CA1122584A - Process for producing plate-shaped denitrating catalysts - Google Patents
Process for producing plate-shaped denitrating catalystsInfo
- Publication number
- CA1122584A CA1122584A CA334,129A CA334129A CA1122584A CA 1122584 A CA1122584 A CA 1122584A CA 334129 A CA334129 A CA 334129A CA 1122584 A CA1122584 A CA 1122584A
- Authority
- CA
- Canada
- Prior art keywords
- sol
- plate
- slurry
- catalyst
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052751 metal Inorganic materials 0.000 claims abstract description 21
- 239000002184 metal Substances 0.000 claims abstract description 21
- 239000002002 slurry Substances 0.000 claims abstract description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011230 binding agent Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000010304 firing Methods 0.000 claims abstract description 12
- 239000011148 porous material Substances 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 4
- 238000010298 pulverizing process Methods 0.000 claims abstract description 3
- 239000002253 acid Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- -1 organic acid salts Chemical class 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 150000005324 oxide salts Chemical class 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000008279 sol Substances 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 1
- 241000264877 Hippospongia communis Species 0.000 description 15
- 235000010215 titanium dioxide Nutrition 0.000 description 15
- 239000000306 component Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0225—Coating of metal substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1023—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1025—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP116187/78 | 1978-09-20 | ||
JP11618778A JPS5541881A (en) | 1978-09-20 | 1978-09-20 | Manufacture of plate type denitrification catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1122584A true CA1122584A (en) | 1982-04-27 |
Family
ID=14680965
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA334,129A Expired CA1122584A (en) | 1978-09-20 | 1979-08-20 | Process for producing plate-shaped denitrating catalysts |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5541881A (de) |
BE (1) | BE877183A (de) |
CA (1) | CA1122584A (de) |
DE (1) | DE2927253C2 (de) |
FR (1) | FR2436628A1 (de) |
GB (1) | GB2029720B (de) |
IT (1) | IT1118887B (de) |
NL (1) | NL179551C (de) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0053884A1 (de) * | 1980-11-27 | 1982-06-16 | Johnson Matthey Public Limited Company | Dreidimensionaler, interstitieller Trägerkatalysator, seine Herstellung und Verwendung |
EP0061304A1 (de) * | 1981-03-18 | 1982-09-29 | Johnson Matthey Public Limited Company | Dreidimensionaler mit Durchgängen versehener Katalysatorträger, seine Herstellung und Verwendung |
EP0179578B1 (de) * | 1984-10-22 | 1990-07-04 | Ford Motor Company Limited | Methode zur Verlängerung der Betriebsdauer eines Katalysators |
DE3526383C1 (de) * | 1985-07-24 | 1986-12-11 | Didier-Werke Ag, 6200 Wiesbaden | Verfahren zur Erzeugung von Katalysatoren fuer die Reduktion von Stickoxiden aus Abgasen und chemische Luftreinigungsverfahren |
JPS6323274U (de) * | 1986-07-28 | 1988-02-16 | ||
JPH03205A (ja) * | 1989-05-26 | 1991-01-07 | Norin Suisansyo Shinrin Sogo Kenkyusho | 表面加熱による集成材の製造方法とその装置 |
DE4141513A1 (de) * | 1991-12-16 | 1993-06-17 | Siemens Ag | Katalysatoranordnung fuer weitgehend staubfreie gase |
DE4229255A1 (de) * | 1992-09-02 | 1994-03-03 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Katalysatoren zur Entfernung von Stickstoffoxiden aus Abgasen |
FR2707527B1 (fr) * | 1993-07-13 | 1995-09-15 | Inst Francais Du Petrole | Catalyseur comprenant un assemblage d'au moins un fil et son utilisation en combustion ou en post-combustion. |
JP3926382B2 (ja) * | 1994-09-26 | 2007-06-06 | エミテク・ゲゼルシャフト・フュール・エミシオーンテクノロギー・ミット・ベシュレンクテル・ハフツング | 交差配置のミクロ構造を有するハニカム本体 |
DE19820433A1 (de) | 1998-05-07 | 1999-11-11 | Emitec Emissionstechnologie | Tragstruktur mit einem Deformationselement mit schräger Krafteinleitung |
DE19820449A1 (de) | 1998-05-07 | 1999-11-11 | Emitec Emissionstechnologie | Tragstruktur mit einem Deformationselement mit verkürzter Restblocklänge |
DE19820463A1 (de) | 1998-05-07 | 1999-11-11 | Emitec Emissionstechnologie | Tragstruktur mit einem Deformationselement mit Radialverformungsbegrenzern |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3437605A (en) * | 1965-01-26 | 1969-04-08 | Engelhard Ind Inc | Method of preparing a supported catalyst |
FR2182614B1 (de) * | 1972-03-17 | 1978-05-05 | Louyot Comptoir Lyon Alemand | |
US4076792A (en) * | 1972-04-12 | 1978-02-28 | Corning Glass Works | Catalyst systems for the reduction of the oxides of nitrogen |
CA1001147A (en) * | 1972-11-30 | 1976-12-07 | Takashi Ohara | Method for the production of exhaust and waste gases purifying catalysts |
US4157315A (en) * | 1973-12-21 | 1979-06-05 | The International Nickel Company, Inc. | Method of preparing a supported catalyst and the catalyst prepared by the method |
JPS5277890A (en) * | 1975-12-23 | 1977-06-30 | Sakai Chemical Industry Co | Method of manufacturing carriers |
JPS5932180B2 (ja) * | 1976-11-27 | 1984-08-07 | 三井化学株式会社 | 窒素酸化物の還元用触媒 |
JPS52129692A (en) * | 1976-04-24 | 1977-10-31 | Nippon Sheet Glass Co Ltd | Honeycomb catalyst structures |
JPS5395892A (en) * | 1977-02-03 | 1978-08-22 | Mizusawa Industrial Chem | Titanium oxide catalyst carrier mold product and manufacture thereof |
-
1978
- 1978-09-20 JP JP11618778A patent/JPS5541881A/ja active Granted
-
1979
- 1979-06-07 GB GB7919782A patent/GB2029720B/en not_active Expired
- 1979-06-08 NL NLAANVRAGE7904502,A patent/NL179551C/xx not_active IP Right Cessation
- 1979-06-22 BE BE2/57901A patent/BE877183A/xx not_active IP Right Cessation
- 1979-06-28 FR FR7916745A patent/FR2436628A1/fr active Granted
- 1979-07-04 IT IT49657/79A patent/IT1118887B/it active
- 1979-07-05 DE DE2927253A patent/DE2927253C2/de not_active Expired
- 1979-08-20 CA CA334,129A patent/CA1122584A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
IT7949657A0 (it) | 1979-07-04 |
NL179551C (nl) | 1986-10-01 |
DE2927253C2 (de) | 1983-12-08 |
IT1118887B (it) | 1986-03-03 |
NL7904502A (nl) | 1980-03-24 |
FR2436628B1 (de) | 1983-06-17 |
DE2927253A1 (de) | 1980-03-27 |
JPS615772B2 (de) | 1986-02-21 |
JPS5541881A (en) | 1980-03-24 |
NL179551B (nl) | 1986-05-01 |
GB2029720A (en) | 1980-03-26 |
BE877183A (fr) | 1979-10-15 |
FR2436628A1 (fr) | 1980-04-18 |
GB2029720B (en) | 1982-12-15 |
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Legal Events
Date | Code | Title | Description |
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MKEX | Expiry |