CA2131172C - High active detergent pastes - Google Patents

High active detergent pastes

Info

Publication number: CA2131172C
Authority: CA; Canada
Prior art keywords: paste; detergent; weight; alkyl; anionic surfactant
Prior art date: 1992-03-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002131172A

Other languages

English (en)

French (fr)

Other versions

CA2131172A1 (en

Inventor

Yousef Georges Aouad

Jose Luis Vega

Paul Irma Albertus Van Dijk

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-03-10

Filing date

1993-03-01

Publication date

1998-08-18

1993-03-01 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

1993-09-16 Publication of CA2131172A1 publication Critical patent/CA2131172A1/en

1998-08-18 Application granted granted Critical

1998-08-18 Publication of CA2131172C publication Critical patent/CA2131172C/en

2013-03-01 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 45
-1 alkyl ethoxy sulphate Chemical compound 0.000 claims abstract description 51
239000000203 mixture Substances 0.000 claims abstract description 51
239000003945 anionic surfactant Substances 0.000 claims abstract description 34
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
238000000034 method Methods 0.000 claims description 35
230000008569 process Effects 0.000 claims description 31
238000006386 neutralization reaction Methods 0.000 claims description 27
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 21
239000000843 powder Substances 0.000 claims description 20
125000004432 carbon atom Chemical group C* 0.000 claims description 18
150000003839 salts Chemical class 0.000 claims description 17
229910021653 sulphate ion Inorganic materials 0.000 claims description 15
238000002156 mixing Methods 0.000 claims description 11
229910052783 alkali metal Inorganic materials 0.000 claims description 9
150000001340 alkali metals Chemical class 0.000 claims description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
230000008719 thickening Effects 0.000 claims description 7
229910021536 Zeolite Inorganic materials 0.000 claims description 5
239000010457 zeolite Substances 0.000 claims description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
239000000377 silicon dioxide Substances 0.000 claims description 4
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
229910019142 PO4 Inorganic materials 0.000 claims description 3
229920002472 Starch Polymers 0.000 claims description 3
150000003863 ammonium salts Chemical class 0.000 claims description 3
230000003472 neutralizing effect Effects 0.000 claims description 3
239000010452 phosphate Substances 0.000 claims description 3
239000008107 starch Substances 0.000 claims description 3
235000019698 starch Nutrition 0.000 claims description 3
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
150000001342 alkaline earth metals Chemical class 0.000 claims description 2
125000001931 aliphatic group Chemical group 0.000 claims 1
239000004094 surface-active agent Substances 0.000 description 35
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 30
239000011734 sodium Substances 0.000 description 29
229910052708 sodium Inorganic materials 0.000 description 29
239000000463 material Substances 0.000 description 20
229910000323 aluminium silicate Inorganic materials 0.000 description 18
239000002245 particle Substances 0.000 description 18
238000005342 ion exchange Methods 0.000 description 17
238000005054 agglomeration Methods 0.000 description 12
230000002776 aggregation Effects 0.000 description 12
125000000217 alkyl group Chemical group 0.000 description 12
238000005469 granulation Methods 0.000 description 12
230000003179 granulation Effects 0.000 description 12
239000003760 tallow Substances 0.000 description 11
238000004519 manufacturing process Methods 0.000 description 9
239000000243 solution Substances 0.000 description 8
150000004996 alkyl benzenes Chemical class 0.000 description 7
239000008187 granular material Substances 0.000 description 7
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000002253 acid Substances 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
238000001035 drying Methods 0.000 description 6
239000012530 fluid Substances 0.000 description 6
239000007788 liquid Substances 0.000 description 6
239000011591 potassium Substances 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
159000000001 potassium salts Chemical class 0.000 description 6
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 6
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 5
238000001816 cooling Methods 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
150000004665 fatty acids Chemical class 0.000 description 5
239000002736 nonionic surfactant Substances 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
235000013162 Cocos nucifera Nutrition 0.000 description 4
244000060011 Cocos nucifera Species 0.000 description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical group [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
239000004614 Process Aid Substances 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
150000001298 alcohols Chemical class 0.000 description 4
229910000019 calcium carbonate Inorganic materials 0.000 description 4
229910001424 calcium ion Inorganic materials 0.000 description 4
238000000518 rheometry Methods 0.000 description 4
239000002002 slurry Substances 0.000 description 4
239000000344 soap Substances 0.000 description 4
238000001694 spray drying Methods 0.000 description 4
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
150000008044 alkali metal hydroxides Chemical class 0.000 description 3
230000008901 benefit Effects 0.000 description 3
235000010216 calcium carbonate Nutrition 0.000 description 3
UZABCLFSICXBCM-UHFFFAOYSA-N ethoxy hydrogen sulfate Chemical compound CCOOS(O)(=O)=O UZABCLFSICXBCM-UHFFFAOYSA-N 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000006254 rheological additive Substances 0.000 description 3
239000007921 spray Substances 0.000 description 3
238000003860 storage Methods 0.000 description 3
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
150000001335 aliphatic alkanes Chemical group 0.000 description 2
229910000272 alkali metal oxide Inorganic materials 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
230000008878 coupling Effects 0.000 description 2
238000010168 coupling process Methods 0.000 description 2
238000005859 coupling reaction Methods 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
239000011552 falling film Substances 0.000 description 2
239000002563 ionic surfactant Substances 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
229910000000 metal hydroxide Inorganic materials 0.000 description 2
150000004692 metal hydroxides Chemical class 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
235000014366 other mixer Nutrition 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
238000005086 pumping Methods 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000002888 zwitterionic surfactant Substances 0.000 description 2
XYJLPCAKKYOLGU-UHFFFAOYSA-N 2-phosphonoethylphosphonic acid Chemical class OP(O)(=O)CCP(O)(O)=O XYJLPCAKKYOLGU-UHFFFAOYSA-N 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical class [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
SXKQTYJLWWQUKA-UHFFFAOYSA-N O.O.O.O.O.O.O.O.O.O.OB(O)O.OB(O)O.OB(O)O.OB(O)O Chemical compound O.O.O.O.O.O.O.O.O.O.OB(O)O.OB(O)O.OB(O)O.OB(O)O SXKQTYJLWWQUKA-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
229920000388 Polyphosphate Chemical class 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
235000010724 Wisteria floribunda Nutrition 0.000 description 1
150000001253 acrylic acids Chemical class 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
125000005192 alkyl ethylene group Chemical class 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
235000019289 ammonium phosphates Nutrition 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000002585 base Substances 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
230000029087 digestion Effects 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
239000000428 dust Substances 0.000 description 1
238000010410 dusting Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
239000003925 fat Substances 0.000 description 1
235000019197 fats Nutrition 0.000 description 1
125000005313 fatty acid group Chemical group 0.000 description 1
235000019387 fatty acid methyl ester Nutrition 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
235000013305 food Nutrition 0.000 description 1
238000009472 formulation Methods 0.000 description 1
235000021588 free fatty acids Nutrition 0.000 description 1
229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
239000008103 glucose Substances 0.000 description 1
125000005456 glyceride group Chemical group 0.000 description 1
159000000011 group IA salts Chemical class 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
239000003752 hydrotrope Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052816 inorganic phosphate Inorganic materials 0.000 description 1
238000004900 laundering Methods 0.000 description 1
230000007774 longterm Effects 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
150000002689 maleic acids Chemical class 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000005341 metaphosphate group Chemical group 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
239000003002 pH adjusting agent Substances 0.000 description 1
239000002304 perfume Substances 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
239000001205 polyphosphate Chemical class 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000000047 product Substances 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
229940071207 sesquicarbonate Drugs 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
239000002689 soil Substances 0.000 description 1
241000894007 species Species 0.000 description 1
230000003019 stabilising effect Effects 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000000271 synthetic detergent Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Noodles (AREA)

CA002131172A 1992-03-10 1993-03-01 High active detergent pastes Expired - Fee Related CA2131172C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP92870040A EP0560001B1 (en)	1992-03-10	1992-03-10	High active detergent pastes
EP92870040.0		1992-03-10

Publications (2)

Publication Number	Publication Date
CA2131172A1 CA2131172A1 (en)	1993-09-16
CA2131172C true CA2131172C (en)	1998-08-18

Family

ID=8212244

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002131172A Expired - Fee Related CA2131172C (en)	1992-03-10	1993-03-01	High active detergent pastes

Country Status (16)

Country	Link
EP (1)	EP0560001B1 (ja)
JP (2)	JP3514758B2 (ja)
CN (2)	CN1054630C (ja)
AT (1)	ATE180273T1 (ja)
AU (1)	AU3781393A (ja)
CA (1)	CA2131172C (ja)
DE (1)	DE69229218T2 (ja)
DK (1)	DK0560001T3 (ja)
EG (1)	EG19954A (ja)
ES (1)	ES2131524T3 (ja)
IE (1)	IE930175A1 (ja)
MA (1)	MA22817A1 (ja)
MX (1)	MX9301337A (ja)
PH (1)	PH30683A (ja)
TR (1)	TR27088A (ja)
WO (1)	WO1993018123A1 (ja)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9226003D0 (en) †	1992-12-14	1993-02-10	Unilever Plc	Detergent production
US6166095A (en) *	1993-12-15	2000-12-26	Albright & Wilson Uk Limited	Method of preparing a drilling fluid comprising structured surfactants
DZ1837A1 (fr) *	1993-12-15	2002-02-17	Albright & Wilson	Surfactants structures.
EP0663439B1 (en) *	1994-01-17	2000-08-16	The Procter & Gamble Company	Process for preparing detergent granules
WO1996025482A1 (en) *	1995-02-13	1996-08-22	The Procter & Gamble Company	Process for producing detergent agglomerates in which particle size is controlled
US5574005A (en) *	1995-03-07	1996-11-12	The Procter & Gamble Company	Process for producing detergent agglomerates from high active surfactant pastes having non-linear viscoelastic properties
US5554587A (en) *	1995-08-15	1996-09-10	The Procter & Gamble Company	Process for making high density detergent composition using conditioned air
ATE264384T1 (de) *	1996-07-04	2004-04-15	Procter & Gamble	Verfahren zur konditionierung von tensidpasten zwecks bildung hochaktiver tensidgranulate
DE19648014C2 (de) *	1996-11-20	2002-09-19	Cognis Deutschland Gmbh	Wasserfreie Tensidgemische
EP1025196B1 (en) *	1997-02-27	2004-07-21	The Procter & Gamble Company	Process for making a detergent composition by adding co-surfactants
WO2015032083A1 (en) *	2013-09-09	2015-03-12	The Procter & Gamble Company	Process of making a liquid cleaning composition
JP6393168B2 (ja) *	2013-12-27	2018-09-19	花王株式会社	内部オレフィンスルホン酸塩の製造方法
EP3719103A4 (en) *	2017-11-29	2021-09-01	Kao Corporation	COMPOSITION OF INTERNAL OLEFIN SULPHONATE AND PROCESS FOR CONSERVING INTERNAL OLEFIN SULPHONATE
US20190292490A1 (en) *	2018-03-22	2019-09-26	The Procter & Gamble Company	Process of making liquid household care compositions
EP3790950B1 (en)	2018-05-10	2023-11-01	The Procter & Gamble Company	Detergent granule

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US469227A (en) *		1892-02-23		William g
DE1692009B2 (de) *	1968-02-17	1973-02-15	Farbwerke Hoechst AG, vormals Mei ster Lucius & Bruning, 6000 Frankfurt	Verfahren zum herstellen pumpbarer, fliessfaehiger waschmittelpasten
JPS5116036B2 (ja) *	1972-05-23	1976-05-21
JPS5116045B2 (ja) *	1972-08-08	1976-05-21
GB1546127A (en) *	1976-11-18	1979-05-16	Shell Int Research	Detergent compositions
US4692271B1 (en) *	1977-12-09	1997-07-22	Albright & Wilson	Concentrated aqueous surfactant compositions
DE2921366A1 (de) *	1978-05-26	1979-12-06	Albright & Wilson	Konzentrierte waessrige oberflaechenaktive zubereitung
EP0024711B2 (de) *	1979-09-01	1989-02-08	Henkel Kommanditgesellschaft auf Aktien	Wässrige Tensidkonzentrate und Verfahren zur Verbesserung des Fliessverhaltens schwer beweglicher wässriger Tensidkonzentrate
EP0039110B1 (en) *	1980-04-24	1985-01-02	THE PROCTER & GAMBLE COMPANY	Liquid detergent compositions
US4487710A (en)	1982-03-01	1984-12-11	The Procter & Gamble Company	Granular detergents containing anionic surfactant and ethoxylated surfactant solubility aid
GB8412045D0 (en) *	1984-05-11	1984-06-20	Unilever Plc	Detergent compositions
ES8607378A1 (es) *	1984-08-06	1986-05-16	Kao Corp	Una composicion detergente en polvo de gran densidad
GB8420945D0 (en) *	1984-08-17	1984-09-19	Unilever Plc	Detergents compositions
JP2662221B2 (ja) *	1987-07-15	1997-10-08	花王株式会社	高密度粒状濃縮洗剤組成物
US5080848A (en) *	1988-12-22	1992-01-14	The Proctor & Gamble Company	Process for making concentrated surfactant granules
ES2076963T3 (es) *	1988-06-29	1995-11-16	Procter & Gamble	Procedimiento para la fabricacion de granulos de tensioactivo concentrado.
CA2017922C (en) *	1989-06-09	1995-07-11	Frank Joseph Mueller	Formation of discrete, high active detergent granules using a continuous neutralization system

1992
- 1992-03-10 AT AT92870040T patent/ATE180273T1/de not_active IP Right Cessation
- 1992-03-10 ES ES92870040T patent/ES2131524T3/es not_active Expired - Lifetime
- 1992-03-10 EP EP92870040A patent/EP0560001B1/en not_active Expired - Lifetime
- 1992-03-10 DK DK92870040T patent/DK0560001T3/da active
- 1992-03-10 DE DE69229218T patent/DE69229218T2/de not_active Expired - Fee Related
1993
- 1993-03-01 WO PCT/US1993/001790 patent/WO1993018123A1/en active Application Filing
- 1993-03-01 AU AU37813/93A patent/AU3781393A/en not_active Abandoned
- 1993-03-01 JP JP51579793A patent/JP3514758B2/ja not_active Expired - Fee Related
- 1993-03-01 CA CA002131172A patent/CA2131172C/en not_active Expired - Fee Related
- 1993-03-03 TR TR00164/93A patent/TR27088A/xx unknown
- 1993-03-08 EG EG13793A patent/EG19954A/xx active
- 1993-03-08 PH PH45832A patent/PH30683A/en unknown
- 1993-03-08 MA MA23111A patent/MA22817A1/fr unknown
- 1993-03-09 IE IE017593A patent/IE930175A1/en not_active IP Right Cessation
- 1993-03-10 MX MX9301337A patent/MX9301337A/es not_active IP Right Cessation
- 1993-03-10 CN CN93104045A patent/CN1054630C/zh not_active Expired - Fee Related
1997
- 1997-11-27 CN CN97122640A patent/CN1098351C/zh not_active Expired - Fee Related
2002
- 2002-09-18 JP JP2002271900A patent/JP2003147390A/ja active Pending

Also Published As

Publication number	Publication date
PH30683A (en)	1997-09-16
EP0560001A1 (en)	1993-09-15
JP2003147390A (ja)	2003-05-21
CN1077486A (zh)	1993-10-20
CA2131172A1 (en)	1993-09-16
JPH07507818A (ja)	1995-08-31
CN1054630C (zh)	2000-07-19
DE69229218T2 (de)	1999-12-16
MA22817A1 (fr)	1993-10-01
EP0560001B1 (en)	1999-05-19
TR27088A (tr)	1994-10-18
JP3514758B2 (ja)	2004-03-31
DE69229218D1 (de)	1999-06-24
CN1190670A (zh)	1998-08-19
MX9301337A (es)	1994-01-31
IE930175A1 (en)	1993-09-22
ES2131524T3 (es)	1999-08-01
ATE180273T1 (de)	1999-06-15
EG19954A (en)	1999-05-31
WO1993018123A1 (en)	1993-09-16
AU3781393A (en)	1993-10-05
CN1098351C (zh)	2003-01-08
DK0560001T3 (da)	1999-11-08

Legal Events

Date	Code	Title	Description
1994-08-30	EEER	Examination request
2008-03-03	MKLA	Lapsed

Publication	Publication Date	Title
US4925585A (en)	1990-05-15	Detergent granules from cold dough using fine dispersion granulation
EP0508543B1 (en)	1997-08-06	Chemical structuring of surfactant pastes to form high active surfactant granules
CA2131172C (en)	1998-08-18	High active detergent pastes
US5080848A (en)	1992-01-14	Process for making concentrated surfactant granules
EP0510746A2 (en)	1992-10-28	Process for preparing condensed detergent granules
NZ233999A (en)	1991-12-23	Preparation of detergent granules by forming active ingredients into a doughy mixture and then mixing the doughy mixture with a deagglomerating agent
US5712242A (en)	1998-01-27	High active granular detergents comprising chelants and polymers, and processes for their preparation
US5494599A (en)	1996-02-27	Agglomeration of high active pastes to form surfactant granules useful in detergent compositions
US5529722A (en)	1996-06-25	High active detergent pastes
CN1054631C (zh)	2000-07-19	制备高活性颗粒状洗涤剂的方法
US5451354A (en)	1995-09-19	Chemical structuring of surfactant pastes to form high active surfactant granules
NZ229756A (en)	1992-04-28	Production of concentrated surfactant granules
EP0618289A1 (en)	1994-10-05	High active granular detergents comprising chelants and polymers, and processes for their preparation
CA2260008C (en)	2002-05-21	Process for conditioning of surfactant pastes to form high active surfactant agglomerates
US6172033B1 (en)	2001-01-09	Process for conditioning of surfactant pastes to form high active surfactant agglomerates
WO1992018603A1 (en)	1992-10-29	Agglomeration of high active pastes to form surfactant granules useful in detergent compositions
WO1995029215A1 (en)	1995-11-02	Process for the manufacture of free-flowing detergent granules
WO2011061045A1 (en)	2011-05-26	Detergent granule and its manufacture
MXPA99002258A (en)	2000-02-02	Process for preparing high bulk density detergent compositions