CA2471202A1 - Marine diesel cylinder lubricant composition - Google Patents

Marine diesel cylinder lubricant composition Download PDF

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Publication number
CA2471202A1
CA2471202A1 CA002471202A CA2471202A CA2471202A1 CA 2471202 A1 CA2471202 A1 CA 2471202A1 CA 002471202 A CA002471202 A CA 002471202A CA 2471202 A CA2471202 A CA 2471202A CA 2471202 A1 CA2471202 A1 CA 2471202A1
Authority
CA
Canada
Prior art keywords
marine diesel
lubricant composition
diesel cylinder
cylinder lubricant
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002471202A
Other languages
French (fr)
Other versions
CA2471202C (en
Inventor
Laurent Chambard
Adrian Dunn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Infineum International Ltd
Original Assignee
Infineum International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Infineum International Ltd filed Critical Infineum International Ltd
Publication of CA2471202A1 publication Critical patent/CA2471202A1/en
Application granted granted Critical
Publication of CA2471202C publication Critical patent/CA2471202C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/028—Overbased salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26—Overbased carboxylic acid salts
    • C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbasedsulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/52—Base number [TBN]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/14—Chemical after-treatment of the constituents of the lubricating composition by boron or a compound containing boron

Abstract

A marine diesel cylinder lubricant composition for a marine diesel engine running on fuel having a sulphur content of less than 1.5%, the composition having a total base number, as determined according to ASTM D2896, of more than 30 and less than 70, and comprising at least 40 wt% of an oil of lubricating viscosity, and at least one detergent prepared from at least two surfactants, one of which is a salicylate.
The marine diesel cylinder lubricant composition demonstrates good ability to reduce deposit formation, especially on pistons. The marine diesel cylinder lubricant composition also demonstrates good lubrication at temperatures above 250°C.

Claims (8)

1. A marine diesel cylinder lubricant composition for a marine diesel engine running on fuel having a sulphur content of less than 1.5%, the composition having a total base number, as determined according to ASTM D2896, of more than 30 and less than 70, and comprising:
- at least 40 wt% of an oil of lubricating viscosity, and - at least one detergent prepared from at least two surfactants, one of which is a salicylate.
2. The marine diesel cylinder lubricant composition as claimed in claim 1, wherein the detergent includes at least 5 mass% of salicylate, preferably at least mass% of salicylate.
3. The marine diesel cylinder lubricant composition as claimed in claims 1 or 2, wherein the detergent further includes at least 5 mass% of phenate and optionally at least 5 mass% of sulphonate.
4. The marine diesel cylinder lubricant composition as claimed in any one of the preceding claims, wherein the lubricant has a base number of less than 60, and preferably less than 50; and preferably more than 32, more preferably more than 35.
5. The marine diesel cylinder lubricant composition as claimed in any one of the preceding claims, further including at least one of the following: a dispersant, an anti-wear agent, an anti-oxidant, a pour point depressant, an anti-foamant and a demulsifier.
6. A method of operating a marine diesel engine running on fuel having at most 1.5% sulphur, the method including the step of using the marine diesel cylinder lubricant composition claimed in any one of claims 1-5 to lubricate the engine.
7. Use of the marine diesel lubricant composition as claimed in any one of claims 1-5 to reduce deposits in a marine diesel cylinder engine running on fuel having at most 1.5% sulphur.
8. Use of the marine diesel cylinder lubricant composition as claimed in any one of claims 1-5 to provide lubricity in a marine diesel engine running on fuel having at most 1.5% sulphur and running at temperatures above 250°C, preferably above 300°C.
CA2471202A 2003-06-13 2004-06-11 Marine diesel cylinder lubricant composition Expired - Fee Related CA2471202C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03253769 2003-06-13
EP03253769.8 2003-06-13

Publications (2)

Publication Number Publication Date
CA2471202A1 true CA2471202A1 (en) 2004-12-13
CA2471202C CA2471202C (en) 2011-11-01

Family

ID=33547787

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2471202A Expired - Fee Related CA2471202C (en) 2003-06-13 2004-06-11 Marine diesel cylinder lubricant composition

Country Status (6)

Country Link
US (1) US20050003972A1 (en)
JP (1) JP4928070B2 (en)
CN (1) CN100500816C (en)
AU (1) AU2004202588B2 (en)
CA (1) CA2471202C (en)
SG (1) SG126767A1 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE518939T1 (en) * 2005-05-11 2011-08-15 Infineum Int Ltd FUEL COMPOSITIONS
EP1728849B1 (en) * 2005-05-27 2019-12-18 Infineum International Limited A method of lubricating the cylinder liner and the crankcase of a cross-head marine diesel engine
US8076274B2 (en) * 2006-07-20 2011-12-13 Infineum International Limited Lubricating oil composition
WO2008119936A1 (en) * 2007-03-30 2008-10-09 Bp P.L.C. Lubrication methods
EP2003189A1 (en) * 2007-06-12 2008-12-17 BP p.l.c. Lubrication methods
EP2507347A1 (en) * 2009-11-30 2012-10-10 The Lubrizol Corporation Methods of controlling sulfur trioxide levels in internal combustion engines
EP2719751B1 (en) * 2012-06-07 2021-03-31 Infineum International Limited Marine engine lubrication
US9434906B2 (en) * 2013-03-25 2016-09-06 Chevron Oronite Company, Llc Marine diesel engine lubricating oil compositions
JP6509239B2 (en) 2013-11-06 2019-05-08 シェブロン・オロナイト・テクノロジー・ビー．ブイ． Marine diesel cylinder lubricating oil composition
KR102253485B1 (en) 2013-11-06 2021-05-21 셰브런 오로나이트 테크놀로지 비.브이. Marine diesel cylinder lubricant oil compositions
JP6386348B2 (en) * 2014-11-18 2018-09-05 Ｊｘｔｇエネルギー株式会社 Cylinder lubricating oil composition for crosshead type diesel engine mounted on scrubber
JP6297477B2 (en) * 2014-11-18 2018-03-20 Ｊｘｔｇエネルギー株式会社 Cylinder lubricating oil composition for crosshead type diesel engine mounted on scrubber
CN107001977B (en) * 2014-11-18 2021-02-05 Jxtg能源株式会社 Cylinder lubricating oil composition for crosshead diesel engine equipped with scrubber
KR20160092963A (en) * 2016-07-13 2016-08-05 윤종식 Method of preventing traffic accidents in crossroad for signal violation and overspeed, and system of the same
US10470798B1 (en) 2018-11-30 2019-11-12 Ohana Biosciences, Inc. Methods for promoting fertilization

Family Cites Families (17)

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Publication number Priority date Publication date Assignee Title
GB9611318D0 (en) * 1996-05-31 1996-08-07 Exxon Chemical Patents Inc Overbased metal-containing detergents
GB9611428D0 (en) * 1996-05-31 1996-08-07 Exxon Chemical Patents Inc Overbased metal-containing detergents
GB9611424D0 (en) * 1996-05-31 1996-08-07 Exxon Chemical Patents Inc Overbased metal-containing detergents
GB9709006D0 (en) * 1997-05-02 1997-06-25 Exxon Chemical Patents Inc Lubricating oil compositions
EP0963429B1 (en) * 1997-11-28 2012-03-07 Infineum USA L.P. Lubricating oil compositions
GB9800436D0 (en) * 1998-01-09 1998-03-04 Exxon Chemical Patents Inc Marine lubricant compositions
US6277794B1 (en) * 1998-12-28 2001-08-21 Infineum Usa L.P. Lubricant compositions
GB9908771D0 (en) * 1999-04-17 1999-06-09 Infineum Uk Ltd Lubricity oil composition
ATE491775T1 (en) * 1999-09-13 2011-01-15 Infineum Int Ltd A METHOD OF LUBRICATION FOR TWO-STROKE MARINE DIESEL ENGINES
JP4011815B2 (en) * 2000-02-14 2007-11-21 シェブロンジャパン株式会社 Lubricating oil composition for two-cycle crosshead diesel internal combustion engine and additive composition for lubricating oil composition
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Also Published As

Publication number Publication date
CN1572864A (en) 2005-02-02
CA2471202C (en) 2011-11-01
AU2004202588B2 (en) 2009-05-21
SG126767A1 (en) 2006-11-29
JP4928070B2 (en) 2012-05-09
CN100500816C (en) 2009-06-17
JP2005002341A (en) 2005-01-06
US20050003972A1 (en) 2005-01-06
AU2004202588A1 (en) 2005-01-06

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MKLA Lapsed

Effective date: 20180611