CA2326133A1 - Dinitrotoluene (dnt)-free single base propellant - Google Patents
Dinitrotoluene (dnt)-free single base propellant Download PDFInfo
- Publication number
- CA2326133A1 CA2326133A1 CA002326133A CA2326133A CA2326133A1 CA 2326133 A1 CA2326133 A1 CA 2326133A1 CA 002326133 A CA002326133 A CA 002326133A CA 2326133 A CA2326133 A CA 2326133A CA 2326133 A1 CA2326133 A1 CA 2326133A1
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- CA
- Canada
- Prior art keywords
- dnt
- propellant
- citrate
- single base
- plasticizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003380 propellant Substances 0.000 title claims abstract description 83
- DYSXLQBUUOPLBB-UHFFFAOYSA-N 2,3-dinitrotoluene Chemical compound CC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O DYSXLQBUUOPLBB-UHFFFAOYSA-N 0.000 title description 65
- 239000000203 mixture Substances 0.000 claims abstract description 54
- 239000000463 material Substances 0.000 claims abstract description 41
- 239000004014 plasticizer Substances 0.000 claims abstract description 37
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 12
- 238000009472 formulation Methods 0.000 claims abstract description 10
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001220 nitrocellulos Polymers 0.000 claims description 42
- 239000000020 Nitrocellulose Substances 0.000 claims description 41
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 40
- 229960002380 dibutyl phthalate Drugs 0.000 claims description 20
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims description 16
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical group CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 claims description 13
- 229940031769 diisobutyl adipate Drugs 0.000 claims description 12
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims description 7
- 150000001860 citric acid derivatives Chemical class 0.000 claims description 7
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 4
- PZIMIYVOZBTARW-UHFFFAOYSA-N centralite Chemical compound C=1C=CC=CC=1N(CC)C(=O)N(CC)C1=CC=CC=C1 PZIMIYVOZBTARW-UHFFFAOYSA-N 0.000 claims 3
- 235000010333 potassium nitrate Nutrition 0.000 claims 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 28
- 239000002904 solvent Substances 0.000 description 27
- 238000012545 processing Methods 0.000 description 14
- 238000012360 testing method Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229940035422 diphenylamine Drugs 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 5
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 5
- 231100000252 nontoxic Toxicity 0.000 description 5
- 230000003000 nontoxic effect Effects 0.000 description 5
- 231100000331 toxic Toxicity 0.000 description 5
- 230000002588 toxic effect Effects 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 2
- 239000000006 Nitroglycerin Substances 0.000 description 2
- 230000003679 aging effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000357 carcinogen Toxicity 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 229960003711 glyceryl trinitrate Drugs 0.000 description 2
- 239000002920 hazardous waste Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- -1 nitrate ester Chemical class 0.000 description 2
- 239000013557 residual solvent Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000001069 triethyl citrate Substances 0.000 description 2
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 2
- 235000013769 triethyl citrate Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 229920005547 polycyclic aromatic hydrocarbon Polymers 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/18—Compositions containing a nitrated organic compound the compound being nitrocellulose present as 10% or more by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/04—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive
- C06B45/06—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component
- C06B45/10—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component the organic component containing a resin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Abstract
A plasticizer material suitable for a DNT-free single base propellant formulation containing an amount of material selected from citrate and adipate compounds.
Description
DINITROTOLUENE (DNT)-FREE SINGLE BASE PROPELLANT
BACKGROUND OF THE INVENTION
I. Field of the Invention The present invention relates generally to single base propellants and, more particularly, to the reduction of environmental hazards by the elimination of the need to incorporate dinitrotoluene (DNT) in single base propellants. The invention provides substitute, less energetic but more efficient, plasticizing compounds which enable the incorporation of additional relative amounts of nitrocellulose (NC) in the mix thereby maintaining overall energy levels.
II. Related Art Single base propellants generally contain colloided nitrocellulose powders as the chief energetic component and this makes up about 85-99$ (weight) of the propellant mix.
The nitrocellulose is combined with a plasticizer to give the mix the desired mechanical properties so that the material can be processed into grains or other shapes utilized in, for example, 155 mm Artillery charges or 120 mm tank ammunition, or for other projectile firing purposes. Varying amounts of other stabilizing additives are added to the mix to reduce hazards sensitivity and to prolong shelf life. Double or multi base propellants, on the other hand, contain the same colloided nitrocellulose component, but utilize a second, liquid energetic compound such as nitroglycerin (NC) or an equivalent energetic liquid nitrate ester as a plasticizer. A third energetic component is also added in triple based composition.
Double base powders typically contain about 80$ colloided nitrocellulose with the major portion of the remaining material consisting of the nitroglycerin fraction. The powders of the present invention are single base propellants. They must be relatively hazard insensitive
BACKGROUND OF THE INVENTION
I. Field of the Invention The present invention relates generally to single base propellants and, more particularly, to the reduction of environmental hazards by the elimination of the need to incorporate dinitrotoluene (DNT) in single base propellants. The invention provides substitute, less energetic but more efficient, plasticizing compounds which enable the incorporation of additional relative amounts of nitrocellulose (NC) in the mix thereby maintaining overall energy levels.
II. Related Art Single base propellants generally contain colloided nitrocellulose powders as the chief energetic component and this makes up about 85-99$ (weight) of the propellant mix.
The nitrocellulose is combined with a plasticizer to give the mix the desired mechanical properties so that the material can be processed into grains or other shapes utilized in, for example, 155 mm Artillery charges or 120 mm tank ammunition, or for other projectile firing purposes. Varying amounts of other stabilizing additives are added to the mix to reduce hazards sensitivity and to prolong shelf life. Double or multi base propellants, on the other hand, contain the same colloided nitrocellulose component, but utilize a second, liquid energetic compound such as nitroglycerin (NC) or an equivalent energetic liquid nitrate ester as a plasticizer. A third energetic component is also added in triple based composition.
Double base powders typically contain about 80$ colloided nitrocellulose with the major portion of the remaining material consisting of the nitroglycerin fraction. The powders of the present invention are single base propellants. They must be relatively hazard insensitive
-2-and so avoid shock or heat sensitive plasticizers. An example of a prior blasting composition using NC and DNT is shown in U.S. Patent No. 3,328,217.
Most single base propellants traditionally contain a significant amount of dinitrotoluene (DNT) which acts as a plasticizer for the nitrocellulose to impart the desirable mechanical properties to the mix which, in turn, facilitate the processing of the mix into grains and other shapes utilized, for example, in the manufacture (loading) of large caliber cartridge munitions such as 155 mm Artillery charges or 120 mm tank ammunition. Such single base propellants normally contain from about 1-10~ DNT which itself is an energetic plasticizer albeit of low hazards sensitivity. In addition to being an energetic plasticizer, DNT also reduces the hygroscopic properties of the nitrocellulose making the mixture more water resistant and can be used to adjust the burning rate as it reduces the burning rate of pure nitrocellulose.
Single base propellants are produced utilizing a solvent-type process. An example of which is found in U.S.
Patent No. 4,525,313 to Muller. Ingredients are mixed utilizing volatile solvents or gelling agents which, as a rule, are selected from ketones, alcohols, ethers or mixtures thereof. The use of such solvents in combination with thermoplastic shaping processes including pressing and extruding equipment enable forming to take place at relatively low working temperatures. For example, nitrocellulose that has been turned into a doughy mass can readily be extruded in desired shapes at <50°C. The use of DNT lends itself readily to such a process inasmuch as that component can be in the form of an oil, solid or an oil-solid mixture which includes all three DNT isomers (i.e., 2,4;2,5 and 2,6 DNT) and generally freezes in the range from about 20-35°C. The solid form is generally para or
Most single base propellants traditionally contain a significant amount of dinitrotoluene (DNT) which acts as a plasticizer for the nitrocellulose to impart the desirable mechanical properties to the mix which, in turn, facilitate the processing of the mix into grains and other shapes utilized, for example, in the manufacture (loading) of large caliber cartridge munitions such as 155 mm Artillery charges or 120 mm tank ammunition. Such single base propellants normally contain from about 1-10~ DNT which itself is an energetic plasticizer albeit of low hazards sensitivity. In addition to being an energetic plasticizer, DNT also reduces the hygroscopic properties of the nitrocellulose making the mixture more water resistant and can be used to adjust the burning rate as it reduces the burning rate of pure nitrocellulose.
Single base propellants are produced utilizing a solvent-type process. An example of which is found in U.S.
Patent No. 4,525,313 to Muller. Ingredients are mixed utilizing volatile solvents or gelling agents which, as a rule, are selected from ketones, alcohols, ethers or mixtures thereof. The use of such solvents in combination with thermoplastic shaping processes including pressing and extruding equipment enable forming to take place at relatively low working temperatures. For example, nitrocellulose that has been turned into a doughy mass can readily be extruded in desired shapes at <50°C. The use of DNT lends itself readily to such a process inasmuch as that component can be in the form of an oil, solid or an oil-solid mixture which includes all three DNT isomers (i.e., 2,4;2,5 and 2,6 DNT) and generally freezes in the range from about 20-35°C. The solid form is generally para or
-3-2,4-dinitrotoluene. This material also lends itself readily to solvent processing with the nitrocellulose.
DNT has had a long and successful use as the major plasticizing and energy adjustment component in single base propellants and, with respect to the properties of the propellants themselves, has been quite successful. The DNT
is normally utilized with an amount of a second plasticizer, generally dibutylphthalate (DBP) which works well in combination with the DNT.
Thus, those skilled in the art appreciate that dinitrotoluene (DNT) has many attributes which make it a successful plasticizer and energy adjustment material for single base propellants: While successful from the standpoint of processing and use of the propellant, DNT
carries with it significant environmental drawbacks which have more recently provoked increasingly important concerns. Fine particulate DNT is considered quite toxic as when dust is produced in de-milling propellant. Residue DNT has traditionally been burned to destroy the material, but this produces undesirable nitrogen oxides (NOx).
Polycyclic aromatics (PAH's) are also given off by the combustion of DNT and these are considered quite carcinogenic. In addition, DNT is soluble up to about 150 PPM in water so that this presents a serious potential waste water problem. The material has not only been classified as a potential carcinogen, but also has been declared a hazardous waste by the EPA.
The dangers associated with use of DNT plasticizers has required high cost, personal protective equipment to be worn by those working with the material and expensive precautions to be taken with respect to containment and treatment of contaminated materials such as waste water containing DNT. Thus, there has long been a need in the manufacture of such single base propellants to provide a
DNT has had a long and successful use as the major plasticizing and energy adjustment component in single base propellants and, with respect to the properties of the propellants themselves, has been quite successful. The DNT
is normally utilized with an amount of a second plasticizer, generally dibutylphthalate (DBP) which works well in combination with the DNT.
Thus, those skilled in the art appreciate that dinitrotoluene (DNT) has many attributes which make it a successful plasticizer and energy adjustment material for single base propellants: While successful from the standpoint of processing and use of the propellant, DNT
carries with it significant environmental drawbacks which have more recently provoked increasingly important concerns. Fine particulate DNT is considered quite toxic as when dust is produced in de-milling propellant. Residue DNT has traditionally been burned to destroy the material, but this produces undesirable nitrogen oxides (NOx).
Polycyclic aromatics (PAH's) are also given off by the combustion of DNT and these are considered quite carcinogenic. In addition, DNT is soluble up to about 150 PPM in water so that this presents a serious potential waste water problem. The material has not only been classified as a potential carcinogen, but also has been declared a hazardous waste by the EPA.
The dangers associated with use of DNT plasticizers has required high cost, personal protective equipment to be worn by those working with the material and expensive precautions to be taken with respect to containment and treatment of contaminated materials such as waste water containing DNT. Thus, there has long been a need in the manufacture of such single base propellants to provide a
-4-non-toxic and environmentally safe chemical to replace the DNT plasticizes without sacrificing performance in the propellant material and which can be processed with existing production equipment for single base propellants.
In addition to DNT, dibubylphthalate (DBP) is also present in many plasticizes systems for NC single base propellant compositions in lesser amounts, normally 2-5$.
While not necessarily as undesirable as DNT, DBP is also considered a toxic material. It would also be advantageous to eliminate this material from the compositions as well.
Furthermore, diphenyl amine (DPA) which is the most common stabilizer used in single-base propellants also presents a potential environmental hazard. DPA is on the Enviromental Protection Agencies Toxic Releases Inventor (TRI) list.
Accordingly, it is a primary object of the present invention to provide a single base propellant which does not require DNT as a modifier or plasticizes material.
Another object of the invention is to provide a single base propellant which does not contain DNT but which can be processed using existing single base processing equipment.
Yet another object of the invention is to provide a single base propellant which does not require DBP in the formula.
An additional object of this invention is to provide a single base propellant which does not use DPA as the stabilizer.
A further object of the present invention is to provide non-toxic and environmentally friendly chemical plasticizers for single base propellants that do not require DNT, DBP or DPA.
It is a yet still further object of the present invention to provide non-toxic and environmentally friendly plasticizers for single base propellants, the incorporation
In addition to DNT, dibubylphthalate (DBP) is also present in many plasticizes systems for NC single base propellant compositions in lesser amounts, normally 2-5$.
While not necessarily as undesirable as DNT, DBP is also considered a toxic material. It would also be advantageous to eliminate this material from the compositions as well.
Furthermore, diphenyl amine (DPA) which is the most common stabilizer used in single-base propellants also presents a potential environmental hazard. DPA is on the Enviromental Protection Agencies Toxic Releases Inventor (TRI) list.
Accordingly, it is a primary object of the present invention to provide a single base propellant which does not require DNT as a modifier or plasticizes material.
Another object of the invention is to provide a single base propellant which does not contain DNT but which can be processed using existing single base processing equipment.
Yet another object of the invention is to provide a single base propellant which does not require DBP in the formula.
An additional object of this invention is to provide a single base propellant which does not use DPA as the stabilizer.
A further object of the present invention is to provide non-toxic and environmentally friendly chemical plasticizers for single base propellants that do not require DNT, DBP or DPA.
It is a yet still further object of the present invention to provide non-toxic and environmentally friendly plasticizers for single base propellants, the incorporation
-5-of which does not result in an overall lowered performance of the propellant.
A yet still further object of the invention is to provide new plasticizers for single base propellants which are non-toxic and environmentally safe and which can be added to the propellant utilizing the same processing solvents used for other components in existing single base processes.
Other objects and advantages of the invention will become apparent to those skilled in the art upon becoming familiar, with the present specification and appended claims.
SUt~IARY OF THE INVENTION
The present invention provides viable environmentally friendly substitutes for dinitrotoluene (DNT) in single base munition propellants which are compatible with existing solvent-type single base propellant manufacturing processes and which, in addition, enable propellants compatible in performance to existing DNT-containing loads.
In accordance with the present invention, it has been discovered that certain adipate and citrate compounds can be used in relatively small quantities to sufficiently plasticize high nitrogen (N) (about 13.2$ N) nitrocellulose (NC) in single base propellants. The required relative quantities are far less than that required using DNT, i.e., about 2-5$ versus about 7-10~ or more of DNT . Although, unlike DNT, these compounds are not energetic themselves, and thus, actually have a negative energy output with respect to the propellant compared to the positive energy of DNT, the lesser required amounts allow corresponding increases in the allowable percentage of NC in the propellant mix which offsets the negative energy of the plasticizers of the invention and results in an overall comparable energy yield for the propellant, typically
A yet still further object of the invention is to provide new plasticizers for single base propellants which are non-toxic and environmentally safe and which can be added to the propellant utilizing the same processing solvents used for other components in existing single base processes.
Other objects and advantages of the invention will become apparent to those skilled in the art upon becoming familiar, with the present specification and appended claims.
SUt~IARY OF THE INVENTION
The present invention provides viable environmentally friendly substitutes for dinitrotoluene (DNT) in single base munition propellants which are compatible with existing solvent-type single base propellant manufacturing processes and which, in addition, enable propellants compatible in performance to existing DNT-containing loads.
In accordance with the present invention, it has been discovered that certain adipate and citrate compounds can be used in relatively small quantities to sufficiently plasticize high nitrogen (N) (about 13.2$ N) nitrocellulose (NC) in single base propellants. The required relative quantities are far less than that required using DNT, i.e., about 2-5$ versus about 7-10~ or more of DNT . Although, unlike DNT, these compounds are not energetic themselves, and thus, actually have a negative energy output with respect to the propellant compared to the positive energy of DNT, the lesser required amounts allow corresponding increases in the allowable percentage of NC in the propellant mix which offsets the negative energy of the plasticizers of the invention and results in an overall comparable energy yield for the propellant, typically
-6-impetus levels of up to 986 J/g.. This is comparable to prior DNT containing loads such as M14 utilized for 120 mm tank cartridges.
The preferred compounds in accordance with the invention include certain adipate and/or citrate compounds including diisobutyl adipate (DIBA), diisooctly adipate (DIOA), acetyltriethyl citrate (ATEC), acetyltri-n-butyl citrate, triethyl citrate and tributyl citrate. Exemplary propellant compositions include from about 94-96$ high N
nitrocellulose (about 13.2$ N), about 2-4~ plasticizer and the remainder dibutylphthalate (DBP). The DBP provides additional plasticizing qualities. In addition, a small amount, nominally 1$, diphenylamine (DPA) is added to the mix as a thermal stabilizing material.
Additional embodiments include up to about 10~ or more ATEC and no DNT or DBP. These compositions contain a lesser amount of high N nitrocellulose (about 88-90$). These formulations may also contain ethyl cellulose as the stabilizer in place of the DPA. These compositions containing approximately 10~ of the new plasticizer system result in lower energy levels that are comparable to currently produced Artillery propellants such as M1, or approximately 930 J/g impetus.
The propellant combination of the invention containing the environmentally friendly plasticizing materials can be processed using conventional single base solvent processing techniques including conventional solvents, presses, extrusion and cutting devices and solvent recovery techniques.
BRIEF DESCRIPTION OF THE DRAWINGS
In the drawings:
Figure 1 shows the accelerated aging properties of certain new compositions according to the invention relative to M14; and Figure 2 depicts ballistic test results using a Gamma Dynagun for a composition of the invention with M19 energetics.
DETAILED DESCRIPTION
In accordance with the invention, improvements have been made in single base propellant compositions which enable them to be more friendly to those engaged in the manufacturing processes and more compatible with the environment. This has been accomplished, for the most part, by eliminating dinitrotoluene (DNT) from single base propellants which is a component that has possessed attributes with regard to enhancing propellant properties but which, at the same time, has presented both a hazard to the people engaged in the manufacturing process and an environmental menace from the standpoint of creating hazardous waste materials in effluents, particularly when burned (as poly aromatic hydrocarbons) and in waste water.
According to the invention, there have been discovered certain plasticizing compounds which enable substitution for DNT without sacrificing overall propellant performance.
These compounds can sufficiently plasticize high N
nitrocellulose (NC) sufficiently to enable proper processing into grains suitable for use in large caliber munitions, particularly, 155 mm Artillery charges and 120 mm tank ammunition.
Thus, it has been discovered that certain citrate and adipate compounds successfully plasticize high N
nitrocellulose (NC) in single base propellant systems utilizing sufficiently low percentages of these non-energetic materials such that additional percentages of NC
can be incorporated,in the formula thereby maintaining the overall energy output substantially constant.
It should be noted that a variety of materials have been evaluated in this regard including adipates and _g_ citrates, phthlates, polycaprolactones, ureas, urethanes and other materials. Attributes desired and evaluated include ability to plasticize NC, toxicity, processing/physical characteristics (compatibility with single base processing solvents and equipment) and mechanical characteristics imparted to the mix, prior usage in propellants, energetic qualities, availability and cost.
As previously noted, DNT has a long history of successful prior usage and its ability to plasticize NC and create processible physical characteristics in the mix. DNT, of course, is moderately energetic and the presence of larger percentages of it does not reduce the overall energy output of the propellant material. Thus, it was quite unexpected that DNT could be replaced using a low or negative energy material without sacrificing the overall performance of the mix.
In accordance with the invention, it has been discovered that a number of citrate compounds, together with at least one adipate successfully meet the necessary criteria for substituting for DNT in single base munition propellants. Thus, according to the present invention, it has been found that diisobutyl adipate (RIBA) available, for example, as Plasthall DIBA from the C.P. Hall Company, Memphis, Tennessee, acetyltriethyl citrate (ATEC) available as Citroflex~ A-2 from Morflex, Inc., Greensboro, North Carolina, and acetyltri-n-butyl citrate available as Citroflex A-4 also from Morflex, Inc. were especially successful. Other citrates, including triethyl citrate, available as Citroflex 2, and tributyl citrate, available as Citroflex 4, both from Morflex, Inc., of Greensboro, North Carolina, were also usable.
According to the invention, then, it has been discovered that DNT-free single base propellants containing from 2-10~ by weight of these new plasticizers display the desirable ballistic, mechanical, thermochemical and stability properties of standard DNT-containing propellant formulations. An important property of these plasticizers is that they can be added to the propellant in a standard pre-mixed form with the processing solvents typically used in single base processes. The plasticizers are relatively non-toxic and are environmentally acceptable under current governmental regulations.
The processing solvents for processing single base propellants include conventional solvents for NC which vary depending on the N content of the nitrocellulose.
Thus, high grade nitrocellulose which has above about 13.15$ N is practically insoluble in ether, but is readily dispersed by plasticizers and acetone. Below about 13.15$ N, either can be used. In some cases, combinations of acetone or ether and other solvents such as alcohols or other ketones are preferred.
In any event, in normal solvent-type processing, solid blocks of NC are broken and blended into the solvent together with an amount of the desired plasticizing agent, which is added or blended in from a slurry utilizing common solvents. Additional stabilizing materials are added prior to final mixing of the solubilized/plasticized nitrocellulose. The ability to add the plasticizers dispersed in a common solvent or solvents, of course, improves the uniformity of the mix and reduces the time of the mixing cycle. In addition to the other ingredients, if more solvent is needed, this is added to the material in the final mix or possibly in stages during the mix. After all the ingredients have been added to the mixer, the mix cycle continues for a given period of time, possibly 1 hour, until the single base propellant is thoroughly mixed.
After the mixing operation has been completed, the mixed propellant is dried by removal and recovery of some of the solvent from the mixed batch until a desired level of plasticity is achieved. Adjustment procedure steps, including drying and adding solvent, may continue until the correct plasticity is achieved and thereafter the mixer is run for a short time to allow the solvent to equalize throughout the mix.
After mixing has been completed and the proper solvent level reached, the material is transferred to a blocking press where it is subjected to a high pressure hydraulic ram to pressurize the material to remove occluded air, improve consolidation and form the blocks into the proper shape for the Braining press.
The blocked material is then transferred to the Braining press. In the Braining press, various techniques are utilized to extrude strands of propellant depending on the desired final configuration or use. The strands of propellant are cut to a specified length for further drying prior to final cutting into actual grain length.
The extruded material is dried in a manner which saves and recovers as much solvent as is practical for reuse and so the first step is normally to process the load in a solvent recovery tank. The material is then subjected to a water-dry operation where additional solvents are extracted into the water and thereafter to an air-dry cycle where the surface moisture is removed. Processing of the new compositions may also be accomplished in new continuos processes where the batch operations are replaced by continuous mixers, extruders and solvent removal.
Having presented an overview of the invention, additional information with respect to certain specific examples, which are intended to exemplify rather than to limit the scope o~ the invention, will next be presented.
Much of the information is in the form of tabular data criteria which will be familiar to those skilled in the art.
Table 1 shows a prior formulation utilizing dinitrotoluene (DNT) as the principle plasticizer and energy adjustment compound. The composition is an example of a mix generally known as M14 and nominally contains about 8$ DNT. Note that the specific example contained 8.29$ DNT and 2$ DBP.
PERCENT
NITROCELLULOSE 90.00 DINITROTOLUENE 8.00 DIBUTYLPHTHALATE 2.00 TOTAL 100.00 DIPHENYLAMINE 1.00 (ADDED) MOISTURE 0.6 RESIDUAL SOLVENT 0.7 GRAPHITE GLAZE 0.2 Table 2A shows three examples (Example 1, Example 2 and Example 3) of percentage compositions formulated in accordance with the present invention in which lesser amounts of the material known as plasticizer "340" has been substituted for the DNT fraction and the percentage of NC
increased. The material known as plasticizer "340" is diisobutyl adipate or (DIBA) available as Plastall DIBA
from the C.P. Hall Company.
TABLE ' 2A
PROPELLANT COMPOSITION
EXAMPLE EXAMPLE EXAMPLE
PERCENT PERCENT PERCENT PERCENT
CONSTITUENT FORMULA MEASURED MEASURED MEASURE
D
NITROCELLULOSE 96.00 96.23 96.09 96.14 PLASTICIZER "340" 2.10 1.95 2.01 1.99 DIBUTYLPHTHALATE 1.90 1.82 1.90 1.87 TOTAL 100.00 DIPHENYLAMINE 1.00 0.97 1.00 0.98 MOISTURE 0.6 0.7 0.6 0.6 RESIDUAL SOLVENT 0.7 0.9 0.8 0.5 GRAPHITE GLAZE 0.2 0.1 0.1 0.1 PROPELLANT COMPOSITION
,.
PERCENT PERCENT
CONSTITUENT FORMULA MEASURED
NITROCELLULOS 95.00 95.04 E
PLASTICIZER 3.10 3.08 "340"
DIBUTYLPHTHAL 1.90 1.88 ATE
TOTAL 100.00 DIPHENYLAMINE 1.00 1.08 MOISTURE 0.6 0.5 RESIDUAL 0.7 0.5 SOLVENT
GRAPHITE 0.2 0.1 GLAZE
Table 2B depicts an additional example, Example 4, in which the DNT fraction is replaced by a lesser amount of a material known as plasticizer "319", which is acetyltriethyl citrate, purchased as Citroflex A-2 from Morflex, Inc.
The stability and physical test result with respect to Examples 1-4 and which correspond to the tests conducted for the prior art DNT-containing material M14 are shown in Table 3. From this it can be seen that the hygroscopicity is slightly higher owing to the superior hygroscopicity reducing properties of DNT, in larger quantities.
Percentages in Examples 1-4, however, are still within tolerable limits and, as can be seen from the remainder of Table 3 and from the closed bomb testing of Examples 1-4 described in Table 4, that the performance and stability of the DNT-free material is comparable to that of M14.
~a>tr_: .
STABILITY AND
PHYSICAL TEST
rvnu~ n r t TEST FORMUIJi ACTUAL ACTUAL ACTUAL ACTUAL
HEAT TEST SP. NO CC 10' CC 60+ CC 60+ CC 60+ CC 60+
131.5 Deg. C
NO EXPLOSION 5 Hrs MIN NE 5 HRS NE 5 HRS NE 5 HRS NE 5 HRS
FORM OF PROPELIJWTCYLINDRICALCYL CYL CYL CYL
BULK DENSITY, INFO 52.29 50.37 18.19 50.78 L8S/CUfT
HOE,cal/g INFO 855.1 858.2 861.6 851.3 HYGROSCOPICITY. INFO 0.99 1.00 1.09 0.98 a ABSOLUTE DENSITY,G/CCINFO 1.54 1.56 1.51 1.5 lfT. UNIFORMITY INFO 110.5 100.8 65.0 121.3 f100 Gtslna). G
TJIiI~ 1 CLOSED BaMBS
rveuorr t rvnuorr Z. rvnuair ~ rvnuorr w TEMPRELATIVERELATIVERELATIVERELATIVERELA?IVERELATIVERELATIVERELATIVE
Oay.QUICKNESSFORCE QUICKNESSFORCE QUICKNESSFORCE QUICKNESSFORCE
+90 85.9 98.1 91.3 98.9 103.8 99.7 85.9 98.1 TEST
-10 82.3 98.2 86.2 98.5 97.3 97.7 82.3 913.2 111592.9 100.9 97.5 100.7 107.7 101.6 92.9 100.9 STD +90 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 Z~
Figure 1 shows the accelerated aging properties of the new composition s) relative to M14 at 150° F. Results of the long term aging show that these formulations age at a comparable rate to the standard M14 propellant.
15 Figure 2A shows ballistic test results from the Gamma Dynagun for the new composition with M19 energetics. The Gamma Dynagun is an interior ballistics test device based on a 105 Howitzer that allows assessment of required charge weights to obtain comparable muzzle velocities and 20 pressures to a standard propellant lot. It can be seen from Figure 2 that the charge weight of the new composition is within the same statistical population as the standard M14 propellant lot and a number of production lots of M14.
As can be seen from the description and examples herein, it is now possible to replace the DNT traction in propellant materials such as M14 without sacrificing other desirable propellant properties. The use of other materials, particularly citrate and adipate compounds, is also promising. Note that the formulation requires less plasticizes than those utilizing DNT allowing these negative energy materials to be compensated by the addition of more NC in the formula.
Example 5 depicts in Table 5 another single base propellant that does not contain either Dinitrotoluene (DNT) or Dibutyl-phthlate (DBP). DNT and DBP as indicated are the two ingredients currently used in the M1 propellant that are considered as carcinogens and toxic materials.
Table 5 shows a comparison of the formulas of Example 5 (PAP 7993) and a batch of M1 material. A non-toxic, citrate type plasticizes Acetyl-triethyl-citrate (ATEC) was selected as replacement for DNT and DBP. The first pilot propellant sample (Example 5) was manufactured at a pilot plant using a conventional ether/alcohol solvent system. The samples were characterized for their stability, density, and burning rate characteristics.
Based on the test results, the M1 modified formulation PAP
7993 had similar burning characteristics to the as M1 propellant and its energy content was also comparable with relative force of 97~ of the M1 reference lot RAD92C071664.
It is believed that the slightly lower energy content of the composition of Example 5 (DNT, DBP, DPA free) can be compensated by increasing the charge weight in the case to give equivalent performance compared to M1 propellant.
PROPELLANT COMPOSITION
(Example 5 -PAP
7993) PERCENT PERCENT
CONSTITUENT EXAMPLE 5 (7993) RAD92C071669 Nitrocellulose 88.00 85.00 (NC) (13.15~N) Acetyltriethyl 10.00 Citrate (ATEC) EC 1.00 KN 1.00 Dinitrololuene 10.00 (DNT) Dibuylphthalate 5.00 (DBP) TOTAL 100.00 100.00 Diphenylamine 1.00 (DPA) GRAPHITE GLAZE 1.00 Impetus (J/g) 932 929 Flame temp (K) 2583 2522 Dimensions: PAP 7993 RAD92C071669 Grain length 0.252 0.221 Grain 0.050 0.052 diameter Perf diameter 0.015 0.020 Web 0.018 0.016 Density 1.56 1.57 (g/cc) Vacuum Stability 1.21(ml gas) Closed Bomb results:
Coefficient 0.00223 0.00874 Pressure 0.742 0.831 exponent RQ 92.47 100.00 RF 97.04 100.00 12,000 psi 2.366 2.147 14,000 2.647 2.424 16, 000 2 . 929 2 .714 18, 000 3.178 2.987 20,000 3.46 3.284 Table 6 shows the ballistic firing results of the new formulation PAP 7993 in the XM231 charge configuration for the 155 mm Howitzer. These data show that the new formulation meets all of the requirements for the XM231 charge.
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.. , , This invention has been described herein in considerable detail in order to comply with the Patent Statutes-and to provide those skilled in the art with the information needed to apply the novel principles and to construct and use embodiments of the example as required.
However, it is to be understood that the invention can be carried out by specifically different devices and that various modifications can be accomplished without departing from the scope of the invention itself.
What is claimed is:
The preferred compounds in accordance with the invention include certain adipate and/or citrate compounds including diisobutyl adipate (DIBA), diisooctly adipate (DIOA), acetyltriethyl citrate (ATEC), acetyltri-n-butyl citrate, triethyl citrate and tributyl citrate. Exemplary propellant compositions include from about 94-96$ high N
nitrocellulose (about 13.2$ N), about 2-4~ plasticizer and the remainder dibutylphthalate (DBP). The DBP provides additional plasticizing qualities. In addition, a small amount, nominally 1$, diphenylamine (DPA) is added to the mix as a thermal stabilizing material.
Additional embodiments include up to about 10~ or more ATEC and no DNT or DBP. These compositions contain a lesser amount of high N nitrocellulose (about 88-90$). These formulations may also contain ethyl cellulose as the stabilizer in place of the DPA. These compositions containing approximately 10~ of the new plasticizer system result in lower energy levels that are comparable to currently produced Artillery propellants such as M1, or approximately 930 J/g impetus.
The propellant combination of the invention containing the environmentally friendly plasticizing materials can be processed using conventional single base solvent processing techniques including conventional solvents, presses, extrusion and cutting devices and solvent recovery techniques.
BRIEF DESCRIPTION OF THE DRAWINGS
In the drawings:
Figure 1 shows the accelerated aging properties of certain new compositions according to the invention relative to M14; and Figure 2 depicts ballistic test results using a Gamma Dynagun for a composition of the invention with M19 energetics.
DETAILED DESCRIPTION
In accordance with the invention, improvements have been made in single base propellant compositions which enable them to be more friendly to those engaged in the manufacturing processes and more compatible with the environment. This has been accomplished, for the most part, by eliminating dinitrotoluene (DNT) from single base propellants which is a component that has possessed attributes with regard to enhancing propellant properties but which, at the same time, has presented both a hazard to the people engaged in the manufacturing process and an environmental menace from the standpoint of creating hazardous waste materials in effluents, particularly when burned (as poly aromatic hydrocarbons) and in waste water.
According to the invention, there have been discovered certain plasticizing compounds which enable substitution for DNT without sacrificing overall propellant performance.
These compounds can sufficiently plasticize high N
nitrocellulose (NC) sufficiently to enable proper processing into grains suitable for use in large caliber munitions, particularly, 155 mm Artillery charges and 120 mm tank ammunition.
Thus, it has been discovered that certain citrate and adipate compounds successfully plasticize high N
nitrocellulose (NC) in single base propellant systems utilizing sufficiently low percentages of these non-energetic materials such that additional percentages of NC
can be incorporated,in the formula thereby maintaining the overall energy output substantially constant.
It should be noted that a variety of materials have been evaluated in this regard including adipates and _g_ citrates, phthlates, polycaprolactones, ureas, urethanes and other materials. Attributes desired and evaluated include ability to plasticize NC, toxicity, processing/physical characteristics (compatibility with single base processing solvents and equipment) and mechanical characteristics imparted to the mix, prior usage in propellants, energetic qualities, availability and cost.
As previously noted, DNT has a long history of successful prior usage and its ability to plasticize NC and create processible physical characteristics in the mix. DNT, of course, is moderately energetic and the presence of larger percentages of it does not reduce the overall energy output of the propellant material. Thus, it was quite unexpected that DNT could be replaced using a low or negative energy material without sacrificing the overall performance of the mix.
In accordance with the invention, it has been discovered that a number of citrate compounds, together with at least one adipate successfully meet the necessary criteria for substituting for DNT in single base munition propellants. Thus, according to the present invention, it has been found that diisobutyl adipate (RIBA) available, for example, as Plasthall DIBA from the C.P. Hall Company, Memphis, Tennessee, acetyltriethyl citrate (ATEC) available as Citroflex~ A-2 from Morflex, Inc., Greensboro, North Carolina, and acetyltri-n-butyl citrate available as Citroflex A-4 also from Morflex, Inc. were especially successful. Other citrates, including triethyl citrate, available as Citroflex 2, and tributyl citrate, available as Citroflex 4, both from Morflex, Inc., of Greensboro, North Carolina, were also usable.
According to the invention, then, it has been discovered that DNT-free single base propellants containing from 2-10~ by weight of these new plasticizers display the desirable ballistic, mechanical, thermochemical and stability properties of standard DNT-containing propellant formulations. An important property of these plasticizers is that they can be added to the propellant in a standard pre-mixed form with the processing solvents typically used in single base processes. The plasticizers are relatively non-toxic and are environmentally acceptable under current governmental regulations.
The processing solvents for processing single base propellants include conventional solvents for NC which vary depending on the N content of the nitrocellulose.
Thus, high grade nitrocellulose which has above about 13.15$ N is practically insoluble in ether, but is readily dispersed by plasticizers and acetone. Below about 13.15$ N, either can be used. In some cases, combinations of acetone or ether and other solvents such as alcohols or other ketones are preferred.
In any event, in normal solvent-type processing, solid blocks of NC are broken and blended into the solvent together with an amount of the desired plasticizing agent, which is added or blended in from a slurry utilizing common solvents. Additional stabilizing materials are added prior to final mixing of the solubilized/plasticized nitrocellulose. The ability to add the plasticizers dispersed in a common solvent or solvents, of course, improves the uniformity of the mix and reduces the time of the mixing cycle. In addition to the other ingredients, if more solvent is needed, this is added to the material in the final mix or possibly in stages during the mix. After all the ingredients have been added to the mixer, the mix cycle continues for a given period of time, possibly 1 hour, until the single base propellant is thoroughly mixed.
After the mixing operation has been completed, the mixed propellant is dried by removal and recovery of some of the solvent from the mixed batch until a desired level of plasticity is achieved. Adjustment procedure steps, including drying and adding solvent, may continue until the correct plasticity is achieved and thereafter the mixer is run for a short time to allow the solvent to equalize throughout the mix.
After mixing has been completed and the proper solvent level reached, the material is transferred to a blocking press where it is subjected to a high pressure hydraulic ram to pressurize the material to remove occluded air, improve consolidation and form the blocks into the proper shape for the Braining press.
The blocked material is then transferred to the Braining press. In the Braining press, various techniques are utilized to extrude strands of propellant depending on the desired final configuration or use. The strands of propellant are cut to a specified length for further drying prior to final cutting into actual grain length.
The extruded material is dried in a manner which saves and recovers as much solvent as is practical for reuse and so the first step is normally to process the load in a solvent recovery tank. The material is then subjected to a water-dry operation where additional solvents are extracted into the water and thereafter to an air-dry cycle where the surface moisture is removed. Processing of the new compositions may also be accomplished in new continuos processes where the batch operations are replaced by continuous mixers, extruders and solvent removal.
Having presented an overview of the invention, additional information with respect to certain specific examples, which are intended to exemplify rather than to limit the scope o~ the invention, will next be presented.
Much of the information is in the form of tabular data criteria which will be familiar to those skilled in the art.
Table 1 shows a prior formulation utilizing dinitrotoluene (DNT) as the principle plasticizer and energy adjustment compound. The composition is an example of a mix generally known as M14 and nominally contains about 8$ DNT. Note that the specific example contained 8.29$ DNT and 2$ DBP.
PERCENT
NITROCELLULOSE 90.00 DINITROTOLUENE 8.00 DIBUTYLPHTHALATE 2.00 TOTAL 100.00 DIPHENYLAMINE 1.00 (ADDED) MOISTURE 0.6 RESIDUAL SOLVENT 0.7 GRAPHITE GLAZE 0.2 Table 2A shows three examples (Example 1, Example 2 and Example 3) of percentage compositions formulated in accordance with the present invention in which lesser amounts of the material known as plasticizer "340" has been substituted for the DNT fraction and the percentage of NC
increased. The material known as plasticizer "340" is diisobutyl adipate or (DIBA) available as Plastall DIBA
from the C.P. Hall Company.
TABLE ' 2A
PROPELLANT COMPOSITION
EXAMPLE EXAMPLE EXAMPLE
PERCENT PERCENT PERCENT PERCENT
CONSTITUENT FORMULA MEASURED MEASURED MEASURE
D
NITROCELLULOSE 96.00 96.23 96.09 96.14 PLASTICIZER "340" 2.10 1.95 2.01 1.99 DIBUTYLPHTHALATE 1.90 1.82 1.90 1.87 TOTAL 100.00 DIPHENYLAMINE 1.00 0.97 1.00 0.98 MOISTURE 0.6 0.7 0.6 0.6 RESIDUAL SOLVENT 0.7 0.9 0.8 0.5 GRAPHITE GLAZE 0.2 0.1 0.1 0.1 PROPELLANT COMPOSITION
,.
PERCENT PERCENT
CONSTITUENT FORMULA MEASURED
NITROCELLULOS 95.00 95.04 E
PLASTICIZER 3.10 3.08 "340"
DIBUTYLPHTHAL 1.90 1.88 ATE
TOTAL 100.00 DIPHENYLAMINE 1.00 1.08 MOISTURE 0.6 0.5 RESIDUAL 0.7 0.5 SOLVENT
GRAPHITE 0.2 0.1 GLAZE
Table 2B depicts an additional example, Example 4, in which the DNT fraction is replaced by a lesser amount of a material known as plasticizer "319", which is acetyltriethyl citrate, purchased as Citroflex A-2 from Morflex, Inc.
The stability and physical test result with respect to Examples 1-4 and which correspond to the tests conducted for the prior art DNT-containing material M14 are shown in Table 3. From this it can be seen that the hygroscopicity is slightly higher owing to the superior hygroscopicity reducing properties of DNT, in larger quantities.
Percentages in Examples 1-4, however, are still within tolerable limits and, as can be seen from the remainder of Table 3 and from the closed bomb testing of Examples 1-4 described in Table 4, that the performance and stability of the DNT-free material is comparable to that of M14.
~a>tr_: .
STABILITY AND
PHYSICAL TEST
rvnu~ n r t TEST FORMUIJi ACTUAL ACTUAL ACTUAL ACTUAL
HEAT TEST SP. NO CC 10' CC 60+ CC 60+ CC 60+ CC 60+
131.5 Deg. C
NO EXPLOSION 5 Hrs MIN NE 5 HRS NE 5 HRS NE 5 HRS NE 5 HRS
FORM OF PROPELIJWTCYLINDRICALCYL CYL CYL CYL
BULK DENSITY, INFO 52.29 50.37 18.19 50.78 L8S/CUfT
HOE,cal/g INFO 855.1 858.2 861.6 851.3 HYGROSCOPICITY. INFO 0.99 1.00 1.09 0.98 a ABSOLUTE DENSITY,G/CCINFO 1.54 1.56 1.51 1.5 lfT. UNIFORMITY INFO 110.5 100.8 65.0 121.3 f100 Gtslna). G
TJIiI~ 1 CLOSED BaMBS
rveuorr t rvnuorr Z. rvnuair ~ rvnuorr w TEMPRELATIVERELATIVERELATIVERELATIVERELA?IVERELATIVERELATIVERELATIVE
Oay.QUICKNESSFORCE QUICKNESSFORCE QUICKNESSFORCE QUICKNESSFORCE
+90 85.9 98.1 91.3 98.9 103.8 99.7 85.9 98.1 TEST
-10 82.3 98.2 86.2 98.5 97.3 97.7 82.3 913.2 111592.9 100.9 97.5 100.7 107.7 101.6 92.9 100.9 STD +90 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 Z~
Figure 1 shows the accelerated aging properties of the new composition s) relative to M14 at 150° F. Results of the long term aging show that these formulations age at a comparable rate to the standard M14 propellant.
15 Figure 2A shows ballistic test results from the Gamma Dynagun for the new composition with M19 energetics. The Gamma Dynagun is an interior ballistics test device based on a 105 Howitzer that allows assessment of required charge weights to obtain comparable muzzle velocities and 20 pressures to a standard propellant lot. It can be seen from Figure 2 that the charge weight of the new composition is within the same statistical population as the standard M14 propellant lot and a number of production lots of M14.
As can be seen from the description and examples herein, it is now possible to replace the DNT traction in propellant materials such as M14 without sacrificing other desirable propellant properties. The use of other materials, particularly citrate and adipate compounds, is also promising. Note that the formulation requires less plasticizes than those utilizing DNT allowing these negative energy materials to be compensated by the addition of more NC in the formula.
Example 5 depicts in Table 5 another single base propellant that does not contain either Dinitrotoluene (DNT) or Dibutyl-phthlate (DBP). DNT and DBP as indicated are the two ingredients currently used in the M1 propellant that are considered as carcinogens and toxic materials.
Table 5 shows a comparison of the formulas of Example 5 (PAP 7993) and a batch of M1 material. A non-toxic, citrate type plasticizes Acetyl-triethyl-citrate (ATEC) was selected as replacement for DNT and DBP. The first pilot propellant sample (Example 5) was manufactured at a pilot plant using a conventional ether/alcohol solvent system. The samples were characterized for their stability, density, and burning rate characteristics.
Based on the test results, the M1 modified formulation PAP
7993 had similar burning characteristics to the as M1 propellant and its energy content was also comparable with relative force of 97~ of the M1 reference lot RAD92C071664.
It is believed that the slightly lower energy content of the composition of Example 5 (DNT, DBP, DPA free) can be compensated by increasing the charge weight in the case to give equivalent performance compared to M1 propellant.
PROPELLANT COMPOSITION
(Example 5 -PAP
7993) PERCENT PERCENT
CONSTITUENT EXAMPLE 5 (7993) RAD92C071669 Nitrocellulose 88.00 85.00 (NC) (13.15~N) Acetyltriethyl 10.00 Citrate (ATEC) EC 1.00 KN 1.00 Dinitrololuene 10.00 (DNT) Dibuylphthalate 5.00 (DBP) TOTAL 100.00 100.00 Diphenylamine 1.00 (DPA) GRAPHITE GLAZE 1.00 Impetus (J/g) 932 929 Flame temp (K) 2583 2522 Dimensions: PAP 7993 RAD92C071669 Grain length 0.252 0.221 Grain 0.050 0.052 diameter Perf diameter 0.015 0.020 Web 0.018 0.016 Density 1.56 1.57 (g/cc) Vacuum Stability 1.21(ml gas) Closed Bomb results:
Coefficient 0.00223 0.00874 Pressure 0.742 0.831 exponent RQ 92.47 100.00 RF 97.04 100.00 12,000 psi 2.366 2.147 14,000 2.647 2.424 16, 000 2 . 929 2 .714 18, 000 3.178 2.987 20,000 3.46 3.284 Table 6 shows the ballistic firing results of the new formulation PAP 7993 in the XM231 charge configuration for the 155 mm Howitzer. These data show that the new formulation meets all of the requirements for the XM231 charge.
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C ~ M
~
Z O tj c ~ 07 ~ y '' w: l .
n L' H t"~
n , n m .
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3 a o .t E
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.. , , This invention has been described herein in considerable detail in order to comply with the Patent Statutes-and to provide those skilled in the art with the information needed to apply the novel principles and to construct and use embodiments of the example as required.
However, it is to be understood that the invention can be carried out by specifically different devices and that various modifications can be accomplished without departing from the scope of the invention itself.
What is claimed is:
Claims (17)
1. A plasticizer material suitable for a DNT-free single base propellant formulation containing an amount of material selected from citrate and adipate compounds.
2. The plasticizer of claim 1 wherein said citrate is selected from. the group consisting of acetyltriethyl citrate and acetyltri-n-butyl citrate and mixtures thereof.
3. The plasticizer of claim 1 wherein said adipate is diisobutyl adipate (DIBA).
4. A DNT-free, single base propellant containing an amount of a plasticizer selected from the group consisting of citrates and adipates.
5. The propellant of claim 4 wherein said citrate is selected from the group consisting of acetyltriethyl citrate and acetyltri-n-butyl citrate and mixtures thereof.
6. The propellant of claim 9 wherein said adipate is diisobutyl adipate (DIBA).
7. A DNT-free,single base propellant comprising:
(a) from about 93 to about 97% nitrocellulose (NC);
(b) from about 2-5% of a plasticizer selected from the group consisting of citrates and adipates;
and (c) about 2% dibutylphthalate (DBP).
(a) from about 93 to about 97% nitrocellulose (NC);
(b) from about 2-5% of a plasticizer selected from the group consisting of citrates and adipates;
and (c) about 2% dibutylphthalate (DBP).
8. The propellant of claim 7 wherein said citrate is selected from the group consisting of acetyltriethyl citrate and acetyltri-n-butyl citrate and mixtures thereof.
9. The propellant of claim 8 wherein said adipate is diisobutyl adipate (DIBA).
10. A DNT and DBP-free, single base propellant comprising:
(a) from about 88% to about 90%$ nitrocellulose (NC);
(b) from about 4% to about 10% citrate plasticizer;
(a) from about 88% to about 90%$ nitrocellulose (NC);
(b) from about 4% to about 10% citrate plasticizer;
11. The propellant of claim 10 further carrying about 1% ethyl centralite (EC).
12. The propellant of claim 11 further comprising from 0 to 1% of K2SO4 or KNO3.. 3. The propellant of claim 10 further comprising from 0% to about 1 % of KNO3 or
K2SO4.
14. A plasticizer composition suitable for a DNT and DBP-free, single base propellant composition containing an amount of citrate comprising acetyltriethyl citrate (ATEC).
15. The plasticizer of claim 14 further comprising an amount of, ethyl centralite.
16. The plasticizer of claim 10 wherein the citrate is ATEC.
17. The propellant of claim 4 wherein said plasticiser is present in an amount from about 2% to about 10%.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8168498P | 1998-04-14 | 1998-04-14 | |
US60/081,684 | 1998-04-14 | ||
PCT/US1999/007737 WO1999059939A2 (en) | 1998-04-14 | 1999-04-14 | Dinitrotoluene (dnt)-free single base propellant |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2326133A1 true CA2326133A1 (en) | 1999-11-25 |
Family
ID=22165727
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002326133A Abandoned CA2326133A1 (en) | 1998-04-14 | 1999-04-14 | Dinitrotoluene (dnt)-free single base propellant |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1077910A2 (en) |
AU (1) | AU756188B2 (en) |
CA (1) | CA2326133A1 (en) |
WO (1) | WO1999059939A2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6620269B1 (en) * | 2000-09-26 | 2003-09-16 | Breed Automotive Technology, Inc. | Autoignition for gas generators |
DE10152397B4 (en) * | 2001-10-24 | 2009-08-06 | BOWAS AG für Industrievertrieb | Preparation of solvent-free propellant powder |
JP5401888B2 (en) * | 2008-09-24 | 2014-01-29 | 日油株式会社 | Single base propellant |
LT3642175T (en) * | 2017-06-23 | 2024-06-25 | Knds Ammo Italy S.P.A. | Composition for single-base propelling powder for ammunition and ammunition provided with such composition |
RU2746078C1 (en) * | 2020-08-21 | 2021-04-06 | Федеральное казенное предприятие "Государственный научно-исследовательский институт химических продуктов" (ФКП "ГосНИИХП") | Dual spherical powder for 12.7 mm cartridge with armor-piercing incendiary bullet |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE567878C (en) * | 1930-06-26 | 1933-01-18 | Du Pont | Process for the production of smokeless, muzzle-fire-free nitrocellulose powder |
US2027114A (en) * | 1932-03-12 | 1936-01-07 | Western Cartridge Co | Manufacture of smokeless powders |
DE1099418B (en) * | 1959-03-06 | 1961-02-09 | Olin Mathieson | Process for the production of powder kernels |
DE1203652B (en) * | 1964-02-18 | 1965-10-21 | Wolff & Co Ag | Process for the production of gelatinized nitrocellulose |
GB1093544A (en) * | 1966-05-13 | 1967-12-06 | Du Pont | Explosive |
US3734793A (en) * | 1971-12-29 | 1973-05-22 | Lory Ind Inc | Nitrocellulose combustible composition having salt of polyethylenimine as oxidizer |
US5218166A (en) * | 1991-09-20 | 1993-06-08 | Mei Corporation | Modified nitrocellulose based propellant composition |
DE29501100U1 (en) * | 1995-01-24 | 1996-05-30 | Hagedorn AG, 49078 Osnabrück | Plasticized cellulose nitrate |
-
1999
- 1999-04-14 WO PCT/US1999/007737 patent/WO1999059939A2/en not_active Application Discontinuation
- 1999-04-14 CA CA002326133A patent/CA2326133A1/en not_active Abandoned
- 1999-04-14 AU AU57691/99A patent/AU756188B2/en not_active Ceased
- 1999-04-14 EP EP99944981A patent/EP1077910A2/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
WO1999059939A2 (en) | 1999-11-25 |
WO1999059939A3 (en) | 2000-01-27 |
AU756188B2 (en) | 2003-01-09 |
EP1077910A2 (en) | 2001-02-28 |
AU5769199A (en) | 1999-12-06 |
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Legal Events
Date | Code | Title | Description |
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EEER | Examination request | ||
FZDE | Discontinued |