ATE522558T1 - Neue trimerisierungskatalysatoren aus sterisch gehinderten salzen - Google Patents

Neue trimerisierungskatalysatoren aus sterisch gehinderten salzen

Info

Publication number
ATE522558T1
ATE522558T1 AT07008702T AT07008702T ATE522558T1 AT E522558 T1 ATE522558 T1 AT E522558T1 AT 07008702 T AT07008702 T AT 07008702T AT 07008702 T AT07008702 T AT 07008702T AT E522558 T1 ATE522558 T1 AT E522558T1
Authority
AT
Austria
Prior art keywords
sterically hindered
trimerization catalysts
salts
new trimerization
new
Prior art date
Application number
AT07008702T
Other languages
English (en)
Inventor
Juan Jesus Burdeniuc
Torsten Panitzsch
John Elton Dewhurst
Original Assignee
Air Prod & Chem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38229993&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE522558(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Prod & Chem filed Critical Air Prod & Chem
Application granted granted Critical
Publication of ATE522558T1 publication Critical patent/ATE522558T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/166Catalysts not provided for in the groups C08G18/18 - C08G18/26
    • C08G18/168Organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/09Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1808Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/22Catalysts containing metal compounds
    • C08G18/225Catalysts containing metal compounds of alkali or alkaline earth metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0025Foam properties rigid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00Oligomerisation
    • C08G2115/02Oligomerisation to isocyanurate groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Catalysts (AREA)
AT07008702T 2006-05-04 2007-04-27 Neue trimerisierungskatalysatoren aus sterisch gehinderten salzen ATE522558T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/418,287 US8530534B2 (en) 2006-05-04 2006-05-04 Trimerization catalysts from sterically hindered salts

Publications (1)

Publication Number Publication Date
ATE522558T1 true ATE522558T1 (de) 2011-09-15

Family

ID=38229993

Family Applications (1)

Application Number Title Priority Date Filing Date
AT07008702T ATE522558T1 (de) 2006-05-04 2007-04-27 Neue trimerisierungskatalysatoren aus sterisch gehinderten salzen

Country Status (8)

Country Link
US (2) US8530534B2 (de)
EP (1) EP1852448B1 (de)
JP (3) JP4898541B2 (de)
KR (2) KR100909643B1 (de)
CN (1) CN101067018B (de)
AT (1) ATE522558T1 (de)
BR (1) BRPI0702265B1 (de)
MX (1) MX2007005295A (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8552077B2 (en) * 2006-05-04 2013-10-08 Air Products And Chemicals, Inc. Trimer catalyst additives for improving foam processability
US8580864B2 (en) * 2006-05-04 2013-11-12 Air Products And Chemicals, Inc. Trimer catalysts with improved processability and surface cure
JP2011521074A (ja) * 2008-05-22 2011-07-21 ダウ グローバル テクノロジーズ エル エルエルシー シス,トランス−1,3−及び1,4−シクロヘキサンジメチルエーテル基を含む熱硬化性ポリウレタン
EP2346917B1 (de) * 2008-11-10 2013-08-28 Dow Global Technologies LLC Isocyanattrimerisationskatalysatorsystem, vorläuferformulierung, verfahren zur trimerisierung von isocyanaten, polyisocyanurat/polyurethan-hartschaumstoffe daraus und verfahren zur herstellung derartiger schaumstoffe
EP2346919B1 (de) * 2008-11-10 2013-09-04 Dow Global Technologies LLC Isocyanattrimerisationskatalysatorsystem, vorläuferformulierung, verfahren zur trimerisierung von isocyanaten, polyisocyanurat/polyurethan-hartschaumstoffe daraus und verfahren zur herstellung derartiger schaumstoffe
EP2346918B1 (de) 2008-11-10 2013-09-18 Dow Global Technologies LLC Isocyanattrimerisationskatalysatorsystem, vorläuferformulierung, verfahren zur trimerisierung von isocyanaten, polyisocyanurat/polyurethan-hartschaumstoffe daraus und verfahren zur herstellung derartiger schaumstoffe
KR101064208B1 (ko) * 2009-02-11 2011-09-14 주식회사 세호테크 무주석, 무독성 유기금속촉매 및 그 제조방법
EP2744839B1 (de) * 2011-08-16 2016-02-24 Covestro Deutschland AG Verfahren zur herstellung eines polyurethan-polyisocyanurat-hartschaums
US10125234B2 (en) 2014-02-26 2018-11-13 Evonik Degussa Gmbh Catalyst compositions and methods for making foam
KR102199218B1 (ko) * 2014-09-05 2021-01-07 삼성디스플레이 주식회사 표시 장치, 표시 제어 장치 및 표시 방법
JP2016124912A (ja) * 2014-12-26 2016-07-11 三洋化成工業株式会社 樹脂製造用活性水素含有組成物およびフォームの製造方法
US10889681B2 (en) 2014-12-31 2021-01-12 Jiangsu Osic Performance Materials Co. Ltd. Polyurethane catalyst and application thereof
CN104558469B (zh) * 2014-12-31 2018-02-23 江苏奥斯佳材料科技有限公司 一种聚氨酯催化剂在合成软质聚氨酯泡沫塑料中的应用
CN104558467B (zh) * 2014-12-31 2018-02-23 江苏奥斯佳材料科技有限公司 一种聚氨酯催化剂及其应用
CN104558468B (zh) * 2014-12-31 2018-02-23 江苏奥斯佳材料科技有限公司 一种聚氨酯催化剂在合成硬质聚氨酯材料中的应用
MX2017016350A (es) * 2015-06-18 2018-05-02 Evonik Degussa Gmbh Catalizadores para la trimerizacion de sales y aminas terciarias con impedimento esterico que tienen grupos reactivos de isocianato.
JP6993238B2 (ja) * 2016-12-08 2022-01-13 積水化学工業株式会社 ウレタン樹脂組成物
CN107913730B (zh) * 2017-11-30 2020-04-10 万华化学集团股份有限公司 亚胺型季铵盐催化剂、其制备方法及多异氰酸酯组合物
CN112805312B (zh) * 2018-08-21 2023-03-21 亨茨曼国际有限公司 用于pir/pur泡沫生产的催化剂
WO2021004842A1 (de) * 2019-07-08 2021-01-14 Covestro Intellectual Property Gmbh & Co. Kg Polymerisierbare zusammensetzungen zur herstellung von polyisocyanuratkunststoffen mit verlängerter topfzeit
CN110560159B (zh) * 2019-08-13 2020-10-20 清华大学 一种用于叔碳酸缩水甘油酯制备的催化剂及其制备方法
JP7343188B2 (ja) 2020-11-26 2023-09-12 キッコウ・ジャパン株式会社 谷地形用排水構造および暗渠ブロック

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3686225A (en) * 1969-04-01 1972-08-22 Du Pont Complexes of polyether compounds and ionic compounds
DE2019767A1 (de) 1970-04-23 1971-12-23 Gen Tire & Rubber Co Katalysatorsysteme fuer Urethanschaeume
US3940517A (en) 1973-01-11 1976-02-24 The Celotex Corporation Polyisocyanurate foam, catalyst composition and process for producing such
US3988267A (en) 1973-07-09 1976-10-26 Air Products And Chemicals, Inc. Quaternary hydroxyalkyl tertiary amine bases as polyurethane catalysts
US3892687A (en) 1973-07-09 1975-07-01 Air Prod & Chem Quaternary hydroxyalkyl tertiary amine bases as poluyrethane catalysts
US3993652A (en) 1973-07-09 1976-11-23 Air Products And Chemicals, Inc. Cyclic quaternary hydroxyalkyl phenoxide catalysts for isocyanate reactions
US4003859A (en) * 1974-01-30 1977-01-18 The Upjohn Company Novel process for trimerizing polyisocyanates
US3989651A (en) 1974-07-09 1976-11-02 The Upjohn Company Catalyst for sprayable polyisocyanurate foam composition
US3954684A (en) 1974-07-09 1976-05-04 The Upjohn Company Foam process using tertiary amine/quaternary ammonium salt catalyst
US4026840A (en) 1975-06-09 1977-05-31 Air Products And Chemicals, Inc. Hydroxyalkyl tertiary amine catalysts for isocyanate reactions
US4148980A (en) 1977-05-03 1979-04-10 Basf Wyandotte Corporation Novel carboxylate catalysts for the preparation of foams characterized by polyisocyanurate, polyurethane and poly (urethane-isocyanurate) linkages
DE2916201A1 (de) 1979-04-21 1980-10-30 Huels Chemische Werke Ag Verfahren zur trimerisierung von diisocyanaten
US4393148A (en) 1982-09-30 1983-07-12 Pennwalt Corporation Reaction of t-alkylhydrazinium salts and ogranic peroxides to foam unsaturated polyester resins
US4460714A (en) 1983-12-01 1984-07-17 Pennwalt Corporation Unsaturated polyester resin foams using inorganic iron salts
US4489177A (en) * 1983-12-29 1984-12-18 Olin Corporation Isocyanate-reactive compounds from TDI distillation residue and polyurethanes prepared therefrom
DE3403277A1 (de) * 1984-01-31 1985-08-01 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von polyisocyanaten mit biuretstruktur
US4503226A (en) 1984-04-30 1985-03-05 Olin Corporation Process for trimerizing organic polyisocyanates
US4623673A (en) * 1985-10-24 1986-11-18 The Dow Chemical Company Urethane-modified polyisocyanurate rigid foam
US4698398A (en) 1985-11-14 1987-10-06 E. I. Du Pont De Nemours And Company Coating composition of a hydroxy functional epoxy polyester graft copolymer
GB8531180D0 (en) 1985-12-18 1986-01-29 Ici Plc Cocatalyst systems
GB8712363D0 (en) 1987-05-26 1987-07-01 Ici Plc Polyisocyanurate rigid foams
US5321050A (en) 1992-08-06 1994-06-14 Nisshinbo Industries, Inc. Method for producing modified polyisocyanurate foams
US5296516A (en) * 1992-12-09 1994-03-22 Basf Corporation Polyurethane and polyisocyanurate rigid foams prepared using ternary blowing agent mixtures
JPH06200069A (ja) 1993-01-05 1994-07-19 Mitsui Toatsu Chem Inc 硬質ポリウレタンフォーム
JPH0797429A (ja) 1993-08-06 1995-04-11 Takeda Chem Ind Ltd 新規なポリオール組成物及びそれを用いる硬質ポリウレタンフオームの製造方法
US5691440A (en) * 1995-10-05 1997-11-25 Arco Chemical Technonogy, L.P. Catalyst and process for producing isocyanate trimers
JPH10139697A (ja) 1996-09-09 1998-05-26 Asahi Glass Co Ltd 含フッ素炭化水素系組成物
DE19813107A1 (de) * 1998-03-25 1999-09-30 Basf Ag Verfahren zur Herstellung von Polyurethanschaumstoffen
US5902835A (en) 1998-05-28 1999-05-11 Air Products And Chemicals, Inc. Group IVB metal blowing catalyst compositions for the production of polyurethane foams
JP2000063475A (ja) * 1998-08-26 2000-02-29 Mitsui Chemicals Inc 硬質ポリウレタンフォーム
JP2002080552A (ja) * 2000-09-06 2002-03-19 Canon Chemicals Inc イソシアネート組成物、ウレタンゴム組成物の製造方法、クリーニングブレード
DE10142296C1 (de) * 2001-08-29 2003-02-13 Bayer Ag Polyurethanelastomere, Verfahren zu ihrer Herstellung und ihre Verwendung
JP3953353B2 (ja) * 2002-04-11 2007-08-08 アキレス株式会社 硬質ポリウレタンフォームの製造方法
EP1511794B1 (de) 2002-05-27 2007-05-02 Huntsman International Llc Expandierte supramolekulare polymere
EP1375546A1 (de) 2002-06-21 2004-01-02 Crompton GmbH Zinn-Katalysatoren mit geringer Emission
US6846850B2 (en) * 2003-01-22 2005-01-25 Bayer Materialscience Llc Rigid polyurethane foams with improved properties
US6825238B2 (en) * 2003-01-29 2004-11-30 Air Products And Chemicals, Inc. Low acid organometallic catalyst for the production of flexible, semi-flexible and rigid polyurethane foams
JP4104539B2 (ja) * 2003-04-22 2008-06-18 花王株式会社 ポリイソシアヌレートフォームの製造法
JP2005307143A (ja) * 2003-06-30 2005-11-04 Bridgestone Corp 硬質ポリウレタンフォーム
DE102004009740A1 (de) 2004-02-25 2005-09-15 Basf Ag Zinn- und Übergangsmetallfreie Polyurethanschaumstoffe
US8729146B2 (en) * 2005-06-14 2014-05-20 Momentive Performance Materials Inc. Catalyst composition and process using same
US8552077B2 (en) * 2006-05-04 2013-10-08 Air Products And Chemicals, Inc. Trimer catalyst additives for improving foam processability

Also Published As

Publication number Publication date
US8530534B2 (en) 2013-09-10
JP2007308696A (ja) 2007-11-29
EP1852448A3 (de) 2008-03-05
JP2015057498A (ja) 2015-03-26
US20130341562A1 (en) 2013-12-26
MX2007005295A (es) 2008-10-30
BRPI0702265A8 (pt) 2018-01-02
KR100909643B1 (ko) 2009-07-27
US20070259983A1 (en) 2007-11-08
CN101067018B (zh) 2013-02-06
KR20090026242A (ko) 2009-03-12
CN101067018A (zh) 2007-11-07
EP1852448B1 (de) 2011-08-31
BRPI0702265B1 (pt) 2019-08-13
JP6006283B2 (ja) 2016-10-12
BRPI0702265A (pt) 2007-12-18
JP2011041948A (ja) 2011-03-03
KR20070108082A (ko) 2007-11-08
EP1852448A2 (de) 2007-11-07
JP4898541B2 (ja) 2012-03-14
US9890236B2 (en) 2018-02-13
JP5722585B2 (ja) 2015-05-20

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