ATE297807T1 - Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden - Google Patents

Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden

Info

Publication number
ATE297807T1
ATE297807T1 AT00111333T AT00111333T ATE297807T1 AT E297807 T1 ATE297807 T1 AT E297807T1 AT 00111333 T AT00111333 T AT 00111333T AT 00111333 T AT00111333 T AT 00111333T AT E297807 T1 ATE297807 T1 AT E297807T1
Authority
AT
Austria
Prior art keywords
ligands
allylamines
phospho
stereospecific
chiral
Prior art date
Application number
AT00111333T
Other languages
English (en)
Inventor
Christian Chapuis
Original Assignee
Firmenich & Cie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich & Cie filed Critical Firmenich & Cie
Application granted granted Critical
Publication of ATE297807T1 publication Critical patent/ATE297807T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/02—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of compounds containing imino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT00111333T 1999-06-17 2000-05-26 Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden ATE297807T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH113199 1999-06-17

Publications (1)

Publication Number Publication Date
ATE297807T1 true ATE297807T1 (de) 2005-07-15

Family

ID=4203230

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00111333T ATE297807T1 (de) 1999-06-17 2000-05-26 Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden

Country Status (6)

Country Link
US (1) US6350910B1 (de)
EP (1) EP1060793B1 (de)
JP (1) JP2001011029A (de)
AT (1) ATE297807T1 (de)
DE (1) DE60020775T8 (de)
ES (1) ES2243171T3 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE60027734T2 (de) * 1999-09-20 2007-04-05 The Penn State Research Foundation Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen
KR100825615B1 (ko) * 2001-12-27 2008-04-25 삼성토탈 주식회사 카르보디이미드계열 리간드의 킬레이트 화합물 촉매를이용한 에틸렌 중합 및 공중합방법
KR100830319B1 (ko) * 2001-12-27 2008-05-16 삼성토탈 주식회사 카르보디이미드계열 리간드의 킬레이트 화합물 촉매를 이용한 에틸렌 중합 또는 공중합 방법
CN100389877C (zh) * 2006-03-30 2008-05-28 复旦大学 一种用于常压制备手性仲醇的负载催化剂及其制备方法
CN103272646B (zh) * 2013-05-29 2015-02-11 上海灏翔生物科技有限公司 用于制备L-薄荷醇中间体d-香茅醛的催化剂及其制备方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS584748A (ja) 1981-06-30 1983-01-11 Takasago Corp エナミンまたはイミンの製造方法
JPS6061587A (ja) * 1983-09-16 1985-04-09 Takasago Corp ロジウム−ホスフイン錯体
JPS60199898A (ja) 1984-03-22 1985-10-09 Takasago Corp ロジウム−ホスフイン錯体
JPS6119203A (ja) 1984-07-05 1986-01-28 Murata Mfg Co Ltd ストリツプライン共振装置
JPS6127949A (ja) * 1984-07-17 1986-02-07 Takasago Corp 光学活性なエナミンの製造法
EP0257411B1 (de) * 1986-08-21 1992-11-25 F. Hoffmann-La Roche Ag Verfahren zur Herstellung von optisch aktiven Enaminen oder von den entsprechenden Aldehyden
DK0398132T3 (da) 1989-05-18 1995-12-18 Hoffmann La Roche Phosphorforbindelser
DE4330730A1 (de) 1993-09-10 1995-03-16 Bayer Ag Neue Bisphosphine für asymmetrische Hydrierkatalysatoren
CN1139930A (zh) 1994-02-02 1997-01-08 希巴-盖吉股份公司 加氢催化剂及其制备方法和加氢方法
DE19630536C2 (de) * 1996-07-29 1998-11-05 Hoechst Ag Katalysator und dessen Verwendung für die Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen
GB9619684D0 (en) * 1996-09-20 1996-11-06 Oxford Asymmetry Ltd Phosphine ligands
DE69913412T2 (de) * 1998-04-07 2004-09-16 Firmenich S.A. Stereospezifische Isomerisierung von Allylaminen unter Verwendung von Chiralen Phospho-Liganden

Also Published As

Publication number Publication date
EP1060793B1 (de) 2005-06-15
US6350910B1 (en) 2002-02-26
EP1060793A1 (de) 2000-12-20
JP2001011029A (ja) 2001-01-16
DE60020775T2 (de) 2006-05-11
DE60020775D1 (de) 2005-07-21
DE60020775T8 (de) 2006-09-28
ES2243171T3 (es) 2005-12-01

Similar Documents

Publication Publication Date Title
Collot et al. Artificial metalloenzymes for enantioselective catalysis based on biotin− avidin
Junge et al. Synthesis of new chiral monodentate phosphines and their use in asymmetric hydrogenation
Ager et al. Reductions of 1, 3-dicarbonyl systems with ruthenium-biarylbisphosphine catalysts
ATE195931T1 (de) Enantioselektive herstellung von optisch reinem albuterol
Ratovelomanana-Vidal et al. Enantioselective ruthenium-mediated hydrogenation: developments and applications
Chen et al. Enantioselective hydrogenation with inexpensive, easily available monodentate phosphite ligands
TR28265A (tr) (L) veya (D) homoalanin-4-yl-(Metil) fosfin asidi ve tuzlarinin racemat parcalanmasi ile imalati metodu.
JP3888677B2 (ja) 不斉水素付加の触媒としての非ｃ２対称性ビスホスフィンリガンドの合成
Wang et al. Readily available chiral phosphine− aminophosphine ligands for highly efficient Rh-catalyzed asymmetric hydrogenation of α-enol ester phosphonates and α-enamido phosphonates
Zhu et al. Direct asymmetric hydrogenation of 2-oxo-4-arylbut-3-enoic acids
ATE297807T1 (de) Stereospezifische isomerierung von allylaminen unter verwendung von immobilisierten chiralen phospho-liganden
DE69710051D1 (de) Auflösungsverfahren von threo-methylphenidate
ATE341640T1 (de) Verfahren zur herstellung von nicht-proteinogenen l-aminosäuren
DE69521605D1 (de) Optisch aktive diphosphine und herstellungsverfahren durch auftrennung der racematmischung
ATE185570T1 (de) Hydrierungskatalysator, verfahren zu seiner herstellung und hydrierungsverfahren
ATE194342T1 (de) Verfahren zur herstellung von optisch aktivem 3- chinuclidinol
ES550091A0 (es) Procedimiento para preparar 1-bencil-3,4-bis-(difenilfosfino)-pirrolidina opticamente activa
ATE126831T1 (de) Verfahren zur herstellung von glukose und fruktose aus sukrose.
EP1041077A3 (de) Phosphin-Derivat und Polymer davon und sie enthaltender Übergangsmetall-Komplex
US5187281A (en) Asymmetric hydrogenation of aromatic-substituted olefins using organoiridium catalyst
ATE367372T1 (de) Verfahren zur herstellung von (r)-salbutamol
DE3874565D1 (de) Verfahren zur herstellung von hydroxybiphenylen.
DE59807664D1 (de) Verfahren zur herstellung von 3-cyano-2,4-dihalogen-5-fluor-benzoesäuren
EP0949241A3 (de) Stereospezifische Isomerisierung von Allylaminen unter Verwendung von Chiralen Phospho-Liganden
DE59207400D1 (de) Racemat-Spaltverfahren und diastereomere Assoziate

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties