CN100389520C - 一种从废镍氢、镍镉电池回收硫酸镍溶液中去除钠离子的方法 - Google Patents
一种从废镍氢、镍镉电池回收硫酸镍溶液中去除钠离子的方法 Download PDFInfo
- Publication number
- CN100389520C CN100389520C CNB2005101002109A CN200510100210A CN100389520C CN 100389520 C CN100389520 C CN 100389520C CN B2005101002109 A CNB2005101002109 A CN B2005101002109A CN 200510100210 A CN200510100210 A CN 200510100210A CN 100389520 C CN100389520 C CN 100389520C
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- China
- Prior art keywords
- nickel
- hydrogen
- sulfuric acid
- waste
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229910001415 sodium ion Inorganic materials 0.000 title claims abstract description 34
- 239000002699 waste material Substances 0.000 title claims abstract description 32
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 28
- 239000001257 hydrogen Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 26
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title claims abstract description 9
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 title claims description 29
- 229910052793 cadmium Inorganic materials 0.000 title 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000001556 precipitation Methods 0.000 claims abstract description 13
- -1 rare earth sulfate Chemical class 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000011541 reaction mixture Substances 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims description 16
- HIRWGWMTAVZIPF-UHFFFAOYSA-N nickel;sulfuric acid Chemical compound [Ni].OS(O)(=O)=O HIRWGWMTAVZIPF-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract description 31
- 239000010405 anode material Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000010926 waste battery Substances 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 29
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 29
- 239000000243 solution Substances 0.000 description 28
- 229910052759 nickel Inorganic materials 0.000 description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 238000002425 crystallisation Methods 0.000 description 6
- 230000008025 crystallization Effects 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 239000012452 mother liquor Substances 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000007773 negative electrode material Substances 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 150000003009 phosphonic acids Chemical class 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910018095 Ni-MH Inorganic materials 0.000 description 2
- 229910018477 Ni—MH Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000010413 mother solution Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000863 Ferronickel Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910018661 Ni(OH) Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- 239000000346 nonvolatile oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Secondary Cells (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
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CNB2005101002109A CN100389520C (zh) | 2005-10-08 | 2005-10-08 | 一种从废镍氢、镍镉电池回收硫酸镍溶液中去除钠离子的方法 |
Applications Claiming Priority (1)
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CNB2005101002109A CN100389520C (zh) | 2005-10-08 | 2005-10-08 | 一种从废镍氢、镍镉电池回收硫酸镍溶液中去除钠离子的方法 |
Publications (2)
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CN1778687A CN1778687A (zh) | 2006-05-31 |
CN100389520C true CN100389520C (zh) | 2008-05-21 |
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CNB2005101002109A Active CN100389520C (zh) | 2005-10-08 | 2005-10-08 | 一种从废镍氢、镍镉电池回收硫酸镍溶液中去除钠离子的方法 |
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CN (1) | CN100389520C (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102249767A (zh) * | 2010-05-18 | 2011-11-23 | 北京有色金属研究总院 | 一种含稀土复盐的复混肥及其制备方法 |
CN101924207B (zh) * | 2010-08-11 | 2012-10-17 | 河南新太行电源有限公司 | 一种碱性袋式电池负极材料的制备方法 |
CN108950245A (zh) * | 2018-07-05 | 2018-12-07 | 东北大学 | 一种从含镍、钴二次资源的浸出液中去除钠离子的方法 |
CN108950244A (zh) * | 2018-07-05 | 2018-12-07 | 东北大学 | 一种从含镍、钴二次资源的浸出液中去除钠离子的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5629600A (en) * | 1993-07-26 | 1997-05-13 | Brother Kogyo Kabushiki Kaisha | Charger for use with a nickel-cadmium battery that uses charge and discharge cycles dependent on voltage and current |
US5858061A (en) * | 1994-12-20 | 1999-01-12 | Varta Batterie Atkiengesellschaft | Process for the recovery of metals from used nickel/metal hydride storage batteries |
CN1357938A (zh) * | 2000-12-08 | 2002-07-10 | 同济大学 | 镍镉废电池的综合回收利用方法 |
CN1617380A (zh) * | 2003-11-11 | 2005-05-18 | 财团法人工业技术研究院 | 从废二次电池回收有价金属的方法 |
-
2005
- 2005-10-08 CN CNB2005101002109A patent/CN100389520C/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5629600A (en) * | 1993-07-26 | 1997-05-13 | Brother Kogyo Kabushiki Kaisha | Charger for use with a nickel-cadmium battery that uses charge and discharge cycles dependent on voltage and current |
US5858061A (en) * | 1994-12-20 | 1999-01-12 | Varta Batterie Atkiengesellschaft | Process for the recovery of metals from used nickel/metal hydride storage batteries |
CN1357938A (zh) * | 2000-12-08 | 2002-07-10 | 同济大学 | 镍镉废电池的综合回收利用方法 |
CN1617380A (zh) * | 2003-11-11 | 2005-05-18 | 财团法人工业技术研究院 | 从废二次电池回收有价金属的方法 |
Non-Patent Citations (4)
Title |
---|
Rare earths recovery from NiMH spent batteries. L.Pietrelli et al.Hydrometallurgy,Vol.66 . 2002 |
Rare earths recovery from NiMH spent batteries. L.Pietrelli et al.Hydrometallurgy,Vol.66 . 2002 * |
废旧MH/Ni电池负极材料的回收利用. 林才顺.湿法冶金,第24卷第2期. 2005 |
废旧MH/Ni电池负极材料的回收利用. 林才顺.湿法冶金,第24卷第2期. 2005 * |
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Publication number | Publication date |
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CN1778687A (zh) | 2006-05-31 |
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GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Jiangmen Fangyuan Environment Technology Development Co.,Ltd. Assignor: Luo Aiping Contract fulfillment period: 2008.10.18 to 2018.10.18 Contract record no.: 2008440000428 Denomination of invention: Method for removing sodium ion from recovered nickle sulfate solution of waste nickle-hydrogen and nickle-cadmium Granted publication date: 20080521 License type: Exclusive license Record date: 20081202 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.10.18 TO 2018.10.18; CHANGE OF CONTRACT Name of requester: JIANGMEN CITY FANGYUAN ENVIRONMENT TECHNOLOGY DEVE Effective date: 20081202 |
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Owner name: JIANGMEN FANGYUAN ENVIRONMENT TECHNOLOGY DEVELOPME Free format text: FORMER OWNER: LUO AIPING Effective date: 20141121 |
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Effective date of registration: 20141121 Address after: Five Xinhui District, Guangdong City, Jiangmen Province, and Farm Industrial Zone, 529162 Patentee after: JIANGMEN FANGYUAN ENVIRONMENT TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 529000 No. 101, Dongcheng village, Pengjiang District, Guangdong, Jiangmen 28 Patentee before: Luo Aiping |
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Address after: Five Xinhui District, Guangdong City, Jiangmen Province, and Farm Industrial Zone, 529162 Patentee after: FANGYUAN ENVIRONMENTAL PROTECTION LTD. Address before: Five Xinhui District, Guangdong City, Jiangmen Province, and Farm Industrial Zone, 529162 Patentee before: Jiangmen Fangyuan Environment Technology Development Co.,Ltd. |
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Address after: 529,145 No. 11, Zone A, Lingang Industrial Park, Gujing Town, Xinhui District, Jiangmen City, Guangdong Province (multiple photos of one site) Patentee after: Guangdong Fangyuan New Material Group Co.,Ltd. Address before: 529162 Wuhe Agricultural Industrial Zone, Xinhui District, Jiangmen City, Guangdong Province Patentee before: FANGYUAN ENVIRONMENTAL PROTECTION LTD. |
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