AR127968A1 - Compuestos útiles para la preparación de varios agroquímicos y sus marcadores - Google Patents
Compuestos útiles para la preparación de varios agroquímicos y sus marcadoresInfo
- Publication number
- AR127968A1 AR127968A1 ARP220103437A ARP220103437A AR127968A1 AR 127968 A1 AR127968 A1 AR 127968A1 AR P220103437 A ARP220103437 A AR P220103437A AR P220103437 A ARP220103437 A AR P220103437A AR 127968 A1 AR127968 A1 AR 127968A1
- Authority
- AR
- Argentina
- Prior art keywords
- exemplified
- compounds
- naphthyl
- unsubstituted
- aryl
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 238000002360 preparation method Methods 0.000 title abstract 3
- 239000003905 agrochemical Substances 0.000 title 1
- 125000003118 aryl group Chemical group 0.000 abstract 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910052799 carbon Inorganic materials 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 125000001624 naphthyl group Chemical group 0.000 abstract 3
- 229920006395 saturated elastomer Polymers 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 239000003550 marker Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000003860 storage Methods 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- SFHYNDMGZXWXBU-LIMNOBDPSA-N 6-amino-2-[[(e)-(3-formylphenyl)methylideneamino]carbamoylamino]-1,3-dioxobenzo[de]isoquinoline-5,8-disulfonic acid Chemical compound O=C1C(C2=3)=CC(S(O)(=O)=O)=CC=3C(N)=C(S(O)(=O)=O)C=C2C(=O)N1NC(=O)N\N=C\C1=CC=CC(C=O)=C1 SFHYNDMGZXWXBU-LIMNOBDPSA-N 0.000 abstract 1
- 102000004190 Enzymes Human genes 0.000 abstract 1
- 108090000790 Enzymes Proteins 0.000 abstract 1
- 239000007818 Grignard reagent Substances 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000004795 grignard reagents Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000001979 organolithium group Chemical group 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 150000007970 thio esters Chemical class 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
- C07D207/273—2-Pyrrolidones with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/36—Oxygen or sulfur atoms
- C07D207/38—2-Pyrrolones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D211/78—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/80—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D211/84—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen directly attached to ring carbon atoms
- C07D211/90—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/32—Oxygen atoms
- C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
La presente invención se refiere a varios compuestos, que son intermedios novedosos y útiles en métodos novedosos para la preparación de ciertos compuestos denominados Objetivos Saturados u formas amorfas y cristalinas de los mismos, y ciertos compuestos marcadores incluyendo Marcador de Almacenamiento compuestos, métodos para su preparación, su uso, y composiciones que los comprenden incluyendo métodos para minimizar su contenido de porcentaje de Marcadores de Almacenamiento en productos y composiciones de Objetivo Saturado. Reivindicación 1: Un proceso B1 para preparar un Objetivo Saturado de fórmula (1) a partir de un Precursor Insaturado de fórmula (2) de acuerdo con el siguiente esquema, que comprende la sustitución del sistema 1,4 ejemplificado por adición 1,4 utilizando reactivo de Grignard, reactivo de órgano-litio, reactivo de órgano-zinc, hidrogenación, fuente de hidruro, fuente de electrones (reducción, ejemplificado por Zn / AcOH) o enzima en donde cada uno de Rᵇ, Aᵃ, Aᵇ, na, Qᵃ y Rᵉ, tienen los mismos significados definidos en el compuesto A2, y Rᵃ es H, halógeno o grupo que contiene carbono ejemplificado por alquilo, arilo, heterocíclico, naftilo, sustituido o no sustituido, éster incluyendo ésteres alifáticos y aromáticos ejemplificado por, C(O)OC₆H₅, -C(O)OC₆H₄F, amida incluyendo alifática y aromática ejemplificado por -C(O)NHC₆H₅), hidrazinamida incluyendo alifática y aromática ejemplificado por, -C(O)NHNHC₆H₅), tioésteres, tionoésteres y compuestos similares ejemplificado por, -C(O)NHOC₆F₅); y -C(S)SC₆H₅), etc., en donde Rᵃ no está conectado al anillo a través de O o átomos N, de modo tal que por ejemplo, Rᵃ no es -OMe, y en donde, cuando se agrega H en la posición 4 del sistema 1,4, Rᵃ no es H, y en donde Rᵍ es H o grupo que contiene carbono tal como alquilo, arilo, naftilo, etc., sustituido o no sustituido, Rᵈ es H o grupo que contiene carbono tal como alquilo, arilo, naftilo, etc., sustituido o no sustituido.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202163289671P | 2021-12-15 | 2021-12-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR127968A1 true AR127968A1 (es) | 2024-03-13 |
Family
ID=85157181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP220103437A AR127968A1 (es) | 2021-12-15 | 2022-12-15 | Compuestos útiles para la preparación de varios agroquímicos y sus marcadores |
Country Status (5)
| Country | Link |
|---|---|
| CN (1) | CN118401112A (es) |
| AR (1) | AR127968A1 (es) |
| CO (1) | CO2024008168A2 (es) |
| IL (1) | IL313538A (es) |
| WO (1) | WO2023112033A2 (es) |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108863787A (zh) * | 2017-05-12 | 2018-11-23 | 南开大学 | 3-烷基-2-乙氧羰基取代环状共轭烯酮的不对称催化氢化及其应用 |
| BR112020000371A2 (pt) * | 2017-07-12 | 2020-07-14 | Syngenta Participations Ag | derivados de oxadiazol microbiocidas |
| US20200181117A1 (en) * | 2017-07-18 | 2020-06-11 | Bayer Cropscience Aktiengesellschaft | Substituted 3-heteroaryloxy-1h-pyrazoles and salts thereof and their use as herbicidal active substances |
| CN111556861A (zh) * | 2018-01-07 | 2020-08-18 | 维达克制药有限公司 | 茉莉酸酯化合物的制备方法 |
| JP7301042B2 (ja) * | 2018-03-30 | 2023-06-30 | 住友化学株式会社 | 複素環化合物及びそれを含有する有害節足動物防除組成物 |
| JP2021121581A (ja) * | 2020-01-31 | 2021-08-26 | クミアイ化学工業株式会社 | ３−（ピラゾール−１−イル）安息香酸アミド誘導体及び有害生物防除剤 |
| JP2021121582A (ja) * | 2020-01-31 | 2021-08-26 | クミアイ化学工業株式会社 | ５−（ピラゾール−５−イル）安息香酸アミド誘導体及び有害生物防除剤 |
| CN111233795B (zh) * | 2020-02-27 | 2023-12-29 | 山东省医学科学院药物研究所（山东省抗衰老研究中心、山东省新技术制药研究所） | 一种手性γ-丁内酯类化合物及其衍生物的制备方法及其应用 |
-
2022
- 2022-12-15 AR ARP220103437A patent/AR127968A1/es unknown
- 2022-12-15 WO PCT/IL2022/051330 patent/WO2023112033A2/en active Application Filing
- 2022-12-15 CN CN202280083483.9A patent/CN118401112A/zh active Pending
- 2022-12-15 IL IL313538A patent/IL313538A/en unknown
-
2024
- 2024-06-24 CO CONC2024/0008168A patent/CO2024008168A2/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN118401112A (zh) | 2024-07-26 |
| WO2023112033A3 (en) | 2023-08-03 |
| IL313538A (en) | 2024-08-01 |
| WO2023112033A2 (en) | 2023-06-22 |
| CO2024008168A2 (es) | 2024-06-27 |
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