ATE60374T1 - MULTIPLE COATING OF AN ANODE WITH PLATINUM/ECA-1500 FOR ANODES USED IN LOW PH, HIGH CURRENT DENSITY ELECTROCHEMICAL PROCESSES. - Google Patents

MULTIPLE COATING OF AN ANODE WITH PLATINUM/ECA-1500 FOR ANODES USED IN LOW PH, HIGH CURRENT DENSITY ELECTROCHEMICAL PROCESSES.

Info

Publication number
ATE60374T1
ATE60374T1 AT86307039T AT86307039T ATE60374T1 AT E60374 T1 ATE60374 T1 AT E60374T1 AT 86307039 T AT86307039 T AT 86307039T AT 86307039 T AT86307039 T AT 86307039T AT E60374 T1 ATE60374 T1 AT E60374T1
Authority
AT
Austria
Prior art keywords
anode
platinum
eca
low
current density
Prior art date
Application number
AT86307039T
Other languages
German (de)
Inventor
Mark J Geusic
Original Assignee
Engelhard Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Engelhard Corp filed Critical Engelhard Corp
Application granted granted Critical
Publication of ATE60374T1 publication Critical patent/ATE60374T1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02Electrodes; Connections thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Chemically Coating (AREA)

Abstract

An anode for use in electroforming copper foil is formed by depositing a multilayer coating on a substrate of a film forming metal. At least one interior layer consists essentially of substantially pore free platinum which is applied electrolytically to a thickness of at least about 5 micrometers (about 200 microinches), and then densified by heat treating in an oxygen containing atmosphere at from 600 to 775 DEG C. At least one of the exterior layers consists essentially of at least 97% iridium oxide and up to about 3% rhodium oxide, which is applied by thermal decomposition of thermally decomposable platinum group metal compounds in an oxygen containing atmosphere at a temperature of not more than about 600 DEG C.
AT86307039T 1985-09-13 1986-09-12 MULTIPLE COATING OF AN ANODE WITH PLATINUM/ECA-1500 FOR ANODES USED IN LOW PH, HIGH CURRENT DENSITY ELECTROCHEMICAL PROCESSES. ATE60374T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US77591185A 1985-09-13 1985-09-13
EP86307039A EP0215649B1 (en) 1985-09-13 1986-09-12 Platinum/eca-1500 combination anode coating for low ph high current density electrochemical process anodes

Publications (1)

Publication Number Publication Date
ATE60374T1 true ATE60374T1 (en) 1991-02-15

Family

ID=25105919

Family Applications (1)

Application Number Title Priority Date Filing Date
AT86307039T ATE60374T1 (en) 1985-09-13 1986-09-12 MULTIPLE COATING OF AN ANODE WITH PLATINUM/ECA-1500 FOR ANODES USED IN LOW PH, HIGH CURRENT DENSITY ELECTROCHEMICAL PROCESSES.

Country Status (5)

Country Link
EP (1) EP0215649B1 (en)
JP (1) JPH0735597B2 (en)
AT (1) ATE60374T1 (en)
CA (1) CA1305447C (en)
DE (1) DE3677108D1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3124848B2 (en) * 1992-11-11 2001-01-15 ペルメレック電極株式会社 Manufacturing method of metal foil by electrolysis
TWI490371B (en) * 2009-07-28 2015-07-01 Industrie De Nora Spa Electrode for electrolytic applications

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4203810A (en) * 1970-03-25 1980-05-20 Imi Marston Limited Electrolytic process employing electrodes having coatings which comprise platinum
CH563464A5 (en) * 1970-09-02 1975-06-30 Engelhard Min & Chem Electrolytic anode
JPS5647597A (en) * 1979-09-25 1981-04-30 Nippon Steel Corp Insoluble electrode for electroplating and preparation thereof
GB2060701B (en) * 1979-10-12 1983-06-08 Diamond Shamrock Corp Electrode coating with platinum- group metal catalyst and semiconducting polymer
JPS56147057A (en) * 1980-04-15 1981-11-14 Ngk Spark Plug Co Ltd Production of oxygen sensor
CA1225066A (en) * 1980-08-18 1987-08-04 Jean M. Hinden Electrode with surface film of oxide of valve metal incorporating platinum group metal or oxide
US4331528A (en) * 1980-10-06 1982-05-25 Diamond Shamrock Corporation Coated metal electrode with improved barrier layer
JPS58171589A (en) * 1982-03-31 1983-10-08 Ishifuku Kinzoku Kogyo Kk Electrode for electrolysis and its manufacture
GB8316778D0 (en) * 1983-06-21 1983-07-27 Ici Plc Cathode

Also Published As

Publication number Publication date
EP0215649A1 (en) 1987-03-25
JPH0735597B2 (en) 1995-04-19
EP0215649B1 (en) 1991-01-23
CA1305447C (en) 1992-07-21
DE3677108D1 (en) 1991-02-28
JPS6280298A (en) 1987-04-13

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