BR112015006495A2 - processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação - Google Patents
processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilaçãoInfo
- Publication number
- BR112015006495A2 BR112015006495A2 BR112015006495A BR112015006495A BR112015006495A2 BR 112015006495 A2 BR112015006495 A2 BR 112015006495A2 BR 112015006495 A BR112015006495 A BR 112015006495A BR 112015006495 A BR112015006495 A BR 112015006495A BR 112015006495 A2 BR112015006495 A2 BR 112015006495A2
- Authority
- BR
- Brazil
- Prior art keywords
- reaction fluid
- stabilizing
- degradation
- hydroformylation reaction
- phosphite
- Prior art date
Links
- 239000012530 fluid Substances 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 4
- 239000011230 binding agent Substances 0.000 title abstract 3
- 230000015556 catabolic process Effects 0.000 title abstract 3
- 238000006731 degradation reaction Methods 0.000 title abstract 3
- 238000007037 hydroformylation reaction Methods 0.000 title abstract 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 title abstract 3
- 230000000087 stabilizing effect Effects 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 4
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 150000003018 phosphorus compounds Chemical class 0.000 abstract 2
- 239000012062 aqueous buffer Substances 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
resumo processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação um processo para estabilizar um ligante fosfito contra degradação num fluido de reação de hidroformilação, o dito processo compreendendo adicionar um epóxido ao fluido de reação, e compreendendo ainda separar um ou mais compostos ácidos de fósforo do fluido de reação tratando o fluido de reação com uma solução aquosa de tampão em condições suficientes para neutralizar e remover pelo menos alguma quantidade dos compostos ácidos de fósforo do fluido de reação. 1/1
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261705194P | 2012-09-25 | 2012-09-25 | |
US61/705,194 | 2012-09-25 | ||
PCT/US2013/058714 WO2014051975A1 (en) | 2012-09-25 | 2013-09-09 | Process for stabilizing a phosphite ligand against degradation |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112015006495A2 true BR112015006495A2 (pt) | 2017-07-04 |
BR112015006495B1 BR112015006495B1 (pt) | 2020-12-15 |
Family
ID=49170945
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015006495-7A BR112015006495B1 (pt) | 2012-09-25 | 2013-09-09 | Processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação |
Country Status (13)
Country | Link |
---|---|
US (1) | US9328047B2 (pt) |
EP (1) | EP2900373B1 (pt) |
JP (1) | JP6068652B2 (pt) |
KR (1) | KR102111182B1 (pt) |
CN (1) | CN104955568B (pt) |
BR (1) | BR112015006495B1 (pt) |
IN (1) | IN2015DN02639A (pt) |
MX (1) | MX2015003905A (pt) |
MY (1) | MY176756A (pt) |
PL (1) | PL2900373T3 (pt) |
RU (1) | RU2639156C2 (pt) |
WO (1) | WO2014051975A1 (pt) |
ZA (1) | ZA201502223B (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10501486B2 (en) | 2014-05-14 | 2019-12-10 | Dow Technology Investments Llc | Stabilized organophosphorous compounds |
TWI709568B (zh) * | 2015-09-30 | 2020-11-11 | 美商陶氏科技投資公司 | 用於製造有機磷化合物的方法 |
CN105498855A (zh) * | 2015-12-08 | 2016-04-20 | 中国海洋石油总公司 | 提高醚后c4羰基合成反应铑-双膦催化剂稳定性的方法 |
BR112018016320B1 (pt) | 2016-02-11 | 2022-07-12 | Dow Technology Investments Llc | Processo para converter olefinas em álcoois, éteres ou combinações dos mesmos |
CN109535197B (zh) * | 2018-12-19 | 2020-04-21 | 山东新和成维生素有限公司 | 一种稳定亚磷酸盐配体的方法及其应用 |
CN114206819B (zh) * | 2019-07-05 | 2024-06-25 | 佩什托普公司 | 减少加氢甲酰化方法中重尾馏分形成和催化剂损失的方法 |
SE543296C2 (en) * | 2019-07-05 | 2020-11-17 | Perstorp Ab | A use of epoxide in order to reduce the formation of heavy ends in a hydroformylation process |
WO2021126421A1 (en) | 2019-12-19 | 2021-06-24 | Dow Technology Investments Llc | Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms |
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WO1988008835A1 (en) | 1987-05-14 | 1988-11-17 | Colorado State University Research Foundation | Asymmetric hydroformylations of prochiral olefins to chiral aldehydes in high enantiomeric excess |
US5113022A (en) | 1988-08-05 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Ionic phosphites used in homogeneous transition metal catalyzed processes |
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DE4026406A1 (de) | 1990-08-21 | 1992-02-27 | Basf Ag | Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden |
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DE10242636A1 (de) | 2002-09-13 | 2004-03-18 | Basf Ag | Verfahren zur Herstellung von Dialdehyden und/oder ethylenisch ungesättigten Monoaldehyden durch Hydroformylierung ethylenisch ungesättigter Verbindungen |
WO2005042458A2 (de) | 2003-10-21 | 2005-05-12 | Basf Aktiengesellschaft | Verfahren zur kontinuierlichen herstellung von aldehyden |
DE102006058682A1 (de) | 2006-12-13 | 2008-06-19 | Evonik Oxeno Gmbh | Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung |
US7586010B2 (en) | 2006-12-21 | 2009-09-08 | Eastman Chemical Company | Phosphonite-containing catalysts for hydroformylation processes |
RU2320412C1 (ru) * | 2006-12-27 | 2008-03-27 | ООО "Объединенный центр исследования и разработок" | Катализатор для гидроформилирования олефинов c6+, способ его получения и способ получения альдегидов c7+ |
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US8513468B2 (en) | 2010-12-30 | 2013-08-20 | Eastman Chemical Company | Process for removing degradation acids from hydroformylation reactions |
SA112330271B1 (ar) | 2011-04-18 | 2015-02-09 | داو تكنولوجى انفستمنتس ال ال سى | تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء |
-
2013
- 2013-09-09 JP JP2015533094A patent/JP6068652B2/ja active Active
- 2013-09-09 RU RU2015115493A patent/RU2639156C2/ru active
- 2013-09-09 KR KR1020157007384A patent/KR102111182B1/ko active IP Right Grant
- 2013-09-09 BR BR112015006495-7A patent/BR112015006495B1/pt not_active IP Right Cessation
- 2013-09-09 PL PL13762708T patent/PL2900373T3/pl unknown
- 2013-09-09 CN CN201380058158.8A patent/CN104955568B/zh active Active
- 2013-09-09 MY MYPI2015700945A patent/MY176756A/en unknown
- 2013-09-09 US US14/429,672 patent/US9328047B2/en active Active
- 2013-09-09 MX MX2015003905A patent/MX2015003905A/es active IP Right Grant
- 2013-09-09 WO PCT/US2013/058714 patent/WO2014051975A1/en active Application Filing
- 2013-09-09 EP EP13762708.9A patent/EP2900373B1/en active Active
- 2013-09-09 IN IN2639DEN2015 patent/IN2015DN02639A/en unknown
-
2015
- 2015-03-31 ZA ZA2015/02223A patent/ZA201502223B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP2900373B1 (en) | 2019-04-17 |
RU2015115493A (ru) | 2016-11-20 |
ZA201502223B (en) | 2017-01-25 |
WO2014051975A1 (en) | 2014-04-03 |
MY176756A (en) | 2020-08-21 |
US9328047B2 (en) | 2016-05-03 |
RU2639156C2 (ru) | 2017-12-20 |
KR102111182B1 (ko) | 2020-05-14 |
IN2015DN02639A (pt) | 2015-09-18 |
PL2900373T3 (pl) | 2019-09-30 |
JP6068652B2 (ja) | 2017-01-25 |
CN104955568B (zh) | 2017-05-03 |
BR112015006495B1 (pt) | 2020-12-15 |
KR20150060714A (ko) | 2015-06-03 |
JP2015530407A (ja) | 2015-10-15 |
EP2900373A1 (en) | 2015-08-05 |
MX2015003905A (es) | 2015-07-17 |
US20150232403A1 (en) | 2015-08-20 |
CN104955568A (zh) | 2015-09-30 |
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Legal Events
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B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
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