BR0214629B1 - composto monomérico de ligante bidentado que contém fósforo, composição catalisadora e processo de hidroformilação. - Google Patents

composto monomérico de ligante bidentado que contém fósforo, composição catalisadora e processo de hidroformilação.

Info

Publication number: BR0214629B1
Authority: BR; Brazil
Prior art keywords: binder; bidentate; catalyst composition; containing phosphorus; hydroformylation process
Prior art date: 2001-11-26

Application number

BRPI0214629-0A

Other languages

English (en)

Other versions

BR0214629A (pt

Inventor

Michel R Gagne

Kenneth G Moloy

Nora S Radu

Brian P Santora

Wilson Tam

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-11-26

Filing date

2002-11-20

Publication date

2012-08-21

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25540315&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR0214629(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2002-11-20 Application filed filed Critical

2004-11-03 Publication of BR0214629A publication Critical patent/BR0214629A/pt

2012-08-21 Publication of BR0214629B1 publication Critical patent/BR0214629B1/pt

Links

OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 2
239000003054 catalyst Substances 0.000 title abstract 2
238000007037 hydroformylation reaction Methods 0.000 title abstract 2
229910052698 phosphorus Inorganic materials 0.000 title abstract 2
239000011574 phosphorus Substances 0.000 title abstract 2
239000011230 binding agent Substances 0.000 title 2
238000000034 method Methods 0.000 title 1
239000003999 initiator Substances 0.000 abstract 2
PPTXVXKCQZKFBN-UHFFFAOYSA-N (S)-(-)-1,1'-Bi-2-naphthol Chemical compound C1=CC=C2C(C3=C4C=CC=CC4=CC=C3O)=C(O)C=CC2=C1 PPTXVXKCQZKFBN-UHFFFAOYSA-N 0.000 abstract 1
238000010438 heat treatment Methods 0.000 abstract 1
238000005669 hydrocyanation reaction Methods 0.000 abstract 1
238000006317 isomerization reaction Methods 0.000 abstract 1
239000002184 metal Substances 0.000 abstract 1
150000002825 nitriles Chemical class 0.000 abstract 1
229920000642 polymer Polymers 0.000 abstract 1
150000003254 radicals Chemical class 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
- B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1885—Ligands comprising two different formal oxidation states of phosphorus in one at least bidentate ligand, e.g. phosphite/phosphinite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2291—Olefins
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
- B01J31/30—Halides
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
- C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
- C07F15/0066—Palladium compounds without a metal-carbon linkage
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
- C08F12/22—Oxygen
- C08F12/24—Phenols or alcohols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
- C08F212/22—Oxygen
- C08F212/24—Phenols or alcohols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/32—Monomers containing only one unsaturated aliphatic radical containing two or more rings
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/828—Platinum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
- C08F212/36—Divinylbenzene

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Health & Medical Sciences (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Emergency Medicine (AREA)
Toxicology (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)
Polyurethanes Or Polyureas (AREA)

BRPI0214629-0A 2001-11-26 2002-11-20 composto monomérico de ligante bidentado que contém fósforo, composição catalisadora e processo de hidroformilação. BR0214629B1 (pt)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US09/994,135 US6660876B2 (en)	2001-11-26	2001-11-26	Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
PCT/US2002/037304 WO2003045552A2 (en)	2001-11-26	2002-11-20	Polymeric phosphorus-containing compositions and their use in hydrocyanation, unsaturated nitrile isomerization and hydroformylation reactions

Publications (2)

Publication Number	Publication Date
BR0214629A BR0214629A (pt)	2004-11-03
BR0214629B1 true BR0214629B1 (pt)	2012-08-21

Family

ID=25540315

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BRPI0214629-0A BR0214629B1 (pt)	2001-11-26	2002-11-20	composto monomérico de ligante bidentado que contém fósforo, composição catalisadora e processo de hidroformilação.

Country Status (13)

Country	Link
US (2)	US6660876B2 (pt)
EP (3)	EP1448298B1 (pt)
JP (2)	JP4373786B2 (pt)
KR (1)	KR20040058321A (pt)
CN (1)	CN100345635C (pt)
AT (1)	ATE482028T1 (pt)
AU (1)	AU2002348313A1 (pt)
BR (1)	BR0214629B1 (pt)
CA (1)	CA2468195A1 (pt)
DE (1)	DE60237781D1 (pt)
MX (1)	MXPA04004938A (pt)
PL (1)	PL370988A1 (pt)
WO (1)	WO2003045552A2 (pt)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2849027B1 (fr) *	2002-12-23	2005-01-21	Rhodia Polyamide Intermediates	Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
US6936171B2 (en) *	2003-01-08	2005-08-30	Invista North America S.A.R.L.	Process for catalyst recovery from hydrocyanation product mixtures
FR2850966B1 (fr)	2003-02-10	2005-03-18	Rhodia Polyamide Intermediates	Procede de fabrication de composes dinitriles
US6844289B2 (en) *	2003-04-08	2005-01-18	Invista North America S.A.R.L.	Process for the preparation of a nickel/phosphorous ligand catalyst
FR2854891B1 (fr)	2003-05-12	2006-07-07	Rhodia Polyamide Intermediates	Procede de preparation de dinitriles
DE10350999A1 (de) *	2003-10-30	2005-06-02	Basf Ag	Katalysator, umfassend wenigstens einen Nickel(O)Komplex stabilisiert durch einen sterisch anspruchsvollen Chelatphosphinitphosphitliganden, sowie ein Verfahren zur Herstellung von Nitrilen
JP4576584B2 (ja) *	2005-01-31	2010-11-10	独立行政法人科学技術振興機構	リン含有高分子固定化パラジウム触媒およびその使用
US7709674B2 (en)	2006-07-14	2010-05-04	Invista North America S.A R.L	Hydrocyanation process with reduced yield losses
US7880028B2 (en)	2006-07-14	2011-02-01	Invista North America S.A R.L.	Process for making 3-pentenenitrile by hydrocyanation of butadiene
WO2008013009A1 (en)	2006-07-25	2008-01-31	National University Corporation Hokkaido University	Polymer-supported metal complex catalyst
DE102007031547A1 (de) *	2007-07-06	2009-01-15	Deutsches Zentrum für Luft- und Raumfahrt e.V.	Robuster kapazitiver Abstandssensor
EP2229354B1 (en)	2008-01-15	2013-03-20	Invista Technologies S.à.r.l.	Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
WO2009091790A1 (en)	2008-01-15	2009-07-23	Invista Technologies S.A.R.L.	Hydrocyanation of pentenenitriles
CN107383087A (zh) *	2009-04-21	2017-11-24	英威达纺织（英国）有限公司	用于制备有机二亚磷酸酯的高选择性方法
US8815186B2 (en)	2009-12-18	2014-08-26	Invista North America S.A.R.L.	Nickel compositions for preparing nickel metal and nickel complexes
WO2012033556A1 (en)	2010-09-07	2012-03-15	Invista Technologies S.A R.L.	Preparing a nickel phosphorus ligand complex
KR101878017B1 (ko) *	2011-06-10	2018-07-12	인비스타 텍스타일스 (유.케이.) 리미티드	촉매적 니켈-리간드 착물의 제조를 위한 니켈 형태
US8822577B2 (en)	2011-11-21	2014-09-02	Bridgestone Sports Co., Ltd.	Rubber composition for golf ball
WO2013095851A1 (en)	2011-12-21	2013-06-27	Invista North America S.A R.L.	Extraction solvent control for reducing stable emulsions
WO2013095853A1 (en)	2011-12-21	2013-06-27	Invista North America S.A R.L.	Extraction solvent control for reducing stable emulsions
EP2794047B1 (en)	2011-12-21	2021-04-14	INVISTA Textiles (U.K.) Limited	Extraction solvent control for reducing stable emulsions
US9676800B2 (en)	2013-06-20	2017-06-13	Invista North America S.A.R.L.	Extraction solvent control for reducing stable emulsions
CN105307741B (zh)	2013-06-20	2019-06-18	英威达纺织（英国）有限公司	用于减少稳定乳液的萃取溶剂控制
EP3010617B1 (en)	2013-06-20	2022-11-30	INVISTA Textiles (U.K.) Limited	Extraction solvent control for reducing stable emulsions
EP3010616B1 (en)	2013-06-20	2022-09-28	INVISTA Textiles (U.K.) Limited	Extraction solvent control for reducing stable emulsions
US10035756B2 (en)	2014-06-27	2018-07-31	Invista North America S.A.R.L.	Integrated process for nitrile manufacture with enhanced liquid-liquid extraction
EP3160907B1 (en)	2014-06-27	2019-11-20	INVISTA Textiles (U.K.) Limited	Enhanced extraction of impurities from mixture comprising nitriles
CN106140302B (zh) *	2015-04-03	2018-11-27	中国科学院大连化学物理研究所	一种含膦有机混聚物-金属多相催化剂及其方法和应用
CN106140303B (zh) *	2015-04-03	2018-11-27	中国科学院大连化学物理研究所	一种含膦有机混聚物-金属多相催化剂及其制备和应用
EP3144289A1 (en) *	2015-09-16	2017-03-22	Evonik Technochemie GmbH	[(2-ethoxy-5-trans-1-propen-1-yl)-phenoxyl]-terminated compounds
CN112480169A (zh) *	2020-12-07	2021-03-12	南雄志一精细化工有限公司	一种液体含磷化合物及其应用和制备方法
CN115873221B (zh) *	2021-12-17	2024-06-04	浙江新和成股份有限公司	一种含磷聚合物及其制备方法和应用
CN116410390B (zh) *	2021-12-31	2024-05-10	中国石油天然气股份有限公司	有机膦配体聚合物及二齿膦配体共聚物催化剂的制备方法
WO2024028719A2 (en) *	2022-08-02	2024-02-08	Inv Nylon Chemicals Americas, Llc	Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3496215A (en)	1965-11-23	1970-02-17	Du Pont	Hydrocyanation of olefins using selected nickel phosphite catalysts
GB1112539A (en)	1965-11-26	1968-05-08	Du Pont	Preparation of organic nitriles
US3496217A (en)	1967-05-23	1970-02-17	Du Pont	Hydrocyanation of olefins
US3655723A (en)	1969-10-31	1972-04-11	Du Pont	Hydrocyanation of olefins
US3631191A (en)	1970-04-08	1971-12-28	Du Pont	Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes
US3907847A (en)	1970-04-27	1975-09-23	Ethyl Corp	Compound and method
US3766237A (en)	1972-01-25	1973-10-16	Du Pont	Hydrocyanation of olefins
US3847959A (en)	1972-10-25	1974-11-12	Du Pont	Process of preparing a zerovalent nickel complex with organic phosphorus compounds
US3846461A (en)	1972-10-25	1974-11-05	Du Pont	Process of preparing a zerovalent nickel complex with organic phosphorus compounds
US3903120A (en)	1973-06-19	1975-09-02	Du Pont	Preparation of zerovalent nickel complexes from elemental nickel
AU535546B2 (en) *	1980-01-15	1984-03-29	Unisearch Limited	Improved heterogeneous catalyst
US4668651A (en)	1985-09-05	1987-05-26	Union Carbide Corporation	Transition metal complex catalyzed processes
US4774353A (en)	1986-06-05	1988-09-27	E. I. Du Pont De Nemours And Company	Triorganotin catalyst promoters for hydrocyanation
US4874884A (en)	1988-03-31	1989-10-17	E. I. Du Pont De Nemours And Company	Promoter synergism in pentenenitrile hydrocyanation
DE3937610A1 (de)	1989-11-11	1991-05-16	Hoechst Ag	Verfahren zur gewinnung von phosphorigsaeure-bis-(2,4-di-tert.-butyl-phenyl)ester-halogeniden
EP0496700B1 (de)	1991-01-25	1996-03-06	Ciba-Geigy Ag	Silangruppen enthaltende Diphosphine, immobilisierte Diophoshine und deren Verwendung als Hydrierkatalysatoren
TW213465B (pt)	1991-06-11	1993-09-21	Mitsubishi Chemicals Co Ltd
US5360938A (en)	1991-08-21	1994-11-01	Union Carbide Chemicals & Plastics Technology Corporation	Asymmetric syntheses
CN1082946C (zh)	1993-11-23	2002-04-17	纳幕尔杜邦公司	用于单烯烃氢氰化的方法和催化剂组合物
US5543536A (en)	1994-04-26	1996-08-06	E. I. Du Pont De Nemours And Company	Monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation
BE1008343A3 (nl)	1994-05-06	1996-04-02	Dsm Nv	Bidentaat fosfineligand
US5512696A (en)	1995-07-21	1996-04-30	E. I. Du Pont De Nemours And Company	Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
IN187044B (pt)	1995-01-27	2002-01-05	Du Pont
US5821378A (en)	1995-01-27	1998-10-13	E. I. Du Pont De Nemours And Company	Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
US5523453A (en)	1995-03-22	1996-06-04	E. I. Du Pont De Nemours And Company	Process for hydrocyanation
US5693843A (en)	1995-12-22	1997-12-02	E. I. Du Pont De Nemours And Company	Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles
TW343195B (en) *	1996-03-15	1998-10-21	Dsm Nv	Process to prepare a terminal aldehyde
US5710306A (en)	1996-03-15	1998-01-20	Dsm N.V.	Process to prepare a multidentate phosphite compound
IN191158B (pt) *	1996-04-02	2003-10-11	Du Pont
DE19717359B4 (de)	1996-04-30	2014-10-30	Mitsubishi Chemical Corp.	Bisphosphitverbindungen und Verfahren zu deren Herstellung
GB9619684D0 (en)	1996-09-20	1996-11-06	Oxford Asymmetry Ltd	Phosphine ligands
JP3892931B2 (ja) *	1997-03-11	2007-03-14	高砂香料工業株式会社	２個のビニル基を有する光学活性ホスフィン誘導体、それをモノマーとするポリマー、及びそれらの遷移金属錯体
JP3892932B2 (ja) *	1997-03-11	2007-03-14	高砂香料工業株式会社	ビニル基を有する光学活性ホスフィン誘導体、それをモノマーとするポリマー、及びそれらの遷移金属錯体
WO1998043935A1 (fr)	1997-03-27	1998-10-08	Mitsubishi Chemical Corporation	Procede de preparation d'aldehydes
MY124170A (en)	1997-07-29	2006-06-30	Invista Tech Sarl	Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor
ZA986369B (en) *	1997-07-29	2000-01-17	Du Pont	Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.
US5959135A (en)	1997-07-29	1999-09-28	E. I. Du Pont De Nemours And Company	Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions thereof
US6031120A (en)	1997-07-29	2000-02-29	E. I. Du Pont De Nemours And Company	Selective synthesis of organodiphosphite compounds
US6121184A (en)	1997-07-29	2000-09-19	E. I. Du Pont De Nemours And Company	Supported bis(phosphorus) ligands
DE19740180A1 (de)	1997-09-12	1999-03-18	Basf Ag	Katalysator, umfassend wenigstens einen Nickel(0)Komplex auf Basis eines Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
US5817850A (en)	1997-10-30	1998-10-06	Ciba Specialty Chemicals Corporation	Ferrocene bis(phosphonite) ligands and complexes for transition-metal-catalyzed reactions
US5990318A (en)	1998-03-06	1999-11-23	The Hong Kong Polytechnic University	Soluble polyester-supported chiral phosphines
DE19810794A1 (de)	1998-03-12	1999-09-16	Basf Ag	Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phosphonitliganden und Verfahren zur Hydroformylierung
US6229052B1 (en)	1998-05-29	2001-05-08	E. I. Du Pont De Nemours And Company	Hydroformylation of olefins using supported bis(phosphorus) ligands
DE19825212A1 (de)	1998-06-05	1999-12-09	Basf Ag	Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
EP1105400A1 (en) *	1998-08-21	2001-06-13	The Penn State Research Foundation	Asymmetric catalysis based on chiral phospholanes
EP1013340A3 (en) *	1998-12-23	2001-05-02	Haldor Topsoe A/S	Polymer supported triphos compound and use thereof as catalyst
JP2000256248A (ja) *	1999-03-11	2000-09-19	Takasago Internatl Corp	光学活性高分子担持ロジウム錯体を用いる光学活性アルデヒドの製造方法
MY134758A (en)	1999-09-20	2007-12-31	Invista Tech Sarl	Multidentate phosphite ligands, catalyst compositions made therefrom and catalytic processes employing such multidentate phosphite ligands
US6284865B1 (en) *	1999-09-20	2001-09-04	E. I. Du Pont De Nemours And Company	Polymeric phosphite composition and hydrocyanation of unsaturated organic compounds and the isomerization of unsaturated nitriles
EP1341797A4 (en) *	2000-11-17	2005-06-15	Penn State Res Found	ORTHO-SUBSTITUTED CHIRAL PHOSPHINES AND PHOSPHINITES AND THEIR USE IN ASYMMETRIC CATALYTIC REACTIONS
US8828098B2 (en)	2006-12-18	2014-09-09	3M Innovative Properties Company	Extenders for fluorochemical treatment of fibrous substrates

2001
- 2001-11-26 US US09/994,135 patent/US6660876B2/en not_active Expired - Lifetime
2002
- 2002-11-20 CA CA002468195A patent/CA2468195A1/en not_active Abandoned
- 2002-11-20 EP EP02782340A patent/EP1448298B1/en not_active Expired - Lifetime
- 2002-11-20 PL PL02370988A patent/PL370988A1/xx unknown
- 2002-11-20 JP JP2003547046A patent/JP4373786B2/ja not_active Expired - Lifetime
- 2002-11-20 BR BRPI0214629-0A patent/BR0214629B1/pt not_active IP Right Cessation
- 2002-11-20 MX MXPA04004938A patent/MXPA04004938A/es active IP Right Grant
- 2002-11-20 EP EP07024054A patent/EP1905511B1/en not_active Expired - Lifetime
- 2002-11-20 KR KR10-2004-7007942A patent/KR20040058321A/ko not_active Application Discontinuation
- 2002-11-20 WO PCT/US2002/037304 patent/WO2003045552A2/en active Application Filing
- 2002-11-20 AU AU2002348313A patent/AU2002348313A1/en not_active Abandoned
- 2002-11-20 CN CNB028275357A patent/CN100345635C/zh not_active Expired - Lifetime
- 2002-11-20 DE DE60237781T patent/DE60237781D1/de not_active Expired - Lifetime
- 2002-11-20 EP EP10178209A patent/EP2277623A3/en not_active Withdrawn
- 2002-11-20 AT AT02782340T patent/ATE482028T1/de not_active IP Right Cessation
2003
- 2003-09-10 US US10/659,205 patent/US6924345B2/en not_active Expired - Lifetime
2009
- 2009-01-28 JP JP2009017149A patent/JP5265400B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
EP1448298A2 (en)	2004-08-25
AU2002348313A8 (en)	2003-06-10
WO2003045552A3 (en)	2003-10-30
EP2277623A2 (en)	2011-01-26
EP1448298B1 (en)	2010-09-22
JP4373786B2 (ja)	2009-11-25
EP2277623A3 (en)	2011-06-08
WO2003045552A2 (en)	2003-06-05
US20030144440A1 (en)	2003-07-31
EP1905511B1 (en)	2013-03-27
DE60237781D1 (de)	2010-11-04
CN1617764A (zh)	2005-05-18
EP1905511A3 (en)	2010-01-27
JP2005510547A (ja)	2005-04-21
CN100345635C (zh)	2007-10-31
KR20040058321A (ko)	2004-07-03
JP5265400B2 (ja)	2013-08-14
AU2002348313A1 (en)	2003-06-10
US20040054105A1 (en)	2004-03-18
CA2468195A1 (en)	2003-06-05
US6924345B2 (en)	2005-08-02
ATE482028T1 (de)	2010-10-15
PL370988A1 (en)	2005-06-13
US6660876B2 (en)	2003-12-09
EP1905511A2 (en)	2008-04-02
JP2009161760A (ja)	2009-07-23
BR0214629A (pt)	2004-11-03
MXPA04004938A (es)	2004-08-11

Legal Events

Date	Code	Title	Description
2006-03-01	B25A	Requested transfer of rights approved	Owner name: INVISTA TECHNOLOGIES S.A.R.L. (US) Free format text: TRANSFERIDO DE: E. I. DUPONT DE NEMOURS AND COMPANY
2007-03-27	B25G	Requested change of headquarter approved	Owner name: INVISTA TECHNOLOGIES S.A.R.L. (CH) Free format text: SEDE ALTERADA CONFORME SOLICITADO NA PETICAO NO 018050042922/SP DE 21/10/2005.
2011-05-10	B07A	Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
2012-01-31	B09A	Decision: intention to grant [chapter 9.1 patent gazette]
2012-08-21	B16A	Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]	Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 20/11/2002, OBSERVADAS AS CONDICOES LEGAIS.
2016-09-27	B21F	Lapse acc. art. 78, item iv - on non-payment of the annual fees in time	Free format text: REFERENTE A 14A ANUIDADE.
2017-01-17	B24J	Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)	Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2386 DE 27-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.

Publication	Publication Date	Title
BR0214629B1 (pt)	2012-08-21	composto monomérico de ligante bidentado que contém fósforo, composição catalisadora e processo de hidroformilação.
BR9607982A (pt)	1998-06-23	Processo de hidrocianaçao
BR9509494A (pt)	1997-10-14	Processo de hidrocianação e composição de catalisador
ATE321792T1 (de)	2006-04-15	Verfahren zur herstellung von homo- und copolymeren des isobutens
DE69823969D1 (de)	2004-06-24	Katalysatorbestandteil, Katalysator und Verfahren zur Polymerisation von äthylenisch ungesättigten Monomeren
CA2044418A1 (en)	1992-10-11	Aminoalkylphosphinates and phosphinic-acid-containing polymers therefrom
ATE194974T1 (de)	2000-08-15	Teilchenförmigen polymer enthaltende phosphomagnesiumzementzusammensetzung
ATE231888T1 (de)	2003-02-15	Katalysatorbestandteil und seine verwendung zur olefinpolymerisation
ATE307149T1 (de)	2005-11-15	Neue latex zusammensetzung für beschichtung von verschiedenen substraten
ATE150044T1 (de)	1997-03-15	Verfahren zur herstellung von polymeren
ATE519859T1 (de)	2011-08-15	Verfahren zur herstellung von ausgewählten intermolekularen quervernetzungen in nukleinsäuren und ihre verwendungen
DE69915694D1 (de)	2004-04-22	Polymerstabilisatoren mit einem niedrigpolydispersat
BR9000285A (pt)	1990-11-27	Composicoes de catalisador,processos para a preparacao de um composto de paladio complexo e de polimeros
BR0115266A (pt)	2004-01-27	Processo para a preparação contìnua de composições polìmeras bem como aplicação
ATE531604T1 (de)	2011-11-15	Vorderfront eines kraftfahrzeuges mit einer stosstange
WO1997000127A3 (en)	1997-04-03	Catalyst composition and process for the preparation of copolymers of carbon monoxide and an olefinically unsaturated compound
DE50004792D1 (de)	2004-01-29	Mit phosphonsäureester-, phosphonsäure- oder carbaboran-funktionen substituierte oligomere und die entsprechenden pna-monomere
ATE250094T1 (de)	2003-10-15	Harzartiges copolymer enthaltend einheiten von phenolverbindungen und von olefinisch ungesättigten nichtsauren terpenverbindungen.
DE69604951D1 (de)	1999-12-09	Verfahren zur Copolymerisation von Kohlenmonoxid mit olefinisch ungesättigten Verbindungen
DE69914303D1 (de)	2004-02-26	Verfahren zur polymerisation von olefinen mit geträgerten ziegler-natta katalysatorsystemen
DE69605701D1 (de)	2000-01-27	Verfahren zur Copolymerisation von Kohlenmonoxid mit olefinisch ungesättigten Verbindungen
DE69504546D1 (de)	1998-10-15	Lebende statistische (Meth)acrylatcopolymere, daraus hergestellte Copolymere und Verfahren zur Herstellung dieser Copolymeren durch anionische Polymerisation
DE69702112D1 (de)	2000-06-29	Initiatorzusammensetzung für die Polymerisation von ungesättigten Monomeren
TW291477B (en)	1996-11-21	Process for the preparation of an aldehyde using a catalyst system comprising a multidentate phosphorous amide ligand and rhodium
ATE7927T1 (de)	1984-06-15	Neue bindemittel, verfahren zu ihrer herstellung und ihre verwendung zur elektrotauchlackierung.