BR112014017476A2 - elastômeros termoplásticos via polimerização de radical por transferência de átomo de óleo de planta - Google Patents
elastômeros termoplásticos via polimerização de radical por transferência de átomo de óleo de plantaInfo
- Publication number
- BR112014017476A2 BR112014017476A2 BR112014017476A BR112014017476A BR112014017476A2 BR 112014017476 A2 BR112014017476 A2 BR 112014017476A2 BR 112014017476 A BR112014017476 A BR 112014017476A BR 112014017476 A BR112014017476 A BR 112014017476A BR 112014017476 A2 BR112014017476 A2 BR 112014017476A2
- Authority
- BR
- Brazil
- Prior art keywords
- block
- monomer
- plant oil
- radically polymerizable
- radical polymerization
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
- C08F267/06—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2555/00—Characteristics of bituminous mixtures
- C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
- C08L2555/80—Macromolecular constituents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
abstract of the disclosure thermoplastic elastomers via atom transfer radical polymerization of plant oil the present invention relates to a block copolymer comprising at least one pa block and at least one pb block. the pa block represents a polymer block comprising one or more units of monomer a, and the pb block represents a polymer block comprising one or more units of monomer b. monomer a is a vinyl, acrylic, diolefin, nitrile, dinitrile, or acrylonitrile monomer. monomer b is a radically polymerizable plant oil monomer containing one or more triglycerides. the present invention also relates to a method of preparing a thermoplastic block copolymer by radical polymerizing a radically polymerizable monomer with a radically polymerizable plant oil monomer containing one or more triglycerides, in the presence of an initiator and a transition-metal catalyst system to form the thermoplastic block copolymer. the polymerized plant oil- based block copolymers are useful in a variety of applications, such as asphalt modifiers, rubber compositions, adhesives, tires, in the automobile industry, footwear, packaging, etc. _____________________________________________________________________ tradução do resumo resumo patente de invenção: "elastômeros termoplásticos via polimerização de radical por transferência de átomo de óleo de planta". a presente invenção se refere a um copolímero em bloco compreendendo pelo menos um bloco de pa e pelo menos um bloco de pb. o bloco de pa representa um bloco de polímero compreendendo uma ou mais unidades de monômero a e o bloco de pb representa um bloco de polímero compreendendo uma ou mais unidades de monômero b. o monômero a é monômero de vinil, acrílico, diolefina, nitrila, dinitrila ou acrilonitrila. o monômero b é um óleo de planta radicalmente polimerizável contendo um ou mais triglicerídeos. a presente invenção também se refere a um método para preparar um copolímero em bloco termoplástico por polimerização em radical de um monômero radicalmente polimerizável com um monômero de óleo de planta radicalmente polimerizável contendo um ou mais triglicerídeos na presença de um iniciador e um sistema de catalisador de metal de transição para formar o copolímero em bloco termoplástico. os copolímeros em bloco à base de óleo de planta polimerizados são úteis em uma variedade de aplicações, tal como modificadores de asfalto, composições de borracha, adesivos, pneus, na indústria automobilística, calçados, embalagens, etc.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261587816P | 2012-01-18 | 2012-01-18 | |
US61/587,816 | 2012-01-18 | ||
PCT/US2013/022131 WO2013109878A1 (en) | 2012-01-18 | 2013-01-18 | Thermoplastic elastomers via atom transfer radical polymerization of plant oil |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112014017476A2 true BR112014017476A2 (pt) | 2017-06-13 |
BR112014017476A8 BR112014017476A8 (pt) | 2017-07-04 |
BR112014017476B1 BR112014017476B1 (pt) | 2021-03-30 |
Family
ID=48780405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112014017476-8A BR112014017476B1 (pt) | 2012-01-18 | 2013-01-18 | Copolímero em bloco, composições elastomérica, asfáltica e adesiva, pneu de veículo, métodos para preparar um polímero ou copolímero em bloco termoplástico, e polímero termoplástico |
Country Status (15)
Country | Link |
---|---|
US (2) | US9932435B2 (pt) |
EP (1) | EP2804882B1 (pt) |
JP (1) | JP2015505339A (pt) |
KR (1) | KR20140119116A (pt) |
CN (3) | CN104204014B (pt) |
BR (1) | BR112014017476B1 (pt) |
CA (1) | CA2860861A1 (pt) |
CL (2) | CL2014001890A1 (pt) |
EA (2) | EA201792241A1 (pt) |
IL (1) | IL233491A0 (pt) |
MX (1) | MX350257B (pt) |
MY (1) | MY185219A (pt) |
SG (1) | SG11201404228UA (pt) |
WO (1) | WO2013109878A1 (pt) |
ZA (1) | ZA201405084B (pt) |
Families Citing this family (24)
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CA2860861A1 (en) | 2012-01-18 | 2013-07-25 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via atom transfer radical polymerization of plant oil |
SG11201509408UA (en) | 2013-05-20 | 2015-12-30 | Univ Iowa State Res Found | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides |
KR20170012234A (ko) | 2014-05-21 | 2017-02-02 | 아이오와 스테이트 유니버시티 리서치 파운데이션, 인코퍼레이티드 | 폴리(아크릴화된 폴리올) 및 이를 제조하는 방법 및 아스팔트 고무 변형제, 접착제, 수압파쇄 첨가제, 또는 수압파쇄 유체로서 이를 사용하는 방법 |
WO2016105983A1 (en) * | 2014-12-23 | 2016-06-30 | Bridgestone Americas Tire Operations, Llc | Hemp oil-containing rubber compositions and related methods |
CN107429196B (zh) * | 2015-02-09 | 2021-07-16 | 阿彻丹尼尔斯米德兰德公司 | 可再生来源衍生的聚合物油大分子引发剂和由其衍生的热塑性嵌段共聚物 |
US20180023259A1 (en) | 2015-02-27 | 2018-01-25 | Cargill, Incorporated | Rejuvenating compositions for asphalt applications & methods of manufacturing the same |
US20180148575A1 (en) * | 2015-05-29 | 2018-05-31 | Cargill, Incorporated | Composite thermoplastic polymers based on reaction with biorenewable oils |
WO2017087655A1 (en) * | 2015-11-17 | 2017-05-26 | University Of Houston System | Biorenewable blends of polylactide and acrylated epoxidized soybean oil compatibilized by a polylactide star polymer |
US20190002697A1 (en) * | 2016-01-15 | 2019-01-03 | Ndsu Research Foundation | Modified plant oils and rubber containing compositions containing the same |
WO2018031373A1 (en) | 2016-08-12 | 2018-02-15 | Iowa State University Research Foundation, Inc. | Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoplastic and thermoset materials |
US11124644B2 (en) * | 2016-09-01 | 2021-09-21 | University Of Florida Research Foundation, Inc. | Organic microgel system for 3D printing of silicone structures |
US10316192B2 (en) | 2017-08-25 | 2019-06-11 | Cargill, Incorporated | Emulsions with polymerized oils and methods of manufacturing the same |
KR102058068B1 (ko) | 2018-04-03 | 2019-12-20 | 한국타이어앤테크놀로지 주식회사 | 타이어 트레드용 고무 조성물, 이의 제조방법 및 이를 이용하여 제조한 타이어 |
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CN111303964B (zh) * | 2020-03-10 | 2023-03-28 | 西安石油大学 | 一种润滑油黏度指数改进剂及其制备方法与应用 |
KR102381429B1 (ko) * | 2020-08-13 | 2022-04-01 | 주식회사 삼양사 | 블로우 몰딩용 열가소성 폴리에스테르계 엘라스토머 수지의 내구성 평가 방법 |
KR20220059236A (ko) * | 2020-11-02 | 2022-05-10 | 코오롱인더스트리 주식회사 | 점착부여 수지, 이의 제조방법 및 이를 포함한 조성물 |
CN112716283B (zh) * | 2020-12-30 | 2022-07-05 | 成都探寻家科技有限公司 | 一种溏心蛋烹饪方法及煮蛋器 |
CN114106349B (zh) * | 2021-11-12 | 2023-01-17 | 华南农业大学 | 一种全生物基超支化光固化预聚物及其制备方法和应用 |
CN114605653B (zh) * | 2022-04-19 | 2023-07-04 | 东南大学 | 一种代替sbs的生物热塑性弹性体的制备方法及其应用 |
CN115028784A (zh) * | 2022-05-25 | 2022-09-09 | 东南大学 | 一种生物基弹性体的制备方法及生物基弹性体改性沥青混合料的制备方法 |
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2013
- 2013-01-18 CA CA2860861A patent/CA2860861A1/en not_active Abandoned
- 2013-01-18 EA EA201792241A patent/EA201792241A1/ru unknown
- 2013-01-18 SG SG11201404228UA patent/SG11201404228UA/en unknown
- 2013-01-18 CN CN201380009567.9A patent/CN104204014B/zh active Active
- 2013-01-18 CN CN201810473383.2A patent/CN108623762B/zh active Active
- 2013-01-18 BR BR112014017476-8A patent/BR112014017476B1/pt active IP Right Grant
- 2013-01-18 MY MYPI2014002118A patent/MY185219A/en unknown
- 2013-01-18 EA EA201491384A patent/EA201491384A1/ru unknown
- 2013-01-18 JP JP2014553449A patent/JP2015505339A/ja not_active Ceased
- 2013-01-18 KR KR1020147022520A patent/KR20140119116A/ko not_active Application Discontinuation
- 2013-01-18 EP EP13738906.0A patent/EP2804882B1/en active Active
- 2013-01-18 CN CN201810474450.2A patent/CN108774300B/zh active Active
- 2013-01-18 US US13/744,733 patent/US9932435B2/en active Active
- 2013-01-18 WO PCT/US2013/022131 patent/WO2013109878A1/en active Application Filing
- 2013-01-18 MX MX2014008636A patent/MX350257B/es active IP Right Grant
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2014
- 2014-07-02 IL IL233491A patent/IL233491A0/en unknown
- 2014-07-11 ZA ZA2014/05084A patent/ZA201405084B/en unknown
- 2014-07-17 CL CL2014001890A patent/CL2014001890A1/es unknown
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2017
- 2017-12-01 CL CL2017003074A patent/CL2017003074A1/es unknown
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2018
- 2018-02-14 US US15/896,151 patent/US10570238B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
KR20140119116A (ko) | 2014-10-08 |
CN108623762B (zh) | 2021-11-23 |
CN104204014A (zh) | 2014-12-10 |
ZA201405084B (en) | 2018-12-19 |
US20130184383A1 (en) | 2013-07-18 |
EA201491384A1 (ru) | 2015-03-31 |
US10570238B2 (en) | 2020-02-25 |
MX2014008636A (es) | 2014-12-08 |
EP2804882A4 (en) | 2015-07-29 |
CN104204014B (zh) | 2018-06-15 |
EA201792241A1 (ru) | 2018-02-28 |
CN108774300A (zh) | 2018-11-09 |
US20180237571A1 (en) | 2018-08-23 |
BR112014017476A8 (pt) | 2017-07-04 |
US9932435B2 (en) | 2018-04-03 |
CL2014001890A1 (es) | 2015-01-30 |
WO2013109878A1 (en) | 2013-07-25 |
MX350257B (es) | 2017-08-31 |
SG11201404228UA (en) | 2014-10-30 |
BR112014017476B1 (pt) | 2021-03-30 |
CL2017003074A1 (es) | 2018-04-06 |
CA2860861A1 (en) | 2013-07-25 |
MY185219A (en) | 2021-04-30 |
EP2804882B1 (en) | 2021-12-22 |
EP2804882A1 (en) | 2014-11-26 |
CN108623762A (zh) | 2018-10-09 |
CN108774300B (zh) | 2022-04-05 |
JP2015505339A (ja) | 2015-02-19 |
IL233491A0 (en) | 2014-08-31 |
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