BE581104A - - Google Patents
Info
- Publication number
- BE581104A BE581104A BE581104DA BE581104A BE 581104 A BE581104 A BE 581104A BE 581104D A BE581104D A BE 581104DA BE 581104 A BE581104 A BE 581104A
- Authority
- BE
- Belgium
- Prior art keywords
- salicylate
- composition according
- polyolefin
- sep
- vis
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims description 33
- 229920000098 polyolefin Polymers 0.000 claims description 26
- -1 p-hydroxyphenyl Chemical group 0.000 claims description 21
- 150000003902 salicylic acid esters Chemical group 0.000 claims description 21
- 229920000573 polyethylene Polymers 0.000 claims description 19
- 239000004698 Polyethylene (PE) Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000003381 stabilizer Substances 0.000 claims description 12
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 11
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- OZAVCEALUDNEKN-UHFFFAOYSA-N octadecyl 2-hydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1O OZAVCEALUDNEKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 229960004889 salicylic acid Drugs 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 claims description 2
- VCZWEXMOZFJYQB-UHFFFAOYSA-N OC1=CC2=CC=CC=C2C=C1C(=O)OCCCCCCCCCCCCCCCCCC Chemical compound OC1=CC2=CC=CC=C2C=C1C(=O)OCCCCCCCCCCCCCCCCCC VCZWEXMOZFJYQB-UHFFFAOYSA-N 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- CJYBKFFVXWWBMY-UHFFFAOYSA-N dodecyl 2-hydroxybenzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1O CJYBKFFVXWWBMY-UHFFFAOYSA-N 0.000 claims description 2
- UMPNUMNCGDXPCS-UHFFFAOYSA-N 2,3,5-tritert-butyl-4-phenylphenol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C(C(C)(C)C)=C1C1=CC=CC=C1 UMPNUMNCGDXPCS-UHFFFAOYSA-N 0.000 claims 1
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 claims 1
- 150000002334 glycols Chemical class 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 229920001098 polystyrene-block-poly(ethylene/propylene) Polymers 0.000 description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 230000000240 adjuvant Effects 0.000 description 8
- 239000002671 adjuvant Substances 0.000 description 8
- 238000002844 melting Methods 0.000 description 7
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N Phenyl salicylate Chemical class OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- 229960000969 phenyl salicylate Drugs 0.000 description 4
- 229960001860 salicylate Drugs 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- ASLNDVUAZOHADR-UHFFFAOYSA-N 2-butyl-3-methylphenol Chemical compound CCCCC1=C(C)C=CC=C1O ASLNDVUAZOHADR-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 3
- WHSXTWFYRGOBGO-UHFFFAOYSA-M 2-carboxy-6-methylphenolate Chemical compound CC1=CC=CC(C([O-])=O)=C1O WHSXTWFYRGOBGO-UHFFFAOYSA-M 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N Chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N Hexamethylenediamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 210000001138 Tears Anatomy 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000004059 degradation Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- OEEPMNFPUJTCOV-UHFFFAOYSA-N 2-[2-[2-[2-(2-hydroxybenzoyl)oxyethoxy]ethoxy]ethoxy]ethyl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OCCOCCOCCOCCOC(=O)C1=CC=CC=C1O OEEPMNFPUJTCOV-UHFFFAOYSA-N 0.000 description 1
- IHZOHAWTUVZDEQ-UHFFFAOYSA-N 2-hydroxy-N-octadecylbenzamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)C1=CC=CC=C1O IHZOHAWTUVZDEQ-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- WHSXTWFYRGOBGO-UHFFFAOYSA-N 3-methylsalicylic acid Chemical compound CC1=CC=CC(C(O)=O)=C1O WHSXTWFYRGOBGO-UHFFFAOYSA-N 0.000 description 1
- GPPRMDWJKBFBMZ-UHFFFAOYSA-N 4-morpholin-4-ylphenol Chemical compound C1=CC(O)=CC=C1N1CCOCC1 GPPRMDWJKBFBMZ-UHFFFAOYSA-N 0.000 description 1
- DFAYQBWQHUIBEA-UHFFFAOYSA-N C(C=1C(O)=CC=CC=1)OCCCCCCCCCCOCC=1C(O)=CC=CC=1 Chemical compound C(C=1C(O)=CC=CC=1)OCCCCCCCCCCOCC=1C(O)=CC=CC=1 DFAYQBWQHUIBEA-UHFFFAOYSA-N 0.000 description 1
- PCXXRPOYNDCHHS-UHFFFAOYSA-N C1(=C(O)C(C)=CC=C1)C(=O)OCCCCCCCCCCCCCCCCCC Chemical compound C1(=C(O)C(C)=CC=C1)C(=O)OCCCCCCCCCCCCCCCCCC PCXXRPOYNDCHHS-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 206010018987 Haemorrhage Diseases 0.000 description 1
- 210000004940 Nucleus Anatomy 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N Pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 206010037844 Rash Diseases 0.000 description 1
- WKEDVNSFRWHDNR-UHFFFAOYSA-N Salicylanilide Chemical compound OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000003078 antioxidant Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000000740 bleeding Effects 0.000 description 1
- 231100000319 bleeding Toxicity 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- YFDUWSBGVPBWKF-UHFFFAOYSA-N butyl 2-hydroxybenzoate Chemical class CCCCOC(=O)C1=CC=CC=C1O YFDUWSBGVPBWKF-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000005712 crystallization Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 125000005469 ethylenyl group Chemical group 0.000 description 1
- 230000001747 exhibiting Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008079 hexane Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- BKBMACKZOSMMGT-UHFFFAOYSA-N methanol;toluene Chemical compound OC.CC1=CC=CC=C1 BKBMACKZOSMMGT-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 230000001617 migratory Effects 0.000 description 1
- HDHYOOMZRWVCLA-UHFFFAOYSA-N octadecyl 2-methoxybenzoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1OC HDHYOOMZRWVCLA-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained Effects 0.000 description 1
- 229950000975 salicylanilide Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N stearylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing Effects 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE581104A true BE581104A (xx) |
Family
ID=191192
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE581104D BE581104A (xx) |
Country Status (1)
| Country | Link |
|---|---|
| BE (1) | BE581104A (xx) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1227650C2 (de) * | 1960-12-21 | 1973-11-29 | Verfahren zur herstellung von thermoplastischen massen aus polyolefinen |
-
0
- BE BE581104D patent/BE581104A/fr unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1227650C2 (de) * | 1960-12-21 | 1973-11-29 | Verfahren zur herstellung von thermoplastischen massen aus polyolefinen | |
| DE1227650B (xx) * | 1960-12-21 | 1973-11-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3022268A (en) | Polyethylene composition | |
| EP0090748B1 (fr) | Procédé de stabilisation de polymères à base de chlorure de vinyle, compositions stabilisantes pour la mise en oeuvre du procédé et polymères ainsi stabilisés | |
| EP2445865B1 (en) | Slip and antiblocking agent | |
| US4696964A (en) | Compositions stabilized with ethers of di- and tri-substituted hydroxylamines | |
| US3006959A (en) | 2-hydroxy-4-n-dodecyloxybenzophenone | |
| FR2458568A1 (fr) | Composition a base d'un sel metallique d'acide gras superieur, d'un alcool polyhydroxylique et d'un compose de magnesium, destinee a stabiliser une resine d'halogenure de vinyle et resine stabilisee avec cette composition | |
| EP0022047A1 (fr) | Procédé de stabilisation de polymères à base de chlorure de polyvinyle et polymères ainsi stabilisés | |
| EP0005678B1 (fr) | Compositions à base de PVC stabilisées thermiquement | |
| FR2645163A1 (fr) | Procede de stabilisation des polymeres halogenes | |
| BE581104A (xx) | ||
| FR2551062A1 (fr) | Polyphenols a liaisons en ortho, leur application en tant que stabilisants de matieres organiques, et compositions stabilisees renfermant de tels polyphenols | |
| LU83317A1 (fr) | Compositions de matieres plastiques ameliorees a base de polyolefines | |
| US4000113A (en) | Acylated derivatives of 2,6-dihydroxy-9-azabicyclo[3.3.1]nonane and stabilized compositions | |
| FR2476104A1 (fr) | Compositions de polyolefine stabilisees contre la radiation ultraviolette avec des amines a chaine ouverte, comportant un encombrement sterique | |
| LU82796A1 (fr) | Composition polymere thermoplastique apte au faconnage,contenant un acetal cyclique en tant qu'agent de nucleation | |
| FR2601006A1 (fr) | Benzylhydroxylamines substituees et leur emploi comme stabilisants, compositions comprenant ces substances et procede pour stabiliser avec ces substances des matieres organiques contre les degradations par oxydation, par la chaleur ou par un rayonnement actinique | |
| EP0010008B1 (fr) | Perfectionnement à la stabilisation de résines halogénovinyliques | |
| CA1090931A (fr) | Compositions plastifiees et stabilisees a base de poly (chlorure de vinyle) | |
| CA1093731A (fr) | Stabilisation des polymeres du chlorure de vinyle a l'aide de composes lactoniques | |
| US3875169A (en) | Bicyclic hindered amines | |
| JPS5945687B2 (ja) | 光安定剤 | |
| EP0024754B1 (fr) | Compositions stabilisées à la chaleur à base de polymères du chlorure de vinyle | |
| FR2617175A1 (fr) | Procede de stabilisation des resines halogeno-vinyliques lors de leur transformation | |
| EP0004826B1 (fr) | Compositions stabilisées à base de chlorure de polyvinyle et produits conformés obtenus à partir de ces compositions | |
| EP0027439B1 (fr) | Procédé de stabilisation de résines à base de polymères du chlorure de vinyle |