AU2001252138A1 - Method for the synthesis of aliphatic carboxylic acids from aldehydes - Google Patents
Method for the synthesis of aliphatic carboxylic acids from aldehydesInfo
- Publication number
- AU2001252138A1 AU2001252138A1 AU2001252138A AU5213801A AU2001252138A1 AU 2001252138 A1 AU2001252138 A1 AU 2001252138A1 AU 2001252138 A AU2001252138 A AU 2001252138A AU 5213801 A AU5213801 A AU 5213801A AU 2001252138 A1 AU2001252138 A1 AU 2001252138A1
- Authority
- AU
- Australia
- Prior art keywords
- aldehydes
- synthesis
- carboxylic acids
- aliphatic carboxylic
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 150000001299 aldehydes Chemical class 0.000 title 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The invention relates to a method for the synthesis of aliphatic carboxylic acids by the catalytic oxidation of aldehydes with oxygen, or oxygen-containing gas mixtures. Metals of groups 5 11 of the periodic table of elements, or the compounds thereof are used as catalyst, in amounts of up to 5 ppm, based upon the amount of aldehyde used.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10010771 | 2000-03-04 | ||
DE10010771A DE10010771C1 (en) | 2000-03-04 | 2000-03-04 | Production of aliphatic carboxylic acid, e.g. n-butyric, 2-methylbutyric, n-heptanoic or isononanoic acid, by oxidizing corresponding aldehyde uses group 5-11 metal or compound as catalyst |
PCT/EP2001/001943 WO2001066504A2 (en) | 2000-03-04 | 2001-02-21 | Method for the synthesis of aliphatic carboxylic acids from aldehydes |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2001252138A1 true AU2001252138A1 (en) | 2001-09-17 |
Family
ID=7633627
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2001252138A Abandoned AU2001252138A1 (en) | 2000-03-04 | 2001-02-21 | Method for the synthesis of aliphatic carboxylic acids from aldehydes |
Country Status (10)
Country | Link |
---|---|
US (1) | US6800783B2 (en) |
EP (1) | EP1263707B1 (en) |
JP (1) | JP4955886B2 (en) |
AT (1) | ATE309189T1 (en) |
AU (1) | AU2001252138A1 (en) |
DE (2) | DE10010771C1 (en) |
ES (1) | ES2251477T3 (en) |
TW (1) | TWI234559B (en) |
WO (1) | WO2001066504A2 (en) |
ZA (1) | ZA200206786B (en) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100682232B1 (en) * | 2003-06-05 | 2007-02-12 | 주식회사 엘지화학 | Method for Preparing Organic Acid |
DE102004055252A1 (en) * | 2004-11-16 | 2006-05-24 | Celanese Chemicals Europe Gmbh | Process for the preparation of aliphatic straight-chain and β-alkyl-branched carboxylic acids |
WO2006054643A1 (en) * | 2004-11-17 | 2006-05-26 | Asahi Kasei Chemicals Corporation | Oxidation catalyst and oxidation method |
DE102006022168B4 (en) * | 2006-05-12 | 2014-02-27 | Oxea Gmbh | Catalytic process for the preparation of aliphatic straight-chain and β-alkyl-branched carboxylic acids |
US8128688B2 (en) | 2006-06-27 | 2012-03-06 | Abbott Cardiovascular Systems Inc. | Carbon coating on an implantable device |
DE102009014626A1 (en) | 2009-03-24 | 2010-10-07 | Oxea Deutschland Gmbh | Process for the preparation of aliphatic carboxylic acids from aldehydes by microreaction technology |
ES2371718B1 (en) * | 2010-05-11 | 2012-11-27 | Otri-Universidad De Almería | PROCEDURE AND CATALYST FOR SELECTIVE OXIDATION OF ALDEHYDE GROUPS. |
FR2983477B1 (en) | 2011-12-01 | 2013-12-27 | Arkema France | PROCESS FOR CUTTING UNSATURATED FAT CHANNELS |
FR2983478B1 (en) | 2011-12-01 | 2013-11-15 | Arkema France | PROCESS FOR PREPARING AMINOACID COMPRISING A HYDROFORMYLATION STEP OF UNSATURATED FATTY NITRILE |
DE102011120587A1 (en) | 2011-12-08 | 2013-06-13 | Oxea Gmbh | Process for recovering aliphatic monocarboxylic acids from distillation residues |
DE102012013969B4 (en) | 2012-07-13 | 2017-09-14 | Oxea Gmbh | Process for the preparation of a mixture of positionally isomeric aliphatic isononanoic acids starting from 2-ethylhexanol |
DE102012013968A1 (en) | 2012-07-13 | 2014-04-03 | Oxea Gmbh | Carboxylic acid ester of isononanoic acid starting from 2-ethylhexanol, process for their preparation and their use |
DE102012014396B4 (en) * | 2012-07-13 | 2018-01-11 | Oxea Gmbh | Process for the preparation of a vinyl ester mixture from a mixture of positionally isomeric aliphatic Isononansäuren starting from 2-ethylhexanol |
DE102013020323B3 (en) | 2013-12-05 | 2015-01-08 | Oxea Gmbh | Process for the preparation of isomeric hexanoic acids from the secondary streams obtained in the preparation of pentanals |
DE102013020322B4 (en) | 2013-12-05 | 2019-04-18 | Oxea Gmbh | A process for the recovery of 2-methylbutanal from the obtained in the preparation of mixtures of isomeric α, ß-unsaturated decenals side streams |
DE102013020320B4 (en) | 2013-12-05 | 2019-04-04 | Oxea Gmbh | Process for the preparation of 2-methylbutyric acid with a reduced content of 3-methylbutyric acid from the secondary streams obtained in the preparation of pentanoic acids |
DE102013113719A1 (en) | 2013-12-09 | 2015-06-11 | Oxea Gmbh | Process for the preparation of pentane derivatives and derivatives of α, β-unsaturated decenals |
DE102013113724A1 (en) | 2013-12-09 | 2015-06-11 | Oxea Gmbh | Process for the preparation of pentane derivatives and derivatives of alpha, beta-unsaturated decenals from propylene |
US9682914B2 (en) | 2014-01-13 | 2017-06-20 | P2 Science, Inc. | Terpene-derived acids and esters and methods for preparing and using same |
US10071944B2 (en) | 2014-06-20 | 2018-09-11 | P2 Science, Inc. | Film ozonolysis in a tubular or multitubular reactor |
JP7028457B2 (en) | 2016-06-21 | 2022-03-02 | ピー2・サイエンス・インコーポレイテッド | Flow-through reactor for continuous quenching of peroxide mixture and method including it |
WO2018053289A1 (en) * | 2016-09-16 | 2018-03-22 | P2 Science, Inc. | Uses of vanadium to oxidize aldehydes and ozonides |
US11814350B2 (en) | 2018-10-19 | 2023-11-14 | P2 Science, Inc. | Methods for disproportionation quenching of ozonides |
US11008275B2 (en) | 2019-06-12 | 2021-05-18 | Evonik Operations Gmbh | Process for preparing carboxylic acids or salts thereof from hydrocarbons |
EP4198014A1 (en) | 2021-12-20 | 2023-06-21 | Evonik Operations GmbH | Method for the preparation of carboxylic acids or their salts and separation of the homogeneous catalyst system using a membrane comprising a separation-active layer of paek and a substructure comprising paek |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2010358A (en) | 1933-02-03 | 1935-08-06 | Shell Dev | Process for the oxidation of isoaldehydes |
GB706009A (en) | 1950-01-19 | 1954-03-24 | Ici Ltd | Improvements in and relating to the production of aliphatic carboxylic acids |
DE1289523B (en) | 1964-04-17 | 1969-02-20 | Asahi Chemical Ind | Process for the production of ª † -valero- or ªŠ-caprolactone |
FR1532460A (en) * | 1967-05-26 | 1968-07-12 | Melle Usines Sa | Process for the oxidation of lower aliphatic aldehydes |
JPS5163118A (en) | 1974-10-23 | 1976-06-01 | Mitsubishi Chem Ind | Ipushiron kapurorakutonruito karubonsanruitono seizohoho |
DE2604545C3 (en) | 1976-02-06 | 1978-08-17 | Basf Ag, 6700 Ludwigshafen | Process for the preparation of alkyl carboxylic acids |
JPS6055494B2 (en) * | 1977-06-20 | 1985-12-05 | 三菱化学株式会社 | Method for producing α-branched aliphatic carboxylic acid |
IT1100096B (en) * | 1978-11-10 | 1985-09-28 | Snia Viscosa | PROCEDURE FOR THE PREPARATION OF ALPHA, OMEGA-DICHARBOXYL ACIDS |
DE2931154C2 (en) * | 1979-08-01 | 1985-08-01 | Ruhrchemie Ag, 4200 Oberhausen | Process for the preparation of aliphatic carboxylic acids from aldehydes |
JPS58121239A (en) * | 1982-01-11 | 1983-07-19 | Kuraray Co Ltd | Preparation of caprylic acid |
US4487720A (en) * | 1982-09-27 | 1984-12-11 | Celanese Corporation | Separation and production of organic saturated monocarboxylic acids |
DE3628664A1 (en) * | 1986-08-23 | 1988-03-03 | Degussa | METHOD FOR PRODUCING 1,12-DODECANDEIAEUR II |
JP3725202B2 (en) * | 1994-05-11 | 2005-12-07 | プラクスエア・テクノロジー・インコーポレイテッド | Enhanced oxidation of organic chemicals |
JP3756537B2 (en) * | 1994-11-16 | 2006-03-15 | 株式会社クラレ | Dimethyldecandial and process for producing the same |
-
2000
- 2000-03-04 DE DE10010771A patent/DE10010771C1/en not_active Expired - Fee Related
-
2001
- 2001-02-21 JP JP2001565325A patent/JP4955886B2/en not_active Expired - Lifetime
- 2001-02-21 US US10/204,619 patent/US6800783B2/en not_active Expired - Lifetime
- 2001-02-21 ES ES01925346T patent/ES2251477T3/en not_active Expired - Lifetime
- 2001-02-21 AT AT01925346T patent/ATE309189T1/en not_active IP Right Cessation
- 2001-02-21 AU AU2001252138A patent/AU2001252138A1/en not_active Abandoned
- 2001-02-21 EP EP01925346A patent/EP1263707B1/en not_active Expired - Lifetime
- 2001-02-21 WO PCT/EP2001/001943 patent/WO2001066504A2/en active IP Right Grant
- 2001-02-21 DE DE50107992T patent/DE50107992D1/en not_active Expired - Lifetime
- 2001-03-01 TW TW090104629A patent/TWI234559B/en not_active IP Right Cessation
-
2002
- 2002-08-23 ZA ZA200206786A patent/ZA200206786B/en unknown
Also Published As
Publication number | Publication date |
---|---|
JP4955886B2 (en) | 2012-06-20 |
ZA200206786B (en) | 2004-01-28 |
US6800783B2 (en) | 2004-10-05 |
WO2001066504A3 (en) | 2002-02-21 |
ES2251477T3 (en) | 2006-05-01 |
WO2001066504A2 (en) | 2001-09-13 |
ATE309189T1 (en) | 2005-11-15 |
DE10010771C1 (en) | 2001-05-03 |
EP1263707B1 (en) | 2005-11-09 |
EP1263707A2 (en) | 2002-12-11 |
US20030078453A1 (en) | 2003-04-24 |
TWI234559B (en) | 2005-06-21 |
JP2003525920A (en) | 2003-09-02 |
DE50107992D1 (en) | 2005-12-15 |
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