CA2067177A1 - Catalyseur de polymerisation d'olefine obtenu a partir d'un melange de trialkylaluminium, de gel de silice et de metallocene - Google Patents
Catalyseur de polymerisation d'olefine obtenu a partir d'un melange de trialkylaluminium, de gel de silice et de metalloceneInfo
- Publication number
- CA2067177A1 CA2067177A1 CA2067177A CA2067177A CA2067177A1 CA 2067177 A1 CA2067177 A1 CA 2067177A1 CA 2067177 A CA2067177 A CA 2067177A CA 2067177 A CA2067177 A CA 2067177A CA 2067177 A1 CA2067177 A1 CA 2067177A1
- Authority
- CA
- Canada
- Prior art keywords
- metallocene
- mixture
- silica gel
- trialkylaluminum
- polymerization catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 239000000741 silica gel Substances 0.000 title 1
- 229910002027 silica gel Inorganic materials 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B2227/00—Photographic printing apparatus
- G03B2227/32—Projection printing apparatus, e.g. enlarging apparatus, copying camera
- G03B2227/325—Microcapsule copiers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Un catalyseur très actif, à support d'alumoxane-métallocène, pour la polymérisation de 1-oléfines est préparé en faisant réagir un gel de silice non déshydraté avec un mélange de triméthyle aluminium et de triisobutylealuminium pour obtenir un produit de silice-alumoxane que l'on fait réagir ensuite avec un métallocène du groupe IVB et/ou du groupe VB de manière à obtenir un catalyseur actif sous forme de poudre appropriée à une utilisation dans des réacteurs de phase gazeuse ou boueuse, par élimination de solvants et par séchage.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/422,357 US5006500A (en) | 1988-10-27 | 1989-10-16 | Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene |
US422,357 | 1989-10-16 | ||
PCT/US1990/005769 WO1991005810A1 (fr) | 1989-10-16 | 1990-10-09 | Catalyseur de polymerisation d'olefines obtenu a partir d'un melange de trialyle aluminium, de gel de silice et d'un metallocene |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2067177A1 true CA2067177A1 (fr) | 1991-04-17 |
CA2067177C CA2067177C (fr) | 2000-03-14 |
Family
ID=23674542
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002067177A Expired - Fee Related CA2067177C (fr) | 1989-10-16 | 1990-10-09 | Catalyseur de polymerisation d'olefine obtenu a partir d'un melange de trialkylaluminium, de gel de silice et de metallocene |
Country Status (12)
Country | Link |
---|---|
US (1) | US5006500A (fr) |
EP (1) | EP0495849B1 (fr) |
JP (1) | JPH0713100B2 (fr) |
KR (1) | KR927003650A (fr) |
AR (1) | AR244711A1 (fr) |
AU (1) | AU6530890A (fr) |
BR (1) | BR9007756A (fr) |
CA (1) | CA2067177C (fr) |
DE (1) | DE69015369T2 (fr) |
IL (1) | IL95982A0 (fr) |
PT (1) | PT95599A (fr) |
WO (1) | WO1991005810A1 (fr) |
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4032266A1 (de) * | 1990-10-11 | 1992-04-16 | Hoechst Ag | Verfahren zur herstellung eines polyolefins |
FI86989C (fi) * | 1990-12-19 | 1992-11-10 | Neste Oy | Foerfarande foer framstaellning av en polymerisationskatalysatorkomponent foer olefiner, en polymerisationskatalysatorkomponent som har framstaellts enligt foerfarandet, och dess anvaendning |
JP3048653B2 (ja) * | 1991-02-07 | 2000-06-05 | 三菱化学株式会社 | α‐オレフィン重合体の製造 |
FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
EP0578838A1 (fr) * | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation |
US5910464A (en) * | 1992-06-18 | 1999-06-08 | Montell Technology Company Bv | Catalysts for the polymerization of olefins |
EP0648230B1 (fr) * | 1992-07-01 | 1999-09-15 | Exxon Chemical Patents Inc. | Metaux de transition utilises comme catalyseurs de polymerisation d'olefines |
US5602067A (en) * | 1992-12-28 | 1997-02-11 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
US5608019A (en) * | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
US5420220A (en) * | 1993-03-25 | 1995-05-30 | Mobil Oil Corporation | LLDPE films |
US5523136A (en) * | 1993-04-30 | 1996-06-04 | Cypress Packaging | Packaging film, packages and methods for using them |
AU680263B2 (en) * | 1993-05-25 | 1997-07-24 | Exxon Chemical Patents Inc. | Novel polyolefin fibers and their fabrics |
US5414180A (en) * | 1993-07-14 | 1995-05-09 | Phillips Petroleum Company | Organo-aluminoxy product and use |
US5455741A (en) * | 1993-10-26 | 1995-10-03 | Pulse Engineering, Inc. | Wire-lead through hole interconnect device |
US5614456A (en) * | 1993-11-15 | 1997-03-25 | Mobil Oil Corporation | Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers |
US5491207A (en) * | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
US5565395A (en) * | 1995-05-26 | 1996-10-15 | Albemarle Corporation | Aluminoxanate compositions |
IT1276752B1 (it) * | 1995-06-20 | 1997-11-03 | Spherilene S P A Ora Montell I | Catalizzatori e procedimenti per la polimerizzazione di olefine |
US5882750A (en) * | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
CN1047388C (zh) * | 1995-07-14 | 1999-12-15 | 中国石油化工总公司 | 负载型金属茂类化合物/铝氧烷催化剂的制备 |
US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
USRE38429E1 (en) * | 1996-03-12 | 2004-02-17 | Tyco Plastics Services Ag | Stretch wrap films |
US5998017A (en) * | 1996-03-12 | 1999-12-07 | Tenneco Packaging | Stretch wrap films |
US5749202A (en) * | 1996-03-12 | 1998-05-12 | Tenneco Packaging | Stretch wrap films |
US5902684A (en) * | 1996-03-12 | 1999-05-11 | Tenneco Packaging Inc. | Multilayered Metallocene stretch wrap films |
US5752362A (en) * | 1996-03-12 | 1998-05-19 | Tenneco Packaging | Stretch wrap films |
US5814399A (en) * | 1996-03-12 | 1998-09-29 | Tenneco Packaging | Stretch wrap films |
US5976682A (en) * | 1996-03-12 | 1999-11-02 | Tenneco Packaging | Stretch wrap films |
US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
EP0912244A4 (fr) * | 1996-07-15 | 2001-09-12 | Mobil Oil Corp | Catalyseur bimetallique pretraite par comonomere pour le moulage par soufflage et pour des applications en films |
US5851070A (en) * | 1996-12-05 | 1998-12-22 | Tenneco Packaging Inc. | Seals for plastic bags |
US6376035B1 (en) | 1996-12-05 | 2002-04-23 | Pactiv Corporation | Zipper fins for plastic bags |
US5919535A (en) * | 1996-12-05 | 1999-07-06 | Tenneco Packaging | Fins for plastic bags |
US5989725A (en) * | 1997-01-16 | 1999-11-23 | Tenneco Packaging | Clear high molecular weight film |
FI970349A (fi) | 1997-01-28 | 1998-07-29 | Borealis As | Uudet metalloseeniyhdisteiden aktivaattorisysteemit |
FI972230A (fi) | 1997-01-28 | 1998-07-29 | Borealis As | Uusi homogeeninen olefiinien polymerointikatalysaattorikoostumus |
US6005463A (en) * | 1997-01-30 | 1999-12-21 | Pulse Engineering | Through-hole interconnect device with isolated wire-leads and component barriers |
US6013378A (en) * | 1997-03-17 | 2000-01-11 | Tenneco Packaging | HMW HDPE film with improved impact strength |
US6093480A (en) * | 1997-05-21 | 2000-07-25 | Tenneco Packaging | Stretch wrap films |
US5907942A (en) * | 1997-05-21 | 1999-06-01 | Tenneco Packaging | Stretch wrap films |
US5922441A (en) * | 1997-06-11 | 1999-07-13 | Tenneco Packaging Inc. | Stretch wrap films |
US5907943A (en) * | 1997-06-11 | 1999-06-01 | Tenneco Packaging Inc. | Stretch wrap films |
US6051525A (en) * | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
US5990035A (en) * | 1997-10-21 | 1999-11-23 | Koeppl; Alexander | Polymerization catalyst systems, their preparation, and use |
US6083611A (en) * | 1997-11-12 | 2000-07-04 | Tenneco Packaging, Inc. | Roll wrap film |
WO1999040133A1 (fr) * | 1998-02-04 | 1999-08-12 | Japan As Represented By Director General Of The Agency Of Industrial Science And Technology | Polymeres de butadiene et procede de production de polymeres dieniques conjugues |
GB9816940D0 (en) * | 1998-08-05 | 1998-09-30 | Bp Chem Int Ltd | Polymerisation catalysts |
US7041618B2 (en) * | 1999-06-22 | 2006-05-09 | Lg Chemical Ltd. | Supported metallocene catalyst and olefin polymerization using the same |
US7247595B2 (en) * | 1999-06-22 | 2007-07-24 | Lg Chem, Ltd. | Supported metallocene catalyst and olefin polymerization using the same |
KR20050035183A (ko) * | 2001-11-30 | 2005-04-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 비-단일 부위/단일 부위 촉매 복합물을 이용하여 제조된에틸렌/알파-올레핀 공중합체, 이의 제조 방법 및 용도 |
EP1352913B1 (fr) * | 2002-04-08 | 2016-06-01 | Tosoh Finechem Corporation | Procédé pour la préparation de methylaluminoxane modifié comme composant catalytique pour la polymérisation d'olefins |
US6884749B2 (en) | 2002-10-17 | 2005-04-26 | Equistar Chemicals L.P. | Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof |
WO2004055061A1 (fr) * | 2002-12-17 | 2004-07-01 | O & D Trading Limited | Catalyseur supporte de polymerisation d'olefines |
US8028588B2 (en) | 2009-09-25 | 2011-10-04 | Rosemount Inc. | Flow measurement using near field microwaves |
BR112015011215B1 (pt) | 2012-11-26 | 2018-11-21 | Braskem S.A. | Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metalocenosuportado e polímero de etileno com distribuição de massa molar ampla ou bimodal |
US11161922B2 (en) | 2017-10-31 | 2021-11-02 | Exxonmobil Chemical Patents Inc. | Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents |
SG11202001743RA (en) | 2017-10-31 | 2020-05-28 | Exxonmobil Chemical Patents Inc | Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents |
WO2019089144A1 (fr) * | 2017-10-31 | 2019-05-09 | Exxonmobil Chemical Patents Inc. | Catalyseurs métallocènes monosites supportés sur silice exempts de toluène contenus dans une formation de mao supportée in-situ dans des solvants aliphatiques |
US20240092947A1 (en) | 2020-11-23 | 2024-03-21 | Exxonmobil Chemical Patents Inc. | Improved In-Situ MAO Derived Silica Supported Single-Site Metallocene Catalysts |
WO2023250240A1 (fr) | 2022-06-24 | 2023-12-28 | Exxonmobil Chemical Patents Inc. | Procédés à faible coût de support de mao in situ et catalyseurs de polyoléfine finis dérivés |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2608863A1 (de) * | 1976-03-04 | 1977-09-08 | Basf Ag | Verfahren zum herstellen von polyaethylen |
DE2608933A1 (de) * | 1976-03-04 | 1977-09-08 | Basf Ag | Verfahren zum herstellen von polyaethylen |
DE3007433C2 (de) * | 1980-02-28 | 1982-06-16 | Maizena Gmbh, 2000 Hamburg | Verfahren zur Herstellung von Polymermassen aus Polyolefinen und Stärke und/oder Lignin sowie gegebenenfalls Cellulosefasern |
DE3007725A1 (de) * | 1980-02-29 | 1981-09-17 | Hansjörg Prof. Dr. 2000 Hamburg Sinn | Verfahren zur herstellung von polyethylen, polypropylen und copolymeren |
DE3240382A1 (de) * | 1982-11-02 | 1984-05-03 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von gefuellten polyolefinen |
DE3424697C2 (de) * | 1984-07-05 | 1999-07-08 | Targor Gmbh | Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen |
JPH0788403B2 (ja) * | 1984-11-01 | 1995-09-27 | 昭和電工株式会社 | ポリオレフインの製造方法 |
US4912075A (en) * | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
US4937217A (en) * | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst |
US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US4935397A (en) * | 1988-09-28 | 1990-06-19 | Exxon Chemical Patents Inc. | Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same |
-
1989
- 1989-10-16 US US07/422,357 patent/US5006500A/en not_active Expired - Lifetime
-
1990
- 1990-10-09 WO PCT/US1990/005769 patent/WO1991005810A1/fr active IP Right Grant
- 1990-10-09 EP EP90915263A patent/EP0495849B1/fr not_active Expired - Lifetime
- 1990-10-09 AU AU65308/90A patent/AU6530890A/en not_active Abandoned
- 1990-10-09 CA CA002067177A patent/CA2067177C/fr not_active Expired - Fee Related
- 1990-10-09 DE DE69015369T patent/DE69015369T2/de not_active Expired - Lifetime
- 1990-10-09 BR BR909007756A patent/BR9007756A/pt not_active Application Discontinuation
- 1990-10-09 JP JP2514190A patent/JPH0713100B2/ja not_active Expired - Fee Related
- 1990-10-09 KR KR1019920700870A patent/KR927003650A/ko not_active Application Discontinuation
- 1990-10-14 IL IL95982A patent/IL95982A0/xx unknown
- 1990-10-15 PT PT95599A patent/PT95599A/pt not_active Application Discontinuation
- 1990-10-16 AR AR90318099A patent/AR244711A1/es active
Also Published As
Publication number | Publication date |
---|---|
US5006500A (en) | 1991-04-09 |
EP0495849A1 (fr) | 1992-07-29 |
JPH05501424A (ja) | 1993-03-18 |
AU6530890A (en) | 1991-05-16 |
PT95599A (pt) | 1991-09-13 |
CA2067177C (fr) | 2000-03-14 |
DE69015369D1 (de) | 1995-02-02 |
JPH0713100B2 (ja) | 1995-02-15 |
IL95982A0 (en) | 1991-07-18 |
EP0495849B1 (fr) | 1994-12-21 |
DE69015369T2 (de) | 1996-01-11 |
WO1991005810A1 (fr) | 1991-05-02 |
KR927003650A (ko) | 1992-12-18 |
BR9007756A (pt) | 1992-10-06 |
AR244711A1 (es) | 1993-11-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2067177A1 (fr) | Catalyseur de polymerisation d'olefine obtenu a partir d'un melange de trialkylaluminium, de gel de silice et de metallocene | |
CA2001941A1 (fr) | Methode de preparation de cire de polyethylene par polymerisation en phase gazeuse | |
AU4624889A (en) | Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst | |
FR2577558B1 (fr) | Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse | |
CA2198776A1 (fr) | Procede de polymerisation | |
NO911071L (no) | Baaret polyolefinkatalysator for (ko-)polymerisasjon av etylen i gassfase. | |
AU3799595A (en) | A process for preparing an in situ polyethylene blend | |
AU8852591A (en) | Ionic catalyst for the production of poly-alpha-olefins of controlled tacticity | |
CA2012637A1 (fr) | Procede de production d'une solution homogene d'aluminoxane | |
US5880302A (en) | Organometallic compound | |
US6433111B1 (en) | Method for producing a supported catalyst system | |
CA2000182A1 (fr) | Procede et catalyseur pour l'oligomerisation de l'ethylene | |
ES2009457A6 (es) | Proceso de preparacion de sistema catalitico tipo ziegler y proceso de preparacion de polietileno de altisimo peso molecular. | |
YU194190A (sh) | Katalizator za polimerizaciju olefina iz smeše trialkilaluminijuma, silikagela i metalocena | |
JPS54141893A (en) | Preparation of ethylene polymer | |
AU616246B2 (en) | Process for the preparation of 1-olefin polymers | |
JPS6454007A (en) | Production of olefin polymer | |
JPS565806A (en) | Polymerization of olefin | |
GB1430463A (en) | Process for the polymerisation of ethylene possibly in admixture with 1-olefins | |
HUT42103A (en) | Process for preparing novel, carrier polymerization catalyst and polymerization process for utilizing the catalyst | |
SU1624765A1 (ru) | СПОСОБ ПРИГОТОВЛЕНИЯ КОМПОНЕНТА КАТАЛИТИЧЕСКОЙ СИСТЕМЫ ДЛЯ ПОЛИМЕРИЗАЦИИ α -ОЛЕФИНОВ | |
CA2042961A1 (fr) | Composition de catalyseur et procede de polymerisation de polymeres presentant une distribution multimodale de poids moleculaires | |
MY135529A (en) | Polymerisation process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |