ATE200295T1 - Metallocenkatalysator für die homo- oder copolymerisation von alpha-olefinen - Google Patents

Metallocenkatalysator für die homo- oder copolymerisation von alpha-olefinen

Info

Publication number
ATE200295T1
ATE200295T1 AT96109936T AT96109936T ATE200295T1 AT E200295 T1 ATE200295 T1 AT E200295T1 AT 96109936 T AT96109936 T AT 96109936T AT 96109936 T AT96109936 T AT 96109936T AT E200295 T1 ATE200295 T1 AT E200295T1
Authority
AT
Austria
Prior art keywords
olefins
alpha
polymerization
catalyst
homo
Prior art date
Application number
AT96109936T
Other languages
English (en)
Inventor
Roberto Santi
Giampiero Borsotti
Antonio Proto
Liliana Gila
Karel Bujadoux
Original Assignee
Enichem Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Spa filed Critical Enichem Spa
Application granted granted Critical
Publication of ATE200295T1 publication Critical patent/ATE200295T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
    • C07C1/328—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being an alkali metal atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT96109936T 1995-07-06 1996-06-20 Metallocenkatalysator für die homo- oder copolymerisation von alpha-olefinen ATE200295T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT95MI001444A IT1275777B1 (it) 1995-07-06 1995-07-06 Catalizzatore metallocenico per la (co)polimerizzazione delle olefine

Publications (1)

Publication Number Publication Date
ATE200295T1 true ATE200295T1 (de) 2001-04-15

Family

ID=11371928

Family Applications (1)

Application Number Title Priority Date Filing Date
AT96109936T ATE200295T1 (de) 1995-07-06 1996-06-20 Metallocenkatalysator für die homo- oder copolymerisation von alpha-olefinen

Country Status (12)

Country Link
US (1) US5753578A (de)
EP (1) EP0752428B1 (de)
JP (1) JPH09286812A (de)
AT (1) ATE200295T1 (de)
CA (1) CA2180671C (de)
DE (1) DE69612331T2 (de)
DK (1) DK0752428T3 (de)
ES (1) ES2155550T3 (de)
GR (1) GR3035816T3 (de)
IT (1) IT1275777B1 (de)
PT (1) PT752428E (de)
SI (1) SI0752428T1 (de)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
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CA2067525C (en) * 1991-05-09 1998-09-15 Helmut G. Alt Organometallic fluorenyl compounds, preparation and use
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US5856256A (en) * 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
IT1283630B1 (it) * 1996-05-09 1998-04-23 Enichem Spa Procedimento per la preparazione di copolimeri elastomerici ep(d)m
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
DE19637669A1 (de) 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
DE69722902T2 (de) 1996-12-09 2004-05-19 Mitsubishi Chemical Corp. Katalysator für Alpha-Olefinpolymerisation
WO1998046547A1 (en) * 1997-04-15 1998-10-22 Montell Technology Company B.V. Process for preparing 2-aryl-substituted indenes
DE19724743A1 (de) * 1997-06-12 1998-12-24 Danubia Petrochem Polymere Blends aus Polyolefinen und Polyvinylaromaten
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6268447B1 (en) 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
IT1295266B1 (it) 1997-10-03 1999-05-04 Enichem Spa Procedimento e catalizzatore per l'idrogenazione di composti olefinicamente insaturi
DE19757540A1 (de) * 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
US6225410B1 (en) * 1997-12-25 2001-05-01 Mitsui Chemicals Ethylene/α-olefin copolymer and process for preparing the same
CN1124296C (zh) * 1998-02-17 2003-10-15 埃克森美孚化学专利公司 乙烯共聚方法
IT1298616B1 (it) 1998-03-10 2000-01-12 Enichem Spa Complesso metallocenico pontato per la (co) polimerizzazione delle olefine
DE69926339T2 (de) * 1998-11-20 2006-01-26 Basell Polyolefine Gmbh Verbrückte metallocene, herstellung und verwendung als olefinpolymerisationskatalysator
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
JP2004536183A (ja) 2001-07-19 2004-12-02 ユニベーション・テクノロジーズ・エルエルシー コモノマー低結合性メタロセン触媒化合物
WO2003050131A1 (en) * 2001-12-10 2003-06-19 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US7157591B2 (en) 2001-12-10 2007-01-02 Exxonmobie Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
KR101538625B1 (ko) * 2006-05-09 2015-07-22 가부시키가이샤 브리지스톤 메탈로센 착체 및 이를 포함하는 중합 촉매 조성물
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
JP5578473B2 (ja) * 2007-10-25 2014-08-27 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング アンサ−メタロセン化合物のラセモ選択的合成、アンサ−メタロセン化合物、それを含む触媒、触媒の使用によってオレフィンポリマーを製造するプロセス、ならびにホモポリマーおよびコポリマー
BRPI0822091B1 (pt) 2007-12-18 2019-10-08 Univation Technologies, Llc Método de polimerização
US8637616B2 (en) 2010-10-07 2014-01-28 Chevron Philips Chemical Company Lp Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
US8609793B2 (en) 2010-10-07 2013-12-17 Chevron Phillips Chemical Company Lp Catalyst systems containing a bridged metallocene
US8629292B2 (en) 2010-10-07 2014-01-14 Chevron Phillips Chemical Company Lp Stereoselective synthesis of bridged metallocene complexes
ES2524430T3 (es) 2010-12-03 2014-12-09 Dow Global Technologies Llc Procesos para preparar composiciones poliméricas basadas en etileno
US9234054B2 (en) * 2011-12-19 2016-01-12 Saudi Basic Industries Corporation Process for the preparation of metallocene complexes
IN2014DN04977A (de) * 2011-12-19 2015-05-15 Saudi Basic Ind Corp Sabic
WO2016086039A1 (en) 2014-11-25 2016-06-02 Univation Technologies, Llc Methods of controlling polyolefin melt index
KR102073252B1 (ko) 2016-12-05 2020-02-04 주식회사 엘지화학 올레핀 공중합체 합성용 촉매 조성물 및 올레핀 공중합체의 제조 방법
KR102234944B1 (ko) * 2016-12-13 2021-03-31 주식회사 엘지화학 올레핀 공중합체
CN117098785A (zh) 2021-04-30 2023-11-21 埃克森美孚化学专利公司 用于聚合反应器中不同聚合催化剂之间的转变的方法
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IT1256603B (it) * 1992-10-30 1995-12-12 Enichem Polimeri Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine

Also Published As

Publication number Publication date
EP0752428A3 (de) 1997-07-16
ITMI951444A1 (it) 1997-01-06
ITMI951444A0 (it) 1995-07-06
EP0752428A2 (de) 1997-01-08
IT1275777B1 (it) 1997-10-17
SI0752428T1 (en) 2001-08-31
CA2180671C (en) 2008-04-29
DE69612331D1 (de) 2001-05-10
DK0752428T3 (da) 2001-06-25
JPH09286812A (ja) 1997-11-04
GR3035816T3 (en) 2001-07-31
CA2180671A1 (en) 1997-01-07
DE69612331T2 (de) 2001-08-23
PT752428E (pt) 2001-07-31
EP0752428B1 (de) 2001-04-04
US5753578A (en) 1998-05-19
ES2155550T3 (es) 2001-05-16

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