CA2630380A1 - Process for preparing olefins from synthesis gas in a reaction column - Google Patents
Process for preparing olefins from synthesis gas in a reaction column Download PDFInfo
- Publication number
- CA2630380A1 CA2630380A1 CA002630380A CA2630380A CA2630380A1 CA 2630380 A1 CA2630380 A1 CA 2630380A1 CA 002630380 A CA002630380 A CA 002630380A CA 2630380 A CA2630380 A CA 2630380A CA 2630380 A1 CA2630380 A1 CA 2630380A1
- Authority
- CA
- Canada
- Prior art keywords
- zone
- reaction
- olefins
- synthesis gas
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 55
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 46
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 45
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000003054 catalyst Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 37
- 238000004821 distillation Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 229940000425 combination drug Drugs 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 21
- 229930195733 hydrocarbon Natural products 0.000 description 16
- 150000002430 hydrocarbons Chemical class 0.000 description 16
- 238000012856 packing Methods 0.000 description 15
- 229910052742 iron Inorganic materials 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 229910017052 cobalt Inorganic materials 0.000 description 10
- 239000010941 cobalt Substances 0.000 description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 230000000737 periodic effect Effects 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 238000007700 distillative separation Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910052596 spinel Inorganic materials 0.000 description 4
- 239000011029 spinel Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- -1 aliphatic alcohols Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000000306 component Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 230000036647 reaction Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005056784A DE102005056784A1 (de) | 2005-11-28 | 2005-11-28 | Verfahren zur Herstellung von Olefinen aus Synthesegas in einer Reaktionskolonne |
| DE102005056784.3 | 2005-11-28 | ||
| PCT/EP2006/068780 WO2007060186A1 (de) | 2005-11-28 | 2006-11-23 | Verfahren zur herstellung von olefinen aus synthesegas in einer reaktionskolonne |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2630380A1 true CA2630380A1 (en) | 2007-05-31 |
Family
ID=37774573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002630380A Abandoned CA2630380A1 (en) | 2005-11-28 | 2006-11-23 | Process for preparing olefins from synthesis gas in a reaction column |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20090005464A1 (de) |
| EP (1) | EP1957614A1 (de) |
| CN (1) | CN101316914A (de) |
| AR (1) | AR057191A1 (de) |
| BR (1) | BRPI0619015A2 (de) |
| CA (1) | CA2630380A1 (de) |
| DE (1) | DE102005056784A1 (de) |
| NO (1) | NO20082131L (de) |
| RU (1) | RU2008126153A (de) |
| WO (1) | WO2007060186A1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011054738A1 (de) | 2009-11-06 | 2011-05-12 | Basf Se | Eisenhaltiger heterogenkatalysator und verfahren zur herstellung von olefinen durch umsetzung von kohlenmonoxid mit wasserstoff |
| CN102711991B (zh) | 2009-11-06 | 2015-01-21 | 巴斯夫欧洲公司 | 含铁和锰的非均相催化剂和通过一氧化碳与氢气反应而制备烯烃的方法 |
| CN102665899B (zh) | 2009-11-06 | 2015-08-12 | 巴斯夫欧洲公司 | 含铁和铜的多相催化剂和通过用氢气转化一氧化碳制备烯烃的方法 |
| GB201018338D0 (en) | 2010-10-29 | 2010-12-15 | Asa Energy Conversions Ltd | Conversion of natural gas |
| RU2484897C1 (ru) * | 2011-04-02 | 2013-06-20 | Ваньхуа Индастриал Груп Ко., Лтд | Высокоселективный катализатор для производства фракций высококачественного бензина из синтез-газа и способ его изготовления |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4439350A (en) * | 1982-06-21 | 1984-03-27 | Chemical Research & Licensing Company | Contact structure for use in catalytic distillation |
| US20030012711A1 (en) * | 1999-11-17 | 2003-01-16 | Conoco Inc. | Honeycomb monolith catalyst support for catalytic distillation reactor |
| US6787576B2 (en) * | 2002-12-27 | 2004-09-07 | Exxonmobil Research And Engineering Company | Linear alpha olefins from natural gas-derived synthesis gas over a nonshifting cobalt catalyst |
| US6933323B2 (en) * | 2003-01-31 | 2005-08-23 | Chevron U.S.A. Inc. | Production of stable olefinic fischer tropsch fuels with minimum hydrogen consumption |
| US6822006B1 (en) * | 2003-07-02 | 2004-11-23 | Chevron U.S.A. Inc. | Methods of controlling the temperature of an exothermic reaction |
-
2005
- 2005-11-28 DE DE102005056784A patent/DE102005056784A1/de not_active Withdrawn
-
2006
- 2006-11-23 EP EP06819684A patent/EP1957614A1/de not_active Withdrawn
- 2006-11-23 US US12/095,127 patent/US20090005464A1/en not_active Abandoned
- 2006-11-23 CN CNA2006800445704A patent/CN101316914A/zh active Pending
- 2006-11-23 CA CA002630380A patent/CA2630380A1/en not_active Abandoned
- 2006-11-23 BR BRPI0619015A patent/BRPI0619015A2/pt not_active IP Right Cessation
- 2006-11-23 RU RU2008126153/04A patent/RU2008126153A/ru not_active Application Discontinuation
- 2006-11-23 WO PCT/EP2006/068780 patent/WO2007060186A1/de active Application Filing
- 2006-11-28 AR ARP060105238A patent/AR057191A1/es unknown
-
2008
- 2008-05-07 NO NO20082131A patent/NO20082131L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1957614A1 (de) | 2008-08-20 |
| NO20082131L (no) | 2008-06-26 |
| WO2007060186A1 (de) | 2007-05-31 |
| US20090005464A1 (en) | 2009-01-01 |
| BRPI0619015A2 (pt) | 2016-09-06 |
| RU2008126153A (ru) | 2010-01-10 |
| CN101316914A (zh) | 2008-12-03 |
| AR057191A1 (es) | 2007-11-21 |
| DE102005056784A1 (de) | 2007-05-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |