AU600060B2 - New pipe reactor - Google Patents
New pipe reactor Download PDFInfo
- Publication number
- AU600060B2 AU600060B2 AU82651/87A AU8265187A AU600060B2 AU 600060 B2 AU600060 B2 AU 600060B2 AU 82651/87 A AU82651/87 A AU 82651/87A AU 8265187 A AU8265187 A AU 8265187A AU 600060 B2 AU600060 B2 AU 600060B2
- Authority
- AU
- Australia
- Prior art keywords
- convergent
- divergent
- pipe reactor
- zone
- reactives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00081—Tubes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Materials For Medical Uses (AREA)
- Fertilizers (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Cleaning In General (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Tubular reactor incorporating a convergent-divergent member or a convergent member at the exit of the zone for introducing reactants and a convergent-divergent member or a convergent member at the exit of the reaction zone just before the exit nozzle for the finished products. <IMAGE>
Description
'-A
COMMONWEALTH OF AUSTRAL 0 0 0 6 0 M1 PATENTS ACT 1952-69 COMPLETE SPECIFICATION (ORIGIN AL) Class I t. Class Application N'umbor: Lodged: Complete Specification Lodged: Accepted: Published: Priority: I ii r'ldnents mande uivd-,n S49 and is co rrcct tor Related Art Name of Applicant: 0 Address of Applicant: CdF~ CHIMIE AZOTE ET FERTILIZANTS 143, Route France cl'Espagne, B.P. No. 3145, F-31053 Toulouse, Actual Inventor' Address for Service: DIMITRIOS ABRIANOJ BELTS, PIERRE CHINAL and JEAN FRANCOIS PRI AT EDWD, WATERS SONS, 50 QUEEN STREET, MELBOURNE, AUSTRALIA, 3000, Complete Specification for the 1I,-.,entlon eri titled: NEW PIPE REACTOR Tho follk wing statement Is a full deicrlption of this Invention, Including the best method of performing It known to, I-IS NEW PIPE REAC; R The present application relates to a new pipe reactor having improved output and flexibility.
Pipe reactors are well known. They are made out of a length of pipe having a rather small diameter and containing no stuffing. Pipe reactors generally used are horizontally set or stand at small iqle (at most 450) relative to an horizontal line. They have an inside diameter ranging between 200 and 10 mm and a length ranging between 1,50 and 10 m. The ratio length/ diameter is generally not less than They are used for neutralizing with ammonia, acids or mixtures of acids such as slurry obtained by attack of natural phosphate by an exces', of sulfuric acid, phosphoric acid and mixtures of these acids. More often they are used for the manufacture of ammonium phosphates or ammonium polyphos- S phates.
f,5 For a good running of the pipe reactor the reactives must be mixed as thoroughly as possible. If mixture is not thorough enough the output j of pipe reactor will be essentially constituted by a dense liquid phase es- S. sentially made out of more or less acid constituants which flow out of the I pipe and of a gaSeous phase made out of ammonia and steam. Therefore ammonia S0 losses are important. When the mixture is thorough no more dense phase is produced. A mist of droplets of more or less GoAr.ated. solution or of dry a particle is formed which can be easily separated from steam. Furthermore the unit should be able to treat as wide as possible range of amounts of reactives.
Different proposals have been made in order to improve the mixture of reactives at the head of the pipe reactor. It has been for example proposed to introduce one of the reactives through a sparger (French Patent 2,172,826). But this parger is liable to get clogged. It has also be proposed to use a jet reactor in which acid and ammonia are introduced t'rough 1 two concentric pipes and are mixed by using an helicoidal screw followed by a convergent. (Phosphorus and Potassium n° 45, 1970, pp. 18-19). But clogging takes place also between spiral screw and wall of the pipe reactor.
The present application relates to a new pipe reactor comprising a zone for the introduction of reactives a reaction zone and a nozzle for the output of reaction product characterized in that the pipe reactor is provided with a convergent-divergent or a convergent fitted in the reaction zone, just after the zone of introduction of reactives and a convergent-divergent or a convergent fitted at the output end of the reaction zone, just before the nozzle for the output of reaction product.
o According to the length of the pipe reactor and to reactives used one at-e-st three convergents-divergents or con\ergents areAplaced beto ween the two above defined convergents-divergents or convergents, 0 It has been noted that the use of these convergents-divergents or .'15 convergents improve the mixing of reactives without plugging risks. The flexibility is also highly improved.
o -00 The description given hereunder as well as the annexed figure will allow to understand better the invention.
oo Pipe reactor comprises a zone for the introduction of 0 va4 ea&Qt.s, a reaction zone and a nozzle for the output of reaction o, products.
According to the embodiment shown on annexed figure a convergentdivergent is fitted at the input of reaction zone According to the invention this convergent-divergent could be replaced by a convergent but (6) convergent-divergent gives a better result. A further conerentvergent-divergent is disposed at the output of reaction zone This convergent-divergent can also be replaced by a convergent. The d44-s4e1of a convergent-divergent) at the output of reaction zone rather than a corvergent is less advantageous than for the convergent-divergent at the input of reaction zone 2 According to the embodiment illustrateda convergent it set between convergents-divergents and A convergent-divergent could be substituted to convergent But it must be noted that according to the present invention their can be no convergent According to the length of the pipe reactor, 'i reaction zone up to 3 convergents-divergents or convergent can be between convergents-divergents anid Therefore reactives rgtting out of the zone of introduction of reactives are accelerated by the convergent-divergent thus improving the mixing of reactives at the beginning of the reaction. Convergent-divergent brings about a further mixing just before the output of the reaction product.
According to the present application reaction zone can be as- 2' sociated to any zone for the introduction of reactives. According to illuso° trated embodiment acid or mixture of acids is introduced into zone (2) o" through a feed pipe which opens perpendicularly in the pipe reactor There could be many feed pipes opening perpendicularly or tangentially in the pipe reactor As shown on the annexed figure two concentric, axially set feed pipes and (10) for feeding respectively water and/or I o washing waters and ammonia, the feed pipe (10) for water and/or washing o *20 brines feeding being inside the feed pipe for ammonia. The feeding pipe could be removed. Therefore feed pipe for ammonia liquid or gaseous S would remain.
The output nozzled pipe can be a frustoconial nozzle as shown on annexed figure. The nozzle could be also dissymetrical or bended in order to direct the spout of reaction product.
EXAMPLE
In a pipe reactor similar to that represented on annexed figure a mixture of ammonium phosphate and ammonium sulfate is prepared by reacting 26 phosphoric acid, 93 sulfuric acid and liquid ammoni.
-3a) when no convergent-divergent or convergent are set in reaction zone (3) 11 t/h to 5,5 t/h of liquid ammonia 26 t/h to 13 t/h of sulfuric acid 11 t/h to 5,5 t/h of phospnoric acid can be treated. The fl-xibility is about 1/2, b) when the reaction ,ne contains convergents-divergents and convergents as illustrated on annexed figure 2.t/h to 11 t/h of liquid ammonia t/h to 26 t/h of sulfuric acid 2 t/h to 11 t/h of phosphoric acid can be treated. The flexibility is about 1/6.
1 co O~t -4- L. i_ i_
Claims (3)
1. A pipe reactor comprising a zone for the introduction of reactives, a reaction zone and a nozzle for the output of the reaction product, characterized in that the pipe reactor is provided with a convergent-divergent or a convergent fitted at an input end of the reaction zone just after the zone of introduction of reactives and a convergent-divergent or convergent fitted at the output end of the reaction zone, just before the nozzle for the output of reaction product.
2. A pipe reactor according to claim 1, characterized in that between the convergent-divergent or convergent at o. o the input end and the convergent-divergent or convergent at the output end there are located up to three conveagent- divergents or convergents. o
3. A pipe reactor according to claim 1, substantially as described with reference to the accompanying figure and the example. DATED this 23rd day of January, 1990. 0 CdF CHIMIE AZOTE ET FERTILIZANTS WATERMARK PATENT 0 TRADEMARK ATTORNEYS 290 BURWOOD ROAD, HAWTHORN, VICTORIA, AUSTRALIA. PLP/KG/BB(7.29)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GR862922A GR862922B (en) | 1986-12-18 | 1986-12-18 | Tubular reactor |
GR862922 | 1986-12-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
AU8265187A AU8265187A (en) | 1988-06-23 |
AU600060B2 true AU600060B2 (en) | 1990-08-02 |
Family
ID=10925510
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU82651/87A Expired AU600060B2 (en) | 1986-12-18 | 1987-12-17 | New pipe reactor |
AU82652/87A Expired AU597133B2 (en) | 1986-12-18 | 1987-12-17 | Improved pipe reactor for the manufacture of ammonium phosphates containing ammonium sulfate |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU82652/87A Expired AU597133B2 (en) | 1986-12-18 | 1987-12-17 | Improved pipe reactor for the manufacture of ammonium phosphates containing ammonium sulfate |
Country Status (12)
Country | Link |
---|---|
EP (2) | EP0272974B1 (en) |
JP (2) | JP2511823B2 (en) |
CN (2) | CN1013490B (en) |
AT (2) | ATE94419T1 (en) |
AU (2) | AU600060B2 (en) |
DE (2) | DE3769771D1 (en) |
DZ (2) | DZ1165A1 (en) |
ES (2) | ES2043683T3 (en) |
GR (2) | GR862922B (en) |
MA (2) | MA21133A1 (en) |
OA (2) | OA08790A (en) |
TN (2) | TNSN87140A1 (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2695840B1 (en) * | 1992-09-22 | 1994-10-21 | Grande Paroisse Sa | Tubular reactor, process for neutralizing acids with NH3 and process for manufacturing fertilizers containing ammonium phosphates, sulfates, nitrates and / or fluosilicates using such a tubular reactor. |
DE4437047A1 (en) | 1994-10-17 | 1996-04-18 | Bayer Ag | Process for the dinitration of aromatic compounds |
FR2755959B1 (en) * | 1996-11-18 | 1998-12-24 | Kaltenbach Thuring Sa | REACTOR, PROCESS AND PLANT FOR THE MANUFACTURE OF AMMONIA SALTS |
ES2208068B1 (en) * | 2002-04-15 | 2005-03-16 | Incro, S.A. | TUBULAR REACTOR FOR OBTAINING AMONIC SALTS EMPLOYED IN THE MANUFACTURE OF FERTILIZERS. |
CN1986042B (en) * | 2005-12-21 | 2010-07-14 | 中国-***化肥有限公司 | Improved tubular reactor |
CN101036871B (en) * | 2006-03-17 | 2011-09-14 | 北京航天石化技术装备工程公司 | High-pressure liquid air tube type quick mixing reactor |
US8082860B2 (en) | 2008-04-30 | 2011-12-27 | Babcock Power Services Inc. | Anti-roping device for pulverized coal burners |
US8104412B2 (en) * | 2008-08-21 | 2012-01-31 | Riley Power Inc. | Deflector device for coal piping systems |
CN101768026B (en) * | 2009-12-28 | 2012-08-15 | 瓮福(集团)有限责任公司 | Method for producing sulfur fertilizer by using diammonium phosphate device to add sulfur powder |
CN102240529B (en) * | 2011-04-28 | 2012-07-18 | 张胜钊 | Synthesizing device and method for synthesizing formate by utilizing same |
SE536607C2 (en) * | 2012-06-21 | 2014-03-25 | Easymining Sweden Ab | Preparation of ammonium phosphates |
CN102835404B (en) * | 2012-09-27 | 2014-04-16 | 贵州大学 | Agricultural chemical for preventing and controlling rice blast |
CN106268499A (en) * | 2015-05-29 | 2017-01-04 | 林新吉 | Automatization's granulating system and comminutor thereof |
JP2018197214A (en) * | 2017-05-24 | 2018-12-13 | 日本合成アルコール株式会社 | Manufacturing method of alcohol |
CN112121618A (en) * | 2020-08-13 | 2020-12-25 | 广东臻鼎环境科技有限公司 | Device and method for improving liquid ammonia absorption efficiency |
EP4194704A1 (en) | 2021-12-13 | 2023-06-14 | Yara International ASA | Jet ejector arrangement, system and use thereof and method for operating the same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2048662A1 (en) * | 1970-10-03 | 1972-05-10 | Basf Ag | Polyamide moulding process - by activated anionic polymerisation of l simultaneous casting and polymerising in a mould |
CH564966A5 (en) * | 1974-02-25 | 1975-08-15 | Sauter Fr Ag Fabrik Elektrisch | |
GB2142835A (en) * | 1983-06-15 | 1985-01-30 | Taisei Corp | Method of mixing fluent materials |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB588884A (en) * | 1944-03-09 | 1947-06-05 | Du Pont | Manufacture of water-insoluble salts |
CH326944A (en) * | 1954-02-12 | 1958-01-15 | Dr Pflock Rudolf E C | Device for carrying out mixing and reaction processes |
US3310371A (en) * | 1962-10-30 | 1967-03-21 | Dorr Oliver Inc | Production of ammonium phosphate |
DE2107960A1 (en) * | 1971-02-19 | 1972-08-24 | Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen | Method and device for mixing a gas and a liquid |
BE790131A (en) * | 1971-10-14 | 1973-04-16 | Basf Ag | METHOD AND DEVICE FOR MIXING LIQUIDS |
DE2238853A1 (en) * | 1972-05-18 | 1974-02-14 | Lorenian Zareh | PROCESS FOR CONTINUOUS, EVEN AND INQUIRED PROMOTION AND SIMULTANEOUS PLASTICIZATION AND MIXING OF MATERIALS, IN PARTICULAR OF POWDER OR POWDER OR GRINDING PLASTICS AND RESIN UNDER |
JPS5350943Y2 (en) * | 1973-05-04 | 1978-12-06 | ||
US3954942A (en) * | 1974-09-16 | 1976-05-04 | Tennessee Valley Authority | Granular ammonium phosphate sulfate and monoammonium phosphate using common pipe-cross-type reactor |
JPS5281492U (en) * | 1975-11-22 | 1977-06-17 | ||
US4358433A (en) * | 1976-04-16 | 1982-11-09 | Pircon Ladislav J | Heterogeneous process |
US4127389A (en) * | 1977-04-04 | 1978-11-28 | Pullman Incorporated | Exchanger reactor |
IT1099588B (en) * | 1978-08-03 | 1985-09-18 | Anic Spa | PROCESS FOR THE PRODUCTION OF AMMONIUM POLYPHOSPHATE AND RELATED EQUIPMENT |
JPS5817125B2 (en) * | 1978-09-21 | 1983-04-05 | 三井東圧化学株式会社 | Method for producing ammonium phosphate slurry |
IT1174670B (en) * | 1980-06-05 | 1987-07-01 | Anic Spa | PROCEDURE FOR THE PRODUCTION OF AMMONIUM POLYPHOSPHATES AND EQUIPMENT TO MAKE IT |
JPS5933529B2 (en) * | 1980-12-02 | 1984-08-16 | セントラル硝子株式会社 | Ammonium phosphate production equipment |
JPS57135034A (en) * | 1981-02-16 | 1982-08-20 | Showa Denko Kk | Mixing method |
US4462543A (en) * | 1981-12-24 | 1984-07-31 | The Procter & Gamble Company | Nozzle |
US4447401A (en) * | 1982-02-22 | 1984-05-08 | Phillips Petroleum Company | Carbon black reactor with angled combustion chamber and non-aligned tangential hot gas entries for production of negative tint residual carbon black |
EP0087798B1 (en) * | 1982-03-01 | 1987-05-06 | Toyota Jidosha Kabushiki Kaisha | A method and apparatus for making a fine powder compound of a metal and another element |
US4522504A (en) * | 1983-12-08 | 1985-06-11 | Pyles Division | Linear in-line mixing system |
-
1986
- 1986-12-18 GR GR862922A patent/GR862922B/en unknown
-
1987
- 1987-12-10 EP EP87402802A patent/EP0272974B1/en not_active Expired - Lifetime
- 1987-12-10 AT AT87402802T patent/ATE94419T1/en not_active IP Right Cessation
- 1987-12-10 DE DE8787402801T patent/DE3769771D1/en not_active Expired - Lifetime
- 1987-12-10 EP EP87402801A patent/EP0272183B1/en not_active Expired - Lifetime
- 1987-12-10 DE DE87402802T patent/DE3787457T2/en not_active Expired - Lifetime
- 1987-12-10 ES ES87402802T patent/ES2043683T3/en not_active Expired - Lifetime
- 1987-12-10 ES ES87402801T patent/ES2022427B3/en not_active Expired - Lifetime
- 1987-12-10 AT AT87402801T patent/ATE63105T1/en not_active IP Right Cessation
- 1987-12-14 TN TNTNSN87140A patent/TNSN87140A1/en unknown
- 1987-12-14 TN TNTNSN87139A patent/TNSN87139A1/en unknown
- 1987-12-15 JP JP62317284A patent/JP2511823B2/en not_active Expired - Lifetime
- 1987-12-15 JP JP62317285A patent/JP2776504B2/en not_active Expired - Lifetime
- 1987-12-15 DZ DZ870219A patent/DZ1165A1/en active
- 1987-12-17 MA MA21374A patent/MA21133A1/en unknown
- 1987-12-17 MA MA21375A patent/MA21134A1/en unknown
- 1987-12-17 AU AU82651/87A patent/AU600060B2/en not_active Expired
- 1987-12-17 AU AU82652/87A patent/AU597133B2/en not_active Expired
- 1987-12-18 OA OA59251A patent/OA08790A/en unknown
- 1987-12-18 DZ DZ870218A patent/DZ1164A1/en active
- 1987-12-18 CN CN87107537A patent/CN1013490B/en not_active Expired
- 1987-12-18 OA OA59250A patent/OA08702A/en unknown
- 1987-12-18 CN CN87107538A patent/CN1017874B/en not_active Expired
-
1991
- 1991-08-01 GR GR91401108T patent/GR3002412T3/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2048662A1 (en) * | 1970-10-03 | 1972-05-10 | Basf Ag | Polyamide moulding process - by activated anionic polymerisation of l simultaneous casting and polymerising in a mould |
CH564966A5 (en) * | 1974-02-25 | 1975-08-15 | Sauter Fr Ag Fabrik Elektrisch | |
GB2142835A (en) * | 1983-06-15 | 1985-01-30 | Taisei Corp | Method of mixing fluent materials |
Also Published As
Publication number | Publication date |
---|---|
EP0272974B1 (en) | 1993-09-15 |
DE3769771D1 (en) | 1991-06-06 |
MA21133A1 (en) | 1988-07-01 |
AU597133B2 (en) | 1990-05-24 |
EP0272974A3 (en) | 1989-03-15 |
ATE94419T1 (en) | 1993-10-15 |
OA08702A (en) | 1989-03-31 |
DE3787457T2 (en) | 1994-03-10 |
DZ1165A1 (en) | 2004-09-13 |
OA08790A (en) | 1989-03-31 |
ATE63105T1 (en) | 1991-05-15 |
ES2043683T3 (en) | 1994-01-01 |
GR862922B (en) | 1987-01-12 |
EP0272974A2 (en) | 1988-06-29 |
AU8265187A (en) | 1988-06-23 |
JPH01119506A (en) | 1989-05-11 |
CN1017874B (en) | 1992-08-19 |
DZ1164A1 (en) | 2004-09-13 |
GR3002412T3 (en) | 1992-12-30 |
EP0272183B1 (en) | 1991-05-02 |
DE3787457D1 (en) | 1993-10-21 |
TNSN87139A1 (en) | 1990-01-01 |
CN87107537A (en) | 1988-08-24 |
MA21134A1 (en) | 1988-07-01 |
JPH01127035A (en) | 1989-05-19 |
JP2511823B2 (en) | 1996-07-03 |
CN87107538A (en) | 1988-07-20 |
ES2022427B3 (en) | 1991-12-01 |
TNSN87140A1 (en) | 1990-01-01 |
CN1013490B (en) | 1991-08-14 |
JP2776504B2 (en) | 1998-07-16 |
AU8265287A (en) | 1988-06-23 |
EP0272183A1 (en) | 1988-06-22 |
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