ATE139577T1 - CHROMATOGRAPHIC SEPARATION OF SUGAR WITH POROUS GEL RESINS - Google Patents

CHROMATOGRAPHIC SEPARATION OF SUGAR WITH POROUS GEL RESINS

Info

Publication number
ATE139577T1
ATE139577T1 AT92921196T AT92921196T ATE139577T1 AT E139577 T1 ATE139577 T1 AT E139577T1 AT 92921196 T AT92921196 T AT 92921196T AT 92921196 T AT92921196 T AT 92921196T AT E139577 T1 ATE139577 T1 AT E139577T1
Authority
AT
Austria
Prior art keywords
porous gel
sugar
separation
liquid mixture
stratum
Prior art date
Application number
AT92921196T
Other languages
German (de)
Inventor
Antonio Dorta
Yog R Dhingra
Bruce W Pynnonen
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ATE139577T1 publication Critical patent/ATE139577T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B20/00—Purification of sugar juices
    • C13B20/14—Purification of sugar juices using ion-exchange materials
    • C13B20/144—Purification of sugar juices using ion-exchange materials using only cationic ion-exchange material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction
    • B01D15/361—Ion-exchange
    • B01D15/362—Cation-exchange

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The present invention is a process for the chromatographic separation of a liquid mixture comprising a first sugar component and at least one secondary component chosen from second sugars, organic acids and salts thereof, alcohols, amino acids, and inorganic salts. In the process, the liquid mixture is contacted with a stratum of a porous gel cation-exchange resin and thereafter eluted such that the first sugar component passes through the stratum at a different rate relative to the secondary components of the liquid mixture. The separation results in a first recoverable product stream rich in the first sugar component and at least one secondary product stream rich in the secondary components. The porous gel cation-exchange resin is prepared by polymerization of at least one monovinylidene monomer with a cross-linking monomer in the presence of an inert diluent. The use of such porous gel resins in the process increases kinetics, improves yields of desired sugar components, and results in a more efficient separation process. The invention is particularly applicable to separation of glucose from fructose in the preparation of high fructose corn syrup.
AT92921196T 1991-10-23 1992-09-28 CHROMATOGRAPHIC SEPARATION OF SUGAR WITH POROUS GEL RESINS ATE139577T1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/781,462 US5176832A (en) 1991-10-23 1991-10-23 Chromatographic separation of sugars using porous gel resins

Publications (1)

Publication Number Publication Date
ATE139577T1 true ATE139577T1 (en) 1996-07-15

Family

ID=25122824

Family Applications (1)

Application Number Title Priority Date Filing Date
AT92921196T ATE139577T1 (en) 1991-10-23 1992-09-28 CHROMATOGRAPHIC SEPARATION OF SUGAR WITH POROUS GEL RESINS

Country Status (10)

Country Link
US (1) US5176832A (en)
EP (1) EP0609279B1 (en)
CN (1) CN1071701A (en)
AT (1) ATE139577T1 (en)
AU (1) AU2753692A (en)
CA (1) CA2121492A1 (en)
DE (1) DE69211705T2 (en)
ES (1) ES2088596T3 (en)
HU (1) HUT69292A (en)
WO (1) WO1993008308A1 (en)

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ES2827527T3 (en) * 2015-02-24 2021-05-21 Archer Daniels Midland Co Manufacture and purification of isoidides
WO2016137787A1 (en) 2015-02-27 2016-09-01 Rohm And Haas Company Chromatographic separation of saccharides using cation exchange resin beads with rough outer surface
WO2016137786A1 (en) 2015-02-27 2016-09-01 Dow Global Technologies Llc Chromatographic separation of saccharides using whole cracked beads of gel-type strong acid exchange resin
US20180001313A1 (en) 2015-03-12 2018-01-04 Dow Global Technologies Llc Chromatographic separation of saccharides using strong acid exchange resin incorporating precipitated barium sulfate
CN107427741B (en) 2015-03-12 2020-04-10 陶氏环球技术有限责任公司 Chromatographic separation of sugars using polymeric macroporous alkylene-bridged resins
CN105017339B (en) * 2015-07-01 2018-03-09 浙江大学 A kind of method that SMBC separation prepares raffinose and stachyose
JP7032435B2 (en) * 2017-04-28 2022-03-08 ダウ グローバル テクノロジーズ エルエルシー Treatment of sugar solution
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CN112973806A (en) * 2021-02-09 2021-06-18 珠海高新区维得力生物工程有限公司 Chromatographic separation filler applied to fructo-oligosaccharide, preparation process and chromatographic separation device
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Also Published As

Publication number Publication date
HUT69292A (en) 1995-09-28
DE69211705T2 (en) 1997-02-20
HU9401142D0 (en) 1994-07-28
CN1071701A (en) 1993-05-05
EP0609279B1 (en) 1996-06-19
CA2121492A1 (en) 1993-04-29
ES2088596T3 (en) 1996-08-16
DE69211705D1 (en) 1996-07-25
WO1993008308A1 (en) 1993-04-29
EP0609279A1 (en) 1994-08-10
US5176832A (en) 1993-01-05
AU2753692A (en) 1993-05-21

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