化工有限公司东方化工厂 | 丙烯酸类及其酯类废水的生物处理方法 |
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2006
- 2006-11-07 CN CNB2006100974199A patent/CN100425554C/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1435594A (zh) * | 2002-01-30 | 2003-08-13 | 株式会社日本触媒 | 丙烯酸和聚丙烯酸生产工艺中的废物处理方法 |
CN1600706A (zh) * | 2004-10-12 | 2005-03-30 | 北京东方石油化工有限公司东方化工厂 | 丙烯酸类及其酯类废水的生物处理方法 |
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CN1948189A (zh) | 2007-04-18 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Zhejiang Satellite Acrylic Manufacturing Co., Ltd. Assignor: Nanjing University Contract fulfillment period: 2007.5.18 to 2012.5.17 Contract record no.: 2009330001789 Denomination of invention: Treatment method of acrylic acid production waste water Granted publication date: 20081015 License type: Exclusive license Record date: 20090803 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.5.18 TO 2012.5.17; CHANGE OF CONTRACT Name of requester: ZHEJIANG PROV SATELLITE PROPYLENE ACID MANUFACTURI Effective date: 20090803 |
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EM01 | Change of recordation of patent licensing contract |
Change date: 20101116 Contract record no.: 2009330001789 Assignee after: Zhejiang Satellite Petro Chemical Co., Ltd. Assignee before: Zhejiang Satellite Acrylic Manufacturing Co., Ltd. |
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EM01 | Change of recordation of patent licensing contract |
Change date: 20101116 Contract record no.: 2009330001789 Assignee after: Zhejiang Satellite Petro Chemical Co., Ltd. Assignee before: Zhejiang Satellite Acrylic Manufacturing Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081015 Termination date: 20201107 |