ATE66935T1 - Titanium-, zirconium- und hafnium-enolate als initiatoren bei der polymerisation von acrylatmonomeren zu lebenden polymeren. - Google Patents
Titanium-, zirconium- und hafnium-enolate als initiatoren bei der polymerisation von acrylatmonomeren zu lebenden polymeren.Info
- Publication number
- ATE66935T1 ATE66935T1 AT87307651T AT87307651T ATE66935T1 AT E66935 T1 ATE66935 T1 AT E66935T1 AT 87307651 T AT87307651 T AT 87307651T AT 87307651 T AT87307651 T AT 87307651T AT E66935 T1 ATE66935 T1 AT E66935T1
- Authority
- AT
- Austria
- Prior art keywords
- polymerization
- enolates
- hafnium
- initiators
- zirconium
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
- C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/901,769 US4728706A (en) | 1986-08-29 | 1986-08-29 | Titanium, zirconium- and hafnium containing initiators in the polymerization of acrylic monomers to "living" polymers |
EP87307651A EP0260838B1 (de) | 1986-08-29 | 1987-08-28 | Titanium-, Zirconium- und Hafnium-Enolate als Initiatoren bei der Polymerisation von Acrylat-Monomeren zu lebenden Polymeren |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE66935T1 true ATE66935T1 (de) | 1991-09-15 |
Family
ID=25414783
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT87307651T ATE66935T1 (de) | 1986-08-29 | 1987-08-28 | Titanium-, zirconium- und hafnium-enolate als initiatoren bei der polymerisation von acrylatmonomeren zu lebenden polymeren. |
Country Status (6)
Country | Link |
---|---|
US (1) | US4728706A (de) |
EP (1) | EP0260838B1 (de) |
JP (1) | JPS6368608A (de) |
AT (1) | ATE66935T1 (de) |
CA (1) | CA1282527C (de) |
DE (1) | DE3772683D1 (de) |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4978723A (en) * | 1989-03-01 | 1990-12-18 | E. I. Du Pont De Nemours And Company | Phosphonate-capped polymers |
US4939211A (en) * | 1989-03-01 | 1990-07-03 | E. I. Du Pont De Nemours And Company | Phosphonate-capped polymers |
JP3117231B2 (ja) * | 1991-03-11 | 2000-12-11 | 三井化学株式会社 | 幅広い分子量分布を有するシンジオタクチックポリ−α−オレフィンの製造方法 |
US5668234A (en) * | 1994-09-12 | 1997-09-16 | Rhodes; Larry Funderburk | Reaction injection molding (RIM) of methyl (meth)acrylate and related monomers using group-4 catalysts |
US5763548A (en) | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
IT1276070B1 (it) | 1995-10-31 | 1997-10-24 | Siac It Additivi Carburanti | Processo per la preparazione di polimeri a base di etilene a basso peso molecolare |
US5807937A (en) * | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
DE69707452T3 (de) | 1996-06-12 | 2015-07-23 | Warwick Effect Polymers Ltd. | Polymerisation-katalysator und -verfahren |
EP0816385B1 (de) * | 1996-06-26 | 2002-01-30 | Kaneka Corporation | Verfahren zur Herstellung von Vinylpolymeren |
DE19651442A1 (de) * | 1996-12-11 | 1998-06-18 | Hoechst Ag | Katalysator zur Herstellung von funktionalisierten Polymeren |
US7125938B2 (en) * | 1997-03-11 | 2006-10-24 | Carnegie Mellon University | Atom or group transfer radical polymerization |
DE59805425D1 (de) | 1997-06-10 | 2002-10-10 | Peroxid Chemie Gmbh & Co Kg | Neue katalysatorsysteme für (co-)polymerisationsreaktionen, metallocenamidhalogenide und ihre verwendung |
AU3919500A (en) | 1999-03-23 | 2000-10-09 | Carnegie Wave Energy Limited | Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby |
US7049373B2 (en) * | 1999-08-06 | 2006-05-23 | Carnegie Mellon University | Process for preparation of graft polymers |
US7332550B2 (en) * | 2000-10-06 | 2008-02-19 | Carnegie Mellon University | Stabilization of transition metal complexes for catalysis in diverse environments |
WO2002028914A2 (en) * | 2000-10-06 | 2002-04-11 | Carnegie Mellon University | A catalyst system for controlled polymerization |
DE60236642D1 (de) * | 2001-04-06 | 2010-07-22 | Univ Carnegie Mellon | Verfahren zur herstellung von nanostrukturierten materialien |
US7064166B2 (en) * | 2001-10-12 | 2006-06-20 | Carnegie Mellon University | Process for monomer sequence control in polymerizations |
WO2003031481A2 (en) | 2001-10-12 | 2003-04-17 | Carnegie Mellon University | Simultaneous reverse and normal initiation of atrp |
AU2003276847A1 (en) * | 2002-08-09 | 2004-02-25 | Carnegie Mellon University | Polymers, supersoft elastomers and methods for preparing the same |
US20050090632A1 (en) * | 2003-06-06 | 2005-04-28 | Carnegie Mellon University | Noel (co) polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
US7795355B2 (en) * | 2004-03-05 | 2010-09-14 | Carnegie Mellon University | Preparation of functional polymers |
US7893174B2 (en) * | 2004-03-05 | 2011-02-22 | Carnegie Mellon University | Atom transfer radical polymerization process |
EP1928919B1 (de) | 2005-08-23 | 2010-02-17 | Carnegie-Mellon University | Radikalische atomtransfer-polymerisation in mikroemulsion und echte emulsionspolymerisation |
US7893173B2 (en) * | 2005-08-26 | 2011-02-22 | Carnegie Mellon University | Polymerization process with catalyst reactivation |
US8367051B2 (en) * | 2006-10-09 | 2013-02-05 | Carnegie Mellon University | Preparation of functional gel particles with a dual crosslink network |
US8252880B2 (en) * | 2007-05-23 | 2012-08-28 | Carnegie Mellon University | Atom transfer dispersion polymerization |
GB2463198B (en) * | 2007-05-23 | 2013-05-22 | Univ Carnegie Mellon | Hybrid particle composite structures with reduced scattering |
WO2010111708A1 (en) | 2009-03-27 | 2010-09-30 | Carnegie Mellon University | Preparation of functional star macromolecules |
US9644042B2 (en) | 2010-12-17 | 2017-05-09 | Carnegie Mellon University | Electrochemically mediated atom transfer radical polymerization |
WO2013028756A1 (en) | 2011-08-22 | 2013-02-28 | Carnegie Mellon University | Atom transfer radical polymerization under biologically compatible conditions |
US9533297B2 (en) | 2012-02-23 | 2017-01-03 | Carnegie Mellon University | Ligands designed to provide highly active catalyst complexes |
US10273315B2 (en) | 2012-06-20 | 2019-04-30 | Chevron Phillips Chemical Company Lp | Methods for terminating olefin polymerizations |
JP6013055B2 (ja) * | 2012-07-09 | 2016-10-25 | ダイキン工業株式会社 | 優れた撥水撥油性を有するアクリル酸エステル重合体、およびその製造方法 |
US9982070B2 (en) | 2015-01-12 | 2018-05-29 | Carnegie Mellon University | Aqueous ATRP in the presence of an activator regenerator |
US11174325B2 (en) | 2017-01-12 | 2021-11-16 | Carnegie Mellon University | Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3114737A (en) * | 1958-02-11 | 1963-12-17 | Nat Lead Co | Aqueous polymerization process incorporating co-catalyst of organo-metallic compound nd halogenated acetic acid |
US3037004A (en) * | 1958-10-07 | 1962-05-29 | Nat Lead Co | Aqueous phase polymerization of vinyl monomers with organic cocatalysts |
US3394156A (en) * | 1960-03-07 | 1968-07-23 | Monsanto Co | Titanium amide borohydrides and chlorides |
DE1176864B (de) * | 1962-11-09 | 1964-08-27 | Basf Ag | Verfahren zum Polymerisieren von Verbindungen mit polymerisierbaren Doppelbindungen |
US3370041A (en) * | 1963-02-25 | 1968-02-20 | Monsanto Co | Polymerization process employing transition metal compounds as catalysts |
US3846389A (en) * | 1968-03-28 | 1974-11-05 | N Kataoka | Production of alternating copolymers of conjugated dienes and conjugated polar vinyl monomers |
US3919180A (en) * | 1968-07-03 | 1975-11-11 | Bridgestone Tire Co Ltd | Method of producing alternating copolymers of donor monomer and acceptor monomer from not less than three monomers |
CA967583A (en) * | 1969-05-28 | 1975-05-13 | Imperial Chemical Industries Limited | Organo-metallic compounds and uses thereof |
GB1314828A (en) * | 1969-08-13 | 1973-04-26 | Ici Ltd | Transition metal compositions and polymerisation process catalysed thereby |
BE763475A (fr) * | 1970-03-03 | 1971-08-25 | Ici Ltd | Compositions pour amorcer la polymerisation des olefines et leur utilisation |
GB1313183A (en) * | 1970-09-03 | 1973-04-11 | Ici Ltd | Polymerisation process and catalysts |
US3773742A (en) * | 1971-02-02 | 1973-11-20 | Hercules Inc | Tetraneopentyltitanium and use as polymerization catalyst |
US3950269A (en) * | 1974-05-20 | 1976-04-13 | E. I. Du Pont De Nemours & Co. | Olefin polymerization catalyst system and process for polymerization of olefins |
US3971767A (en) * | 1974-05-20 | 1976-07-27 | E. I. Du Pont De Nemours And Company | Olefin polymerization catalyst system and process for polymerization of olefins |
JPS55137178A (en) * | 1979-04-11 | 1980-10-25 | Kanebo Ltd | Adhesive material for rigid living tissue |
JPS56136865A (en) * | 1980-03-28 | 1981-10-26 | Kanebo Ltd | Adhesive composition for hard living tissue |
US4508880A (en) * | 1981-06-30 | 1985-04-02 | E. I. Du Pont De Nemours And Company | "Living" polymers and process for their preparation |
US4417034A (en) * | 1981-06-30 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Living polymers and process for their preparation |
US4681918A (en) * | 1981-06-30 | 1987-07-21 | E. I. Du Pont De Nemours And Company | "Living" polymers and process for their preparation |
US4414372A (en) * | 1982-06-17 | 1983-11-08 | E. I. Du Pont De Nemours & Co. | Process for preparing living polymers |
JPS6126607A (ja) * | 1984-07-16 | 1986-02-05 | Idemitsu Kosan Co Ltd | エチレン共重合体の製造法 |
US4605716A (en) * | 1985-02-14 | 1986-08-12 | E. I. Du Pont De Nemours And Company | Lewis base-catalyzed polymerization |
US4588795A (en) * | 1985-03-01 | 1986-05-13 | E. I. Du Pont De Nemours And Company | Oxyanion-catalyzed polymerization |
-
1986
- 1986-08-29 US US06/901,769 patent/US4728706A/en not_active Expired - Fee Related
-
1987
- 1987-08-25 CA CA000545310A patent/CA1282527C/en not_active Expired - Lifetime
- 1987-08-28 EP EP87307651A patent/EP0260838B1/de not_active Expired
- 1987-08-28 DE DE8787307651T patent/DE3772683D1/de not_active Expired - Lifetime
- 1987-08-28 JP JP62213183A patent/JPS6368608A/ja active Pending
- 1987-08-28 AT AT87307651T patent/ATE66935T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JPS6368608A (ja) | 1988-03-28 |
EP0260838A1 (de) | 1988-03-23 |
DE3772683D1 (de) | 1991-10-10 |
US4728706A (en) | 1988-03-01 |
EP0260838B1 (de) | 1991-09-04 |
CA1282527C (en) | 1991-04-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
UEP | Publication of translation of european patent specification | ||
REN | Ceased due to non-payment of the annual fee |