BR112013025627A2 - processo para produzir álcoois graxos a partir de ácidos graxos - Google Patents

processo para produzir álcoois graxos a partir de ácidos graxos

Info

Publication number
BR112013025627A2
BR112013025627A2 BR112013025627A BR112013025627A BR112013025627A2 BR 112013025627 A2 BR112013025627 A2 BR 112013025627A2 BR 112013025627 A BR112013025627 A BR 112013025627A BR 112013025627 A BR112013025627 A BR 112013025627A BR 112013025627 A2 BR112013025627 A2 BR 112013025627A2
Authority
BR
Brazil
Prior art keywords
fatty
ester
wax
stream
fatty alcohol
Prior art date
Application number
BR112013025627A
Other languages
English (en)
Other versions
BR112013025627A8 (pt
BR112013025627B1 (pt
Inventor
Michael Anthony Wood
Paul Appleton
Robert Wild
Original Assignee
Davy Process Techn Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Davy Process Techn Ltd filed Critical Davy Process Techn Ltd
Publication of BR112013025627A2 publication Critical patent/BR112013025627A2/pt
Publication of BR112013025627A8 publication Critical patent/BR112013025627A8/pt
Publication of BR112013025627B1 publication Critical patent/BR112013025627B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
    • C07C29/1285—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/10—Ester interchange
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

resumo da patente de invenção para: “processo para produzir álcoois graxos a partir de ácidos graxos”. um processo para a produção de álcool graxo ou álcoois graxos que compreendem: submeter um ácido graxo ou uma mistura de ácidos graxos a esterificação com um alcanol inferior em um reator de esterificação mantido sob condições de esterificação para formar uma corrente que compreende o correspondente éster de alquil inferior ou os correspondentes ésteres de alquil inferior; vaporizar a corrente da etapa (a); submeter a corrente vaporizada da etapa (b) à hidrogenação em uma primeira zona de hidrogenação operada sob condições de hidrogenação para formar uma corrente que compreende álcool graxo ou álcoois graxos e uma quantidade de éster de alquil inferior ou ésteres de alquil inferior não convertidos; submeter a corrente da etapa (c) à transesterificação em um reator de éster de cera mantido sob condições de transesterificação na presença de um catalisador de transesterificação sólido desta forma para converter pelo menos uma porção do éster de ácido graxo de alquil inferior pela troca de éster com uma quantidade correspondente de álcool graxo ou álcoois graxos para alcanol inferior e para um éster de cera ou ésteres de cera derivados a partir do álcool graxo e um ácido graxo; separar o álcool graxo ou os álcoois graxos e éster de cera ou ésteres de cera da etapa (d) pela destilação para produzir um álcool graxo ou produto de álcoois e uma corrente que compreende éster de cera ou ésteres de cera; passar a dita compreende que compreende o éster de cera ou ésteres de cera para uma segunda zona de hidrogenação que opera sob as condições para efetuar a hidrogenação na fase líquida para reverter o éster de cera ou ésteres de cera para álcool graxo ou álcoois graxos; e retornar o álcool graxo ou álcoois graxos para a etapa de separação (e).
BR112013025627-3A 2011-11-17 2012-11-01 Processo para produzir álcoois graxos a partir de ácidos graxos BR112013025627B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1119871.0 2011-11-17
GBGB1119871.0A GB201119871D0 (en) 2011-11-17 2011-11-17 Process
PCT/GB2012/052726 WO2013072664A1 (en) 2011-11-17 2012-11-01 Process for producing fatty alcohols from fatty acids

Publications (3)

Publication Number Publication Date
BR112013025627A2 true BR112013025627A2 (pt) 2016-12-27
BR112013025627A8 BR112013025627A8 (pt) 2018-07-31
BR112013025627B1 BR112013025627B1 (pt) 2020-03-03

Family

ID=45444290

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013025627-3A BR112013025627B1 (pt) 2011-11-17 2012-11-01 Processo para produzir álcoois graxos a partir de ácidos graxos

Country Status (12)

Country Link
US (1) US8884078B1 (pt)
EP (1) EP2614043B1 (pt)
CN (1) CN103282335B (pt)
BR (1) BR112013025627B1 (pt)
CO (1) CO6852059A2 (pt)
EA (1) EA024091B1 (pt)
ES (1) ES2626328T3 (pt)
GB (2) GB201119871D0 (pt)
MY (1) MY161764A (pt)
SG (1) SG189442A1 (pt)
TW (1) TWI541223B (pt)
WO (1) WO2013072664A1 (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201218078D0 (en) 2012-10-09 2012-11-21 Davy Process Techn Ltd Process
GB201219983D0 (en) 2012-11-06 2012-12-19 Davy Process Techn Ltd Apparatus and process
DE102013106382A1 (de) 2013-06-19 2014-12-24 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren zum Herstellen von Fettalkoholen aus Fettsäuremethylester
DE102014113197A1 (de) * 2014-09-12 2016-03-17 L’AIR LIQUIDE Société Anonyme pour l’Etude et l’Exploitation des Procédés Georges Claude Verfahren und Anlage zur Herstellung von Fettalkoholen
CN105777488B (zh) * 2016-03-29 2018-07-10 青岛科技大学 一种催化制备脂肪醇的方法
CN108516924A (zh) * 2018-03-30 2018-09-11 江苏丰益化工科技有限公司 一种用于高纯度脂肪醇的生产***
CN108821967A (zh) * 2018-08-07 2018-11-16 中国天辰工程有限公司 一种高纯度酯类物质的合成工艺
CN111320527B (zh) * 2018-12-13 2022-08-12 中国石油化工股份有限公司 一种脂肪酸非临氢转化的方法

Family Cites Families (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1190783B (it) 1981-04-29 1988-02-24 Davy Mckee Oil & Chem Processo per l'idrogenolisi di esteri di acidi carbossilici
GB2121545B (en) 1982-06-09 1985-09-25 Picker Int Ltd Nuclear magnetic resonance method and apparatus
US4559180A (en) 1982-11-26 1985-12-17 Bp Chemicals Limited Transesterification of esters
GB8900993D0 (en) 1989-01-17 1989-03-08 Davy Mckee London Process
WO1990008121A1 (en) 1989-01-17 1990-07-26 Davy Mckee (London) Limited Process for the production of fatty alcohols
EP0454719B1 (en) 1989-01-17 1996-06-05 Davy Process Technology Limited A continuous process for the production of carboxylic acid esters
JP2601941B2 (ja) 1990-10-19 1997-04-23 宇部興産株式会社 低級アルコールの回収法及び回収装置
DE4124283A1 (de) 1991-07-15 1993-01-21 Degussa Umesterung von peptiden
US5498751A (en) 1993-09-03 1996-03-12 Cps Chemical Company, Inc. Organotin catalyzed transesterification
US5606103A (en) 1993-09-03 1997-02-25 Cps Chemical Company, Inc. Organotin catalyzed transesterification
US5436357A (en) 1994-06-06 1995-07-25 Rohm And Haas Company Polymer supported organotin catalyst
US6376701B1 (en) 1995-12-29 2002-04-23 Council Of Scientific & Industrial Research Process for the transesterification of keto esters using solid acids as catalysts
EP1209144A1 (de) 1996-12-20 2002-05-29 Ciba SC Holding AG An feste Trägermaterialien fixierte Umesterungskatalysatoren
CA2245326C (en) 1997-09-29 2005-04-05 Elf Atochem North America, Inc. Heterogeneous organotin catalysts
DE19857314A1 (de) 1997-12-12 2000-02-03 Sec Dep Of Science And Technol Stark saurer mensoporöser synergistischer Festkörper-Katalysator und Verwendung desselben
FR2772756B1 (fr) 1997-12-18 2000-02-11 Inst Francais Du Petrole Procede de fabrication d'esters de corps gras et les esters de haute purete obtenus
US5840957A (en) 1998-03-16 1998-11-24 E. I. Du Pont De Nemours And Company Transesterification process using lanthanum compound catalyst
DE19950593A1 (de) 1999-10-20 2001-05-17 Siegfried Peter Verfahren zur Gewinnung einfacher Fettsäure-Ester aus Fett und/oder Öl biologischen Ursprungs
EP1108702A1 (en) * 1999-12-13 2001-06-20 Kvaerner Process Technology Limited Process for the co-production of aliphatic diols and cyclic ethers
KR100520308B1 (ko) 2000-05-19 2005-10-13 도꾸리쯔교세이호징 가가꾸 기쥬쯔 신꼬 기꼬 에스테르화 반응 및 에스테르교환 반응용 촉매 및 에스테르류의 제조방법
DE10029517A1 (de) 2000-06-21 2002-01-17 Stockhausen Chem Fab Gmbh Verfahren zur Herstellung von Aminoalkyl(meth)acrylaten
DE10132842C1 (de) 2001-07-06 2002-11-28 Siegfried Peter Verfahren zur Umesterung von Fett und/oder Öl mittels Alkoholyse
WO2003020782A2 (en) 2001-08-29 2003-03-13 Ptc Organics, Inc. Transesterification using phase transfer catalysts
JP3946982B2 (ja) 2001-11-01 2007-07-18 ニッケイ・メル株式会社 ジルコニア・セリア基複合酸化物の製造方法
US6743942B1 (en) 2002-11-08 2004-06-01 Council Of Scientific & Industrial Research Process for the transesterification of keto ester with alcohol using polyaniline salts as catalyst
WO2004085583A1 (ja) 2003-03-26 2004-10-07 Japan Energy Corporation 固体酸触媒を用いたエステル交換反応によるエステルの製造方法
US7696376B2 (en) 2003-06-30 2010-04-13 Japan Energy Corporation Method for manufacture of esters by transesterification
US7122688B2 (en) 2003-10-16 2006-10-17 Iowa State University Research Foundation Use of functionalized mesoporous silicates to esterify fatty acids and transesterify oils
HRP20040341B1 (en) 2004-04-15 2011-01-31 Institut "Ruder Boskovic" N,n',n"-tris-(3-dimethylaminopropyl)-guanidine. the procedure of preparation from carbodimide and application in reactions of oil
JP4515840B2 (ja) 2004-07-13 2010-08-04 株式会社レボインターナショナル 脂肪酸アルキルエステルの製造方法
GB0417344D0 (en) 2004-08-04 2004-09-08 Phosphonics Ltd Substituted organopolysiloxanes and use thereof
DE102004044660A1 (de) 2004-09-15 2006-03-30 Siegfried Prof. Dr. Peter Verfahren zur Umesterung von Fetten und Ölen biologischen Ursprungs mittels Alkoholyse unter Verwendung spezieller Kohlensäuresalze
ITMI20042163A1 (it) 2004-11-11 2005-02-11 Aser S R L Processo per la produzione di esteri da oli vegetali o grassi animali con l'impiego di catalizzatori eterogenei
WO2006070661A1 (ja) 2004-12-28 2006-07-06 Japan Energy Corporation エステル交換反応によるエステルの製造方法
KR101234969B1 (ko) 2005-06-03 2013-02-20 라이온 가부시키가이샤 지방산 저급 알킬에스테르의 제조 방법 및 지방산 저급알킬에스테르 및 경유 대체연료
CA2611347A1 (en) 2005-06-09 2006-12-14 Biosphere Environmental Energy Llc Systems and methods for esterification and transesterification of fats and oils
GB0514502D0 (en) 2005-07-14 2005-08-24 Phosphonics Ltd Substituted organopolysiloxanes containing phosphonic groups,method for the production and use thereof
BRPI0504759A (pt) 2005-09-01 2007-06-12 Univ Rio De Janeiro processo catalìtico para transesterificação de óleos vegetais e gorduras utilizando-se catalisadores sólidos básicos
US7754643B2 (en) 2005-10-07 2010-07-13 Council Of Scientific & Industrial Research Transesterification catalyst and a process for the preparation thereof
WO2007074592A1 (ja) 2005-12-27 2007-07-05 Lion Corporation 脂肪酸低級アルキルエステルの製造方法
US20090069585A1 (en) 2006-03-29 2009-03-12 Halpern Marc E Transesterification Reacton of Triglycerides and Monohydric Alcohols
HUE051542T2 (hu) 2006-07-23 2021-03-01 Univ Iowa State Res Found Inc Biodízel-elõállítás kompozitkatalizátorok alkalmazásával
DE102007033636A1 (de) 2007-07-19 2009-01-22 Cognis Ip Management Gmbh Reinigung von Fettalkoholen
GB0906031D0 (en) * 2009-04-07 2009-05-20 Davy Process Techn Ltd Process

Also Published As

Publication number Publication date
EP2614043A1 (en) 2013-07-17
ES2626328T3 (es) 2017-07-24
EP2614043B1 (en) 2017-05-03
US8884078B1 (en) 2014-11-11
BR112013025627A8 (pt) 2018-07-31
MY161764A (en) 2017-05-15
EA201300537A1 (ru) 2014-04-30
EA024091B1 (ru) 2016-08-31
TW201321343A (zh) 2013-06-01
CO6852059A2 (es) 2014-01-30
TWI541223B (zh) 2016-07-11
BR112013025627B1 (pt) 2020-03-03
US20140323773A1 (en) 2014-10-30
SG189442A1 (en) 2013-05-31
GB201402408D0 (en) 2014-03-26
CN103282335A (zh) 2013-09-04
WO2013072664A1 (en) 2013-05-23
GB201119871D0 (en) 2011-12-28
CN103282335B (zh) 2016-04-27
GB2507687A (en) 2014-05-07

Similar Documents

Publication Publication Date Title
BR112013025627A2 (pt) processo para produzir álcoois graxos a partir de ácidos graxos
BR112015016021A2 (pt) processo para a produção de bio - nafta a partir de misturas complexas de gorduras & óleos de ocorrência natural
BR112013025996A2 (pt) processo para isolamento de micronutrientes
WO2008099051A3 (en) Process for isolation of fatty acids, resin acids and sterols from tall oil pitch
BR112012008608A2 (pt) processos de refinação e produção de combustível partindo de materiais-primas de óleo natural.
BR112012028566A2 (pt) processo para produção de álcool integrando corrente de alimentação de ácido acético que compreende água do processo de carbonilação
BR112013018857A2 (pt) processo para a produção dos ésteres de álcool dos ácidos graxos e composição do processo de fermentação do álcool
MY171087A (en) Method for the production of polyols and uses thereof
BR112016000352A8 (pt) produção de produtos a partir de matérias-primas contendo ácidos graxos livres
BR112013025609A2 (pt) métodos para produzir biocombustíveis, clorofilas e carotenoides
BR112014009333A2 (pt) processo para produzir um éster de ácido graxo epoxidizado a partir de uma gordura ou óleo natural epoxidizado
BR112022005548A2 (pt) Metátese de engajamento da produção de alceno renovável
BR112015021070A2 (pt) métodos para refinar e produzir ésteres de ácidos graxos isomerizados e ácidos graxos a partir de matérias-primas de petróleo
AR098639A1 (es) Un procedimiento para preparar éster succinato
BR112015019271A2 (pt) processo para o preparo de éster de ácido succínico
CN103820224A (zh) 一种生物柴油及其制备方法
BRPI0822195A8 (pt) Processo e dispositivo para a produção de hidrocarbonetos
AR086131A1 (es) Proceso para reducir etanol reciclado hasta reactor de hidrogenacion
PH12015500206A1 (en) Process for the production of a fatty alcohol from a fatty acid
BR112017025177A2 (pt) produção de esteróis
WO2010082210A3 (en) A process for production of biodiesel
BR112015007629A2 (pt) síntese de éster
AR086202A1 (es) Proceso para reducir la concentracion de acido acetico en un producto de alcohol en bruto
WO2012032002A3 (de) VERFAHREN ZUR HERSTELLUNG VON ε-CAPROLACTON UND 1,6-HEXANDIOL
BR112013033261A2 (pt) processo para produzir um éster de ácido graxo epoxidado com cor reduzida ou mistura de ésteres a partir de um óleo ou gordura natural epoxidada

Legal Events

Date Code Title Description
B25D Requested change of name of applicant approved

Owner name: JOHNSON MATTHEY DAVY TECHNOLOGIES LIMITED (GB)

B25G Requested change of headquarter approved

Owner name: JOHNSON MATTHEY DAVY TECHNOLOGIES LIMITED (GB)

B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 01/11/2012, OBSERVADAS AS CONDICOES LEGAIS.