CA2857536A1 - Plasma heated furnace for iron ore pellet induration - Google Patents

Plasma heated furnace for iron ore pellet induration Download PDF

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Publication number
CA2857536A1
CA2857536A1 CA2857536A CA2857536A CA2857536A1 CA 2857536 A1 CA2857536 A1 CA 2857536A1 CA 2857536 A CA2857536 A CA 2857536A CA 2857536 A CA2857536 A CA 2857536A CA 2857536 A1 CA2857536 A1 CA 2857536A1
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CA
Canada
Prior art keywords
firing
plasma torch
pelletizing
air
pellets
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CA2857536A
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French (fr)
Inventor
Michel G. Drouet
Pierre Carabin
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Pyrogenesis Canada Inc
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Pyrogenesis Canada Inc
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Filing date
Publication date
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Publication of CA2857536A1 publication Critical patent/CA2857536A1/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • C22B1/2406Binding; Briquetting ; Granulating pelletizing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16Sintering; Agglomerating
    • C22B1/20Sintering; Agglomerating in sintering machines with movable grates
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • C22B1/2413Binding; Briquetting ; Granulating enduration of pellets
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B21/00Open or uncovered sintering apparatus; Other heat-treatment apparatus of like construction
    • F27B21/06Endless-strand sintering machines
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/44Plasma torches using an arc using more than one torch
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • H05H1/3452Supplementary electrodes between cathode and anode, e.g. cascade
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/143Reduction of greenhouse gas [GHG] emissions of methane [CH4]

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  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

In the present pelletizing apparatus, the induration of iron ore concentrate pellets is achieved in a tunnel furnace heated by plasma torches, wherein the generation of CO2 by the conventional iron ore pelletizing processes is reduced by using electricity powered plasma torches instead of burning natural gas, heavy oil or pulverized coal in burners, thereby reducing considerably industrial pollution of the atmosphere.

Description

TITLE OF THE INVENTION
PLASMA HEATED FURNACE FOR IRON ORE PELLET INDURATION
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This Application claims priority on U.S. Provisional Application No. 61/566,403, now pending, filed on December 2, 2011, which is herein incorporated by reference.
FIELD OF THE INVENTION
[0002] The present invention relates to the induration of iron ore concentrate pellets.
BACKGROUND OF THE INVENTION
[0003] In the face of shrinking world reserves of high-grade iron ore, low-grade ores are used, which must be concentrated before further processing.

The concentrated iron ore fines obtained cannot be used as such, for example in a blast furnace to produce pig iron or to produce sponge iron in a direct reduction iron plant (DRI).
[0004] The fines have first to be mixed with additives such as bentonite or other binders such as described for example in U.S. Patent No. 5,685,893 issued to Field et al., and then shaped into small lumps, the pellets, which are then hardened by firing in a furnace at temperature up to 1350 C.
SUBSTITUTE SHEET (RULE 26)
[0005] The total world production of such iron pellets is about 400 million metric tonnes per year, which corresponds to about 20% of the total iron ore production.
[0006] The most commonly employed method of heat-hardening, such as described for example in U.S. Patent No. 3,947,001 issued to Leighton, is of disposing the iron ore pellets on a travelling grate to carry the pellets through a tunnel-like enclosure where they are progressively subjected to drying, preheating, firing, after-firing and cooling. An alternative technology, as described for example in U.S. Patent No. 4,168,951 issued to Drugge, or as proposed by Metso, is to use a rotary kiln for the firing zone of the process instead of a moving grate.
[0007] The initial step of drying is carried out at moderate temperature to allow a gradual release of the moisture in the pellets. After drying, the pellets are fired at the required temperature to cause the pellets to fuse.
[0008] The process heat is provided by fuel burners, such as proposed by companies such as MetaI7, located on the side of the tunnel-like furnace enclosure. However, it has been reported, for example in aforementioned U.S.
Patent No. 3,947,001, that direct exposure of the radiant heat from the burning fuel flame has to be avoided as it could cause overheating of the top layer of pellets.
To overcome this possibility, it was proposed to install each burner in a small port extension located on the furnace tunnel, as illustrated in Fig. 1 of U.S.
Patent No.
3,947,001, thus shielding the pellets from the radiant heat from the burners.
[0009] As again illustrated in Fig. 1 of U.S. Patent No. 3,947,001, SUBSTITUTE SHEET (RULE 26) Leighton proposed two different burner installations: on the right of this figure, the burner is installed in a vertical shaft, while on the left of the figure, the burner is horizontal. In both cases the pellets are shielded from the burner flame radiant heat.
[0010] In the case of the processing of pellets fired in a kiln, such as, for example in a Metso plant, it is not possible to prevent exposure of the pellets to the radiant heat from the flame of the kiln single burner installed on the kiln axis, although tumbling of the pellets in the rotating kiln may minimize overheating.
[0011] The combustion, in the burners, of natural gas, heavy oil and/or pulverized coal results, unfortunately, in the production of very important amounts of CO2. For example, a typical pellet plant producing annually 10 million metric tonnes of pellets emits about one million metric tonnes of CO2; therefore, the total world pellet production of 400 million metric tonnes of pellets corresponds to the production of about 40 million metric tonnes of CO2 per year.
[0012] Once the very hot combustion gases have gone through the bed of pellets being fired, they are used to preheat and dry the green oncoming pellets before being released to the atmosphere. The released gas temperature being about 350 C, the process energy efficiency would be of only about 80%.
[0013] Furthermore, the combustion gases, which are used to dry the ore pellets, are, in addition to CO2, composed of water vapor, which is not an optimal composition as a drying gas.
SUBSTITUTE SHEET (RULE 26)
[0014] Because of the important release of green-house gases, of the low energy efficiency of the heating process and of the fact that a wet gas (that is a combustion gas containing water vapor in addition to carbon dioxide and nitrogen) is used in the drying zone of the furnace, there is a need for an improved technology for the induration of iron ore concentrate pellets.
SUMMARY OF THE INVENTION
[0015] It is therefore an aim of the present invention to provide a novel process and apparatus to reduce the generation of CO2 by iron ore pelletizing processes.
[0016] Therefore, in accordance with the present invention, there is provided a pelletizing apparatus comprising a firing chamber, a travelling grate for sequentially transporting ore pellets in drying, firing and cooling zones and at least one plasma torch for providing the air, heated at very high temperature, required for indurating the dried pellets in the firing chamber and drying the green pellets fed into the furnace.
[0017] More specifically, recuperated air from the pellet cooling zone of the apparatus is introduced in a chamber, where it is mixed with the extremely hot air from the plasma torch, prior to entering the pellet firing chamber.
[0018] As the process air is heated, not by fuel combustion, but by the torch electric arc, the hot air is very dry as it enters the pellet drying zone providing significant drying efficiency.
SUBSTITUTE SHEET (RULE 26)
[0019] Also in accordance with the present invention, there is provided a pelletizing apparatus, comprising a firing chamber, a traveling grate for sequentially transporting ore pellets in drying, firing and cooling zones, and at least one plasma torch for providing a heat required for indurating the ore pellets in the firing chamber.
[0020]
Further in accordance with the present invention, there is provided a pelletizing method, wherein ore pellets are fed sequentially through drying, firing and cooling zones, and wherein heat required for the process is provided by at least one plasma torch.
[0021] Still further in accordance with the present invention, there is provided a firing device in a pelletizing apparatus, comprising a firing chamber for ore pellets being transported through the pelletizing apparatus, and at least one plasma torch for providing a heat required for indurating the ore pellets in the firing chamber.
[0022] Still further in accordance with the present invention, there is provided a plasma torch for use in a firing device of an iron ore pelletizing apparatus, comprising at least two electrodes, namely one cathode and one anode, an electric arc being sustained between the two electrodes, a vortex ring for injecting compressed gas, such as air, between the two electrodes and for spinning the gas at high speed, an electrical insulator placed between the two electrodes, a jet of hot plasma gas exiting the torch for use in heating air before it reaches a firing chamber of the firing device.
SUBSTITUTE SHEET (RULE 26)
[0023] Other objects, advantages and features of the present invention will become more apparent upon reading of the following non-restrictive description of embodiments thereof, given by way of example only with reference to the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0024] Reference will now be made to the accompanying drawings, showing by way of illustration an illustrative embodiment of the present invention, and in which:
[0025] Fig. 1 is a schematic transverse vertical cross-sectional view of a conventional firing chamber construction;
[0026] Fig. 2 is a graphic representation of the dependence of the energy transfer efficiency on the off-gas temperature for a fuel or gas burner and a plasma torch;
[0027] Fig. 3 is a schematic transverse vertical cross-sectional view of a firing chamber of an induration tunnel furnace showing the location of the plasma torch, in accordance with the present invention;
[0028] Fig. 4 is a schematic vertical cross-sectional view of the plasma torch; and
[0029] Fig. 5 is a schematic transverse vertical cross-sectional view of a SUBSTITUTE SHEET (RULE 26) firing chamber of an induration tunnel furnace, in accordance with another embodiment of the present invention.
DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
[0030] The present pelletizing apparatus uses a plasma heated furnace to reduce, or even eliminate, the generation of CO2 in an iron ore pelletizing process, to increase the energy transfer efficiency of the pellet heating process, and to provide a dry gas (air) in the green pellets drying section. Plasma torches are used to heat the induration furnace in place of the conventional natural gas, heavy oil or/and pulverized coal burners and, in doing so, to contribute to reducing considerable pollution of the atmosphere and saving energy.
[0031] For a conventional burner section of the firing zone equipped, for example a 3.75 MW Metal7 burner, the required combustion air consumption would be about 3500 Nm3/h. By contrast, given both the facts that no combustion air is required and the higher heat transfer efficiency of the substitute plasma torch, as illustrated in Fig. 2, the air flow required would be only about 430 Nm3/h with the present plasma heated furnace.
[0032] In the induration tunnel, the green pellets are charged onto a grate; with the grate moving, the pellets sequentially pass through drying, preheat, firing and cooling zones.
[0033] With reference to Fig. 1, a transverse vertical cross-section of a conventional firing zone is therein shown with two possible and different burner SUBSTITUTE SHEET (RULE 26) arrangements: on the left of Fig. 1, a burner 42 is horizontal while on the right of Fig. 1, a burner 52 is in a vertical position. Depending on the arrangement considered, hot recuperated air is conveyed from the pellet cooling zone of the tunnel furnace, via conduit 40 and downcomer pipe 41, or conduit 51, to be heated by the flame from the fuel burner 42, or burner 52, and the heated air being directed horizontally into a firing chamber 43 via a laterally extending tunnel 44, or a shaft 50.
[0034] Green pellets 45 distributed on pallets 46 and previously dried and preheated, are then heat-hardened in the firing chamber 43.
[0035] In a typical pelletizing plant such as that shown in Fig. 1, a plurality of downcomers 41 or conduits 51, burners 42 or 52 and laterally extending tunnels 44 or shaft 50, are employed at spaced intervals along the firing chamber 43.
[0036] Now referring to Fig. 3, a transverse vertical cross-section of the firing zone of the present pelletizing apparatus is shown with two possible locations for the installation of a plasma torch: on the left of Fig. 3, a plasma torch 12 is horizontal while on the right, a plasma torch 22 is mounted vertically.
Depending on the arrangement considered, hot recuperated air is conveyed from the pellet cooling zone of the tunnel furnace, via conduit 10 and downcomer 11, or conduit 21, to be mixed with extremely hot air heated by plasma torch 12, or 22.
The hot air mixture is then directed towards a firing chamber 13 via a conduit 14, or a shaft 24.
SUBSTITUTE SHEET (RULE 26)
[0037] Green pellets 15, uniformly distributed onto a grate 16 and previously dried and preheated, are then heat-hardened in the firing chamber 13.
[0038] In a plasma fired iron ore induration furnace, from conduit 10 providing hot recuperated air from the pellet cooling zone, there would be a plurality of downcomers 11, or conduits 21, leading to the laterally extending tunnels 14, or shafts 24, where the hot recuperated air would be mixed with the extremely hot air heated by the plasma torches 12, or 22, before entering the firing chamber 13. Such a plurality of downcomers 11, conduits 21, plasma torches 12 and 22, laterally extending tunnels 14 and shafts 24 would, as required by the process, be employed at spaced intervals along the length of the firing chamber 13.
[0039] It is important to notice that, in both proposed arrangements for the installation of the torches 12 and 22, the pellets are shielded from exposure to the plasma flame intense radiant heat, thus preventing local pellet overheating.
[0040] The plasma torches 12 and 22 each use electricity to heat air to very high temperatures (5000 ¨10000 Kelvin). No fossil fuels are used to generate the heat. Other gases can be heated by the plasma torch such as nitrogen or argon.
[0041] As seen in Fig. 4, the plasma torches 12 and 22 can each comprise at least two electrodes: one cathode 23 and one anode 26. An electric arc 18 is sustained between the two electrodes 23 and 26. Compressed air (or another gas) is injected between the two electrodes through a vortex ring 20 that SUBSTITUTE SHEET (RULE 26) spins the air at high speed, limiting point erosion on the anode. An electrical insulator 25 made of ceramic or other electrically insulating material is placed between the two electrodes. In order to attain high power, multiple anodes and vortexes are used to increase arc length and volume of hot gas. The internal parts of the torch are mounted inside a water cooled shell 27 that keeps the electrodes cool relative to the hot process environment. A jet of hot plasma gas 28 exits the torch and is used to heat the air in the downcomer pipe 11.
[0042] Fig. 5 shows another embodiment, similar to that of Fig. 3, but wherein there is only the plasma torch 12. Hot recuperated air is conveyed from the pellet cooling zone of the tunnel, via the conduit 10 and the downcomer pipe 11, such that it can be heated to a higher temperature by the mixing thereof with the extremely hot air heated by the plasma torch 12. The heated air is directed horizontally into the firing chamber 13 via the laterally extending tunnel 14.
The pellets 15, distributed onto the grate 16 and previously dried and preheated, are then heat-hardened in the firing chamber 13.
[0043]
Although the invention has herein been described in detail with reference to a preferred embodiment, many variations may be made by those skilled in the art without departing from the spirit and scope thereof. For example, the placement of the plasma torch may vary. In addition, although the invention has been illustrated with reference to a straight-line type of pelletizing apparatuses, it is equally applicable to a pelletizing apparatus having a circular configuration.
[0044]
Finally, although the present invention has been described SUBSTITUTE SHEET (RULE 26) hereinabove by way of embodiments thereof, it may be modified, without departing from the nature and teachings of the subject invention as described herein.
SUBSTITUTE SHEET (RULE 26)

Claims (15)

CLAIMS:
1. A pelletizing apparatus, comprising a firing chamber, a traveling grate for sequentially transporting ore pellets in drying, firing and cooling zones, and at least one plasma torch for providing a heat required for indurating the ore pellets in the firing chamber.
2. A pelletizing apparatus according to Claim 1, wherein means are provided for conveying air heated by the plasma torch to the drying zone for drying green pellets located upstream of the firing zone.
3. A pelletizing apparatus according to Claims 1 and 2, wherein means are provided for introducing air recuperated from the pellet cooling zone in at least one chamber, where it is mixed with the extremely hot air from the plasma torch, prior to entering the pellet firing chamber.
4. A pelletizing apparatus according to Claims 1 to 3, wherein there are provided two plasma torches.
5. A pelletizing method, wherein ore pellets are fed sequentially through drying, firing and cooling zones, and wherein heat required for the process is provided by at least one plasma torch.
6. A pelletizing method according to Claim 5, wherein the ore pellets are transported by a traveling grate through the drying, firing and cooling zones.
7. A pelletizing method according to Claims 5 and 6, wherein recuperated air from the cooling zone is introduced in at least one chamber, where it is mixed with the extremely hot air from the plasma torch, prior to entering the pellet firing chamber.
8. A pelletizing method according to Claims 5 to 7, wherein air heated by the plasma torch is used in the drying zone for drying green pellets located upstream of the firing zone.
9. A firing device in a pelletizing apparatus, comprising a firing chamber for ore pellets being transported through the pelletizing apparatus, and at least one plasma torch for providing a heat required for indurating the ore pellets in the firing chamber.
10. A firing device according to Claim 9, wherein at least one conduit is provided to convey hot air from a cooling zone of the pelletizing apparatus to the plasma torch, where the hot air from a cooling zone is mixed with very hot air heated by the plasma torch, a resulting hot air mixture being directed to the firing chamber.
11. A firing device according to Claims 9 and 10, wherein there are provided two plasma torches, each being fed via conduits with hot air from the cooling zone.
12. A firing device according to Claim 11, wherein a common main conduit is provided for conveying hot air from the cooling zone to the at least one conduit associated with each plasma torch.
13. A plasma torch for use in a firing device of an iron ore pelletizing apparatus, comprising at least two electrodes, namely one cathode and one anode, an electric arc being sustained between the two electrodes, a vortex ring for injecting compressed gas, such as air, between the two electrodes and for spinning the gas at high speed, an electrical insulator placed between the two electrodes, a jet of hot plasma gas exiting the torch for use in heating air before it reaches a firing chamber of the firing device.
14. A plasma torch according to Claim 13, wherein multiple anodes and vortexes are used to increase arc length and volume of hot gas.
15. A plasma torch according to Claims 13 and 14, wherein internal parts of the torch are mounted inside a water cooled shell for keeping the electrodes cool relative to the hot process environment.
CA2857536A 2011-12-02 2012-12-03 Plasma heated furnace for iron ore pellet induration Pending CA2857536A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161566403P 2011-12-02 2011-12-02
US61/566,403 2011-12-02
PCT/CA2012/001107 WO2013078549A1 (en) 2011-12-02 2012-12-03 Plasma heated furnace for iron ore pellet induration

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CA2857536A1 true CA2857536A1 (en) 2013-06-06

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AU (5) AU2012344688B2 (en)
CA (1) CA2857536A1 (en)
WO (1) WO2013078549A1 (en)

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Publication number Priority date Publication date Assignee Title
US9752206B2 (en) * 2011-12-02 2017-09-05 Pyrogenesis Canada Inc. Plasma heated furnace for iron ore pellet induration
EP3337840B1 (en) * 2015-08-17 2019-11-27 Basf Se Aqueous polymer compositions comprising polyurethane (meth)acrylates
WO2019219340A1 (en) 2018-05-15 2019-11-21 Tata Steel Nederland Technology B.V. Method for the direct reduction of iron ore

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WO2013078549A1 (en) 2013-06-06
AU2018200146A1 (en) 2018-01-25
AU2020200669A1 (en) 2020-02-20
AU2022200713A1 (en) 2022-02-24
US20140311286A1 (en) 2014-10-23
AU2024203476A1 (en) 2024-06-13
AU2012344688A1 (en) 2014-07-24
US20180087126A1 (en) 2018-03-29
AU2012344688B2 (en) 2017-10-12
US9752206B2 (en) 2017-09-05

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