CA2303638A1 - Single- or multi-phase detergent tablets containing special bleach activators - Google Patents

Single- or multi-phase detergent tablets containing special bleach activators Download PDF

Info

Publication number: CA2303638A1
Authority: CA; Canada
Prior art keywords: tablet; weight; phase; alkyl; tablets
Prior art date: 1999-03-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002303638A

Other languages

English (en)

French (fr)

Inventor

Joerg Poethkow

Horst-Dieter Speckmann

Andreas Lietzmann

Monika Boecker

Christian Nitsch

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-03-31

Filing date

2000-03-31

Publication date

2000-09-30

2000-03-31 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2000-09-30 Publication of CA2303638A1 publication Critical patent/CA2303638A1/en

Status Abandoned legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 120
239000007844 bleaching agent Substances 0.000 title claims abstract description 105
239000012190 activator Substances 0.000 title claims abstract description 54
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 139
-1 cationic nitrites Chemical class 0.000 claims abstract description 77
125000000217 alkyl group Chemical group 0.000 claims abstract description 34
239000007864 aqueous solution Substances 0.000 claims abstract description 17
125000001424 substituent group Chemical group 0.000 claims abstract description 13
125000003342 alkenyl group Chemical group 0.000 claims abstract description 11
150000001450 anions Chemical group 0.000 claims abstract description 11
125000005024 alkenyl aryl group Chemical group 0.000 claims abstract description 10
125000003118 aryl group Chemical group 0.000 claims abstract description 7
125000000547 substituted alkyl group Chemical group 0.000 claims abstract description 5
238000000034 method Methods 0.000 claims description 49
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 47
125000002091 cationic group Chemical group 0.000 claims description 45
239000002245 particle Substances 0.000 claims description 39
102000004190 Enzymes Human genes 0.000 claims description 36
108090000790 Enzymes Proteins 0.000 claims description 36
229920002678 cellulose Polymers 0.000 claims description 34
239000004094 surface-active agent Substances 0.000 claims description 31
239000001913 cellulose Substances 0.000 claims description 25
239000002304 perfume Substances 0.000 claims description 20
239000004615 ingredient Substances 0.000 claims description 19
239000003112 inhibitor Substances 0.000 claims description 18
239000002736 nonionic surfactant Substances 0.000 claims description 18
239000000126 substance Substances 0.000 claims description 17
239000003945 anionic surfactant Substances 0.000 claims description 16
239000008187 granular material Substances 0.000 claims description 14
238000004519 manufacturing process Methods 0.000 claims description 13
239000000975 dye Substances 0.000 claims description 11
238000005260 corrosion Methods 0.000 claims description 8
230000007797 corrosion Effects 0.000 claims description 8
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 7
125000000129 anionic group Chemical group 0.000 claims description 7
229910052709 silver Inorganic materials 0.000 claims description 7
239000004332 silver Substances 0.000 claims description 7
230000001012 protector Effects 0.000 claims description 6
230000003287 optical effect Effects 0.000 claims description 5
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 5
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 claims description 4
BNNMDMGPZUOOOE-UHFFFAOYSA-N 4-methylbenzenesulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1.CC1=CC=C(S(O)(=O)=O)C=C1 BNNMDMGPZUOOOE-UHFFFAOYSA-N 0.000 claims description 4
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 claims description 4
238000002845 discoloration Methods 0.000 claims description 4
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 4
238000012546 transfer Methods 0.000 claims description 4
229940071104 xylenesulfonate Drugs 0.000 claims description 4
239000000969 carrier Substances 0.000 claims description 3
239000006260 foam Substances 0.000 claims description 3
229920002545 silicone oil Polymers 0.000 claims description 3
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims 2
238000004061 bleaching Methods 0.000 abstract description 13
239000000203 mixture Substances 0.000 description 58
229940088598 enzyme Drugs 0.000 description 33
235000010980 cellulose Nutrition 0.000 description 32
239000002253 acid Substances 0.000 description 31
150000003839 salts Chemical class 0.000 description 31
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
239000010457 zeolite Substances 0.000 description 27
239000010410 layer Substances 0.000 description 25
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 24
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 21
229910021536 Zeolite Inorganic materials 0.000 description 20
235000019441 ethanol Nutrition 0.000 description 20
125000004432 carbon atom Chemical group C* 0.000 description 18
239000000306 component Substances 0.000 description 18
150000007513 acids Chemical class 0.000 description 17
235000019832 sodium triphosphate Nutrition 0.000 description 17
108091005804 Peptidases Proteins 0.000 description 15
239000004365 Protease Substances 0.000 description 15
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 15
150000001875 compounds Chemical class 0.000 description 15
229910052708 sodium Inorganic materials 0.000 description 14
239000000243 solution Substances 0.000 description 14
230000000694 effects Effects 0.000 description 13
238000011049 filling Methods 0.000 description 13
230000002366 lipolytic effect Effects 0.000 description 13
239000003921 oil Substances 0.000 description 13
235000019198 oils Nutrition 0.000 description 13
239000011734 sodium Substances 0.000 description 13
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
150000002191 fatty alcohols Chemical class 0.000 description 12
239000000047 product Substances 0.000 description 12
238000005406 washing Methods 0.000 description 12
108090001060 Lipase Proteins 0.000 description 11
102000004882 Lipase Human genes 0.000 description 11
239000004367 Lipase Substances 0.000 description 11
235000014113 dietary fatty acids Nutrition 0.000 description 11
239000000194 fatty acid Substances 0.000 description 11
229930195729 fatty acid Natural products 0.000 description 11
235000019421 lipase Nutrition 0.000 description 11
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
150000004760 silicates Chemical class 0.000 description 10
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
150000001298 alcohols Chemical class 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 9
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 9
238000002844 melting Methods 0.000 description 9
230000008018 melting Effects 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
229910052700 potassium Inorganic materials 0.000 description 9
239000011591 potassium Substances 0.000 description 9
235000019419 proteases Nutrition 0.000 description 9
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
108010065511 Amylases Proteins 0.000 description 8
102000013142 Amylases Human genes 0.000 description 8
229920002245 Dextrose equivalent Polymers 0.000 description 8
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical class OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 8
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
235000019418 amylase Nutrition 0.000 description 8
238000000576 coating method Methods 0.000 description 8
239000000843 powder Substances 0.000 description 8
238000003825 pressing Methods 0.000 description 8
229940045872 sodium percarbonate Drugs 0.000 description 8
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 8
102000004157 Hydrolases Human genes 0.000 description 7
108090000604 Hydrolases Proteins 0.000 description 7
229910019142 PO4 Inorganic materials 0.000 description 7
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 7
239000003054 catalyst Substances 0.000 description 7
150000004665 fatty acids Chemical class 0.000 description 7
239000012013 faujasite Substances 0.000 description 7
230000007062 hydrolysis Effects 0.000 description 7
238000006460 hydrolysis reaction Methods 0.000 description 7
239000000463 material Substances 0.000 description 7
235000021317 phosphate Nutrition 0.000 description 7
150000003013 phosphoric acid derivatives Chemical class 0.000 description 7
229920003023 plastic Polymers 0.000 description 7
239000004033 plastic Substances 0.000 description 7
229920005646 polycarboxylate Polymers 0.000 description 7
229910000029 sodium carbonate Inorganic materials 0.000 description 7
238000003860 storage Methods 0.000 description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
239000004375 Dextrin Substances 0.000 description 6
229920001353 Dextrin Polymers 0.000 description 6
102000035195 Peptidases Human genes 0.000 description 6
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 6
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
229940025131 amylases Drugs 0.000 description 6
239000011248 coating agent Substances 0.000 description 6
235000019425 dextrin Nutrition 0.000 description 6
238000004090 dissolution Methods 0.000 description 6
235000011007 phosphoric acid Nutrition 0.000 description 6
239000000344 soap Substances 0.000 description 6
239000001488 sodium phosphate Substances 0.000 description 6
239000001226 triphosphate Substances 0.000 description 6
108010059892 Cellulase Proteins 0.000 description 5
108010084185 Cellulases Proteins 0.000 description 5
102000005575 Cellulases Human genes 0.000 description 5
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 5
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 5
239000013543 active substance Substances 0.000 description 5
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 5
238000004140 cleaning Methods 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
238000004851 dishwashing Methods 0.000 description 5
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 5
239000010419 fine particle Substances 0.000 description 5
238000005469 granulation Methods 0.000 description 5
230000003179 granulation Effects 0.000 description 5
125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
239000000178 monomer Substances 0.000 description 5
239000002994 raw material Substances 0.000 description 5
159000000000 sodium salts Chemical class 0.000 description 5
235000000346 sugar Nutrition 0.000 description 5
239000003760 tallow Substances 0.000 description 5
229910052723 transition metal Inorganic materials 0.000 description 5
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
239000004382 Amylase Substances 0.000 description 4
235000008733 Citrus aurantifolia Nutrition 0.000 description 4
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
102000004316 Oxidoreductases Human genes 0.000 description 4
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229920002472 Starch Polymers 0.000 description 4
235000011941 Tilia x europaea Nutrition 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 4
150000001408 amides Chemical class 0.000 description 4
229940106157 cellulase Drugs 0.000 description 4
150000001868 cobalt Chemical class 0.000 description 4
238000000354 decomposition reaction Methods 0.000 description 4
230000003111 delayed effect Effects 0.000 description 4
239000001177 diphosphate Substances 0.000 description 4
238000009826 distribution Methods 0.000 description 4
UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
238000009472 formulation Methods 0.000 description 4
239000008103 glucose Substances 0.000 description 4
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
239000004571 lime Substances 0.000 description 4
235000019796 monopotassium phosphate Nutrition 0.000 description 4
229910000402 monopotassium phosphate Inorganic materials 0.000 description 4
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 4
150000004965 peroxy acids Chemical class 0.000 description 4
125000000864 peroxy group Chemical group O(O*)* 0.000 description 4
229920006324 polyoxymethylene Polymers 0.000 description 4
BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 4
230000002829 reductive effect Effects 0.000 description 4
235000019698 starch Nutrition 0.000 description 4
239000004753 textile Substances 0.000 description 4
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
239000004115 Sodium Silicate Substances 0.000 description 3
239000002535 acidifier Substances 0.000 description 3
239000001361 adipic acid Substances 0.000 description 3
235000011037 adipic acid Nutrition 0.000 description 3
150000001299 aldehydes Chemical class 0.000 description 3
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 3
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
150000001720 carbohydrates Chemical class 0.000 description 3
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239000007795 chemical reaction product Substances 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
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239000000470 constituent Substances 0.000 description 3
238000002425 crystallisation Methods 0.000 description 3
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150000004691 decahydrates Chemical class 0.000 description 3
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XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 3
235000011180 diphosphates Nutrition 0.000 description 3
ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 3
229910000397 disodium phosphate Inorganic materials 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000004744 fabric Substances 0.000 description 3
239000003925 fat Substances 0.000 description 3
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125000003147 glycosyl group Chemical group 0.000 description 3
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238000010438 heat treatment Methods 0.000 description 3
150000002576 ketones Chemical class 0.000 description 3
229910052748 manganese Inorganic materials 0.000 description 3
239000011572 manganese Substances 0.000 description 3
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239000002243 precursor Substances 0.000 description 3
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238000006384 oligomerization reaction Methods 0.000 description 1
229920001542 oligosaccharide Polymers 0.000 description 1
150000002482 oligosaccharides Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000007530 organic bases Chemical class 0.000 description 1
125000005429 oxyalkyl group Chemical group 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
239000003346 palm kernel oil Substances 0.000 description 1
235000019865 palm kernel oil Nutrition 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
229960005382 phenolphthalein Drugs 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
229940067107 phenylethyl alcohol Drugs 0.000 description 1
QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
229960001553 phloroglucinol Drugs 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
150000003016 phosphoric acids Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
150000003021 phthalic acid derivatives Chemical class 0.000 description 1
239000006223 plastic coating Substances 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
150000003109 potassium Chemical class 0.000 description 1
OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
238000004886 process control Methods 0.000 description 1
POSICDHOUBKJKP-UHFFFAOYSA-N prop-2-enoxybenzene Chemical compound C=CCOC1=CC=CC=C1 POSICDHOUBKJKP-UHFFFAOYSA-N 0.000 description 1
229940079877 pyrogallol Drugs 0.000 description 1
230000011514 reflex Effects 0.000 description 1
239000005871 repellent Substances 0.000 description 1
230000002940 repellent Effects 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
238000005185 salting out Methods 0.000 description 1
239000010671 sandalwood oil Substances 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical class O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000002893 slag Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
150000003388 sodium compounds Chemical class 0.000 description 1
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
235000019830 sodium polyphosphate Nutrition 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229940012831 stearyl alcohol Drugs 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
235000007586 terpenes Nutrition 0.000 description 1
229940116411 terpineol Drugs 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
229960002622 triacetin Drugs 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
229940062627 tribasic potassium phosphate Drugs 0.000 description 1
ZKWDCFPLNQTHSH-UHFFFAOYSA-N tribromoisocyanuric acid Chemical compound BrN1C(=O)N(Br)C(=O)N(Br)C1=O ZKWDCFPLNQTHSH-UHFFFAOYSA-N 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
235000019798 tripotassium phosphate Nutrition 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
239000010679 vetiver oil Substances 0.000 description 1
239000011800 void material Substances 0.000 description 1
239000004552 water soluble powder Substances 0.000 description 1
ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/3925—Nitriles; Isocyanates or quarternary ammonium nitriles
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

CA002303638A 1999-03-31 2000-03-31 Single- or multi-phase detergent tablets containing special bleach activators Abandoned CA2303638A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19914812.0		1999-03-31
DE19914812A DE19914812A1 (de)	1999-03-31	1999-03-31	Ein- oder mehrphasige Wasch- und Reinigungsmittelformkörper mit speziellen Bleichaktivatoren

Publications (1)

Publication Number	Publication Date
CA2303638A1 true CA2303638A1 (en)	2000-09-30

Family

ID=7903208

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002303638A Abandoned CA2303638A1 (en)	1999-03-31	2000-03-31	Single- or multi-phase detergent tablets containing special bleach activators

Country Status (8)

Country	Link
EP (1)	EP1165742B1 (de)
JP (1)	JP2002541302A (de)
KR (1)	KR20010110469A (de)
AU (1)	AU3814200A (de)
CA (1)	CA2303638A1 (de)
DE (2)	DE19914812A1 (de)
ES (1)	ES2255995T3 (de)
WO (1)	WO2000060035A2 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7030075B2 (en)	2002-12-18	2006-04-18	Procter & Gamble Company	Organic activator

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ES2290242T5 (es) *	2002-12-24	2015-07-13	Dalli-Werke Gmbh & Co. Kg	Sistema de detergente y producto de limpieza optimizado para una acción blanqueante mejorada a bajas temperaturas
DE10314441A1 (de) *	2003-03-31	2004-10-21	Henkel Kgaa	Bleichaktivator-Compounds
US10280386B2 (en)	2015-04-03	2019-05-07	Ecolab Usa Inc.	Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid
US9783766B2 (en)	2015-04-03	2017-10-10	Ecolab Usa Inc.	Enhanced peroxygen stability using anionic surfactant in TAED-containing peroxygen solid
CA3102614C (en)	2018-06-15	2023-02-28	Ecolab Usa Inc.	Enhanced peroxygen stability using fatty acid in bleach activating agent containing peroxygen solid
JP7252601B2 (ja) *	2019-02-08	2023-04-05	株式会社ニイタカ	固形洗浄剤組成物、カートリッジ洗浄剤、洗浄方法、及び、微生物の除菌方法又は菌叢凝塊の除去方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9011618D0 (en) *	1990-05-24	1990-07-11	Unilever Plc	Bleaching composition
GB9012001D0 (en) *	1990-05-30	1990-07-18	Unilever Plc	Bleaching composition
GB9022724D0 (en) *	1990-10-19	1990-12-05	Unilever Plc	Detergent compositions
AU6413096A (en) *	1995-07-13	1997-02-10	Joh. A. Benckiser Gmbh	Dish washer product in tablet form
DE19758183A1 (de) *	1997-12-30	1999-07-01	Henkel Kgaa	Waschaktiver Formkörper mit spezifischer Oberfläche
JP2002532615A (ja) *	1998-12-15	2002-10-02	ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン	漂白活性剤としてのアセトニトリル誘導体

1999
- 1999-03-31 DE DE19914812A patent/DE19914812A1/de not_active Withdrawn
2000
- 2000-03-22 EP EP00916991A patent/EP1165742B1/de not_active Expired - Lifetime
- 2000-03-22 DE DE50012128T patent/DE50012128D1/de not_active Expired - Fee Related
- 2000-03-22 ES ES00916991T patent/ES2255995T3/es not_active Expired - Lifetime
- 2000-03-22 KR KR1020017012454A patent/KR20010110469A/ko active IP Right Grant
- 2000-03-22 WO PCT/EP2000/002533 patent/WO2000060035A2/de active IP Right Grant
- 2000-03-22 AU AU38142/00A patent/AU3814200A/en not_active Abandoned
- 2000-03-22 JP JP2000609527A patent/JP2002541302A/ja not_active Withdrawn
- 2000-03-31 CA CA002303638A patent/CA2303638A1/en not_active Abandoned

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7030075B2 (en)	2002-12-18	2006-04-18	Procter & Gamble Company	Organic activator

Also Published As

Publication number	Publication date
WO2000060035A3 (de)	2001-01-04
KR20010110469A (ko)	2001-12-13
JP2002541302A (ja)	2002-12-03
ES2255995T3 (es)	2006-07-16
EP1165742A2 (de)	2002-01-02
DE50012128D1 (de)	2006-04-13
EP1165742B1 (de)	2006-01-25
WO2000060035A2 (de)	2000-10-12
DE19914812A1 (de)	2000-10-05
AU3814200A (en)	2000-10-23

Legal Events

Date	Code	Title	Description
2002-07-03	FZDE	Dead

Publication	Publication Date	Title
US7205266B2 (en)	2007-04-17	Laundry or dishwasher detergent tablet having at least one cavity
US6329335B1 (en)	2001-12-11	Detergent tablets
CA2313356A1 (en)	2001-01-03	Process for producing laundry detergent and cleaning product tablets
CA2307429A1 (en)	2000-11-03	Coated detergent tablets
CA2303638A1 (en)	2000-09-30	Single- or multi-phase detergent tablets containing special bleach activators
CA2315298A1 (en)	2000-10-29	Washing and cleaning agent shaped body with bleaching agent
CA2304316A1 (en)	2000-09-30	Detergent tablets containing special bleach activators
CA2297443A1 (en)	2000-07-28	Multiphase detergent tablets
CA2315303A1 (en)	2000-10-29	Shaped bodies of detergent with improved properties
CA2324070A1 (en)	2001-04-21	Detergent tablets with improved abrasion resistance
CA2302141A1 (en)	2000-09-25	A builder-containing tablet
CA2335039A1 (en)	2000-12-14	Multiphase washing and cleaning agent shaped bodies containing perfume
WO2000014196A1 (de)	2000-03-16	Waschmitteltabletten mit bindemitteln
CA2299445A1 (en)	2000-08-25	Abrasion-resistant detergent tablets containing solid additives
CA2300017A1 (en)	2000-08-25	A process for the production of rapidly disintegrating detergent tablets
CA2300616A1 (en)	2000-09-11	Detergent tablets containing a surfactant/bleaching agent/builder combination
CA2306722A1 (en)	2000-10-29	Detergent tablets containing binder compound
CA2306724A1 (en)	2000-10-29	Detergent tablets containing solid binders
CA2300604A1 (en)	2000-09-11	Detergent tablets containing a surfactant/builder combination
CA2298966A1 (en)	2000-08-20	Color-stable detergent tablets
CA2306381A1 (en)	2000-10-24	Detergent tablets containing bleaching agents
CA2304409A1 (en)	2000-10-03	Detergent tablets containing special surfactant granules
CA2300016A1 (en)	2000-08-25	Storage-stable detergent tablet
DE19919444B4 (de)	2016-06-30	Wasch- und Reinigungsmittelformkörper mit Bindemittelcompound, Verfahren zu seiner Herstellung sowie Verwendung von Bindemittelcompounds
CA2316591A1 (en)	2001-02-26	Laundry detergent or cleaning product tablets

CA2303638A1 - Single- or multi-phase detergent tablets containing special bleach activators - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=7903208

Family Applications (1)

Country Status (8)

Cited By (1)

Families Citing this family (6)

Family Cites Families (6)

Cited By (1)

Also Published As

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