CA2615895C - Produits lubrifiants obtenus d'alimentations d'alpha-olefines melangees - Google Patents
Produits lubrifiants obtenus d'alimentations d'alpha-olefines melangees Download PDFInfo
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- CA2615895C CA2615895C CA2615895A CA2615895A CA2615895C CA 2615895 C CA2615895 C CA 2615895C CA 2615895 A CA2615895 A CA 2615895A CA 2615895 A CA2615895 A CA 2615895A CA 2615895 C CA2615895 C CA 2615895C
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- alpha
- olefins
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
- C10G50/02—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation of hydrocarbon oils for lubricating purposes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/02—Well-defined hydrocarbons
- C10M105/04—Well-defined hydrocarbons aliphatic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1088—Olefins
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/302—Viscosity
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/304—Pour point, cloud point, cold flow properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
- C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Lubricants (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
L'invention concerne un procédé amélioré consistant à utiliser des alpha-oléfines mélangées pour alimenter des systèmes catalyseurs de métallocène actif, de manière à obtenir des polymères liquides essentiellement aléatoires utilisés en particulier dans des composants lubrifiants ou en tant que fluides fonctionnels.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US70060305P | 2005-07-19 | 2005-07-19 | |
US60/700,603 | 2005-07-19 | ||
PCT/US2006/021399 WO2007011462A1 (fr) | 2005-07-19 | 2006-06-02 | Lubrifiants obtenus à partir de charges d'alpha-oléfines mélangées |
USPCT/US2006/021399 | 2006-06-02 | ||
PCT/US2006/027591 WO2007011832A1 (fr) | 2005-07-19 | 2006-07-14 | Produits lubrifiants obtenus d'alimentations d'alpha-olefines melangees |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2615895A1 CA2615895A1 (fr) | 2007-01-25 |
CA2615895C true CA2615895C (fr) | 2012-10-30 |
Family
ID=37309317
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2615895A Active CA2615895C (fr) | 2005-07-19 | 2006-07-14 | Produits lubrifiants obtenus d'alimentations d'alpha-olefines melangees |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1920031B1 (fr) |
AU (1) | AU2006270083B2 (fr) |
CA (1) | CA2615895C (fr) |
WO (1) | WO2007011832A1 (fr) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7989670B2 (en) | 2005-07-19 | 2011-08-02 | Exxonmobil Chemical Patents Inc. | Process to produce high viscosity fluids |
WO2007011462A1 (fr) | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Lubrifiants obtenus à partir de charges d'alpha-oléfines mélangées |
WO2007011459A1 (fr) | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Nouvelles compositions polyalphaolefiniques et procedes de realisation afferents |
US8834705B2 (en) | 2006-06-06 | 2014-09-16 | Exxonmobil Research And Engineering Company | Gear oil compositions |
US8535514B2 (en) | 2006-06-06 | 2013-09-17 | Exxonmobil Research And Engineering Company | High viscosity metallocene catalyst PAO novel base stock lubricant blends |
US8501675B2 (en) | 2006-06-06 | 2013-08-06 | Exxonmobil Research And Engineering Company | High viscosity novel base stock lubricant viscosity blends |
US8299007B2 (en) | 2006-06-06 | 2012-10-30 | Exxonmobil Research And Engineering Company | Base stock lubricant blends |
US8921290B2 (en) | 2006-06-06 | 2014-12-30 | Exxonmobil Research And Engineering Company | Gear oil compositions |
JP5555490B2 (ja) | 2006-07-19 | 2014-07-23 | エクソンモービル・ケミカル・パテンツ・インク | メタロセン触媒を用いたポリオレフィンの製造方法 |
US8513478B2 (en) * | 2007-08-01 | 2013-08-20 | Exxonmobil Chemical Patents Inc. | Process to produce polyalphaolefins |
US8143467B2 (en) | 2007-12-18 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for synthetic lubricant production |
US8227392B2 (en) * | 2008-01-25 | 2012-07-24 | Exxonmobil Research And Engineering Company | Base stocks and lubricant blends containing poly-alpha olefins |
CN101925617B (zh) * | 2008-01-31 | 2012-11-14 | 埃克森美孚化学专利公司 | 在生产茂金属催化的聚α烯烃中线性α烯烃的改进利用 |
US7943807B2 (en) * | 2008-02-06 | 2011-05-17 | Chemtura Corporation | Controlling branch level and viscosity of polyalphaolefins with propene addition |
US8865959B2 (en) | 2008-03-18 | 2014-10-21 | Exxonmobil Chemical Patents Inc. | Process for synthetic lubricant production |
CN101977944A (zh) | 2008-03-31 | 2011-02-16 | 埃克森美孚化学专利公司 | 剪切稳定的高粘度pao的制备 |
WO2009148685A1 (fr) * | 2008-06-05 | 2009-12-10 | Exxonmobil Chemical Patents Inc. | Agent d’abaissement du point d’écoulement pour compositions d’hydrocarbures |
US8642522B2 (en) * | 2008-06-05 | 2014-02-04 | Exxonmobil Research And Engineering Company | Pour point depressant for hydrocarbon compositions |
US8394746B2 (en) | 2008-08-22 | 2013-03-12 | Exxonmobil Research And Engineering Company | Low sulfur and low metal additive formulations for high performance industrial oils |
JP5319992B2 (ja) * | 2008-09-08 | 2013-10-16 | 三井化学株式会社 | ギヤ油用潤滑油組成物 |
US8247358B2 (en) | 2008-10-03 | 2012-08-21 | Exxonmobil Research And Engineering Company | HVI-PAO bi-modal lubricant compositions |
JP2011121990A (ja) * | 2008-11-17 | 2011-06-23 | Idemitsu Kosan Co Ltd | 潤滑油組成物 |
JP5555478B2 (ja) * | 2008-11-17 | 2014-07-23 | 出光興産株式会社 | 変速機用潤滑油組成物 |
EP2380918B1 (fr) * | 2008-12-26 | 2019-07-24 | Idemitsu Kosan Co., Ltd. | Procédé de préparation d'un polymère alpha-oléfinique, polymère alpha-oléfinique et composition d'huile lubrifiante |
JP5745277B2 (ja) * | 2009-01-23 | 2015-07-08 | 出光興産株式会社 | 歯車用潤滑油 |
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US8716201B2 (en) | 2009-10-02 | 2014-05-06 | Exxonmobil Research And Engineering Company | Alkylated naphtylene base stock lubricant formulations |
WO2011079042A2 (fr) | 2009-12-24 | 2011-06-30 | Exxonmobil Chemical Patents Inc. | Procédé de production d'huiles de base synthétiques inédites |
US20120302481A1 (en) | 2010-01-26 | 2012-11-29 | Idemitsu Kosan Co., Ltd. | Alpha-olefin (co)polymer, hydrogenated alpha-olefin (co)polymer and lubricating oil composition containing the same |
US8642523B2 (en) | 2010-02-01 | 2014-02-04 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
US8598103B2 (en) | 2010-02-01 | 2013-12-03 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low, medium and high speed engines by reducing the traction coefficient |
US8728999B2 (en) | 2010-02-01 | 2014-05-20 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
EP2531585B1 (fr) | 2010-02-01 | 2018-06-20 | ExxonMobil Research and Engineering Company | Utilisation de compositions d'huiles moteur pour ameliorer le rendement énergétique de moteurs rapides, lents et semi-rapides par réduction du coefficient de traction |
US8748362B2 (en) | 2010-02-01 | 2014-06-10 | Exxonmobile Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed gas engines by reducing the traction coefficient |
US8759267B2 (en) | 2010-02-01 | 2014-06-24 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
BR112013002591A2 (pt) | 2010-08-04 | 2016-06-07 | Exxonmobil Chem Patents Inc | polialfaolefinas de elevada viscosidade estáveis em cisalhamento |
EP2609125B1 (fr) | 2010-08-25 | 2019-12-04 | ExxonMobil Chemical Patents Inc. | Hydrocarbures synthétiques fluides pouvant être fonctionnalisés et leur procédé intégré de production |
US9815915B2 (en) | 2010-09-03 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Production of liquid polyolefins |
WO2012134688A1 (fr) | 2011-03-30 | 2012-10-04 | Exxonmobil Chemical Patents Inc. | Polyalpha-oléfines par oligomérisation et isomérisation |
US20130005633A1 (en) | 2011-06-30 | 2013-01-03 | Exxonmobil Research And Engineering Company | Lubricating Compositions Containing Polyalkylene Glycol Mono Ethers |
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EP2726583A1 (fr) | 2011-06-30 | 2014-05-07 | ExxonMobil Research and Engineering Company | Compositions lubrifiantes contenant des polyétheramines |
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AU2012321290B2 (en) | 2011-10-10 | 2016-07-07 | Exxonmobil Chemical Patents Inc. | Poly alpha olefin compositions and process to produce poly alpha olefin compositions |
WO2013109371A1 (fr) | 2012-01-17 | 2013-07-25 | Exxonmobil Chemical Patents Inc. | Procédé d'obtention de polyoléfines liquides |
WO2014022013A1 (fr) * | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Polyalphaoléfines préparées en utilisant des composés de catalyseur salan modifiés |
US9422497B2 (en) | 2012-09-21 | 2016-08-23 | Exxonmobil Research And Engineering Company | Synthetic lubricant basestocks and methods of preparation thereof |
US20140274849A1 (en) | 2013-03-14 | 2014-09-18 | Exxonmobil Research And Engineering Company | Lubricating composition providing high wear resistance |
US10738258B2 (en) | 2017-03-24 | 2020-08-11 | Exxonmobil Research And Engineering Company | Method for improving engine fuel efficiency and energy efficiency |
US10443008B2 (en) | 2017-06-22 | 2019-10-15 | Exxonmobil Research And Engineering Company | Marine lubricating oils and method of making and use thereof |
KR102111865B1 (ko) * | 2018-11-27 | 2020-05-18 | 대림산업 주식회사 | 균일한 구조를 가지는 폴리알파올레핀 및 이의 제조방법 |
WO2020176171A1 (fr) | 2019-02-28 | 2020-09-03 | Exxonmobil Research And Engineering Company | Compositions d'huile pour engrenage de faible viscosivité pour véhicules électriques et hybrides |
WO2020264534A2 (fr) | 2019-06-27 | 2020-12-30 | Exxonmobil Research And Engineering Company | Procédé pour réduire les teneurs en cuivre solubilisé dans des huiles d'engrenage d'éolienne |
WO2021108160A1 (fr) | 2019-11-25 | 2021-06-03 | Exxonmobil Chemical Patents Inc. | Adhésifs thermofusibles sensibles à la pression et leurs procédés de fabrication |
WO2021133583A1 (fr) | 2019-12-23 | 2021-07-01 | Exxonmobil Research And Engineering Company | Procédé et appareil de production en continu de graisse à base de polyurée |
US11345872B2 (en) | 2020-01-30 | 2022-05-31 | ExxonMobil Technology and Engineering Company | Sulfur-free, ashless, low phosphorus lubricant compositions with improved oxidation stability |
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US20230383022A1 (en) | 2020-11-17 | 2023-11-30 | Exxonmobil Chemical Patents Inc. | Concurrent Isomerization/Hydrogenation Of Unsaturated Polyalphaolefin In The Presence Of A High Activity Catalyst |
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CA2110654C (fr) | 1992-12-17 | 2006-03-21 | Albert Rossi | Procede pour la polymerisation d'un copolymere ethylene-alpha-olefine utilisant des catalyseurs a base de metallocene, en milieu dilue |
EP0613873A3 (fr) * | 1993-02-23 | 1995-02-01 | Shell Int Research | Procédé d'oligomérisation. |
CN1208291C (zh) * | 1998-04-28 | 2005-06-29 | 萨索尔技术(控股)有限公司 | 二聚体的生产 |
US6858767B1 (en) * | 2000-08-11 | 2005-02-22 | Uniroyal Chemical Company, Inc. | Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same |
WO2002066404A1 (fr) * | 2001-02-22 | 2002-08-29 | Stichting Dutch Polymer Institute | Systeme de catalyseur pour la trimerisation d'olefines |
US6646174B2 (en) * | 2002-03-04 | 2003-11-11 | Bp Corporation North America Inc. | Co-oligomerization of 1-dodecene and 1-decene |
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2006
- 2006-07-14 CA CA2615895A patent/CA2615895C/fr active Active
- 2006-07-14 AU AU2006270083A patent/AU2006270083B2/en active Active
- 2006-07-14 EP EP06787492.5A patent/EP1920031B1/fr active Active
- 2006-07-14 WO PCT/US2006/027591 patent/WO2007011832A1/fr active Application Filing
Also Published As
Publication number | Publication date |
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AU2006270083B2 (en) | 2011-01-20 |
WO2007011832A1 (fr) | 2007-01-25 |
EP1920031A1 (fr) | 2008-05-14 |
CA2615895A1 (fr) | 2007-01-25 |
EP1920031B1 (fr) | 2018-01-10 |
AU2006270083A1 (en) | 2007-01-25 |
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