BR9913900A - Processo para a manufatura de glicidilésteres de ácidos monocarboxìlicos alfa-ramificados - Google Patents

Processo para a manufatura de glicidilésteres de ácidos monocarboxìlicos alfa-ramificados

Info

Publication number
BR9913900A
BR9913900A BR9913900-6A BR9913900A BR9913900A BR 9913900 A BR9913900 A BR 9913900A BR 9913900 A BR9913900 A BR 9913900A BR 9913900 A BR9913900 A BR 9913900A
Authority
BR
Brazil
Prior art keywords
monocarboxylic acid
alkali metal
water
manufacture
branched monocarboxylic
Prior art date
Application number
BR9913900-6A
Other languages
English (en)
Other versions
BR9913900B1 (pt
Inventor
Hendrik Stichter
Denis Marie Charles Heymans
Gerrit Gerardus Rosenbrand
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26150717&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR9913900(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of BR9913900A publication Critical patent/BR9913900A/pt
Publication of BR9913900B1 publication Critical patent/BR9913900B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/27—Condensation of epihalohydrins or halohydrins with compounds containing active hydrogen atoms
    • C07D301/30—Condensation of epihalohydrins or halohydrins with compounds containing active hydrogen atoms by reaction with carboxyl radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO PARA A MANUFATURA DE GLICIDILéSTERES DE áCIDOS MONOCARBOXìLICOS ALFA-RAMIFICADOS" Um processo para a manufatura de glicidilésteres de ácidos monocarboxílicos ramificados, compreendendo (a) a reação do ácido monocarboxílico <244>-ramificado com um monoepóxido halo substituído tal como uma epialoidrina (p. ex., epicloroidrina), em um excesso molar de 2-20, na presença de água e um solvente miscível com água como solvente e na presença de um catalisador, em uma quantidade de no máximo 45% em mol da quantidade molar dos grupos ácidos monocarboxílicos e, preferivelmente, no máximo 30% em mol, em uma temperatura na faixa de 50 a 110, durante um período na faixa de 0,8 a 2,5 h, (b) adição de hidróxido de metal alcalino ou alcanolato de metal alcalino adicional até próximo de uma quantidade equimolar quanto ao ácido monocarboxílico e reação em uma temperatura de 40 a 80°C, (c) distilação da mistura de reação obtida para remover o excesso de monoepóxido halo substituído e do solvente e água formados, e (d) remoção do sal de haleto de metal alcalino, p. ex., pela lavagem do glicidiléster obtido com água após opcionalmente tratar o produto residual com uma solução de hidróxido de metal alcalino aquosa concentrada, a fim de completar a desidroalogenação (e, preferivelmente, uma desidrocloração).
BRPI9913900-6A 1998-09-23 1999-09-22 processo para a manufatura de glicidilÉsteres de Ácidos monocarboxÍlicos alfa-ramificados. BR9913900B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP98203204.7 1998-09-23
EP98203204 1998-09-23
EP9920442.2 1999-07-23
EP99202442 1999-07-23
PCT/EP1999/007393 WO2000017179A1 (en) 1998-09-23 1999-09-22 Process for the preparation of glycidylesters of branched carboxylic acids

Publications (2)

Publication Number Publication Date
BR9913900A true BR9913900A (pt) 2001-07-03
BR9913900B1 BR9913900B1 (pt) 2010-03-23

Family

ID=26150717

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9913900-6A BR9913900B1 (pt) 1998-09-23 1999-09-22 processo para a manufatura de glicidilÉsteres de Ácidos monocarboxÍlicos alfa-ramificados.

Country Status (13)

Country Link
US (1) US6433217B1 (pt)
EP (1) EP1115714B1 (pt)
KR (1) KR100663575B1 (pt)
CN (1) CN1147484C (pt)
AR (1) AR020494A1 (pt)
AT (1) ATE217618T1 (pt)
AU (1) AU6333899A (pt)
BR (1) BR9913900B1 (pt)
CA (1) CA2344450C (pt)
DE (1) DE69901510T2 (pt)
PL (1) PL348105A1 (pt)
TW (1) TW455584B (pt)
WO (1) WO2000017179A1 (pt)

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EP2149569A1 (en) 2008-08-01 2010-02-03 Hexion Specialty Chemicals Research Belgium S.A. Process for the manufacture of a 1,2-Epoxide
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DE102009056187A1 (de) 2008-11-28 2010-07-15 Basf Se Polyesterharz auf Basis von 2-Propylheptansäureglycidester und/oder 4-Methyl-2 propylhexansäureglycidester
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CN102408396B (zh) * 2010-09-26 2014-09-10 西南化工研究设计院 一种叔碳酸缩水甘油酯的制备方法
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JP6116577B2 (ja) 2011-11-17 2017-04-19 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ グリセロールジエステルを含有する被覆剤および多層塗膜における当該被覆剤の使用
WO2013075806A2 (en) * 2011-11-25 2013-05-30 Momentive Specialty Chemicals Research Beigium Sa Epoxy compositions
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CN103183652B (zh) * 2011-12-28 2016-04-06 河北四友卓越科技有限公司 叔碳酸缩水甘油酯的制备方法
DE102012105879A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isononylderivaten
DE102012013969B4 (de) 2012-07-13 2017-09-14 Oxea Gmbh Verfahren zur Herstellung eines Gemisches stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol
CN102924407A (zh) * 2012-11-30 2013-02-13 西南化工研究设计院有限公司 一种一元羧酸缩水甘油酯的精制方法
DE102013009323B4 (de) 2013-06-01 2018-09-20 Oxea Gmbh Verfahren zur Herstellung von Gemischen enthaltend tertiäre Isononansäuren ausgehend von 2-Ethylhexanol
US9884981B2 (en) 2014-02-21 2018-02-06 IFS Industries Inc. Polyol compositions for hot melt adhesives
KR101590446B1 (ko) 2014-04-25 2016-02-02 주식회사 케이씨씨 고순도 분지형 모노카르복실산 변성 에폭시 반응성 희석제의 제조 방법
DE102014013123B4 (de) 2014-08-30 2020-01-02 Oxea Gmbh Verfahren zur Herstellung von Gemischen enthaltend tertiäre lsononansäuren ausgehend von 2-Ethylhexanol
KR101650528B1 (ko) * 2015-04-24 2016-08-23 대달산업주식회사 알파-분지형 지방족 모노카르복시산의 글리시딜 에스테르의 제조 방법
EP3115409A1 (en) * 2015-07-10 2017-01-11 Hexion Research Belgium SA Odorless polyester stabilizer compositions
WO2017077846A1 (ja) * 2015-11-05 2017-05-11 日産化学工業株式会社 エポキシ系反応性希釈剤及びそれを含むエポキシ樹脂組成物
KR20170112515A (ko) 2016-03-31 2017-10-12 코오롱인더스트리 주식회사 글리시딜에스테르 화합물의 제조방법
KR20180022284A (ko) * 2016-08-24 2018-03-06 주식회사 케이씨씨 에폭시 반응성 희석제의 제조 방법
CN106957284B (zh) * 2017-04-14 2019-02-19 西南化工研究设计院有限公司 一种叔碳酸缩水甘油酯粗产品的分离提纯精制工艺
KR101970883B1 (ko) * 2017-06-23 2019-04-19 주식회사 케이씨씨 글리시딜 에스테르의 제조방법
TWI647265B (zh) * 2018-02-05 2019-01-11 Taiwan Union Technology Corporation 樹脂組合物，以及使用該組合物所製得之預浸漬片、金屬箔積層板、與印刷電路板
CN109851503B (zh) * 2019-01-30 2022-06-03 天津现代职业技术学院 一种水相制备柠檬酸单脂肪酸甘油酯的方法
KR20210146298A (ko) * 2019-03-27 2021-12-03 세키스이가가쿠 고교가부시키가이샤 수지 재료 및 다층 프린트 배선판
CN110385902B (zh) * 2019-07-31 2021-06-04 四川省川汇塑胶有限公司 一种增强热塑性塑料复合管及其制备方法
CN115701284A (zh) * 2020-03-20 2023-02-07 英格维蒂南卡罗来纳有限责任公司 妥尔油衍生的缩水甘油酯及其制备方法
CN113845495B (zh) * 2021-10-20 2023-08-01 清华大学 两段式新癸酸缩水甘油酯的连续合成方法

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Also Published As

Publication number Publication date
EP1115714A1 (en) 2001-07-18
KR100663575B1 (ko) 2007-01-02
AU6333899A (en) 2000-04-10
JP2002526484A (ja) 2002-08-20
PL348105A1 (en) 2002-05-06
KR20010090503A (ko) 2001-10-18
WO2000017179A1 (en) 2000-03-30
CA2344450C (en) 2009-08-11
EP1115714B1 (en) 2002-05-15
US6433217B1 (en) 2002-08-13
CA2344450A1 (en) 2000-03-30
CN1147484C (zh) 2004-04-28
CN1325392A (zh) 2001-12-05
BR9913900B1 (pt) 2010-03-23
DE69901510T2 (de) 2002-08-29
AR020494A1 (es) 2002-05-15
JP4672145B2 (ja) 2011-04-20
ATE217618T1 (de) 2002-06-15
DE69901510D1 (de) 2002-06-20
TW455584B (en) 2001-09-21

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