CA1296821C - Dynamically crosslinked thermoplastic elastomer - Google Patents

Dynamically crosslinked thermoplastic elastomer

Info

Publication number: CA1296821C
Authority: CA; Canada
Prior art keywords: epoxidized; epoxy; elastomer; parts; thermoplastic elastomer
Prior art date: 1986-11-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000550197A

Other languages

English (en)

French (fr)

Inventor

Lawrence Clark

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Armstrong World Industries Inc

Original Assignee

Armstrong World Industries Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-11-17

Filing date

1987-10-26

Publication date

1992-03-03

1987-10-26 Application filed by Armstrong World Industries Inc filed Critical Armstrong World Industries Inc

1992-03-03 Application granted granted Critical

1992-03-03 Publication of CA1296821C publication Critical patent/CA1296821C/en

2009-03-03 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 19
239000004593 Epoxy Substances 0.000 claims abstract description 92
239000000203 mixture Substances 0.000 claims abstract description 50
229920001971 elastomer Polymers 0.000 claims abstract description 32
239000000806 elastomer Substances 0.000 claims abstract description 31
229910021645 metal ion Inorganic materials 0.000 claims abstract description 19
239000003431 cross linking reagent Substances 0.000 claims abstract description 15
229920000459 Nitrile rubber Polymers 0.000 claims abstract description 12
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims abstract description 12
239000004716 Ethylene/acrylic acid copolymer Substances 0.000 claims abstract description 8
238000004132 cross linking Methods 0.000 claims description 26
229920000642 polymer Polymers 0.000 claims description 20
229910052751 metal Inorganic materials 0.000 claims description 19
239000002184 metal Substances 0.000 claims description 19
238000002156 mixing Methods 0.000 claims description 18
-1 alkyl glycidyl ether Chemical compound 0.000 claims description 13
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 11
239000005977 Ethylene Substances 0.000 claims description 11
229920001577 copolymer Polymers 0.000 claims description 10
230000001965 increasing effect Effects 0.000 claims description 10
239000000178 monomer Substances 0.000 claims description 10
150000003839 salts Chemical class 0.000 claims description 10
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
CABDEMAGSHRORS-UHFFFAOYSA-N oxirane;hydrate Chemical compound O.C1CO1 CABDEMAGSHRORS-UHFFFAOYSA-N 0.000 claims description 6
229920005989 resin Polymers 0.000 claims description 6
239000011347 resin Substances 0.000 claims description 6
235000012424 soybean oil Nutrition 0.000 claims description 5
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
244000043261 Hevea brasiliensis Species 0.000 claims description 4
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims description 4
229920003052 natural elastomer Polymers 0.000 claims description 4
229920001194 natural rubber Polymers 0.000 claims description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
150000001491 aromatic compounds Chemical class 0.000 claims description 3
229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 3
239000000945 filler Substances 0.000 claims description 3
239000000049 pigment Substances 0.000 claims description 3
229920002857 polybutadiene Polymers 0.000 claims description 3
229920005862 polyol Polymers 0.000 claims description 3
239000003784 tall oil Substances 0.000 claims description 3
229920006305 unsaturated polyester Polymers 0.000 claims description 3
239000003963 antioxidant agent Substances 0.000 claims description 2
230000003078 antioxidant effect Effects 0.000 claims description 2
QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 claims description 2
239000003921 oil Substances 0.000 claims description 2
235000019198 oils Nutrition 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims description 2
239000004014 plasticizer Substances 0.000 claims description 2
229920005992 thermoplastic resin Polymers 0.000 claims description 2
235000021388 linseed oil Nutrition 0.000 claims 2
239000000944 linseed oil Substances 0.000 claims 2
235000010469 Glycine max Nutrition 0.000 claims 1
229920003182 Surlyn® Polymers 0.000 description 37
229920000554 ionomer Polymers 0.000 description 28
239000004971 Cross linker Substances 0.000 description 23
229920013647 Krynac Polymers 0.000 description 22
238000012360 testing method Methods 0.000 description 15
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 14
238000000034 method Methods 0.000 description 11
229940093470 ethylene Drugs 0.000 description 10
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 8
238000007792 addition Methods 0.000 description 8
239000011734 sodium Substances 0.000 description 8
150000001875 compounds Chemical class 0.000 description 7
230000000704 physical effect Effects 0.000 description 7
239000004416 thermosoftening plastic Substances 0.000 description 7
239000011787 zinc oxide Substances 0.000 description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
239000002253 acid Substances 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
238000003801 milling Methods 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
239000004615 ingredient Substances 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
229910052725 zinc Inorganic materials 0.000 description 5
239000011701 zinc Substances 0.000 description 5
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
229920001169 thermoplastic Polymers 0.000 description 4
KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
230000006835 compression Effects 0.000 description 3
238000007906 compression Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000000463 material Substances 0.000 description 3
229920003319 Araldite® Polymers 0.000 description 2
229920003345 Elvax® Polymers 0.000 description 2
241000156978 Erebia Species 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000001816 cooling Methods 0.000 description 2
NZNMSOFKMUBTKW-UHFFFAOYSA-M cyclohexanecarboxylate Chemical compound [O-]C(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-M 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
125000001183 hydrocarbyl group Chemical group 0.000 description 2
230000003993 interaction Effects 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
VYQNWZOUAUKGHI-UHFFFAOYSA-N monobenzone Chemical compound C1=CC(O)=CC=C1OCC1=CC=CC=C1 VYQNWZOUAUKGHI-UHFFFAOYSA-N 0.000 description 2
230000003472 neutralizing effect Effects 0.000 description 2
229920001223 polyethylene glycol Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000008569 process Effects 0.000 description 2
230000009467 reduction Effects 0.000 description 2
KGSFMPRFQVLGTJ-UHFFFAOYSA-N 1,1,2-triphenylethylbenzene Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(C=1C=CC=CC=1)CC1=CC=CC=C1 KGSFMPRFQVLGTJ-UHFFFAOYSA-N 0.000 description 1
YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
229930185605 Bisphenol Natural products 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
101100130497 Drosophila melanogaster Mical gene Proteins 0.000 description 1
101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
241001274660 Modulus Species 0.000 description 1
101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
UCTLHLZWKJIXJI-LXIBVNSESA-N [(3s,8r,9s,10r,13s,14s)-17-chloro-16-formyl-10,13-dimethyl-2,3,4,7,8,9,11,12,14,15-decahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(Cl)=C(C=O)C[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 UCTLHLZWKJIXJI-LXIBVNSESA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
235000006708 antioxidants Nutrition 0.000 description 1
230000008901 benefit Effects 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
230000000332 continued effect Effects 0.000 description 1
238000006735 epoxidation reaction Methods 0.000 description 1
BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
238000009413 insulation Methods 0.000 description 1
229920000831 ionic polymer Polymers 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
238000000465 moulding Methods 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
229920003986 novolac Polymers 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
150000008442 polyphenolic compounds Chemical class 0.000 description 1
235000013824 polyphenols Nutrition 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
239000001294 propane Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
NMGNJWORLGLLHQ-UHFFFAOYSA-M sulcofuron-sodium Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 NMGNJWORLGLLHQ-UHFFFAOYSA-M 0.000 description 1
229940117958 vinyl acetate Drugs 0.000 description 1
238000004073 vulcanization Methods 0.000 description 1
XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0876—Neutralised polymers, i.e. ionomers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Epoxy Resins (AREA)
Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

CA000550197A 1986-11-17 1987-10-26 Dynamically crosslinked thermoplastic elastomer Expired - Lifetime CA1296821C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US93138986A	1986-11-17	1986-11-17
US931,389		1986-11-17

Publications (1)

Publication Number	Publication Date
CA1296821C true CA1296821C (en)	1992-03-03

Family

ID=25460714

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000550197A Expired - Lifetime CA1296821C (en)	1986-11-17	1987-10-26	Dynamically crosslinked thermoplastic elastomer

Country Status (9)

Country	Link
JP (1)	JPS63159437A (it)
BE (1)	BE1001175A3 (it)
CA (1)	CA1296821C (it)
DE (1)	DE3738335A1 (it)
FR (1)	FR2606780A1 (it)
GB (1)	GB2197654B (it)
GR (1)	GR871731B (it)
IT (1)	IT1223126B (it)
SE (1)	SE8704473L (it)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5091478A (en) *	1986-11-14	1992-02-25	E. I. Du Pont De Nemours And Company	Partially grafted thermoplastic compositions
JP2521807B2 (ja) *	1989-01-31	1996-08-07	三井・デュポンポリケミカル株式会社	アイオノマ―の組成物
JP3064090B2 (ja) *	1992-02-17	2000-07-12	住友ゴム工業株式会社	ゴルフボール
JP2709562B2 (ja) *	1993-07-02	1998-02-04	住友ゴム工業株式会社	ゴルフボール
JP2004507375A (ja) *	1999-08-26	2004-03-11	ピレリ・プネウマティチ・ソチエタ・ペル・アツィオーニ	タイヤを製造する方法、それによって得られたタイヤおよびそれに使用されるエラストマー組成物
EP1326916A2 (en) *	2000-09-26	2003-07-16	PIRELLI PNEUMATICI S.p.A.	Tyre for vehicle wheel and process for producing it
KR101695168B1 (ko)	2009-03-05	2017-01-11	아크조노벨코팅스인터내셔널비.브이.	하이드록실 작용성 오일 폴리올 아크릴계 그라프트 코폴리머
US9260625B2 (en)	2011-12-21	2016-02-16	Akzo Nobel Coatings International B.V.	Water-based coating compositions
WO2013092541A1 (en)	2011-12-21	2013-06-27	Akzo Nobel Coatings International B.V.	Solvent-based coating compositions
DE102013000708A1 (de)	2012-10-11	2014-04-17	Entex Rust & Mitschke Gmbh	Verfahren zur Extrusion von Kunststoffen, die zum Kleben neigen
DE102016002143A1 (de)	2016-02-25	2017-08-31	Entex Rust & Mitschke Gmbh	Füllteilmodul in Planetwalzenextruderbauweise
DE102016007290A1 (de)	2016-06-16	2017-12-21	Entex Rust & Mitschke Gmbh	Starter für das Devulkanisieren von Altgummi
DE102017006638A1 (de)	2017-07-13	2019-01-17	Entex Rust & Mitschke Gmbh	Füllteilmodul in Planetwalzenextruderbauweise
WO2019166125A1 (de)	2018-02-28	2019-09-06	Entex Rust & Mitschke Gmbh	Verfahren zur herstellung und verarbeitung von polymeren und polymermischungen in einem modular aufgebauten planetwalzenextruder

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1054699B (de) *	1957-08-14	1959-04-09	Egon Eloed Dr Ing	Verfahren zur Vulkanisation von Carboxylgruppen enthaltendem synthetischem Kautschuk
US3437718A (en) *	1967-01-23	1969-04-08	Du Pont	Polymer blends
JPS4744351B1 (it) *	1970-04-06	1972-11-09
US4415690A (en) *	1982-05-17	1983-11-15	The Goodyear Tire & Rubber Company	Succinic anhydride derivatives as a scorch inhibitor for carboxylated rubbers
US4639487A (en) *	1984-07-11	1987-01-27	Exxon Research & Engineering Co.	Heat shrinkable thermoplastic olefin composition
GB8510392D0 (en) *	1985-04-24	1985-05-30	British Petroleum Co Plc	Production of thermoplastic elastomer composition

1987
- 1987-10-26 CA CA000550197A patent/CA1296821C/en not_active Expired - Lifetime
- 1987-11-11 DE DE19873738335 patent/DE3738335A1/de not_active Withdrawn
- 1987-11-13 GR GR871731A patent/GR871731B/el unknown
- 1987-11-13 IT IT22638/87A patent/IT1223126B/it active
- 1987-11-16 GB GB8726795A patent/GB2197654B/en not_active Expired - Lifetime
- 1987-11-16 SE SE8704473A patent/SE8704473L/xx not_active Application Discontinuation
- 1987-11-17 BE BE8701299A patent/BE1001175A3/fr not_active IP Right Cessation
- 1987-11-17 JP JP62288616A patent/JPS63159437A/ja active Pending
- 1987-11-17 FR FR8715865A patent/FR2606780A1/fr not_active Withdrawn

Also Published As

Publication number	Publication date
GR871731B (en)	1988-03-28
DE3738335A1 (de)	1988-05-26
GB8726795D0 (en)	1987-12-23
IT8722638A0 (it)	1987-11-13
SE8704473D0 (sv)	1987-11-16
IT1223126B (it)	1990-09-12
SE8704473L (sv)	1988-05-18
JPS63159437A (ja)	1988-07-02
FR2606780A1 (fr)	1988-05-20
BE1001175A3 (fr)	1989-08-08
GB2197654A (en)	1988-05-25
GB2197654B (en)	1990-08-29

Legal Events

Date	Code	Title	Description
1996-09-03	MKLA	Lapsed

Publication	Publication Date	Title
CA1296821C (en)	1992-03-03	Dynamically crosslinked thermoplastic elastomer
CA1309786C (en)	1992-11-03	Polyester resin composition
EP0247580B1 (en)	1992-08-12	Thermoplastic composition of crystalline polyolefin and ethylene-containing copolymer
US4829124A (en)	1989-05-09	Dynamically crosslinked thermoplastic elastomer
DE3788254T2 (de)	1994-06-16	Polyamid enthaltende thermoplastische Harzzusammensetzung.
CA2119394A1 (en)	1994-10-01	Golf ball cover
EP0557069B1 (en)	1997-05-28	Golf ball
EP0534779B1 (en)	1996-01-10	Golf ball
EP0013481A1 (en)	1980-07-23	Compositions of chlorinated polyethylene rubber and nylon
US6525139B2 (en)	2003-02-25	Golf ball
JPH09510243A (ja)	1997-10-14	ゴルフボールのカバーに有用な高流動性イオノマー樹脂組成物
US4119592A (en)	1978-10-10	Rubbery bladders from epoxy compositions
DD283830A5 (de)	1990-10-24	Thermoplastische elastomerzusammensetzungen
CA1276342C (en)	1990-11-13	Thermoplastic elastomers containing cross-linked epihalohydrin rubbers
EP2123694A1 (de)	2009-11-25	Copolyamide
US4661563A (en)	1987-04-28	Polyamide-rubber blend composition
CA2187763A1 (en)	1995-10-26	Epoxidized low viscosity rubber toughening modifiers for epoxy resins
US4258917A (en)	1981-03-31	Rotocasting process for producing rubbery reinforced articles
EP0040060A2 (en)	1981-11-18	Compositions of cured epichlorohydrin rubber and nylon
DE69028027T2 (de)	1997-01-02	Verformbare Polyamidharzmischung und deren Herstellung
EP0214724B1 (en)	1992-02-26	Resin composition of saponified ethylenic copolymer
EP0146965A2 (en)	1985-07-03	Polymer blends containing a polymer having pendant oxazoline groups
US6384139B1 (en)	2002-05-07	Crosslinked elastomers processes for their manufacture and articles made from these elastomers
WO1983000158A1 (en)	1983-01-20	Clear, autoclavable thermoplastic formulation for medical liquid containers
JPH062876B2 (ja)	1994-01-12	ゴム状樹脂組成物