AU2001295476B2

AU2001295476B2 - Frozen confectionery

Info

Publication number: AU2001295476B2
Application number: AU2001295476A
Authority: AU
Inventors: Myriam Schlegel; Pierre Wuersch
Original assignee: Societe des Produits Nestle SA; Nestle SA
Current assignee: Societe des Produits Nestle SA
Priority date: 2001-08-17
Filing date: 2001-08-17
Publication date: 2008-06-26
Anticipated expiration: 2021-08-17
Also published as: WO2003015530A1; IL160054A0; BR0117104A; CN1543314A; IL160054A; MXPA04001502A

Description

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FROZEN CONFECTIONERY Field of the Invention The present inv ntion relates to the field of frozen confectioneries nd in particular to ice-cream.

Background of th Invention Any discussion of the prior art throughout the specification should in no way be considered as an admission that uch prior art is widely known or forms part of common g neral knowledge in the field.

Ice-creams are traditionally made using ingredients such as: fat, milk solids-not-fat, sweeteners, emulsifiers and water. The various ingredients are homogenized, th mixture is then pasteurised, cooled and optionally llowed to mature at about 2 to 40C and deep-frozen with stirring with injection of air to provide a degree of overrun of the order of 75 to 120%.

In general, starch, by virtue of its physicochemical characteristics and its rheological properties, is often used in the food industry as a thickener and/or as a binder. Th s, numerous documents describe the use of native or gelatinised starch, physically or chemically modi ied or not, in frozen confectioneries, as fat substitute or texturing agent.

Frozen confectioneries are particularly appreciated for their creamy and unctuous characteristics. However, these products, in order to preserve their optimum organoleptic characteristics of unctuousness, have to be stored and handled with care. Thus, temperature variations, even small, can be observed during storage, distribution or handling. This is particularly the case when the consu er buys a frozen confectionery, when they do not consume it straight away and when there is a gap between -he time the product is taken from the deep-frozen se tion and when it is placed in the 2 00 00

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domestic freezer. In such circumstances, substantial or partial defrosting of the product occurs before it is refrozen. Such cycles of temperature variation are responsible for crystalline growth of ice crystals in the product. 1 crystallized texture thus results therefrom. This texture and this crystallized mouth feel accompanie by an impaired appearance of the product compromises or at the very least reduces its overall quality s perceived by the consumer.

Various gums ad/or emulsifiers have been used as additives with the aim of improving the stability, the creaminess and the resistance of frozen confectioneries to heat shocks. These may include guar gum, carob or guar seed flou alginate, carboxymethyl cellulose, xanthan, carragE enan, synthetic or natural emulsifiers such as egg yolk. The milk proteins contained in the milk dry extrac participate in this stabilization by virtue of their water-binding property.

However, the uhe of gums has the disadvantage of conferring on tle product a texture which is sometimes firm or gummy. Moreover, the addition of such stabilizing com ounds is often poorly viewed by the consumer and heir use is regulated. Furthermore, additives of the type including milk solids-not-fat and/or proteins or milk protein derivatives are particularly expensive.

It is an object of the present invention to overcome or ameliorate at east one of the disadvantages of the prior art, or t provide a useful alternative.

It is an object of an especially preferred form of the present invention to provide an inexpensive formulation for frozen confectioneries which makes it possible to increase their stability during heat shocks without compromising thEir organoleptic qualities.

2a 00 Unless the context clearly requires otherwise, throughout the description and the claims, the words "comprise", "comprising", and the like are to be 5 construed in an inclusive sense as opposed to an 00 exclusive or exhaustive sense; that is to say, in the sense of "including, but not limited to".

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Although the invention will be described with reference to specific examples it will be appreciated by those skilled in the art that the invention may be embodied in many other forms.

Summary of the Invention According to a first aspect of the present invention there is provided frozen confectionery comprising, by weight, 2 to 12% of fat, 10 to 25% of sweeteners, 2 to of milk solids-not-fat, 0.5 to 3% of starch and to 85% of water, wherein the sum of the quantities of starch and milk solids-not-fat is between 2.5 and 18% by weight and wherein the starch/milk solids-not-fat weight ratio is between 0.03 and According to a second aspect of the present invention there is provided a process for making frozen confectioneries, wherein said confectioneries comprise a relative increase in stability during heat shock without compromising its organoleptic qualities, said process comprising the steps of: dispersion, heating and homogenisation of the ingredients entering into the composition of a frozen confectionery according to any one of claims 1 to 9 at a temperature, a pressure and for a period sufficient to hydrate and gelatinise the starch and pasteurise the mixture, cooling of the mixture to a temperature of between 2 0C and 8 0C, 2b 00 0 ripening of the mixture at a Stemperature of between 2 °C and 6 without stirring, freezing to a temperature of between 3 °C and -7 providing a degree of overrun of (CN between 70 and 130%, hardening of the mixture by deep- ND freezing to a temperature of between -20 °C and -40 °C.

According to a third aspect of the present invention Sthere is provided frozen confectioneries, when made by (CN a process according to the second aspect of the present invention.

To this end, the present invention consists in a frozen confectionery, in particular an ice-cream, comprising fat, sweeteners, milk solids-not-fat, water and starch, characterized in that the sum of the quantities of starch and milk solids-not-fat is between 2.5 and 18% and in that the starch/milk solids-not-fat weight ratio is between 0.03 and A frozen confectionery according to the present invention may comprise 2 to 12% of fat, 10 to 25% of 7 WO 03/015530 PCT/EP01/09473 3 sweeteners, 2 to 15% of milk solids-not-fat, 0.5 to3% of starch and 45 to 85% of water.

The percentages indicated in the description relate to the percentages by weight except in the case of the overrun values which are defined in by volume.

Thus, according to the invention, the partial replacement of the milk solids-not-fat traditionally used by starch allows substantial savings while improving the resistance to heat shocks. Furthermore, the product thus obtained has a creamy and unctuous mouth feel close to or even superior to that of the traditional product. Thus, apart from the mere economic advantage, the invention makes it possible to simultaneously improve the pleasantness of use and the textural and organoleptic qualities of frozen confectioneries.

The starch used in the present invention may be a native starch or a chemically or physically modified starch. It may thus include native starches from maize rice, potato or tapioca, for example, which are used alone or in the form of a mixture or alternatively chemically modified starches of these same origins, such as hydroxypropylated starches, for example. Such starches have a gelatinization temperature of between approximately 50 and 850°C, and a granule diameter of between approximately 3 and 100 ptm.

The ingredients used for making a frozen confectionery according to the invention are, apart from the starch, milk solids-not-fat such as powdered or concentrated skimmed milk, for example. This may also include powdered or concentrated defatted sweet whey, for example. These milk solids-not-fat may also be derived from a commercial mixture of milk powder and whey proteins whose functionality is controlled by specific WO 03/015530 PCT/EP01/09473 4 denaturation treatments. These may include for example Nollibel® The frozen compositions according to the invention may optionally comprise one or more emulsifiers in an amount of 0.2 to 0.3% which facilitate the emulsification of the various ingredients during manufacture. These may thus include, for example, monoor diglycerides or polysorbates or a mixture thereof, for example.

The frozen confectioneries according to the present invention may comprise stabilizing agents; these may include carob flour, guar flour, alginates, carboxymethyl cellulose, xanthan, carrageenan, used alone or in the form of a mixture at a dose of 0.1 to preferably 0.25%.

The fat used may be a vegetable or animal fat, hydrogenated or otherwise, for example. It may be a mixture of fat of plant origin, such as palm, coconut or palm kernel oil, hydrogenated or not.

The sweetener used may be sucrose, glucose, fructose or glucose syrup with variable DE varying from 20 to or a mixture thereof, for example. The formulation of the product according to the invention may in addition comprise colourings such as beta-carotene, for example, and/or any type of flavourings or perfumes customarily used to flavour frozen confectioneries, such as vanilla or chocolate for example.

The frozen confectioneries according to the invention may be composed of milk solids-not-fat, sweeteners, fat and water. The proportions of ingredients such as starch and milk solids-not-fat make it possible to obtain increased stability of the products as well a substantial reduction in the cost price of these products. These savings are made through the partial WO 03/015530 PCT/EP01/09473 5 replacement of the milk solids-not-fat traditionally used by starch. Furthermore, the organoleptic qualities of the frozen compositions according to the invention are not reduced compared with the traditional products.

Thus, the characteristics of unctuousness and creaminess are increased and in particular better preserved during the period of storage. In the frozen compositions according to the invention, it is the addition of starch in place of a portion of the milk solids-not-fat which makes it possible to slow down the rate of melting of the products obtained and thus confers greater stability to heat shocks on the product.

The frozen compositions according to the invention may have a dry extract of the order of 25 to preferably 30 to 40% and more preferably still from 33 to 36%. The compositions according to the invention may in addition optionally comprise additions such as fruit or fruit pieces, for example, or nuts, or hazelnuts, whole or in pieces, for example.

The invention also relates to a process for making frozen confectioneries comprising the following steps: dispersion, heating and homogenization of the ingredients entering into the composition of a frozen confectionery according to the present invention at a temperature, a pressure and for a period sufficient to hydrate and gelatinize the starch and pasteurize the mixture, cooling of the mixture to a temperature of between 2 and ripening of the mixture at a temperature of between 2 and 60°C, without stirring, freezing to a temperature of between -3 0 C and -7 0 C, providing a degree of overrun of between 70 and 130%, hardening of the mixture by deep-freezing to a temperature of between -20°C and -40 0

C.

WO 03/015530 PCT/EP01/09473 6 Optionally, the step of ripening of the mixture may be carried out with stirring.

The ingredients entering into the composition of a frozen confectionery according to the present invention may be dispersed at around approximately 60 to 70°C for approximately 15 to 30 minutes, for example. The whole may be heated and homogenized at around 70 to 75 0 C, for example, at a pressure of the order of 140 to 220 bar, for example. These steps of dispersion, heating and homogenization make it possible to bring about hydration and swelling of the starch.

The mixture may then be pasteurized according to methods known to persons skilled in the art, for example at around 80 to 900°C for 10 to 30 seconds. The homogenization-heating step may be carried out at a pasteurization temperature which brings about, on its own, pasteurization of the mixture. The mixture may then be cooled to around 2 to 8 0 C by known means. This mixture may then be ripened or otherwise for 4 to 48 hours at around 2 to 6 0 C, for example, with or without stirring. After this ripening step, the mixture may be frozen at around -3 to -7 0 C with stirring with injection of gas so as to produce a degree of overrun of the order of 70 to 130%, for example. The mixture obtained may then be hardened by freezing at around to -40°C, for example.

After the ripening step, the frozen compositions may, for example, be extruded in the form of quenelles having a greater or lesser degree of overrun, with the aid of an ice-cream industry refrigerated extruder, with or without injection of gas, for example.

To evaluate the influence of the partial replacement of milk solids-not-fat by starch, various textural, microscopic and macroscopic tests may be carried out.

WO 03/015530 PCT/EP01/09473 7 Measurement of the melting of ice-creams: The melting tests are carried out both on samples stored at -30 0 C and on samples which have been subjected to a heat shock.

Standard heat shock: the samples initially stored at 0 C are subjected, for 7 days, to a temperature cycle of -10oC/20 0 C. After the 7 days, the melting parameters are evaluated for these samples which were subjected to a heat shock.

The temperature for the melting test is set at 20 0 C, in a chamber saturated with moisture. Before the test, the samples are tempered overnight at -20 0 C. Each ice-cream sample is unmoulded and deposited on a grid on top of a scale. The duration of the test is between 30 and 240 minutes approximately. The mass of unmelted product is thus recorded over time. The parameters measured are the following: M: percentage by weight of product which has flowed through the grid at the end of the test.

S: time taken for 1% of the initial mass to have flowed.

Measurement of the viscosity of the mixtures for frozen confectionery: The measurement of the viscosity is carried out on the mixture during the ripening step at around 4°C, for example. A measuring probe is inserted into the mixture and connected to a motor which brings about its rotation at a predefined constant speed.

The viscosity can thus be measured at around 4 0 C with the aid of a Brookfield LVT-DV2 viscometer, for example. The speed of rotation of the probe may be established at 30 revolutions per minute, for example.

WO 03/015530 PCT/EP01/09473 8 The visocity may then be read on the display of the viscometer. This viscosity may be expressed in Pa.s or a multiple.

Size and distribution of the ice crystals in an icecream An aliquot of ice-cream is mixed with an equivalent quantity of glycerol and observed under a microscope at a temperature of -10 0 C. The measurement may be carried out in a chamber at -10°C equipped with microscope and a camera. It is thus possible to measure the mean diameter of the crystals (in grn) in the finished products and in the products which have been subjected to a heat shock. Knowing the mean diameter of the crystals, the crystalline growth which has taken place in the product can be easily evaluated.

Embodiments of the invention include, for example, frozen bars, ice-creams, frozen yoghurts and any frozen confectionery or dessert with a greater or lesser degree of overrun.

It can thus be observed that the samples containing for example 1.5% starch and 6% milk solids-not-fat have a homogeneous viscosity compared with a control sample traditionally containing 10% milk solids-not-fat and no starch. Thus, the mixture, after the ripening stage, exhibits no phase separation, remains pumpable and shows no signs of developing a gelled structure.

As regards the heat shock resistance properties, the parameters measured demonstrate retardation as regards the rate of melting of the samples containing starch compared with the traditional product.

The frozen confectioneries according to the present invention exhibit improved stability and organoleptic characteristics similar to traditional products. Such WO 03/015530 PCT/EP01/09473 9 products according to the invention preserve their organoleptic properties of creaminess and unctuousness throughout their preservation, storage, handling, distribution and more especially with respect to heat shocks which are harmful to these characteristics.

These products indeed exhibit reduced crystalline growth compared with traditional products. This contributes to their unctuous consistency and to the preservation of this characteristic despite unfavourable storage conditions responsible for the development of ice crystals which may be responsible for a crystallized and sandy structure. Such functionalities make it possible to envisage production, storage and distribution of the products according to the invention extending over time, volume and space.

A frozen confectionery according to the present invention is therefore characterized in that it preserves its unctuousness and exhibits reduced crystalline growth during a heat shock followed by refreezing.

The expression "reduced crystalline growth" is understood to mean an increase in the mean diameter of the ice crystals of less than 50% after heat shock (see Table 4).

The invention is described below with reference to various precise examples of preferred embodiments and modes of formulation. However, various adaptations and/or modifications may be made while remaining within the scope of the present invention.

MANUFACTURE OF THE VARIOUS SAMPLES Various examples of manufacture of frozen confectionery according to the present invention are produced WO 03/015530 PCT/EP01/09473 10 according to the formulations indicated in Table 1 below.

The various ingredients are dispersed at 65 0 C and then undergo a hydration step at 60 0 C for 20 minutes. The mixture is preheated to 720C, which brings about gelatinization of the starch present, where appropriate. The mixture is then homogenized at 180 bar with the aid of an ice-cream industry homogenizer and then pasteurized at 860C for 20 seconds. After cooling to 50C, the mixture is ripened for 24 hours at without stirring. Finally, the mixture is frozen at about -5 0 C with a degree of overrun of 100%. The icecream obtained is hardened at -30°C by conventional means.

Table 1 Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. Nollibel® 10 6 6 6 0 Skimmed milk powder 0 0 0 0 Hydroxypropylated potato 0 1.5 0 0 0 starch Hydroxypropylated tapioca 0 0 0 1.5 0 starch Native maize starch 0 0 1.5 0 0 Cremodano 0.5 0.5 0.5 0.5 Vegetable fat Polawar® 8 8 8 8 8 Sugar 14 15 15 15 14 Glucose syrup DE 38-42 4 5 5 5 4 Water 63.5 64.5 64.5 64.5 63.5 Nollibel®: mixture of milk powder and functional whey proteins.

Cremodan®: mixture of emulsifiers and stabilizers.

Polawar®: mixture of fractionated and partially hydrogenated vegetable fat from palm kernel.

WO 03/015530 PCT/EP01/09473 11 Variation of the viscosity of the mixtures Figure 1 shows the viscosities of the mixtures and the variation of these viscosities during the ripening step at All the mixtures are homogeneous after 24 hours of ripening, that is to say that no phase separation is observed in spite of the absence of stirring. The mixtures remain pumpable and are not gelled. A slight increase in viscosity may be noted over the period of time measured. Furthermore, the viscosity ranges are fairly narrow and are within the values of the reference examples (Examples 1 and Melting tests: Table 2 Samples stored at -300C Dry extract S (min) variation M variation Example 1 36.5 31 Example 2 35.6 31 0.00% 24 -20.00% Example 3 35.9 49 58.06% 21 -30.00% Example 4 35.9 48 54.84% 19 -36.67% Example 5 36.5 50 61.29% 40 33.33% Table 3 Samples after heat shock Dry extract S (min) variation M variation Example 1 36.5 26.5 51 Example 2 35.6 44 66.04% 40 -21.57% Example 3 35.9 52 96.23% 34 -33.33% Example 4 35.9 43 62.26% 25 -50.98% Example 5 36.5 40 50.94% 53 3.92% WO 03/015530 PCT/EP01/09473 12 Tables 2 and 3 show that all the samples containing starch begin to melt later than (S value always higher, up to 100% increase, or equal) and their percentage of molten product at the end of the test is always less than for the references. These conclusions are valid for the products stored at -30 0 C but also, which is more important, for the products which were subjected to a heat shock.

Size of the crystals and crystalline growth: Table 4 Mean diameter of the ice Growth after heat crystals (pm) shock Storage at -30 0 C After heat shock m Example 1 32 49 16 53 Example 2 30 45 15 49 Example 3 32 42 10 31 Example 4 31 44 13.5 43 Example 5 30 50 19.5 67 Table 4 shows the mean diameter of the ice crystals in various frozen products. It may be observed that the products containing starch have, on the one hand, a mean crystal diameter smaller than the references, this being so particularly after heat shock. The samples with starch exhibit increases in crystal size which are significantly less than for the references. Analysis of the size and of the distribution of the ice crystals makes it possible to show that the partial replacement of the milk solids-not-fat by starch improves the stability of the samples during heat shock.

Sensory analysis: The five samples were evaluated by a panel of people trained in the evaluation of texture and flavour.

WO 03/015530 PCT/EP01/09473 13 The questionnaire distributed contains the descriptive attributes for: texture sweet taste flavour All the texture descriptions show significant product effects, reflecting the differences between the products. The products do not appear to be significantly different for the flavour descriptions.

Furthermore, surprisingly, the samples with starch have a higher score as regards the description relating to the cream flavour.

The samples with starch (compared with the control samples) have a greater mouthfill, are slightly harder, smoother, melt less rapidly, are less cold and are slightly more gummy, which appears to correspond to the presence of crystals in the control sample. It is thus confirmed that these samples with starch would therefore withstand heat shock better.

Claims

2. Frozen confectionery according to claim 1, (1 wherein the starch is chosen from the group consisting of native starches from potato, maize, tapioca or rice or a mixture thereof.
3. Frozen confectionery according to claim 1 or claim 2, wherein the starch is a chemically or physically modified starch.
4. Frozen confectionery according to any one of the preceding claims, comprising one or more emulsifiers.
5. Frozen confectionery according to any one of the preceding claims, comprising at least one stabilizer chosen from the following group: carob or guar seed flour, alginates, cellulose, xanthan, carrageenans.
6. Frozen confectionery according to any one of the preceding claims, wherein the milk solids-not- fat are chosen from the group composed of powdered or concentrated skimmed milk, powdered or concentrated defatted sweet whey, a commercial mixture of milk powder and of whey proteins. 15 00 0 7. Frozen confectionery according to any one of the O preceding claims, wherein the sweeteners are chosen from the group comprising sucrose, glucose, fructose or glucose syrups or a mixture of these agents. 00 (N
8. Frozen confectionery according to claim 7, IND wherein the glucose syrups have a DE of between and
9. A process for making frozen confectioneries, Swherein said confectioneries comprise a relative (Ni increase in stability during heat shock without compromising its organoleptic qualities, said process comprising the steps of: dispersion, heating and homogenisation of the ingredients entering into the composition of a frozen confectionery according to any one of claims 1 to 9 at a temperature, a pressure and for a period sufficient to hydrate and gelatinise the starch and pasteurise the mixture, cooling of the mixture to a temperature of between 2 0C and 8 0C, ripening of the mixture at a temperature of between 2 0C and 6 0C, without stirring, freezing to a temperature of between 3 0 C and -7 0C, providing a degree of overrun of between 70 and 130%, hardening of the mixture by deep- freezing to a temperature of between -20 0C and 0C.
10. A process according to claim 10, wherein the step of ripening of the mixture is carried out with stirring. 16 00
11. Frozen confectioneries, when made by a process according to claim 9.
12. Frozen confectionery substantially as herein 5 described with reference to any one of the 00 (C embodiments of the invention illustrated in the accompanying drawings and/or examples. \O
13. A process for making frozen confectioneries, said process substantially as herein described with reference to any one of the embodiments of the invention illustrated in the accompanying (1 drawings and/or examples.
14. Frozen confectioneries, when made by a process substantially as herein described with reference to any one of the embodiments of the invention illustrated in the accompanying drawings and/or examples. Dated this 27 th day of May 2008 Shelston IP Attorneys for: Societe De Produits Nestle S.A.