CN100348759C - Ti3C2/Cu-Al ceramet material and its preparation method - Google Patents
Ti3C2/Cu-Al ceramet material and its preparation method Download PDFInfo
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- CN100348759C CN100348759C CNB2005100121505A CN200510012150A CN100348759C CN 100348759 C CN100348759 C CN 100348759C CN B2005100121505 A CNB2005100121505 A CN B2005100121505A CN 200510012150 A CN200510012150 A CN 200510012150A CN 100348759 C CN100348759 C CN 100348759C
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Abstract
The present invention relates to Ti3C2/Cu-Al metal ceramic material and a preparing method thereof. The material comprises 3.825 to 63 wt% of Ti3C2, 27.82 to 95.54 wt% of Cu and 0.63 to 10.12 wt% of Al, the bending strength is from 750 to 985MPa, and the maximal deformation rate is from 1.7 to 8.5%. The material can be widely used for manufacturing key devices of machinery, electrical engineering, chemical engineering and delivery vehicles. The preparing method of the material comprises: 5 to 81 wt% of Ti3AlC2 powder and 19 to 95% of pure copper powder are proportioned, mixed through ball milling, dried, molded through cold pressing under 140 to 180MPa and sintered under normal pressure at 1100 to 1180 DEG C under the protection of argon gas, the heat is preserved for 20 to 30 min, and then, the Ti3C2/Cu-Al metal ceramic material of the present invention is obtained.
Description
Technical field
The present invention relates to a kind of Ti
3C
2/ Cu-Al cermet material and preparation method thereof.
Background technology
The cermet material of forming by one or more ceramic phases and metallographic phase or alloy, the satisfactory electrical conductivity of existing metal and thermal conductivity, high intensity and toughness, have the characteristic such as high temperature resistant, corrosion-resistant, wear-resistant of pottery again, have been widely used in fields such as electrician, chemical industry, traffic, machineries.For example, as the aluminum oxide/tungsten/chromium material of guided missile nozzle insert, as titanium carbide/cobalt (nickel, chromium) material of turbine blade or cutting tool, as the stannic oxide/ag material of electrical contact.
Titanium aluminium carbon (Ti
3AlC
2) be a kind of novel double carbide pottery, find first and at " J.Phase Equilib " 1994 the 15th phases 392 pages of open reports by M.A.Pietzka and J.C.Schuster.Titanium aluminium carbon belongs to hexagonal system, and crystal grain is that laminate structure, profile are tabular, and theoretical density is 4.25g/cm
3The Vickers' hardness of its polycrystalline bulk material is that 3.5GPa, Young's modulus are that 297GPa, room temperature resistance are that 0.35 μ Ω m, 25～1200 ℃ of interior thermal expansivity of scope are 9.0 * 10
-6K
-1, the room temperature compressive strength is that 540～580MPa, room temperature flexural strength are 360～390MPa, intensity does not reduce after 1100 ℃ of quenchings, but machining (reference: N.V.Tzenov and M.W.Barsoum, J.Am.Ceram.Soc., 2000,83[4]: 825).In addition, its polycrystalline bulk material has good tribological property; Under 0.8MPa pressure and 60m/s sliding velocity, the dry friction coefficient of soft steel is about 0.1, wear rate is about 2.5 * 10
-6Mm
3/ Nm (reference: H-X Zhai, et al, Mater.Sci.Forum, 2005[475-479]: 1251).But, also do not utilize this new ceramics to prepare the report of high-performance metal stupalith so far.
Summary of the invention
The object of the present invention is to provide a kind of is the Ti that raw material is made with titanium aluminium carbon and fine copper
3C
2/ Cu-Al cermet material and preparation method thereof.
Technical scheme of the present invention:
Ti of the present invention
3C
2/ Cu-Al cermet material, its composition is as follows:
Ti
3C
2＝3.83～62.06wt％，
Cu＝27.82～95.54wt％，
Al＝0.63～10.12wt％。
Ti of the present invention
3C
2/ Cu-Al cermet material, its microstructure is as follows:
The titanium aluminium carbon granule of raw material keeps initial appearance profile, forms Ti in the appearance profile scope of each titanium aluminium carbon granule
3C
2The laminate structure that layer is successively alternate with the Cu-Al alloy layer; The thickness of each layer is 0.2～0.3 μ m.
Ti of the present invention
3C
2/ Cu-Al cermet material, its mechanical property is as follows:
Bending strength: 750～985MPa,
Maximum distortion rate: 1.7～8.5%.
Ti of the present invention
3C
2The preparation method of/Cu-Al cermet material comprises following each step:
Step 1, batching: with titanium aluminium carbon (Ti
3AlC
2) powder and fine copper (Cu) powder prepare burden in following ratio:
Ti
3AlC
2＝5～81wt％，
Cu＝19～95wt％；
Step 2, batch mixing: add 70～120 milliliters dehydrated alcohol, the agate ball of 200～380 grams in the above-mentioned batching of per 100 grams, ball milling 2～4 hours, 60～70 ℃ of oven dry in baking oven with the mixing raw material grinding of oven dry, are crossed 70～100 mesh sieves;
Step 3, coldmoulding: the base substrate that the raw material behind the above-mentioned batch mixing is pressed into Any shape under 140～180MPa pressure;
Step 4, sintering: the base substrate of above-mentioned coldmoulding is put into High Temperature Furnaces Heating Apparatus, and under argon shield, the temperature rise rate by 10～40 ℃/min rises to 1100～1180 ℃ with furnace temperature, insulation 20～30min, the speed cooling with 10～15 ℃/min promptly obtains Ti of the present invention
3C
2/ Cu-Al cermet material.
The beneficial effect that the present invention had:
Ti of the present invention
3C
2/ Cu-Al cermet material, its bending strength are much higher than monophasic titanium alumina-carbon material, also are higher than common Cu alloy material.Its bending strength is different according to the proportioning raw materials of titanium aluminium carbon and copper with the maximum distortion rate; The big more made Ti of the ratio of titanium aluminium carbon
3C
2The bending strength of/Cu-Al cermet material is big more and the maximum distortion rate is more little.For Ti of the present invention
3C
2The application of/Cu-Al cermet material can be chosen the suitable titanium aluminium carbon and the proportioning raw materials of copper according to the service requirements of reality.
Ti of the present invention
3C
2The preparation method of/Cu-Al cermet material, its main benefit be the prescription and preparation technology simple; By implementation step of the present invention, the Al in sintering process in the titanium aluminium carbon is dissolved, and Cu enters into the laminate structure of titanium aluminium carbon, forms the Ti of 0.2～0.3 μ m thickness
3C
2The stratiform microstructure that layer is successively alternate with the Cu-Al layer, and this special submicron laminate structure is made Ti
3C
2/ Cu-Al cermet material has the fundamental cause of higher-strength.
Ti of the present invention
3C
2/ Cu-Al cermet material can be widely used in fields such as machinery, electrician, traffic, chemical industry, for example is used to make contact, slide block of various high performance bearings, piston ring, various high power switch or contactor etc.
Ti of the present invention
3C
2/ Cu-Al cermet material sintering under normal pressure just can obtain, and is well suited for the suitability for industrialized production of the device of large-sized or complicated shape.
Description of drawings
Fig. 1 is Ti of the present invention
3C
2The microstructural scanning electronic microscope of/Cu-Al cermet material (SEM) photo.
Fig. 2 is Ti of the present invention
3C
2The scanning electronic microscope of the fracture of/Cu-Al cermet material (SEM) photo.
Embodiment
Embodiment one
Take by weighing purity and be 98.4% Ti
3AlC
2Powder 0.765 gram, purity are 99.9% Cu powder 14.42 grams; mix the back and add 11 milliliters of dehydrated alcohols and 32 gram agate balls; ball mill mixing 2 hours is dried then, grinds, is crossed 100 mesh sieves, is cold-pressed into the bar shaped base substrate under 140MPa pressure; put into the graphite jig of High Temperature Furnaces Heating Apparatus; argon shield is warming up to 1100 ℃ with the speed of 40 ℃/min, insulation 20min; speed with 10～15 ℃/min is reduced to 60 ℃ with furnace temperature, promptly obtains Ti of the present invention
3C
2/ Cu-Al cermet material; Ti wherein
3C
2Content be about 0.57 the gram, all the other are Cu and Al.
With above-mentioned Ti
3C
2/ Cu-Al cermet material is processed into the sample of 3mm * 4mm * 36mm, carries out the three-point bending strength test, and span is 30mm; The breaking tenacity that records is 752.30MPa, and the maximum distortion rate is 8.5%.
Embodiment two
Take by weighing purity and be 98.4% Ti
3AlC
2Powder 2.3 grams, purity are 99.9% Cu powder 11.2 grams; mix the back and add 11 milliliters of dehydrated alcohols and 32 gram agate balls; ball mill mixing 2.5 hours is dried then, grinds, is crossed 100 mesh sieves, is cold-pressed into the bar shaped base substrate under 150MPa pressure; put into the graphite jig of High Temperature Furnaces Heating Apparatus; argon shield is warming up to 1130 ℃ with the speed of 30 ℃/min, insulation 25min; speed with 10～15 ℃/min is reduced to 60 ℃ with furnace temperature, promptly obtains Ti of the present invention
3C
2/ Cu-Al cermet material; Ti wherein
3C
2Content be about 0.98 the gram, all the other are Cu and Al.
With above-mentioned Ti
3C
2/ Cu-Al cermet material is processed into the sample of 3mm * 4mm * 36mm, carries out the three-point bending strength test, and span is 30mm; The breaking tenacity that records is 832.70MPa, and the maximum distortion rate is 7.36%.
Embodiment three
Take by weighing purity and be 98.4% Ti
3AlC
2Powder 3.83 grams, purity are 99.9% Cu powder 8.01 grams; mix the back and add 11 milliliters of dehydrated alcohols and 32 gram agate balls; ball mill mixing 3 hours is dried then, grinds, is crossed 100 mesh sieves, is cold-pressed into the bar shaped base substrate under 160MPa pressure; put into the graphite jig of High Temperature Furnaces Heating Apparatus; argon shield is warming up to 1150 ℃ with the speed of 30 ℃/min, insulation 30min; speed with 10～15 ℃/min is reduced to 60 ℃ with furnace temperature, promptly obtains Ti of the present invention
3C
2/ Cu-Al cermet material; Ti wherein
3C
2Content be about 2.93 the gram, all the other are Cu and Al.
With above-mentioned Ti
3C
2/ Cu-Al cermet material is processed into the sample of 3mm * 4mm * 36mm, carries out the three-point bending strength test, and span is 30mm; The breaking tenacity that records is 807.75MPa, and the maximum distortion rate is 3.38%.
Embodiment four
Take by weighing purity and be 98.4% Ti
3AlC
2Powder 5.355 grams, purity are 99.9% Cu powder 4.806 grams; mix the back and add 10 milliliters of dehydrated alcohols and 32 gram agate balls; ball mill mixing 3 hours is dried then, grinds, is crossed 100 mesh sieves, is cold-pressed into the bar shaped base substrate under 170MPa pressure; put into the graphite jig of High Temperature Furnaces Heating Apparatus; argon shield is warming up to 1160 ℃ with the speed of 30 ℃/min, insulation 30min; speed with 10～15 ℃/min is reduced to 60 ℃ with furnace temperature, promptly obtains Ti of the present invention
3C
2/ Cu-Al cermet material; Ti wherein
3C
2Content be about 4.10 the gram, all the other are Cu and Al.
With above-mentioned Ti
3C
2/ Cu-Al cermet material is processed into the sample of 3mm * 4mm * 36mm, carries out the three-point bending strength test, and span is 30mm; The breaking tenacity that records is 983.89MPa, and the maximum distortion rate is 2.64%.
Embodiment five
Take by weighing purity and be 98.4% Ti
3AlC
2Powder 6.885 grams, purity are 99.9% Cu powder 1.602 grams; mix the back and add 10 milliliters of dehydrated alcohols and 32 gram agate balls; ball mill mixing 4 hours is dried then, grinds, is crossed 100 mesh sieves, is cold-pressed into the bar shaped base substrate under 180MPa pressure; put into the graphite jig of High Temperature Furnaces Heating Apparatus; argon shield is warming up to 1180 ℃ with the speed of 30 ℃/min, insulation 30min; speed with 10～15 ℃/min is reduced to 60 ℃ with furnace temperature, promptly obtains Ti of the present invention
3C
2/ Cu-Al cermet material; Ti wherein
3C
2Content be about 5.267 the gram, all the other are Cu and Al.
With above-mentioned Ti
3C
2/ Cu-Al cermet material is processed into the sample of 3mm * 4mm * 36mm, carries out the three-point bending strength test, and span is 30mm; The breaking tenacity that records is 983.66MPa, and the maximum distortion rate is 1.73%.
The Ti that above-mentioned embodiment uses
3AlC
2Powder is a number of patent application: 200510011650.7, and denomination of invention: " a kind of titanium aluminium carbide powder and be the synthetic method of reaction promoter with tin " prepared titanium aluminium carbide powder.
Claims (3)
1. Ti
3C
2/ Cu-Al cermet material is characterized in that: its composition is as follows:
Ti
3C
2＝3.83～62.06wt％，
Cu＝27.82～95.54wt％，
Al＝0.63～10.12wt％。
2. the described Ti of claim 1
3C
2/ Cu-Al cermet material is characterized in that, its microstructure is as follows:
The titanium aluminium carbon granule of raw material keeps initial appearance profile, forms Ti in the appearance profile scope of each titanium aluminium carbon granule
3C
2The laminate structure that layer is successively alternate with the Cu-Al alloy layer; The thickness of each layer is 0.2～0.3 μ m.
3. Ti
3C
2The preparation method of/Cu-Al cermet material is characterized in that, this method may further comprise the steps:
Step 1, batching: with Ti
3AlC
2Powder and pure copper powder are prepared burden in following ratio:
Ti
3AlC
2＝5～81wt％，
Cu＝19～95wt％；
Step 2, batch mixing: add 70～120 milliliters dehydrated alcohol, the agate ball of 200～400 grams in the above-mentioned batching of per 100 grams, ball milling 2～4 hours, 60～70 ℃ of oven dry in baking oven with the mixing raw material grinding of oven dry, are crossed 70～100 mesh sieves;
Step 3, coldmoulding: the base substrate that the raw material behind the above-mentioned batch mixing is pressed into Any shape under 140～180MPa pressure;
Step 4, sintering: the base substrate of above-mentioned coldmoulding is put into High Temperature Furnaces Heating Apparatus, and under argon shield, the temperature rise rate by 10～40 ℃/min rises to 1100～1180 ℃ with furnace temperature, insulation 20～30min, the speed cooling with 10～15 ℃/min promptly obtains Ti of the present invention
3C
2/ Cu-Al cermet material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100121505A CN100348759C (en) | 2005-07-12 | 2005-07-12 | Ti3C2/Cu-Al ceramet material and its preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100121505A CN100348759C (en) | 2005-07-12 | 2005-07-12 | Ti3C2/Cu-Al ceramet material and its preparation method |
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|---|---|
| CN1733955A CN1733955A (en) | 2006-02-15 |
| CN100348759C true CN100348759C (en) | 2007-11-14 |
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|---|---|---|---|
| CNB2005100121505A Expired - Fee Related CN100348759C (en) | 2005-07-12 | 2005-07-12 | Ti3C2/Cu-Al ceramet material and its preparation method |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101028749B (en) * | 2007-04-18 | 2010-12-01 | 北京交通大学 | (Cu Al)/(Ti3 C2 Cu-Al) laminated composite material and its production |
| CN102242302A (en) * | 2011-06-28 | 2011-11-16 | 钢铁研究总院 | Preparation method of layered ternary ceramic reinforced copper composite material |
| CN102260803B (en) * | 2011-07-15 | 2014-07-09 | 北京交通大学 | Nano TiC0.5 particle in situ reinforced Cu(Al) composite material and preparation method thereof |
| CN103938048B (en) * | 2014-05-07 | 2016-06-01 | 攀枝花学院 | Carbon aluminium titanium base electric contact material and its production and use |
| CN107774985B (en) * | 2017-10-19 | 2019-09-27 | 西安科技大学 | A kind of metal composite wear-resistant material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1198780A (en) * | 1995-10-02 | 1998-11-11 | 陶氏化学公司 | Singal step synthesis and densification of ceramic-ceramic and ceramic-metal composite materials |
| RU2165473C2 (en) * | 1999-03-11 | 2001-04-20 | Институт физики прочности и материаловедения СО РАН | Hard alloy and method of its production |
| US6332903B1 (en) * | 2000-08-04 | 2001-12-25 | Tony U. Otani | Materials processing cylinder containing titanium carbide |
-
2005
- 2005-07-12 CN CNB2005100121505A patent/CN100348759C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1198780A (en) * | 1995-10-02 | 1998-11-11 | 陶氏化学公司 | Singal step synthesis and densification of ceramic-ceramic and ceramic-metal composite materials |
| RU2165473C2 (en) * | 1999-03-11 | 2001-04-20 | Институт физики прочности и материаловедения СО РАН | Hard alloy and method of its production |
| US6332903B1 (en) * | 2000-08-04 | 2001-12-25 | Tony U. Otani | Materials processing cylinder containing titanium carbide |
Non-Patent Citations (1)
| Title |
|---|
| Ti3AlC2的制备与微观结构 梅炳初等.硅酸盐学报，第32卷第7期 2004 * |
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