CA2348625A1 - Production of hydrogen-containing gas streams - Google Patents

Production of hydrogen-containing gas streams Download PDF

Info

Publication number: CA2348625A1
Authority: CA; Canada
Prior art keywords: mesh; catalyst; steam; reforming; support
Prior art date: 1998-11-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002348625A

Other languages

English (en)

French (fr)

Inventor

Nelleke Van Der Puil

Robert E. Trubac

Erwin M. Platvoet

Chiung-Yuan Huang

Rudolf A. Overbeek

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

CB&I Technology Inc

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-11-05

Filing date

1999-11-04

Publication date

2000-05-11

1999-11-04 Application filed by Individual filed Critical Individual

2000-05-11 Publication of CA2348625A1 publication Critical patent/CA2348625A1/en

Status Abandoned legal-status Critical Current

Links

239000007789 gas Substances 0.000 title description 14
229910052739 hydrogen Inorganic materials 0.000 title description 8
239000001257 hydrogen Substances 0.000 title description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title description 7
238000004519 manufacturing process Methods 0.000 title description 4
239000003054 catalyst Substances 0.000 claims abstract description 108
238000000629 steam reforming Methods 0.000 claims abstract description 54
238000000034 method Methods 0.000 claims description 38
239000002245 particle Substances 0.000 claims description 30
239000000835 fiber Substances 0.000 claims description 26
230000008569 process Effects 0.000 claims description 26
229910052751 metal Inorganic materials 0.000 claims description 23
239000002184 metal Substances 0.000 claims description 23
239000011800 void material Substances 0.000 claims description 22
238000006243 chemical reaction Methods 0.000 claims description 13
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
239000004215 Carbon black (E152) Substances 0.000 claims description 8
229930195733 hydrocarbon Natural products 0.000 claims description 7
150000002430 hydrocarbons Chemical class 0.000 claims description 7
238000012856 packing Methods 0.000 claims description 7
230000015572 biosynthetic process Effects 0.000 claims description 5
229910052759 nickel Inorganic materials 0.000 claims description 5
238000003786 synthesis reaction Methods 0.000 claims description 4
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
229910052703 rhodium Inorganic materials 0.000 claims description 2
239000010948 rhodium Substances 0.000 claims description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
229910052707 ruthenium Inorganic materials 0.000 claims description 2
238000000576 coating method Methods 0.000 abstract description 40
239000011248 coating agent Substances 0.000 abstract description 39
239000000463 material Substances 0.000 description 23
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 14
239000007788 liquid Substances 0.000 description 12
239000002002 slurry Substances 0.000 description 11
239000010410 layer Substances 0.000 description 10
239000008199 coating composition Substances 0.000 description 9
238000007598 dipping method Methods 0.000 description 8
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
239000011148 porous material Substances 0.000 description 7
238000012546 transfer Methods 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
238000001035 drying Methods 0.000 description 5
238000002407 reforming Methods 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 4
238000001354 calcination Methods 0.000 description 4
239000012018 catalyst precursor Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000002904 solvent Substances 0.000 description 4
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
229910002091 carbon monoxide Inorganic materials 0.000 description 3
238000003618 dip coating Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
238000011068 loading method Methods 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
230000000717 retained effect Effects 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
238000001833 catalytic reforming Methods 0.000 description 2
230000008859 change Effects 0.000 description 2
230000004907 flux Effects 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
230000035515 penetration Effects 0.000 description 2
238000006057 reforming reaction Methods 0.000 description 2
238000005507 spraying Methods 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
208000021017 Weight Gain Diseases 0.000 description 1
ULGYAEQHFNJYML-UHFFFAOYSA-N [AlH3].[Ca] Chemical compound [AlH3].[Ca] ULGYAEQHFNJYML-UHFFFAOYSA-N 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000007605 air drying Methods 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
235000021053 average weight gain Nutrition 0.000 description 1
230000000903 blocking effect Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000006255 coating slurry Substances 0.000 description 1
239000000571 coke Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000008021 deposition Effects 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910001055 inconels 600 Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
239000012046 mixed solvent Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
239000011368 organic material Substances 0.000 description 1
238000000643 oven drying Methods 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
239000003973 paint Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000000047 product Substances 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000013589 supplement Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
-1 titanic Chemical compound 0.000 description 1
238000005406 washing Methods 0.000 description 1
235000019786 weight gain Nutrition 0.000 description 1
230000004584 weight gain Effects 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1094—Promotors or activators
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Combustion & Propulsion (AREA)
Inorganic Chemistry (AREA)
Hydrogen, Water And Hydrids (AREA)
Catalysts (AREA)

CA002348625A 1998-11-05 1999-11-04 Production of hydrogen-containing gas streams Abandoned CA2348625A1 (en)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US10712798P	1998-11-05	1998-11-05
US60/107,127		1998-11-05
US43273799A	1999-11-02	1999-11-02
US09/432,737		1999-11-02
PCT/US1999/026148 WO2000026137A1 (en)	1998-11-05	1999-11-04	Production of hydrogen-containing gas streams

Publications (1)

Publication Number	Publication Date
CA2348625A1 true CA2348625A1 (en)	2000-05-11

Family

ID=26804424

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002348625A Abandoned CA2348625A1 (en)	1998-11-05	1999-11-04	Production of hydrogen-containing gas streams

Country Status (10)

Country	Link
EP (1)	EP1127029A1 (pt)
JP (1)	JP2003526590A (pt)
KR (1)	KR20010080393A (pt)
CN (1)	CN1350507A (pt)
AR (1)	AR021084A1 (pt)
AU (1)	AU1468800A (pt)
BR (1)	BR9914728A (pt)
CA (1)	CA2348625A1 (pt)
WO (1)	WO2000026137A1 (pt)
ZA (1)	ZA200103122B (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6797244B1 (en) *	1999-05-27	2004-09-28	Dtc Fuel Cells Llc	Compact light weight autothermal reformer assembly
US6746650B1 (en) *	1999-06-14	2004-06-08	Utc Fuel Cells, Llc	Compact, light weight methanol fuel gas autothermal reformer assembly
WO2001000323A1 (en) *	1999-06-29	2001-01-04	Abb Lummus Global, Inc.	Process for coating metal fibrous material
JP4551538B2 (ja) *	2000-07-13	2010-09-29	株式会社フルヤ金属	水蒸気改質触媒の製造方法
ZA200306075B (en) *	2001-02-16	2004-09-08	Battelle Memorial Institute	Integrated reactors, methods of making same, and methods of conducting simultaneous exothermic and endothermic reactions.
US7901662B2 (en) *	2005-11-01	2011-03-08	Celanese International Corporation	Steam generation apparatus and method
WO2010089265A2 (de) *	2009-02-09	2010-08-12	Basf Se	Hydrierkatalysatoren, deren herstellung und verwendung
WO2016080551A1 (en) *	2014-11-20	2016-05-26	Kao Corporation	Method for producing catalyst fibrous structure
CN105663319A (zh) *	2016-03-16	2016-06-15	石药集团河北永丰药业有限公司	一种治疗贫血的中药组合物、颗粒制剂及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3068525D1 (en) *	1979-09-06	1984-08-16	Ici Plc	A process and apparatus for catalytically reacting steam with a hydrocarbon in endothermic conditions
GB8514344D0 (en) *	1985-06-06	1985-07-10	Ici Plc	Catalyst support
US4716023A (en) *	1986-11-13	1987-12-29	Energy Research Corporation	Composite partial oxidizer and reformer
DE3714262A1 (de) *	1987-04-29	1988-11-10	Huels Chemische Werke Ag	Plattenfoermiger katalysator zur entfernung von stickstoffoxiden aus abgasen
DE69322129T2 (de) *	1992-06-24	1999-05-12	Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage	Verfahren zur katalytischen Kohlenwasserstoffteiloxidation
JPH1017303A (ja) *	1996-06-28	1998-01-20	Daikin Ind Ltd	燃料電池用改質器
US20020068026A1 (en) *	1997-08-08	2002-06-06	Lawrence L. Murrell	Reactor

1999
- 1999-11-04 CN CN99815103A patent/CN1350507A/zh active Pending
- 1999-11-04 AU AU14688/00A patent/AU1468800A/en not_active Abandoned
- 1999-11-04 WO PCT/US1999/026148 patent/WO2000026137A1/en not_active Application Discontinuation
- 1999-11-04 KR KR1020017005646A patent/KR20010080393A/ko not_active Application Discontinuation
- 1999-11-04 EP EP99971397A patent/EP1127029A1/en not_active Ceased
- 1999-11-04 CA CA002348625A patent/CA2348625A1/en not_active Abandoned
- 1999-11-04 AR ARP990105582A patent/AR021084A1/es not_active Application Discontinuation
- 1999-11-04 BR BR9914728-9A patent/BR9914728A/pt not_active IP Right Cessation
- 1999-11-04 JP JP2000579529A patent/JP2003526590A/ja not_active Withdrawn
2001
- 2001-04-17 ZA ZA2001/03122A patent/ZA200103122B/en unknown

Also Published As

Publication number	Publication date
WO2000026137A1 (en)	2000-05-11
JP2003526590A (ja)	2003-09-09
AR021084A1 (es)	2002-06-12
EP1127029A1 (en)	2001-08-29
ZA200103122B (en)	2002-06-26
AU1468800A (en)	2000-05-22
KR20010080393A (ko)	2001-08-22
CN1350507A (zh)	2002-05-22
BR9914728A (pt)	2001-08-07

Legal Events

Date	Code	Title	Description
2003-11-04	FZDE	Discontinued

Publication	Publication Date	Title
CA2470025C (en)	2012-02-21	Carbon nanotube-containing structures, methods of making, and processes using same
AU2009200661B2 (en)	2012-02-23	Carbon nanotube-containing structures, methods of making, and processes using same
KR100362624B1 (ko)	2002-11-29	반응기와 촉매 구조물을 포함하는 장치, 당해 장치를 사용하는 공정 및 당해 장치에 사용하기 위한 촉매 구조물
KR101346465B1 (ko)	2014-01-02	수소-풍부 기체로부터 일산화탄소를 제거하기 위한, 백금,구리 및 철을 함유하는 개선된 선택적 산화 촉매
US20050176580A1 (en)	2005-08-11	Catalyst for partial oxidation of hydrocarbon, process for producing the same, process for producing hydrogen-containing gas with the use of the catalyst and method of using hydrogen-containing gas produced with the use of the catalyst
KR20130014364A (ko)	2013-02-07	금속 구조체 촉매 및 이의 제조방법
CA2348625A1 (en)	2000-05-11	Production of hydrogen-containing gas streams
AU689996B2 (en)	1998-04-09	Process for preparation of supports
KR101511363B1 (ko)	2015-04-10	수증기-이산화탄소 복합개질을 위한 고내구성 금속폼 지지 촉매 및 그 제조방법
JP2616043B2 (ja)	1997-06-04	触媒および触媒担体
MXPA01003980A (en)	2001-11-21	Production of hydrogen-containing gas streams
KR20200051886A (ko)	2020-05-14	촉매 담지량 및 열충격시 박리 내구성이 향상된 촉매 담지용 금속 또는 세라믹 지지체의 제조 방법
WO2001000323A1 (en)	2001-01-04	Process for coating metal fibrous material
RU2638831C1 (ru)	2017-12-18	Способ приготовления катализатора для получения синтез-газа из метана, катализатор, приготовленный по этому способу, и способ получения синтез-газа из метана с его использованием
Wang et al.	2006	Carbon nanotube-containing structures, methods of making, and processes using same
Sanders et al.	2005	Supported Nanocomposite Catalysts for High Temperature Reactions: Building a Catalyst from the Nanoparticle up
MXPA00001359A (es)	2001-12-04	Reactor que incluye una estructura de malla para sostener particulas cataliticas
MXPA01007318A (es)	2002-03-05	Procedimiento de hidrogenacion selectiva y catalizador para el mismo