AR115090A1 - PYRROLIDIN-2,4-DIONES SUBSTITUTED WITH 2-BROMO-6-ALCOXIFENIL AND ITS USE AS HERBICIDES - Google Patents
PYRROLIDIN-2,4-DIONES SUBSTITUTED WITH 2-BROMO-6-ALCOXIFENIL AND ITS USE AS HERBICIDESInfo
- Publication number
- AR115090A1 AR115090A1 ARP190101277A ARP190101277A AR115090A1 AR 115090 A1 AR115090 A1 AR 115090A1 AR P190101277 A ARP190101277 A AR P190101277A AR P190101277 A ARP190101277 A AR P190101277A AR 115090 A1 AR115090 A1 AR 115090A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- methylpyridine
- alkoxy
- bromo
- independently
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/54—Spiro-condensed
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Derivados de pirrolidin-2,4-dionas sustituidas con 2-bromo-6-alcoxifenilo y sus sales agroquímicamente aceptables como agentes herbicidas, un método para su preparación y su uso para el combate de malezas y pastos dañinos en cultivos de plantas útiles. Reivindicación 1: Pirrolidin-2,4-dionas sustituidas con 2-bromo-6-alcoxifenilo de la fórmula general (1), y sus sales agroquímicamente tolerables, caracterizadas porque R¹ es alquilo C₁₋₆, haloalquilo C₂₋₄ o cicloalquilo C₃₋₆; R² es alcoxi C₁₋₂ o alcoxi C₁₋₄-alquilo C₁₋₄; G es hidrógeno, un grupo escindible L o un catión E, en donde L es uno de los restos del grupo de fórmulas (2), en donde R⁴ es alquilo C₁₋₄ o alcoxi C₁₋₃-alquilo C₂₋₄; R⁵ es alquilo C₁₋₄; R⁶ es alquilo C₁₋₄, un fenilo no sustituido o mono- o polisustituido con halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, nitro o ciano; R⁷, R⁷’ son, de modo independiente entre sí, metoxi o etoxi; R⁸, R⁹ son, de modo independiente entre sí, metilo, etilo, fenilo o juntos forman un anillo saturado de 5, 6 ó 7 miembros o juntos forman un heterociclo saturado de 5, 6 ó 7 miembros con un átomo de oxígeno o de azufre; E es un ión de metal alcalino, un equivalente iónico de un metal alcalinotérreo, un equivalente iónico de aluminio, un equivalente iónico de un metal de transición o es un catión de magnesio-halógeno, es un ión amonio en el que opcionalmente uno, dos, tres o los cuatro pueden estar reemplazados por átomos de hidrógeno por restos iguales o diferentes de los grupos alquilo C₁₋₁₀ o cicloalquilo C₃₋₇, en donde pueden estar mono- o polisustituidos, independientemente entre sí, con flúor, cloro, bromo, ciano, hidroxi o pueden estar interrumpidos por uno o varios átomos de oxígeno o azufre, es un ión amonio cíclico secundario o alifático terciario o heteroalifático, por ejemplo, en cada caso, morfolinio, tiomorfolinio, piperidinio, pirrolidino o en cada caso 1,4-diazabiciclo[1.1.2]octano protonado (DABCO) o 1,5-diazabiciclo[4.3.0]undec-7-eno (DBU), es un catión amonio heteroaromático, por ejemplo, piridina, 2-metilpiridina, 3-metilpiridina, 4-metilpiridina, 2,4-dimetilpiridina, 2,5-dimetilpiridina, 2,6-dimetilpiridina, 5-etil-2-metilpiridina, colidina, pirrol, imidazol, quinolina, quinoxalina, 1,2-dimetilimidazol, 1,3-metilsulfato de dimetilimidazolio en cada caso protonados o también puede representar un ión trimetilsulfonio.Derivatives of 2-bromo-6-alkoxyphenyl substituted pyrrolidine-2,4-diones and their agrochemically acceptable salts as herbicidal agents, a method for their preparation and their use to combat harmful weeds and grasses in useful plant crops. Claim 1: 2-bromo-6-alkoxyphenyl substituted pyrrolidine-2,4-diones of the general formula (1), and their agrochemically tolerable salts, characterized in that R¹ is C₁₋₆ alkyl, C₂₋₄ haloalkyl or C₃₋ cycloalkyl ₆; R² is C₁₋₂ alkoxy or C₁₋₄ alkoxy-C₁₋₄ alkyl; G is hydrogen, a cleavable group L or a cation E, where L is one of the moieties from the group of formulas (2), where R⁴ is C₁₋₄ alkyl or C₁₋₃ alkoxy-C₂₋₄ alkyl; R⁵ is C₁₋₄ alkyl; R⁶ is C₁₋₄ alkyl, an unsubstituted phenyl or mono- or polysubstituted with halogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, nitro or cyano; R⁷, R⁷ 'are, independently of one another, methoxy or ethoxy; R⁸, R⁹ are, independently of each other, methyl, ethyl, phenyl or together they form a saturated 5, 6 or 7 membered ring or together they form a saturated 5, 6 or 7 membered heterocycle with an oxygen or sulfur atom ; E is an alkali metal ion, an ionic equivalent of an alkaline earth metal, an ionic equivalent of aluminum, an ionic equivalent of a transition metal or is a magnesium-halogen cation, is an ammonium ion in which optionally one, two , three or all four can be replaced by hydrogen atoms by the same or different residues of the C₁₋₁₀ alkyl or C₃₋₇ cycloalkyl groups, where they can be mono- or polysubstituted, independently of each other, with fluorine, chlorine, bromine, cyano, hydroxy or may be interrupted by one or more oxygen or sulfur atoms, it is a secondary cyclic ammonium ion or tertiary aliphatic or heteroaliphatic, for example, in each case, morpholinium, thiomorpholinium, piperidinium, pyrrolidino or in each case 1,4 -diazabicyclo [1.1.2] protonated octane (DABCO) or 1,5-diazabicyclo [4.3.0] undec-7-ene (DBU), is a heteroaromatic ammonium cation, eg pyridine, 2-methylpyridine, 3-methylpyridine , 4-methylpyridine, 2,4-dimethylpyridine, 2,5-dimethylpyrid idine, 2,6-dimethylpyridine, 5-ethyl-2-methylpyridine, collidine, pyrrole, imidazole, quinoline, quinoxaline, 1,2-dimethylimidazole, 1,3-dimethylimidazolium 1,3-methylsulfate in each case protonated or can also represent a trimethylsulfonium ion .
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP18174682 | 2018-05-29 |
Publications (1)
Publication Number | Publication Date |
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AR115090A1 true AR115090A1 (en) | 2020-11-25 |
Family
ID=66448583
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP190101277A AR115090A1 (en) | 2018-05-29 | 2019-05-14 | PYRROLIDIN-2,4-DIONES SUBSTITUTED WITH 2-BROMO-6-ALCOXIFENIL AND ITS USE AS HERBICIDES |
Country Status (2)
Country | Link |
---|---|
AR (1) | AR115090A1 (en) |
WO (1) | WO2019228788A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20230180758A1 (en) | 2020-05-27 | 2023-06-15 | Bayer Aktiengesellschaft | Substituted pyrroline-2-ones and their use as herbicides |
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2019
- 2019-05-13 WO PCT/EP2019/062172 patent/WO2019228788A1/en active Application Filing
- 2019-05-14 AR ARP190101277A patent/AR115090A1/en unknown
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WO2019228788A1 (en) | 2019-12-05 |
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