CA2253514A1 - Procede de preparation d'un terpolymere d'ethylene, une .alpha.-olefine et un diene - Google Patents
Procede de preparation d'un terpolymere d'ethylene, une .alpha.-olefine et un diene Download PDFInfo
- Publication number
- CA2253514A1 CA2253514A1 CA002253514A CA2253514A CA2253514A1 CA 2253514 A1 CA2253514 A1 CA 2253514A1 CA 002253514 A CA002253514 A CA 002253514A CA 2253514 A CA2253514 A CA 2253514A CA 2253514 A1 CA2253514 A1 CA 2253514A1
- Authority
- CA
- Canada
- Prior art keywords
- group
- transition metal
- process according
- ligand
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
L'invention concerne un procédé de préparation d'un terpolymère d'éthylène, une .alpha.-oléfine et un diène, ce procédé consistant à utiliser un complexe d'un métal de transition et un co-catalyseur. L'invention se caractérise en ce que la polymérisation est effectuée à l'aide d'un complexe d'un métal de transition consistant en un complexe d'un métal de transition à balance réduite choisi dans les groupes 4 à 6 de la table périodique des éléments, avec un ligand monoanionique multidenté et avec deux ligands monoanioniques, à une température comprise entre -10 et 220 ·C. En particulier, le métal de transition réduit dans le complexe est le titane (Ti).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96201112 | 1996-05-03 | ||
EP96201112.8 | 1996-05-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2253514A1 true CA2253514A1 (fr) | 1997-11-13 |
Family
ID=8223921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002253514A Abandoned CA2253514A1 (fr) | 1996-05-03 | 1997-05-01 | Procede de preparation d'un terpolymere d'ethylene, une .alpha.-olefine et un diene |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0896597A1 (fr) |
JP (1) | JP2000510175A (fr) |
KR (1) | KR20000010950A (fr) |
AU (1) | AU2412097A (fr) |
BR (1) | BR9708891A (fr) |
CA (1) | CA2253514A1 (fr) |
EA (1) | EA199800975A1 (fr) |
ID (1) | ID16858A (fr) |
WO (1) | WO1997042239A1 (fr) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999057159A1 (fr) | 1998-05-01 | 1999-11-11 | Exxon Chemical Patents Inc. | Complexes metalliques catalytiques contenant un ligand tridentate et destines a la polymerisation d'olefines |
US7078164B1 (en) | 2000-06-19 | 2006-07-18 | Symyx Technologies, Inc. | High throughput screen for identifying polymerization catalysts from potential catalysts |
KR100826080B1 (ko) * | 2001-12-27 | 2008-04-29 | 삼성토탈 주식회사 | 고용융체 강도를 갖는 에틸렌/디엔 공중합체의 제조방법 |
KR100501398B1 (ko) * | 2003-01-15 | 2005-07-18 | 삼성토탈 주식회사 | 긴가지를 갖는 α-올레핀/환상올레핀/디엔 공중합체 및 그제조방법 |
KR100586922B1 (ko) * | 2004-11-18 | 2006-06-08 | 금호폴리켐 주식회사 | 고수율의 이피(디)엠의 제조방법 및 수율의 제어방법,이피(디)엠의 회수방법 |
KR101829222B1 (ko) | 2011-02-15 | 2018-02-19 | 엘지전자 주식회사 | 냉장고 |
KR101212637B1 (ko) * | 2011-06-09 | 2012-12-14 | 에스케이종합화학 주식회사 | 신규한 사이클로펜타[b]플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
KR101391692B1 (ko) | 2012-11-14 | 2014-05-07 | 주식회사 엘지화학 | 3원계 탄성 공중합체 및 이의 제조 방법 |
KR101391693B1 (ko) | 2012-11-14 | 2014-05-07 | 주식회사 엘지화학 | 3원계 탄성 공중합체 및 이의 제조 방법 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1327673C (fr) * | 1988-06-16 | 1994-03-08 | Sigmund Floyd | Procede pour la production d'elastomeres epdm a poids moleculaires eleves, a l'aide d'un systeme de catalyseur metallocene-alumoxane |
US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
ES2116776T3 (es) * | 1994-10-31 | 1998-07-16 | Dsm Nv | Composicion catalitica y procedimiento para la polimerizacion de una olefina. |
-
1997
- 1997-05-01 BR BR9708891A patent/BR9708891A/pt not_active Application Discontinuation
- 1997-05-01 WO PCT/NL1997/000244 patent/WO1997042239A1/fr not_active Application Discontinuation
- 1997-05-01 EP EP97919764A patent/EP0896597A1/fr not_active Withdrawn
- 1997-05-01 KR KR1019980709099A patent/KR20000010950A/ko not_active Application Discontinuation
- 1997-05-01 CA CA002253514A patent/CA2253514A1/fr not_active Abandoned
- 1997-05-01 EA EA199800975A patent/EA199800975A1/ru unknown
- 1997-05-01 JP JP09539794A patent/JP2000510175A/ja active Pending
- 1997-05-01 AU AU24120/97A patent/AU2412097A/en not_active Abandoned
- 1997-05-02 ID IDP971472A patent/ID16858A/id unknown
Also Published As
Publication number | Publication date |
---|---|
JP2000510175A (ja) | 2000-08-08 |
ID16858A (id) | 1997-11-20 |
EP0896597A1 (fr) | 1999-02-17 |
BR9708891A (pt) | 1999-08-03 |
KR20000010950A (ko) | 2000-02-25 |
AU2412097A (en) | 1997-11-26 |
EA199800975A1 (ru) | 1999-04-29 |
WO1997042239A1 (fr) | 1997-11-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5442020A (en) | Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers | |
CA2210496C (fr) | Catalyseurs a base de borabenzene pour la polymerisation d'olefines | |
US5986029A (en) | Catalyst composition and process for the polymerization of an olefin | |
JP2684154B2 (ja) | 付加重合触媒及びその使用法 | |
MXPA97008182A (en) | S $! azaborolinilo metallic complexs as olefi polymerization catalysts | |
WO1994011406A1 (fr) | Composes d'indenyle et constituants catalytiques destines a la polymerisation des olefines | |
AU1546399A (en) | Mixed catalyst composition for the production of olefin polymers | |
KR102226823B1 (ko) | 굴곡탄성율이 우수한 폴리올레핀 제조용 촉매 조성물 | |
KR20160147642A (ko) | 메탈로센 담지 촉매의 제조 방법 | |
EP0896596A1 (fr) | Procede de production de polyolefines fonctionnelles | |
CA2253576A1 (fr) | Procede de polymerisation d'.alpha.-olefines | |
CA2253514A1 (fr) | Procede de preparation d'un terpolymere d'ethylene, une .alpha.-olefine et un diene | |
CA2253542A1 (fr) | Procede de preparation d'un copolymere d'.alpha.-olefine et d'ethylene | |
WO1997042228A1 (fr) | Composition de catalyseur sur support et procede pour la polymerisation de monomeres d'olefines | |
KR102565858B1 (ko) | 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀 | |
WO1997042237A1 (fr) | Procede pour fabriquer des polyolefines ayant des repartitions larges des poids moleculaires | |
US6383968B1 (en) | Process for the polymerization of olefins | |
EP0896598A1 (fr) | Procede pour la copolymerisation d'une olefine et d'un monomere aromatique de vinyle | |
WO1997042238A1 (fr) | Copolymeres polyolefiniques inverses | |
EP1028983B1 (fr) | Composition catalytique comprenant un complexe de metal de transition reduit et un cocatalyseur | |
WO1997042235A1 (fr) | Procede pour la production de polymeres contenant des olefines cycliques | |
KR20160021102A (ko) | 올레핀 중합용 촉매, 이의 제조 방법 및 용도 | |
WO1997042233A1 (fr) | Procede de polymerisation de monomeres aromatiques de vinyle | |
MXPA98009115A (en) | Procedure for the co-polymerization of an olefine and an aromat vinyl monomer | |
MXPA98009110A (en) | Composition of supported catalyst and procedure for the polymerization of olef monomers |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FZDE | Dead |