CA2632530A1 - Processus de recuperation de fer a partir de laitier de cuivre - Google Patents
Processus de recuperation de fer a partir de laitier de cuivre Download PDFInfo
- Publication number
- CA2632530A1 CA2632530A1 CA 2632530 CA2632530A CA2632530A1 CA 2632530 A1 CA2632530 A1 CA 2632530A1 CA 2632530 CA2632530 CA 2632530 CA 2632530 A CA2632530 A CA 2632530A CA 2632530 A1 CA2632530 A1 CA 2632530A1
- Authority
- CA
- Canada
- Prior art keywords
- copper
- slag
- iron
- reductant
- recovery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000010949 copper Substances 0.000 title claims abstract description 92
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 87
- 239000002893 slag Substances 0.000 title claims abstract description 86
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 84
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 45
- 230000008569 process Effects 0.000 title claims abstract description 34
- 238000011084 recovery Methods 0.000 title claims abstract description 32
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 30
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 27
- 230000004907 flux Effects 0.000 claims abstract description 9
- 238000000227 grinding Methods 0.000 claims abstract description 8
- 229910001018 Cast iron Inorganic materials 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 8
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 8
- 239000004571 lime Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 239000002006 petroleum coke Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000010079 rubber tapping Methods 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 238000010309 melting process Methods 0.000 claims description 2
- 239000002699 waste material Substances 0.000 abstract description 11
- 239000012141 concentrate Substances 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 239000008240 homogeneous mixture Substances 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 230000009467 reduction Effects 0.000 description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- 229910017052 cobalt Inorganic materials 0.000 description 8
- 239000010941 cobalt Substances 0.000 description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 6
- 239000010970 precious metal Substances 0.000 description 4
- 238000003723 Smelting Methods 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000805 Pig iron Inorganic materials 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 229910052598 goethite Inorganic materials 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910020637 Co-Cu Inorganic materials 0.000 description 1
- -1 FeO Chemical compound 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000009852 extractive metallurgy Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011361 granulated particle Substances 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- 238000005058 metal casting Methods 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 231100000041 toxicology testing Toxicity 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0054—Slag, slime, speiss, or dross treating
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/04—Working-up slag
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
- C21B13/0013—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/12—Making spongy iron or liquid steel, by direct processes in electric furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B3/00—General features in the manufacture of pig-iron
- C21B3/04—Recovery of by-products, e.g. slag
- C21B3/06—Treatment of liquid slag
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/10—Dry methods smelting of sulfides or formation of mattes by solid carbonaceous reducing agents
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/02—Physical or chemical treatment of slags
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C2300/00—Process aspects
- C21C2300/04—Avoiding foam formation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IN3331DEL2005 | 2005-12-09 | ||
IN3331DE2005 | 2005-12-09 | ||
PCT/IN2005/000452 WO2007066350A1 (fr) | 2005-12-09 | 2005-12-29 | Processus de récupération de fer à partir de laitier de cuivre |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2632530A1 true CA2632530A1 (fr) | 2007-06-14 |
Family
ID=36499109
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2632530 Abandoned CA2632530A1 (fr) | 2005-12-09 | 2005-12-29 | Processus de recuperation de fer a partir de laitier de cuivre |
Country Status (6)
Country | Link |
---|---|
US (1) | US20070283785A1 (fr) |
KR (1) | KR20080081258A (fr) |
AU (1) | AU2005338902B2 (fr) |
CA (1) | CA2632530A1 (fr) |
MY (1) | MY144628A (fr) |
WO (1) | WO2007066350A1 (fr) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101886154B (zh) * | 2010-07-02 | 2012-06-20 | 昆明理工大学 | 一种铜渣与铁矿石混合熔融还原制得低铜铁水的方法 |
CN101921919B (zh) * | 2010-09-09 | 2011-12-21 | 山东天力干燥股份有限公司 | 一种熔融铜渣综合利用工艺及其*** |
FI124912B (fi) * | 2012-04-16 | 2015-03-31 | Outotec Oyj | Menetelmä ei-rautametallien metallurgisten kuonien käsittelemiseksi |
KR101272291B1 (ko) * | 2012-09-07 | 2013-06-07 | 한국지질자원연구원 | 물리화학적 선별법에 의한 구리, 아연, 납 등 비철제련공정에서 배출되는 폐비철 슬래그로부터 철을 분리 회수하는 방법 |
CN103060502B (zh) * | 2013-01-14 | 2014-03-26 | 白银龙家丰金属渣综合利用有限公司 | 利用铜废渣一次性还原炼硅酸铁工艺 |
KR101295157B1 (ko) * | 2013-04-30 | 2013-08-09 | 한국지질자원연구원 | 코발트 정광의 처리방법 |
CN103614607B (zh) * | 2013-09-12 | 2016-01-13 | 昆明理工大学 | 一种含镍物料作用下热态铜渣熔融还原制不锈钢原料的方法 |
DE102014010442A1 (de) * | 2014-07-11 | 2016-01-14 | Aurubis Ag | Verfahren und Vorrichtung zur Aufbereitung von Eisensilikatgestein |
KR20160066804A (ko) * | 2014-12-03 | 2016-06-13 | 주식회사 대창 | 칼슘 와이어를 사용한 구리합금 스크랩으로부터 납 제거 방법 |
JP6542560B2 (ja) * | 2015-03-31 | 2019-07-10 | Jx金属株式会社 | 非鉄製錬スラグの処理方法 |
CN105838870B (zh) * | 2016-05-24 | 2018-07-03 | 江苏省冶金设计院有限公司 | 制备还原铁的***及其应用 |
CN107699698A (zh) * | 2017-09-30 | 2018-02-16 | 江苏省冶金设计院有限公司 | 处理铜渣的方法 |
CN108728660B (zh) * | 2018-06-20 | 2020-07-17 | 中国恩菲工程技术有限公司 | 铜渣贫化方法 |
CN110578028B (zh) * | 2019-10-10 | 2021-06-29 | 尚明东 | 一种基于炼铜废渣提炼铁的方法 |
CL2019002935A1 (es) * | 2019-10-16 | 2020-03-13 | Univ Concepcion | Un proceso cero residuos que utiliza las escorias finales de fundición de cobre para producir productos comerciales |
CN112680600B (zh) * | 2020-12-17 | 2022-06-10 | 有研资源环境技术研究院(北京)有限公司 | 一种从海绵铜渣中生物氧化回收铜和富集贵金属的工艺 |
MX2023008678A (es) | 2021-01-26 | 2023-08-02 | Nucor Corp | Metodo y sistema para reducir el contenido de metal no ferroso de la chatarra de acero. |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1544048A (en) * | 1921-11-23 | 1925-06-30 | Stout Harry Howard | Treatment of copper metallurgical slag |
US1822588A (en) * | 1929-01-14 | 1931-09-08 | United Verde Copper Company | Recovering copper from slags |
US3157490A (en) * | 1961-10-23 | 1964-11-17 | Pullman Inc | Method for refining of metals |
US4110107A (en) * | 1977-06-16 | 1978-08-29 | The United States Of America As Represented By The Secretary Of The Interior | Process for reducing molten furnace slags by carbon injection |
FI71770C (fi) * | 1985-05-31 | 1987-02-09 | Outokumpu Oy | Reducering av smaelt metallurgiskt slagg kontinuerligt i en elektrisk ugn. |
-
2005
- 2005-12-29 AU AU2005338902A patent/AU2005338902B2/en not_active Ceased
- 2005-12-29 KR KR1020087013405A patent/KR20080081258A/ko not_active Application Discontinuation
- 2005-12-29 CA CA 2632530 patent/CA2632530A1/fr not_active Abandoned
- 2005-12-29 WO PCT/IN2005/000452 patent/WO2007066350A1/fr active Application Filing
-
2006
- 2006-03-21 US US11/386,575 patent/US20070283785A1/en not_active Abandoned
- 2006-03-28 MY MYPI20061365 patent/MY144628A/en unknown
Also Published As
Publication number | Publication date |
---|---|
MY144628A (en) | 2011-10-14 |
WO2007066350A1 (fr) | 2007-06-14 |
KR20080081258A (ko) | 2008-09-09 |
AU2005338902B2 (en) | 2011-09-01 |
AU2005338902A1 (en) | 2007-06-14 |
US20070283785A1 (en) | 2007-12-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
FZDE | Discontinued |
Effective date: 20131211 |