CN100365169C - 从烃化合物工业电解生产氢 - Google Patents
从烃化合物工业电解生产氢 Download PDFInfo
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- CN100365169C CN100365169C CNB018198643A CN01819864A CN100365169C CN 100365169 C CN100365169 C CN 100365169C CN B018198643 A CNB018198643 A CN B018198643A CN 01819864 A CN01819864 A CN 01819864A CN 100365169 C CN100365169 C CN 100365169C
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/40—Cells or assemblies of cells comprising electrodes made of particles; Assemblies of constructional parts thereof
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
国家 | 年产量/百万吨 | 用于电/% |
中国 | 1029 | 80 |
美国 | 914 | 56 |
印度 | 290 | 68 |
南非 | 224 | 90 |
波兰 | 112 | 96 |
近似分析 | |
组成/wt% | 组成/wt% |
水分2.90 | 碳,C 80.31 |
挥发性物质22.05 | 氢,H<sub>2</sub>4.47 |
不挥发碳68.50 | 硫,S1.54 |
灰份6.55 | 氧,O<sub>2</sub>2.85 |
氮,N<sub>2</sub>1.38 | |
水份,H<sub>2</sub>O 2.90 | |
灰份6.55 | |
总计100.00 | 总计100.00 |
热值,Btu/Lb 14100 |
煤电解 | 2H<sub>2</sub>-2H<sub>2</sub>O的总瓦时 | 煤电解的燃料电池功率瓦时 | 煤电解输入功率瓦时 | 电力装置生产的输入功率瓦时 | 净功率/瓦时 | C-CO<sub>2</sub>的总功率 | 煤-锅炉-气轮机***的净瓦时 | ||||||
电压伏 | 瓦时 | 燃料电池装置 | 气轮机装置 | ||||||||||
燃料电池 | 气轮机 | 净功率 | 电效率% | 净功率 | 电效率% | 褐煤 | 黑煤 | ||||||
0.2100 | 23.70 | 158.86 | 31.60 | 133.04 | 127.26 | 127.26 | 95.45 | 87.29 | 72.16 | 65.99 | 109.34 | 30.62 | 38.27 |
0.2625 | 29.62 | 158.86 | 39.50 | 138.96 | 119.36 | 119.36 | 89.52 | 81.87 | 67.68 | 61.90 | 109.34 | 30.62 | 38.27 |
0.3150 | 35.55 | 158.86 | 47.40 | 144.89 | 111.46 | 111.46 | 83.60 | 76.46 | 63.20 | 57.80 | 109.34 | 30.62 | 38.27 |
0.3675 | 41.47 | 158.86 | 55.29 | 150.81 | 103.56 | 103.56 | 77.67 | 71.04 | 58.72 | 53.70 | 109.34 | 30.62 | 38.27 |
0.4200 | 47.40 | 158.86 | 63.19 | 156.74 | 95.66 | 95.66 | 71.75 | 65.62 | 54.24 | 49.61 | 109.34 | 30.62 | 38.27 |
0.4725 | 53.32 | 158.86 | 71.09 | 162.66 | 87.76 | 87.76 | 65.82 | 60.20 | 49.76 | 45.51 | 109.34 | 30.62 | 38.27 |
0.5250 | 59.24 | 158.86 | 78.99 | 168.58 | 79.87 | 79.87 | 59.90 | 54.78 | 45.28 | 41.42 | 109.34 | 30.62 | 38.27 |
0.5775 | 65.17 | 158.86 | 86.89 | 174.51 | 71.97 | 71.97 | 53.97 | 49.36 | 40.80 | 37.32 | 109.34 | 30.62 | 38.27 |
0.6300 | 71.09 | 158.86 | 94.79 | 180.43 | 64.07 | 64.07 | 48.05 | 43.95 | 36.33 | 33.22 | 109.34 | 30.62 | 38.27 |
0.6825 | 77.02 | 158.86 | 102.69 | 186.36 | 56.17 | 56.17 | 42.13 | 38.53 | 31.85 | 29.13 | 109.34 | 30.62 | 38.27 |
0.7350 | 82.94 | 158.86 | 110.59 | 192.28 | 48.27 | 48.27 | 36.20 | 33.11 | 27.37 | 25.03 | 109.34 | 30.62 | 38.27 |
0.7875 | 88.87 | 158.86 | 118.49 | 198.21 | 40.37 | 40.37 | 30.28 | 27.69 | 22.89 | 20.93 | 109.34 | 30.62 | 38.27 |
0.8400 | 94.79 | 158.86 | 126.39 | 204.13 | 32.47 | 32.47 | 24.35 | 22.27 | 18.41 | 16.84 | 109.34 | 30.62 | 38.27 |
列A | B | C | D | E | F | G | H | I | J | K | L | M | N |
装置规模 | 每个电解池的电流 | 电解池数 | 总电流 |
5KW | 7296 | 1 | 7296 |
100KW | 149625 | 1 | 149625 |
1MW | 1466325 | 1 | 1466325 |
10MW | 7241850 | 2 | 14483700 |
100MW | 24139500 | 6 | 144837000 |
煤电解池大小 | 煤电解池电极面积m2 | 煤电解电流密度A/m2 | 煤电解每池产生的有效电流A | 煤电解每池产生的电力KW | 煤电解每天需要的电力KWH | 煤电解每天每池产生的氢g mol | 燃料电池每天产生的电KWH | 每池输出的总功率KW | 每池输出的净功率KW | 总电效率% | 所需池数100MW | 所需池数10MW | 所需池数10MW | 所需池数100KW | 所需池数5KW | |||
电极宽m | 电极高m | 每个电解池中电极数 | 电解池额定长度m | |||||||||||||||
0.25 | 0.64 | 4.0 | 0.6 | 3 | 3000 | 7296 | 3 | 74 | 6533 | 195 | 8 | 5.04 | 62.21 | 1.0 | ||||
0.75 | 1.25 | 14 | 1.8 | 53 | 3000 | 149625 | 63 | 1508 | 133986 | 3991 | 166 | 103 | 62.21 | 1.0 | ||||
0.70 | 1.00 | 10.0 | 1.32 | 28 | 3000 | 79800 | 34 | 804 | 71459 | 2128 | 89 | 55 | 62.21 | 1813 | 181.26 | 18.1 | 16.1 | 0.6 |
1.50 | 1.75 | 49.0 | 6 | 515 | 3000 | 1466325 | 616 | 14781 | 1313059 | 39111 | 1630 | 1014 | 62.21 | 99 | 9.86 | 1.0 | 16.1 | 10.1 |
1.50 | 2.75 | 154.0 | 18.6 | 2541 | 3000 | 7241850 | 3042 | 72998 | 6484903 | 193159 | 8048 | 5007 | 62.21 | 2.00 | ||||
2.00 | 3.00 | 264.0 | 31.8 | 6336 | 3000 | 18057600 | 7584 | 182021 | 16170147 | 481642 | 20068 | 12484 | 62.21 | 8.01 | 0.80 | 0.1 | 16.1 | 124.8 |
2.50 | 3.50 | 242.0 | 29.16 | 8470 | 3000 | 24139500 | 10139 | 243326 | 21616342 | 643862 | 26828 | 16689 | 62.21 | 6 | ||||
3.00 | 4.00 | 242.0 | 29.16 | 11616 | 3000 | 33105600 | 13904 | 333704 | 29645270 | 883010 | 36792 | 22888 | 62.21 | 4 | 0.44 | |||
3.50 | 5.00 | 242.0 | 29.16 | 16940 | 3000 | 48279000 | 20277 | 486652 | 43232685 | 1287723 | 53655 | 33378 | 62.21 | 3 | 0.30 |
Claims (50)
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
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AUPR1777 | 2000-11-30 | ||
AUPR1777A AUPR177700A0 (en) | 2000-11-30 | 2000-11-30 | Electrolytic production of hydrogen from gas,liquid,or solid hydrocarbon compounds |
AUPR1847A AUPR184700A0 (en) | 2000-12-04 | 2000-12-04 | Additions to electrolytic production of hydrogen from gas, liquid, or solid hydrocarbon compounds |
AUPR1847 | 2000-12-04 | ||
AUPR2138 | 2000-12-18 | ||
AUPR2138A AUPR213800A0 (en) | 2000-12-18 | 2000-12-18 | More additions to electrolytic production of hydrogen from gas, liquid, or solid hydrocarbon compounds |
AUPR4350A AUPR435001A0 (en) | 2001-04-11 | 2001-04-11 | Further additions to the process of producing hydrogen from solid, liquid and gas hydrocarbons |
AUPR4350 | 2001-04-11 |
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CN1478056A CN1478056A (zh) | 2004-02-25 |
CN100365169C true CN100365169C (zh) | 2008-01-30 |
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US (1) | US7182851B2 (zh) |
CN (1) | CN100365169C (zh) |
AU (1) | AU2300602A (zh) |
DE (1) | DE10196986T5 (zh) |
GB (1) | GB2388120B (zh) |
WO (1) | WO2002044081A1 (zh) |
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- 2001-11-28 CN CNB018198643A patent/CN100365169C/zh not_active Expired - Fee Related
- 2001-11-28 GB GB0311591A patent/GB2388120B/en not_active Expired - Fee Related
- 2001-11-28 DE DE10196986T patent/DE10196986T5/de not_active Withdrawn
- 2001-11-28 WO PCT/AU2001/001551 patent/WO2002044081A1/en not_active Application Discontinuation
- 2001-11-28 AU AU2300602A patent/AU2300602A/xx active Pending
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GB2388120B (en) | 2004-10-20 |
GB0311591D0 (en) | 2003-06-25 |
GB2388120A (en) | 2003-11-05 |
AU2300602A (en) | 2002-06-11 |
US7182851B2 (en) | 2007-02-27 |
WO2002044081A1 (en) | 2002-06-06 |
CN1478056A (zh) | 2004-02-25 |
US20050098443A1 (en) | 2005-05-12 |
DE10196986T5 (de) | 2004-05-06 |
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