AU2001269725A1 - Polymerization of olefins - Google Patents

Polymerization of olefins

Info

Publication number
AU2001269725A1
AU2001269725A1 AU2001269725A AU6972501A AU2001269725A1 AU 2001269725 A1 AU2001269725 A1 AU 2001269725A1 AU 2001269725 A AU2001269725 A AU 2001269725A AU 6972501 A AU6972501 A AU 6972501A AU 2001269725 A1 AU2001269725 A1 AU 2001269725A1
Authority
AU
Australia
Prior art keywords
transition metal
hydrocarbyl
ligand
olefin
metal complex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001269725A
Inventor
Alex S. Ionkin
Lynda K Johnson
Lin Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27395149&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AU2001269725(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of AU2001269725A1 publication Critical patent/AU2001269725A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene

Claims (20)

CLAIMS What is claimed is :
1. A transition metal complex of a ligand of the formula (I)
wherein:
Y is oxo, NR12 or PR12
Z is O, NR13, S or PR13; each of R1, R2 and R3 is independently hydrogen, hydro- carbyl , substituted hydrocarbyl or a functional group; n is 0 or 1; each R12 is independently hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group; each R13 is independently hydrogen, hydrocarbyl, substi- tuted hydrocarbyl or a functional group; and provided that any two of R1, R2 and R3 geminal or vicinal to one another taken together may form a ring.
2. The transition metal complex of claim 1, character- ized in that the transition metal is a Group 3-11 transition metal .
3. The transition metal complex of claim 2, characterized in that the transition metal is selected from the group consisting of Ni, Zr, Ti , Fe, Co and Cu.
4. The transition metal complex of claim 1, characterized in that Z is O or NR13, and n is 0.
53
5. The transition metal complex of claim 1, characterized in that:
Y is oxo; Z is NR13; R1 is hydrogen or hydrocarbyl; n is 0; and R13 is hydrocarbyl or substituted hydrocarbyl having an Es of less than -1.0 or aryl or substituted aryl in which at least one bond vicinal to the free bond of the aromatic group is substituted; or
Y is NR12; Z is NR13; n is 0; R1 is hydrogen or hydrocarbyl; R12 and R13 are each independently hydrocarbyl or substi- tuted hydrocarbyl, one or both having an Es of less than
-1.0, or aryl or substituted aryl in which at least one bond vicinal to the free bond of the aromatic group is substituted.
6. The transition metal complex of claim 1, characterized in that it has the formula (L1) x (L2) y (L3) ZM (VIII), wherein L3 is (I); z is 1 or 2; M is a transition metal of oxidation state q; y is an integer of 1 to 3; x=(q-z); each L1 is independently a monodentate, monoanionic ligand, wherein at least one L1 group is a ligand that may add to an olefin; and L2 is a monodentate neutral ligand which may be displaced by an olefin, or an empty coordination site; or L1 and L2 taken together are a monoanionic, bidentate ligand into which an olefin molecule may insert between the ligand and M.
7. The transition metal complex of claim 1, characterized in that it has the formula (III), (IV), (V) or (VI):
54
wherein M is the transition metal; each L1 is independently a monodentate, monoanionic ligand, wherein at least one L1 group is a ligand that may add to an olefin; and L2 is a monodentate neutral ligand which may be displaced by an olefin, or an empty coordination site; or L1 and L2 taken together are a monoanionic, bidentate ligand into which an olefin molecule may insert between the ligand and M.
8. A process for the polymerization of olefins, comprising the step of contacting, under olefin polymerizing conditions : a monomer component comprising one or more of olefins of the formula H2C=CHR4, a norbornene, a styrene, a cyclopen-
55 tene or a polar olefin, especially an olefin of the formula H2C=CHR4 and/or a polar olefin of the formula H2C=CHR5C02R6 , wherein R4 is hydrogen, alkyl or substituted alkyl, R5 is a covalent bond, alkylene or substituted alkylene, and R6 is hydrogen, a metal cation, hydrocarbyl or substituted hydrocarbyl, with a transition metal polymerization catalyst, characterized in that the transition metal polymerization catalyst comprises a transition metal complex as set forth in any one of claims 1-7.
9. The process of claim 8, characterized in that a cocatalyst is present.
10. The process of claim 8, characterized in that the monomer component comprises ethylene.
11. A process for the manufacture of a polar copolymer, wherein one or more hydrocarbon olefins, one or more polar olefins, and a polymerization catalyst system having a transition metal complex component containing a transition metal of groups 6-11 or a lanthanide metal, are contacted under polymerizing conditions to form said polar copolymer, characterized in that the transition metal complex component comprises a Zwitterionic complex.
12. The process of claim 11, characterized in that said transition metal is from Groups 8-11.
13. The process of claim 12, characterized in that said transition metal is Pd, Ni or Cu.
56
14. The process of claim 13, characterized in that said transition metal is Ni .
15. The process of claim 11, characterized in that said Zwitterionic complex is a Lewis acid adduct of a transition metal complex, the transition metal complex comprising a transition metal complexed to a ligand, wherein a Lewis base is present in the ligand, and wherein the Lewis acid is coordinated to the Lewis base.
16. The process of claim 15, characterized in that the transition metal complex is as set forth in any one of claims 1-7.
17. The process of claim 11, characterized in that said Zwitterionic complex is a Lewis acid adduct of a transition metal complex, wherein said Lewis acid is a borane or an aluminane .
18. The process of claim 17, characterized in that said Lewis acid is a tris (pentafluorophenyl) borane, triphenylbo- rane or a trihydrocarbylaluminum.
19. The process of any one of claims 11-18, character- ized in that said hydrocarbon olefin is ethylene, and said polar olefin is one or more of H2C=CHR5C02R6, wherein R5 is n- alkylene or a covalent bond, and R6 is hydrocarbyl or substituted hydrocarbyl .
20. The process of claim 19, characterized in that an ethylene pressure is about 700 kPa or more, and said process is run at about 50°C to about 170°C.
57
AU2001269725A 2000-05-31 2001-05-31 Polymerization of olefins Abandoned AU2001269725A1 (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US20808700P 2000-05-31 2000-05-31
US60/208,087 2000-05-31
US21160100P 2000-06-15 2000-06-15
US60/211,061 2000-06-15
US21403600P 2000-06-23 2000-06-23
US60/214,036 2000-06-23
PCT/US2001/017636 WO2001092348A2 (en) 2000-05-31 2001-05-31 Polymerization of olefins

Publications (1)

Publication Number Publication Date
AU2001269725A1 true AU2001269725A1 (en) 2001-12-11

Family

ID=27395149

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001269725A Abandoned AU2001269725A1 (en) 2000-05-31 2001-05-31 Polymerization of olefins

Country Status (10)

Country Link
US (3) US6506861B2 (en)
EP (1) EP1290043A2 (en)
JP (1) JP2003535107A (en)
KR (1) KR20030005432A (en)
CN (1) CN100406478C (en)
AU (1) AU2001269725A1 (en)
BR (1) BR0111338A (en)
CA (1) CA2408663A1 (en)
MX (1) MXPA02011811A (en)
WO (1) WO2001092348A2 (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6245871B1 (en) * 1997-04-18 2001-06-12 Eastman Chemical Company Group 8-10 transition metal olefin polymerization catalysts
SG96633A1 (en) * 2000-07-04 2003-06-16 Mitsui Chemicals Inc Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby
US20030130452A1 (en) * 2001-10-12 2003-07-10 Johnson Lynda Kaye Copolymers of ethylene with various norbornene derivatives
US7030200B2 (en) * 2002-03-06 2006-04-18 E.I. Du Pont De Nemours And Company Catalysts for olefin polymerization
US7037990B2 (en) * 2003-01-03 2006-05-02 Nippon Synthetic Chemical Company Transition metal complexes in the controlled synthesis of polyolefins substituted with functional groups
DE10304158A1 (en) * 2003-02-03 2004-08-05 Bayer Ag New transition metal complexes with azo ligands, useful as catalysts, particularly for polymerization of olefins, especially in presence of polar additives
US7754839B2 (en) * 2003-03-03 2010-07-13 The Regents Of The University Of California Quasi-living metal catalyst for ethylene homo-polymerization and co-polymerization with 5-norbornen -2-yl acetate
US7825200B2 (en) * 2003-02-28 2010-11-02 The Regents Of The University Of California Controlled free radical grafting from polyolefins
US7968487B2 (en) 2003-02-28 2011-06-28 The Regents Of The University Of California Single component, phosphine-free, initiators for ethylene homopolymerization and copolymerization with functionalized co-monomers
US7259214B2 (en) * 2003-02-28 2007-08-21 The Regents Of The University Of California Metal catalyst for olefin polymerization and co-polymerization with functional monomers
DE10310289A1 (en) * 2003-03-10 2004-09-23 Bayer Ag Process for the preparation of an azo catalyst for the polymerization of olefins
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7005489B2 (en) * 2003-09-29 2006-02-28 Equistar Chemicals, Lp Zwitterionic Metallocycles
US6903169B1 (en) * 2003-12-30 2005-06-07 Equistar Chemicals, Lp LTMC polymerization of unsaturated monomers
US7199074B2 (en) * 2004-06-14 2007-04-03 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7172986B2 (en) * 2004-06-14 2007-02-06 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US7635739B2 (en) * 2005-08-31 2009-12-22 Rohm And Haas Company Substantially linear polymers and methods of making and using same
FR2937643B1 (en) 2008-10-27 2011-10-14 Arkema France NOVEL BLOCK COPOLYMERS OF POLAR AND APOLAR OLEFINS
US20110065950A1 (en) * 2009-09-03 2011-03-17 Technical University Of Denmark Palladium catalyst system comprising zwitterion and/or acid-functionalyzed ionic liquid
WO2011026860A1 (en) 2009-09-03 2011-03-10 Technical Univeristy Of Denmark Palladium catalyst system comprising zwitterion and/or acid-functionalized ionic liquid
IT201700006307A1 (en) * 2017-01-20 2018-07-20 Versalis Spa BONE-AZOTATE COMPLEX OF IRON, CATALYTIC SYSTEM INCLUDING THE BONE-AZOTATE COMPLEX OF IRON AND PROCEDURE FOR (CO) POLYMERIZATION OF CONJUGATED DIENES
CN109694436A (en) * 2017-10-24 2019-04-30 中国石油化工股份有限公司 A kind of alkene-alkene alkoxide polymer and preparation method thereof
CN109096139B (en) * 2018-09-03 2021-03-02 贵州大学 Preparation method of alpha-carbonyl amide derivative
CN112759710B (en) * 2021-01-22 2023-09-08 吴军化 Para-phenoxy substituted alpha-diimine iron catalyst and preparation method thereof

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE188967T1 (en) * 1994-06-13 2000-02-15 Targor Gmbh TRANSITION METAL JOINTS
US5486632A (en) * 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
US5972822A (en) * 1994-08-02 1999-10-26 The Dow Chemical Company Biscyclopentadienyldiene complex containing addition polymerization catalysts
US5942461A (en) * 1995-11-06 1999-08-24 Minnesota Mining And Manufacturing Company Polymerizable compositions comprising alpha-olefin hydrocarbon monomers and methods of use therefor
US6174974B1 (en) * 1996-07-05 2001-01-16 Bayer Aktiengesellschaft Method for producing thermoplastic elastomers
US5939503A (en) * 1996-08-09 1999-08-17 California Institute Of Technology Group IV zwitterion ansa metallocene (ZAM) catalysts for α-olefin polymerization
US6174975B1 (en) 1998-01-13 2001-01-16 E.I. Du Pont De Nemours And Company Polymerization of olefins
EP0952998B1 (en) 1997-01-14 2002-06-19 E.I. Du Pont De Nemours And Company Polymerization of ethylene
WO1998030609A1 (en) * 1997-01-14 1998-07-16 E.I. Du Pont De Nemours And Company Polymerization of olefins
US6103658A (en) * 1997-03-10 2000-08-15 Eastman Chemical Company Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom
US6200925B1 (en) 1997-03-13 2001-03-13 Eastman Chemical Company Catalyst compositions for the polymerization of olefins
US6573345B1 (en) 1997-03-24 2003-06-03 Cryovac, Inc. Catalyst compositions and processes for olefin oligomerization and polymerization
US6410664B1 (en) 1997-03-24 2002-06-25 Cryovac, Inc. Catalyst compositions and processes for olefin polymers and copolymers
US6174976B1 (en) * 1998-02-24 2001-01-16 Eastman Chemical Company Neutral nickel complexes for olefin polymerization
TW562810B (en) * 1998-04-16 2003-11-21 Mitsui Chemicals Inc Catalyst for olefinic polymerization and method for polymerizing olefine
JP3747354B2 (en) * 1998-08-27 2006-02-22 三井化学株式会社 Transition metal compound, catalyst for olefin polymerization, and polymerization method
US6465385B1 (en) * 1999-02-12 2002-10-15 Sunoco, Inc. (R&M) Zwitterionic polymerization catalyst
AU7507001A (en) * 2000-05-31 2001-12-11 Du Pont Catalysts for olefin polymerization

Also Published As

Publication number Publication date
CN1432027A (en) 2003-07-23
KR20030005432A (en) 2003-01-17
EP1290043A2 (en) 2003-03-12
MXPA02011811A (en) 2003-05-14
US20020028741A1 (en) 2002-03-07
BR0111338A (en) 2003-06-17
US20030130453A1 (en) 2003-07-10
CN100406478C (en) 2008-07-30
US7683147B2 (en) 2010-03-23
WO2001092348A3 (en) 2002-07-25
WO2001092348A2 (en) 2001-12-06
US20030130449A1 (en) 2003-07-10
US7115763B2 (en) 2006-10-03
US6506861B2 (en) 2003-01-14
JP2003535107A (en) 2003-11-25
CA2408663A1 (en) 2001-12-06

Similar Documents

Publication Publication Date Title
AU2001269725A1 (en) Polymerization of olefins
EP0906344B1 (en) Elevated pressure polymerization processes with late transition metal catalyst systems
JP3398381B2 (en) Transition metal olefin polymerization catalyst
JP2003510382A5 (en)
Lassahn et al. Borane Activators for Late‐Transition Metal Catalysts in Norbornene Polymerization
JP2003535190A5 (en)
WO2001092347A2 (en) Polymerization of olefins
Ma et al. Recent progress in the vinylic polymerization and copolymerization of norbornene catalyzed by transition metal catalysts
WO2001081436A1 (en) Olefin polymerizations using ionic liquids as solvents
EP2987797B1 (en) Ligand compound, catalyst system for oligomerizing olefin, and method for oligomerizing olefin using same
US6759361B2 (en) Aluminoboronate activators for single-site olefin polymerization catalysts
CA2457577A1 (en) Method for making late transition metal catalysts for olefin polymerization
WO2016186291A1 (en) Catalyst system for olefin oligomerization, and method for oligomerizing olefins by using same
Xiong et al. Asymmetric cationic [P, O] type palladium complexes in olefin homopolymerization and copolymerization
CN109535298A (en) Early transition metal compound and preparation method and catalyst for olefines polymerizing composition and application and the method for preparing olefin polymer
CN109535289A (en) Early transition metal compound and preparation method and catalyst for olefines polymerizing composition and application and the method for preparing olefin polymer
US8236907B2 (en) Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods
CN109535286A (en) Early transition metal compound and preparation method and catalyst for olefines polymerizing composition and application and the method for preparing olefin polymer
CN110386957B (en) Heteronuclear bimetallic complex, preparation method thereof and application thereof in preparing bimodal distribution olefin polymer
WO2004078801B1 (en) A metal catalyst for olefin polymerization and co-polymerization with functional monomers
EP1334134B1 (en) Bimetallic olefin polymerization catalysts
US11529622B2 (en) Catalyst systems
CN113816981B (en) Binuclear nitrogen-containing ligand IVB transition metal complex and application thereof in olefin high-temperature polymerization
US11623901B1 (en) Catalyst systems that include silyl ether moieties
WO2006094302B1 (en) Supported olefin polymerization catalysts