CA987332A - Organolithiumpolymerization initiators and use thereof in polymerization processes - Google Patents

Organolithiumpolymerization initiators and use thereof in polymerization processes

Info

Publication number
CA987332A
CA987332A CA102,960A CA102960A CA987332A CA 987332 A CA987332 A CA 987332A CA 102960 A CA102960 A CA 102960A CA 987332 A CA987332 A CA 987332A
Authority
CA
Canada
Prior art keywords
organolithiumpolymerization
initiators
polymerization processes
polymerization
processes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA102,960A
Other languages
English (en)
Other versions
CA102960S (en
Inventor
Robert C. Morrison
Conrad W. Kamienski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lithium Corp of America Inc
Original Assignee
Lithium Corp of America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lithium Corp of America Inc filed Critical Lithium Corp of America Inc
Application granted granted Critical
Publication of CA987332A publication Critical patent/CA987332A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/02—Lithium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/36—Polymerisation in solid state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
CA102,960A 1970-01-19 1971-01-18 Organolithiumpolymerization initiators and use thereof in polymerization processes Expired CA987332A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US412670A 1970-01-19 1970-01-19

Publications (1)

Publication Number Publication Date
CA987332A true CA987332A (en) 1976-04-13

Family

ID=21709291

Family Applications (1)

Application Number Title Priority Date Filing Date
CA102,960A Expired CA987332A (en) 1970-01-19 1971-01-18 Organolithiumpolymerization initiators and use thereof in polymerization processes

Country Status (9)

Country Link
US (1) US3668263A (de)
AU (1) AU2398771A (de)
BE (1) BE761691A (de)
CA (1) CA987332A (de)
DE (1) DE2063642A1 (de)
FR (1) FR2075655A5 (de)
GB (1) GB1297331A (de)
NL (1) NL7100697A (de)
ZA (1) ZA708708B (de)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3862251A (en) * 1970-02-11 1975-01-21 Us Navy Organo-dilithium initiator for anionic polymerization, a novel polyisoprene, and processes for production thereof
US3954894A (en) * 1973-05-18 1976-05-04 Lithium Corporation Of America Organotrilithium polymerization initiators
US3931107A (en) * 1973-06-21 1976-01-06 Phillips Petroleum Company Polyalkoxy monovinylaromatic compound in copolymerization of a conjugated diene with a monovinyl-substituted aromatic compound
FR2313389A1 (fr) * 1975-06-06 1976-12-31 Anvar Nouveaux amorceurs de polymerisation organolithiens bi-fonctionnels et leurs applications, en particulier pour l'obtention d'elastomeres thermoplastiques
CA1098913A (en) * 1975-08-01 1981-04-07 Lu H. Tung Multifunctional lithium containing initiator
US4205016A (en) * 1975-08-01 1980-05-27 The Dow Chemical Company Multifunctional lithium containing initiator
GB1555729A (en) * 1976-06-17 1979-11-14 Charbonnages Ste Chimique Bifunctional and trifunctional organo-lithium initiators and their use
US4311818A (en) * 1976-06-17 1982-01-19 Societe Chimique Des Charbonnages-Cdf. Chimie Bi- and Trifunctional organolithium initiators and applications thereof
US4179480A (en) * 1976-11-05 1979-12-18 Phillips Petroleum Company Blends of cyclodiene-containing copolymers and block copolymers having improved high temperature green tensile strength
US4138536A (en) * 1976-12-20 1979-02-06 Phillips Petroleum Company Polymerization of 1,3-cyclodiene with vinylaromatic hydrocarbon
US4311803A (en) * 1979-05-01 1982-01-19 Phillips Petroleum Company Continuous solution polymerization process
US4297451A (en) * 1979-07-10 1981-10-27 Phillips Petroleum Company Dienyllithium initiated polymers
DE2938658A1 (de) * 1979-09-25 1981-04-09 Basf Ag, 6700 Ludwigshafen Loesungen bifunktioneller organolithiumverbindungen in nichtpolaren organischen kohlenwasserstoffen als loesungsmittel, verfahren zur herstellung solcher loesungen und deren verwendung
IT1195303B (it) * 1981-12-22 1988-10-12 Anic Spa Iniziatori anionici multifunzionali e loro impiego
JPS58154703A (ja) * 1982-03-09 1983-09-14 Daicel Chem Ind Ltd 光学活性な高分子の合成方法
DE3309748A1 (de) * 1982-07-23 1984-03-01 Veb Chemische Werke Buna, Ddr 4212 Schkopau Verfahren zur herstellung mehrfunktioneller polymerisationsinitiatoren
US4713424A (en) * 1984-11-05 1987-12-15 Phillips Petroleum Company Polymerization of olefinic hydrocarbons and complex-initiator therefor
US5210359A (en) * 1990-01-16 1993-05-11 Mobil Oil Corporation Vulcanizable liquid compositions
US5637783A (en) * 1990-01-16 1997-06-10 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5633415A (en) * 1990-01-16 1997-05-27 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5149895A (en) * 1990-01-16 1992-09-22 Mobil Oil Corporation Vulcanizable liquid compositions
US5780540A (en) * 1990-01-16 1998-07-14 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5147951A (en) * 1990-09-21 1992-09-15 Bridgestone/Firestone, Inc. Method for preparing ultra high molecular weight copolymers of conjugated dienes and aromatic vinyl compounds
US5272203A (en) * 1990-09-21 1993-12-21 Bridgestone/Firestone, Inc. High performance tire treads and tires
US5260370A (en) * 1990-09-21 1993-11-09 Bridgestone Corporation Oil extended ultra high molecular weight elastomers
US5080835A (en) * 1990-09-21 1992-01-14 Bridgestone/Firestone, Inc. Polymetalated 1-alkyne compositions
TW322493B (de) * 1994-06-27 1997-12-11 Shell Int Research
EP0690075B1 (de) 1994-06-27 1999-05-06 Shell Internationale Researchmaatschappij B.V. Verfahren zur Herstellung von Blockcopolymeren unter Verwendung von difunktionellen anionischen Polymerisationsinitiatoren
US5464914A (en) * 1994-06-29 1995-11-07 The Dow Chemical Company Preparation of a low polydisperse polymer
DE19516563A1 (de) * 1995-05-05 1996-11-07 Basf Ag Verfahren zur Herstellung von Styrol-Oligomeren und deren Verwendung als Schmiermittel in Thermoplasten
US6306962B1 (en) 1999-09-30 2001-10-23 The Dow Chemical Company Flow carbonate polymer blends
US6380304B1 (en) 1999-09-30 2002-04-30 The Dow Chemical Company Mass polymerized rubber-modified monovinylidene aromatic copolymer compositions
US6380303B1 (en) 2000-02-24 2002-04-30 The Dow Chemical Company Flow carbonate polymer blends
US20010046938A1 (en) * 2000-03-04 2001-11-29 Halasa Adel Farhan Synthesis of dilithium initiator
CN101045756B (zh) * 2006-03-30 2011-01-12 北京化工大学 一种阴离子聚合用多官能团有机碱金属引发剂的制备方法
MX2009013127A (es) * 2007-06-07 2010-01-15 Albemarle Corp Polimeros bromados de bajo peso molecular y su uso en formulaciones termoplasticas.
US8993684B2 (en) * 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
KR20110028538A (ko) * 2008-07-09 2011-03-18 바스프 에스이 이속사졸린 화합물 ⅱ를 포함하는 살충 혼합물
WO2010065467A1 (en) * 2008-12-02 2010-06-10 Albemarle Corporation Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses
KR20110103942A (ko) * 2008-12-02 2011-09-21 알베마를 코포레이션 톨루엔 및 스티렌으로부터 유도된 텔로머 혼합물의 브롬화
WO2010065462A2 (en) * 2008-12-02 2010-06-10 Albemarle Corporation Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom
JO3423B1 (ar) * 2008-12-02 2019-10-20 Albemarle Corp مؤخرات لهب معالجة بالبروم و مواد مشتقه منها
KR20120088535A (ko) 2009-05-01 2012-08-08 알베마를 코포레이션 펠렛화된 저분자량 브롬화 방향족 고분자 조성물
JO3059B1 (ar) 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
ES2633097T3 (es) 2009-06-30 2017-09-19 Bridgestone Corporation Iniciadores de polimerización aniónica y procesos
EP2864375B1 (de) * 2012-06-26 2018-01-03 INEOS Styrolution Europe GmbH Verfahren zur herstellung von polymeren aus vinylaromaten sowie von vinylaromat-dien-blockcopolymeren

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3308170A (en) * 1963-08-28 1967-03-07 Nat Distillers Chem Corp Substantially linear polydiene alcohols having majority of hydroxy groups terminal by preparing polydiene in hydrocarbon and then using ether medium during epoxide addition
US3402159A (en) * 1963-12-20 1968-09-17 Phillips Petroleum Co Process for polymerizing butadiene and styrene terminated in short blocks of polystyrene
US3301840A (en) * 1964-09-17 1967-01-31 Phillips Petroleum Co Preparation of polymers of conjugated dienes using organolithium/polar compound catalyst systems
US3492369A (en) * 1965-05-24 1970-01-27 Phillips Petroleum Co Graft polymerizing by first lithiating in the presence of polar compounds
US3452111A (en) * 1966-12-09 1969-06-24 Lithium Corp Stabilization of secondary alkyllithiums

Also Published As

Publication number Publication date
US3668263A (en) 1972-06-06
GB1297331A (de) 1972-11-22
ZA708708B (en) 1971-10-27
NL7100697A (de) 1971-07-21
FR2075655A5 (de) 1971-10-08
AU2398771A (en) 1972-07-06
DE2063642A1 (de) 1971-07-29
BE761691A (fr) 1971-07-01

Similar Documents

Publication Publication Date Title
CA987332A (en) Organolithiumpolymerization initiators and use thereof in polymerization processes
CA925637A (en) Polymer mixtures and preparation thereof
AU460416B2 (en) Improvements in and relating to olefin polymerization
AU2989771A (en) Improvements in and relating to olefin polymerization
AU2723571A (en) Improvements in and relation tothe polymerization of olefins
CA843485A (en) Polymerization process and product thereof
CA833669A (en) Polymerisation and copolymerisation process
AU446030B2 (en) Improvements in polymerization
CA847268A (en) Polymers and their use in photography
AU421871B2 (en) Multifunctional polymerization initiators and preparation thereof
CA853774A (en) Polymerization process and polymers thereof
AU2483971A (en) Improvements in polymerization
CA837194A (en) Carboalkoxyphenyl acrylates and polymers thereof
CA854767A (en) Olefin polymerization and copolymerization process
AU1040070A (en) Multifunctional polymerization initiators and preparation thereof
CA835496A (en) Polymerization method and product
AU445277B2 (en) Polymer and process
CA832065A (en) Polymerization catalyst and process
CA804098A (en) 3-ethyl-1-heptene and polymers thereof
CA955954A (en) Dinorbornenes and polymers thereof
CA961050A (en) Acryloyloxyphenols and polymers thereof
AU434609B2 (en) Acryloyloxyphenols and polymers thereof
CA856900A (en) Polymerization process and product thereof
AU452885B2 (en) Polymerization process and product
CA849617A (en) Polymerization process and product