BR9913221A - Composições catalisadoras sustentadas altamente ativas - Google Patents

Composições catalisadoras sustentadas altamente ativas

Info

Publication number
BR9913221A
BR9913221A BR9913221-4A BR9913221A BR9913221A BR 9913221 A BR9913221 A BR 9913221A BR 9913221 A BR9913221 A BR 9913221A BR 9913221 A BR9913221 A BR 9913221A
Authority
BR
Brazil
Prior art keywords
catalyst compositions
highly active
active sustained
sustained catalyst
olefins
Prior art date
Application number
BR9913221-4A
Other languages
English (en)
Other versions
BR9913221B1 (pt
Inventor
Anthony N Speca
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of BR9913221A publication Critical patent/BR9913221A/pt
Publication of BR9913221B1 publication Critical patent/BR9913221B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Patente de Invenção: <B>"COMPOSIçõES CATALISADORAS SUSTENTADAS ALTAMENTE ATIVAS"<D>. Esta invenção refere-se a composições catalisadoras de metaloceno que são altamente ativas para a polimerização de olefinas, particularmente <244>-olefinas proquirais. As composições catalisadoras contêm pelo menos um metaloceno, e pelo menos um ativador e um suporte que foi fluorado usando um composto contendo fluoreto.
BRPI9913221-4A 1998-08-26 1999-06-24 composiÇço catalisadora suportada de metaloceno. BR9913221B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US9800798P 1998-08-26 1998-08-26
PCT/US1999/014577 WO2000012565A1 (en) 1998-08-26 1999-06-24 Highly active supported catalyst compositions

Publications (2)

Publication Number Publication Date
BR9913221A true BR9913221A (pt) 2001-05-22
BR9913221B1 BR9913221B1 (pt) 2008-11-18

Family

ID=22266211

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9913221-4A BR9913221B1 (pt) 1998-08-26 1999-06-24 composiÇço catalisadora suportada de metaloceno.

Country Status (11)

Country Link
US (5) US6368999B1 (pt)
EP (1) EP1109839B1 (pt)
JP (1) JP2002523568A (pt)
KR (1) KR100592621B1 (pt)
CN (1) CN1142190C (pt)
BR (1) BR9913221B1 (pt)
CA (1) CA2338603C (pt)
DE (1) DE69908147T2 (pt)
ES (1) ES2197649T3 (pt)
HK (1) HK1039134A1 (pt)
WO (1) WO2000012565A1 (pt)

Families Citing this family (104)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6613712B1 (en) * 1999-11-24 2003-09-02 Phillips Petroleum Company Organometal catalyst compositions with solid oxide supports treated with fluorine and boron
US6548442B1 (en) * 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6576583B1 (en) * 2000-02-11 2003-06-10 Phillips Petroleum Company Organometal catalyst composition
US7098277B2 (en) * 2000-08-22 2006-08-29 Exxonmobil Chemical Patents Inc. Polypropylene films
DE60137341D1 (de) 2000-08-22 2009-02-26 Exxonmobil Chem Patents Inc Polypropylen filme
US6914027B2 (en) * 2000-12-01 2005-07-05 Univation Technologies, Llc Polymerization reactor operability using static charge modifier agents
KR100422940B1 (ko) * 2000-12-23 2004-03-12 주식회사 엘지화학 하프 메탈로센 촉매 및 이를 이용한 입체규칙성을 가진비닐 방향족 중합체의 제조방법
CA2357385C (en) * 2001-09-17 2010-06-15 Nova Chemicals Corporation Supported phosphinimine polymerization catalyst
US7381778B2 (en) 2002-06-06 2008-06-03 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US7223823B2 (en) * 2002-06-06 2007-05-29 Exxon Mobil Chemical Patents Inc. Catalyst system and process
JP2005528512A (ja) * 2002-06-06 2005-09-22 エクソンモービル・ケミカル・パテンツ・インク 触媒系及びオレフィン重合法
US7192901B2 (en) * 2004-10-27 2007-03-20 Exxonmobil Chemical Patents Inc. Method of preparing a treated support
US6884748B2 (en) * 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
EP1556423A1 (en) * 2002-10-09 2005-07-27 Exxonmobil Chemical Patents Inc. Methods of feed purification for olefin polymerization
EP1556422B1 (en) * 2002-10-09 2006-03-29 Exxonmobil Chemical Patents Inc. Methods of delivering catalyst systems for propylene polymerization
EP1556424B1 (en) * 2002-10-09 2006-03-22 Exxonmobil Chemical Patents Inc. Methods for injecting catalyst into a polymerization reactor
KR100497172B1 (ko) * 2002-11-11 2005-06-28 주식회사 엘지화학 양쪽 메탈로센 유도체 화합물을 리간드로 가진 다중핵반쪽 메탈로센 촉매 및 이를 이용한 스티렌 중합체의제조방법
US6900154B2 (en) * 2002-11-26 2005-05-31 Univation Technologies, Llc Methods of forming a supported activated catalyst composition
WO2005003184A1 (en) * 2003-06-11 2005-01-13 Exxonmobil Chemical Patents Inc. Polymerization processes using antistatic agents
US6992034B2 (en) * 2003-07-10 2006-01-31 Formosa Plastics Corporation, U.S.A. Catalyst component for olefin polymerization
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US7217676B2 (en) * 2004-01-16 2007-05-15 Exxon Mobil Chemical Patents Inc. Hydrophobization and silica for supported catalyst
US7456021B2 (en) * 2004-01-16 2008-11-25 Exxonmobil Chemical Patents Inc. Analysis method
BRPI0513057A (pt) * 2004-07-08 2008-04-22 Exxonmobil Chem Patents Inc produção de polìmero em condições supercrìticas
EP1805226A1 (en) 2004-10-29 2007-07-11 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
FR2879479B1 (fr) * 2004-12-17 2007-11-09 Armines Ass Loi De 1901 Structures composites en etat amorphe pour la photocatalyse
EP1829897B1 (en) * 2004-12-17 2014-12-10 Yangzi Petrochemical Company Co., Ltd. Supported non-metallocene olefin polymerization catalyst, and preparation and use thereof
US7247594B2 (en) * 2005-04-13 2007-07-24 Chevron Phillips Chemical Co. Lp Catalysts for olefin polymerization
EP1741725B1 (en) * 2005-07-08 2014-04-09 Borealis Technology Oy Propylene polymer composition
EP1749842A1 (en) * 2005-08-03 2007-02-07 Total Petrochemicals Research Feluy Transition metal complexes supported on activating fluorinated support
US8110518B2 (en) * 2006-04-28 2012-02-07 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US20070255026A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Process for polyolefin production using fluorinated transition metal catalysts having a low pH
US20070255028A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
WO2007127416A2 (en) * 2006-04-28 2007-11-08 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US20070254800A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US8138285B2 (en) * 2007-10-26 2012-03-20 Fina Technology, Inc. Fluorinated impregnated catalyst systems and methods of forming the same
EP2112175A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane
KR101271055B1 (ko) * 2008-03-28 2013-06-04 에스케이종합화학 주식회사 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의제조방법
US8204156B2 (en) * 2008-12-31 2012-06-19 Intel Corporation Phase error detection with conditional probabilities
MY173869A (en) 2009-06-16 2020-02-25 Chevron Phillips Chemical Co Lp Oligomerization of alpha olefins using metallocene-ssa catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends
EP2485839A1 (en) * 2009-10-06 2012-08-15 Chevron Phillips Chemical Company LP Oligomerization of olefin waxes using metallocene-based catalyst systems
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
WO2013028283A1 (en) * 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
JP6016426B2 (ja) * 2012-04-16 2016-10-26 三井化学株式会社 オレフィン重合用触媒
JP6618356B2 (ja) * 2012-04-27 2019-12-11 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 活性剤組成物、その調製、及び触媒におけるその使用
EP3183059A1 (en) * 2014-08-19 2017-06-28 Univation Technologies, LLC Fluorinated catalyst supports and catalyst systems
BR112017003170B1 (pt) * 2014-08-19 2022-02-15 Univation Technologies, Llc Método para fazer um suporte de catalisador de alumina-sílica fluorado e sistema de catalisador de alumina-sílica fluorado
CA2958435C (en) * 2014-08-19 2023-06-13 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
KR101761394B1 (ko) 2014-09-30 2017-07-25 주식회사 엘지화학 섬유 제조용 폴리올레핀 중합체의 제조방법
WO2016171808A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
EP3274380B1 (en) 2015-04-20 2020-08-19 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
US10647786B2 (en) 2015-04-20 2020-05-12 Exxonmobil Chemical Patents, Inc. Supported catalyst systems and processes for use thereof
KR102066335B1 (ko) 2015-04-20 2020-01-14 엑손모빌 케미칼 패턴츠 인코포레이티드 지지된 촉매 시스템 및 이의 사용 방법
EP3274381B1 (en) 2015-04-20 2019-05-15 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
US9988410B2 (en) 2015-07-15 2018-06-05 Exxonmobil Chemical Patents Inc. Substituted bis indenyl metallocene catalyst compounds comprising-Si—Si-bridge
WO2017011073A1 (en) * 2015-07-15 2017-01-19 Exxonmobil Chemical Patents Inc. Substituted bis indenyl metallocene catalyst compounds comprising-si-si-bridge
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
EP3344665A4 (en) 2015-08-31 2019-08-14 ExxonMobil Chemical Patents Inc. ALUMINUM ALKYLE WITH HANGING OLEFINS FOR POLYOLEFINREACTIONS
CN107921424A (zh) 2015-08-31 2018-04-17 埃克森美孚化学专利公司 粘土上的具有悬垂烯烃的烷基铝
US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
US9975973B2 (en) 2015-10-02 2018-05-22 Exxonmobil Chemical Patents Inc. Asymmetric fluorenyl-substituted salan catalysts
US10414887B2 (en) * 2015-10-02 2019-09-17 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
US10000593B2 (en) 2015-10-02 2018-06-19 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
WO2017058392A1 (en) * 2015-10-02 2017-04-06 Exxonmobil Chemical Patents Inc. Supported bis phenolate transition metal complexes, production and use thereof
US9994657B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9994658B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
WO2017058386A1 (en) * 2015-10-02 2017-04-06 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
WO2017058388A1 (en) * 2015-10-02 2017-04-06 Exxonmobil Chemical Patents Inc. Supported salan catalysts
US9982076B2 (en) 2015-10-02 2018-05-29 Exxonmobil Chemical Patents Inc. Supported bis phenolate transition metals complexes, production and use thereof
WO2017192226A1 (en) 2016-05-03 2017-11-09 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
KR101856202B1 (ko) * 2016-07-12 2018-05-10 대림산업 주식회사 개질된 담체를 포함하는 폴리올레핀 중합 촉매 및 이를 이용한 폴리올레핀의 제조 방법
BR112019005191B1 (pt) 2016-09-30 2022-12-20 Univation Technologies, Llc Catalisador de polimerização e método de produção de polietileno tendo encadeamento de etileno aprimorado
BR112019005082B1 (pt) 2016-09-30 2022-12-20 Univation Technologies, Llc Sistema de catalisador de polimerização bimodal e método para produzir um polietileno bimodal
WO2018075243A1 (en) 2016-10-19 2018-04-26 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
US11299563B2 (en) 2016-10-28 2022-04-12 Univation Technologies, Llc Controlling reactor split and a product parameter
BR112019008131B1 (pt) 2016-11-08 2022-12-20 Univation Technologies, Llc Polietileno bimodal
WO2018102080A1 (en) 2016-12-02 2018-06-07 Exxonmobil Chemical Patens Inc. Olefin polymerization catalyst systems and methods for making the same
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US10723819B2 (en) 2017-02-20 2020-07-28 Exxonmobil Chemical Patents, Inc. Supported catalyst systems and processes for use thereof
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
US10676551B2 (en) 2017-03-01 2020-06-09 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
US10913808B2 (en) 2017-08-04 2021-02-09 Exxonmobil Chemical Patents Inc. Mixed catalysts with unbridged hafnocenes with -CH2-SiMe3 moieties
US10844150B2 (en) 2017-08-04 2020-11-24 Exxonmobil Chemical Patents Inc. Mixed catalysts with 2,6-bis(imino)pyridyl iron complexes and bridged hafnocenes
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
CN111372954B (zh) 2017-11-14 2022-06-28 埃克森美孚化学专利公司 制备聚乙烯宽分子量分布和分子量的(二)硅桥联金属茂
US10926250B2 (en) 2017-12-01 2021-02-23 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
WO2019108977A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
US10851187B2 (en) 2018-01-31 2020-12-01 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10865258B2 (en) 2018-01-31 2020-12-15 Exxonmobil Chemical Patents Inc. Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
WO2019156968A1 (en) 2018-02-07 2019-08-15 Exxonmobil Chemical Patents Inc. Supported catalysts systems and polymerization processes for using the same
US10894841B2 (en) 2018-03-19 2021-01-19 Exxonmobil Chemical Patents Inc. Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
WO2019194961A1 (en) 2018-04-06 2019-10-10 Exxonmobil Chemical Patents Inc. Themoplastic vulcanizate compositions
WO2020056119A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
EP3927765A1 (en) 2019-02-20 2021-12-29 Fina Technology, Inc. Polymer compositions with low warpage
US20220251361A1 (en) 2019-07-17 2022-08-11 Exxonmobil Chemical Patents Inc. High Propylene Content EP Having Low Glass Transition Temperatures
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
EP4277936A1 (en) 2021-01-12 2023-11-22 ExxonMobil Chemical Patents Inc. Asymmetric constrained geometry catalysts
JP2024518327A (ja) 2021-04-26 2024-05-01 フイナ・テクノロジー・インコーポレーテツド 薄シングルサイト触媒ポリマーシート

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3340319A (en) 1964-05-18 1967-09-05 Phillips Petroleum Co Selective polymerization of isobutene
LU61899A1 (pt) 1970-10-20 1972-06-28
US4130505A (en) 1974-09-26 1978-12-19 Phillips Petroleum Company Two stage activation of fluorided chromium-containing catalyst
US4101445A (en) 1976-09-22 1978-07-18 Union Carbide Corporation Preparation of modified and activated chromocene catalysts for ethylene polymerization
US4347162A (en) 1981-03-06 1982-08-31 Euteco Impianti S.P.A. Catalyst for the polymerization of alpha-olefins
US4359403A (en) 1981-04-13 1982-11-16 Chemplex Company Polymerization catalyst and method
AU8807882A (en) 1981-09-21 1983-03-31 Mobil Oil Corp. Catalyst composition with zeolite support
US4424139A (en) * 1982-03-30 1984-01-03 Phillips Petroleum Company Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4806513A (en) 1984-05-29 1989-02-21 Phillips Petroleum Company Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same
US4596862A (en) 1984-12-24 1986-06-24 Phillips Petroleum Company Olefin polymerization using chromium on fluorided aluminophosphate
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4912075A (en) 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
JP2775705B2 (ja) 1989-05-30 1998-07-16 三井化学株式会社 シンジオタクチックポリプロピレンの製造方法
AU6725790A (en) 1989-11-01 1991-05-31 Exxon Chemical Patents Inc. Support adjuvant for improved vanadium polymerization catalyst
US5064796A (en) 1991-01-07 1991-11-12 Exxon Chemical Patents Inc. Support adjuvant for improved vanadium polymerization catalyst
US5108975A (en) 1991-01-28 1992-04-28 Phillips Petroleum Company Composition and method of making high porosity, high strength compositions
US5364915A (en) 1992-09-25 1994-11-15 Phillips Petroleum Company Ethylene polymerization process
US5284926A (en) 1992-09-25 1994-02-08 Phillips Petroleum Company Catalyst system and process
EP0594914A1 (en) 1992-10-26 1994-05-04 Bp Chemicals S.N.C. Preparation of a catalyst for the manufacture of polyethylene
JP2882241B2 (ja) * 1993-06-07 1999-04-12 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
AU8052194A (en) 1993-10-20 1995-05-08 Enzon, Inc. 2'- and/or 7- substituted taxoids
US5543376A (en) * 1994-02-25 1996-08-06 Phillips Petroleum Company Process for producing polyolefins
EP0676418B1 (en) 1994-04-07 2000-07-26 BP Chemicals Limited Polymerisation process
US5643847A (en) 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
DE69523764T2 (de) 1994-08-03 2002-08-01 Exxonmobil Chem Patents Inc Ionische katalysatorzusammensetzung auf träger
US5939347A (en) 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
DE69611554T2 (de) 1995-02-20 2001-07-05 Tosoh Corp Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
WO1996041808A1 (fr) 1995-06-08 1996-12-27 Showa Denko K.K. Composes ioniques et catalyseurs destines a polymeriser les olefines au moyen de ces composes
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
KR100245267B1 (ko) 1996-06-03 2000-02-15 모리 하루오 차량용 네비게이션 장치
DE19622481A1 (de) 1996-06-05 1997-12-11 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6021480A (en) 1996-06-05 2000-02-01 Compaq Computer Corporation Aligning a memory read request with a cache line boundary when the request is for data beginning at a location in the middle of the cache line
FR2769245B1 (fr) 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants

Also Published As

Publication number Publication date
US20020123582A1 (en) 2002-09-05
BR9913221B1 (pt) 2008-11-18
KR20010079694A (ko) 2001-08-22
HK1039134A1 (zh) 2002-04-12
US6667272B2 (en) 2003-12-23
JP2002523568A (ja) 2002-07-30
DE69908147T2 (de) 2004-02-19
ES2197649T3 (es) 2004-01-01
US6664348B2 (en) 2003-12-16
US6846770B2 (en) 2005-01-25
US6368999B1 (en) 2002-04-09
CN1142190C (zh) 2004-03-17
CA2338603A1 (en) 2000-03-09
DE69908147D1 (de) 2003-06-26
US6524988B2 (en) 2003-02-25
CA2338603C (en) 2008-11-18
WO2000012565A1 (en) 2000-03-09
US20010051698A1 (en) 2001-12-13
KR100592621B1 (ko) 2006-06-23
EP1109839B1 (en) 2003-05-21
US20020160914A1 (en) 2002-10-31
CN1314918A (zh) 2001-09-26
EP1109839A1 (en) 2001-06-27
US20020169261A1 (en) 2002-11-14

Similar Documents

Publication Publication Date Title
BR9913221A (pt) Composições catalisadoras sustentadas altamente ativas
BR0014446A (pt) Composições catalisadoras organometais
BR0215405A (pt) Composições e processos de uso de collajolie
BR0014332A (pt) Composições de catalisadores organometálicos
BR9916132A (pt) Composições e utilização das mesmas
DK0892780T3 (da) m-Amidinophenylanaloger som faktor Xa-inhibitorer
ES2152653T3 (es) Cocatalizador de metaloceno.
UY26092A1 (es) Uso de inhibidores de cyp2d6 en terapias de combinacion
BR0300500B1 (pt) composiÇço poliolefÍnica, processo para estabilizaÇço de uma poliolefina e uso de uma mistura.
AU2733997A (en) N-(amidinophenyl)-n&#39;-(subst.)-3h-2,4-benzodiazepin-3-one derivatives as factor xa inhibitors
ES2195970T3 (es) L-ribavirina y usos de la misma.
BR0112030A (pt) Novos compostos que possuem atividade antibacteriana, antifúngica ou antitumor
ES2186720T3 (es) Composiciones para inhibir la reabsorcion osea mediada por osteoclastos.
PT1073470E (pt) Composicoes farmaceuticas contendo compostos com actividade capaz de melhorar a absorcao de ingredientes activos
BR0213207A (pt) remodelagem e glicoconjugação de peptìdeos
TR200000782T2 (tr) Resorsinol türevleri.
BR9913144B1 (pt) processo para polimerização de olefinas.
DE60324544D1 (de) Muskarin antagonisten
BR9910920A (pt) Composição não inflamável, e, processos de limpeza e de revestimento
DK0700380T3 (da) N-Alkylthiopolyaminderivater som radioprotektive midler
CU23043A1 (es) Composicion farmaceutica que contiene factor de crecimiento epidrmico (egf) para la prevencion de la amputacion de pie diabetico.
BR0212353A (pt) Composto, composição farmacêutica, e, uso de um composto
NO995963D0 (no) Karboksamider anvendelige som 5-HTIF-agonister
SE9801494D0 (sv) Novel use
PT1089625E (pt) Agentes ectoparasiticidas

Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/06/1999, OBSERVADAS AS CONDICOES LEGAIS.

B24C Patent annual fee: request for for restoration

Free format text: REFERENTE A 12A E 13A ANUIDADE(S), CONFORME ART. 87 DA LPI 9.279.

B24H Lapse because of non-payment of annual fees (definitively: art 78 iv lpi)
B24F Patent annual fee: publication cancelled

Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2259 DE 22/04/2014 POR TER SIDO INDEVIDA.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE AS 12A E 13A ANUIDADES.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2607 DE 22-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.