AR105607A1 - Derivados heterocíclicos condensados sustituidos por 2-(het)arilo como pesticidas - Google Patents

Derivados heterocíclicos condensados sustituidos por 2-(het)arilo como pesticidas

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AR105607A1
AR105607A1 ARP160102394A ARP160102394A AR105607A1 AR 105607 A1 AR105607 A1 AR 105607A1 AR P160102394 A ARP160102394 A AR P160102394A AR P160102394 A ARP160102394 A AR P160102394A AR 105607 A1 AR105607 A1 AR 105607A1
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Argentina
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alkyl
alkoxy
cycloalkyl
alkylsulfinyl
alkylthio
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ARP160102394A
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Turberg Andreas
Grgens Ulrich
Portz Daniela
Willot Matthieu
Hoffmeister Laura
Ilg Kerstin
Hager Dominik
Kausch-Busies Nina
Wilcke David
Fischer Rdiger
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Bayer Cropscience Ag
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Publication of AR105607A1 publication Critical patent/AR105607A1/es

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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
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    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C07D403/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
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    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems
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    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
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    • C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D498/04—Ortho-condensed systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

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  • Chemical & Material Sciences (AREA)
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  • Health & Medical Sciences (AREA)
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  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

Reivindicación 1: Compuestos de la fórmula (1) en la que A¹ representa nitrógeno, =N⁺-O⁻ o =C-R⁴; R¹ representa C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-cianoalquilo, C₁₋₆-hidroxialquilo, C₁₋₆-alcoxi-C₁₋₆-alquilo, C₁₋₆-haloalcoxi-C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alqueniloxi-C₁₋₆-alquilo, C₂₋₆-haloalqueniloxi-C₁₋₆-alquilo, C₂₋₆-haloalquenilo, C₂₋₆-cianoalquenilo, C₂₋₆-alquinilo, C₂₋₆-alquiniloxi-C₁₋₆-alquilo, C₂₋₆-haloalquiniloxi-C₁₋₆-alquilo, C₂₋₆-haloalquinilo, C₂₋₆-cianoalquinilo, C₃₋₈-cicloalquilo, C₃₋₈-cicloalquilo-C₃₋₈-cicloalquilo, C₁₋₆-alquilo-C₃₋₈-cicloalquilo, halógeno-C₃₋₈-cicloalquilo, amino, C₁₋₆-alquilamino, di-C₁₋₆-alquilamino, C₃₋₈-cicloalquilamino, C₁₋₆-alquilcarbonilamino, C₁₋₆-alquiltio-C₁₋₆-alquilo, C₁₋₆-haloalquiltio-C₁₋₆-alquilo, C₁₋₆-alquilsulfinilo-C₁₋₆-alquilo, C₁₋₆-haloalquilsulfinilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfonilo-C₁₋₆-alquilo, C₁₋₆-haloalquilsulfonilo-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alquiltio-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfinilo-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfonilo-C₁₋₆-alquilo, C₁₋₆-alquilcarbonilo-C₁₋₆-alquilo, C₁₋₆-haloalquilcarbonilo-C₁₋₆-alquilo, C₁₋₆-alcoxicarbonilo-C₁₋₆-alquilo, C₁₋₆-haloalcoxicarbonilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfonilamino, aminosulfonilo-C₁₋₆-alquilo, C₁₋₆-alquilaminosulfonilo-C₁₋₆-alquilo, di-C₁₋₆-alquilaminosulfonilo-C₁₋₆-alquilo, o representa C₁₋₆-alquilo, C₁₋₆-alcoxi, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₈-cicloalquilo ,sustituido en cada caso opcionalmente en forma simple o múltiple, idéntico o distinto, por arilo, heteroarilo o heterociclilo, donde arilo, heteroarilo o heterociclilo en cada caso opcionalmente en forma simple o múltiple, idéntico o distinto pueden estar sustituidos por halógeno, ciano, nitro, hidroxi, amino, carboxi, carbamoil, aminosulfonilo, C₁₋₆-alquilo, C₂₋₆-cicloalquilo, C₁₋₆-alcoxi, C₁₋₆-haloalquilo, C₁₋₆-haloalcoxi, C₁₋₆-alquiltio, C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfonilo, C₁₋₆-alquilsulfimino, C₁₋₆-alquilsulfimino-C₁₋₆-alquilo, C₁₋₆-alquilsulfimino-C₂₋₆-alquilcarbonilo, C₁₋₆-alquilsulfoximino, C₁₋₆-alquilsulfoximino-C₁₋₆-alquilo, C₁₋₆-alquilsulfoximino C₂₋₆-alquilcarbonilo, C₁₋₆-alcoxicarbonilo, C₁₋₆-alquilcarbonilo, C₃₋₆-trialquilsililo o bencilo, o R¹ representa arilo, heteroarilo o heterociclilo sustituidos en cada caso opcionalmente en forma simple o múltiple, idéntico o distinto por halógeno, ciano, nitro, hidroxi, amino, carboxi, carbamoil, C₁₋₆-alquilo, C₃₋₈-cicloalquilo, C₁₋₆-alcoxi, C₁₋₆-haloalquilo, C₁₋₆-haloalcoxi, C₁₋₆-alquiltio, C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfonilo, C₁₋₆-alquilsulfimino, C₁₋₆-alquilsulfimino-C₁₋₆-alquilo, C₁₋₆-alquilsulfimino-C₂₋₆-alquilcarbonilo, C₁₋₆-alquilsulfoximino, C₁₋₆-alquilsulfoximino-C₁₋₆-alquilo, C₁₋₆-alquilsulfoximino-C₂₋₆-alquilcarbonilo, C₁₋₆-alcoxicarbonilo, C₁₋₆-alquilcarbonilo, C₃₋₆-trialquilsililo, (=O) (sólo en el caso de heterociclilo) o (=O)₂ (sólo en el caso de heterociclilo); R² representa en cada caso opcionalmente en forma simple o múltiple, idéntico o distinto un anillo heterocíclico saturado, parcialmente saturado o heteroaromático, en el que al menos un átomo C está sustituido por un heteroátomo, donde al menos puede estar contenido un grupo carbonilo y/o donde se consideran como sustituyentes: hidrógeno, ciano, carboxilo, halógeno, nitro, acetil, hidroxi, amino, SCN, tri-C₁₋₆-alquilsililo, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-cianoalquilo, C₁₋₆-hidroxialquilo, hidroxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-cianoalquenilo, C₂₋₆-alquinilo, C₂₋₆-haloalquinilo, C₂₋₆-cianoalquinilo, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquilo-C₃₋₆-cicloalquilo, C₁₋₄-alquilo-C₃₋₆-cicloalquilo C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₁₋₆-cianoalcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, C₁₋₆-alcoxiimino, -N=C(H)-OC₁₋₆-alquilo, -C(H)=N-OC₁₋₆-alquilo, C₁₋₆-haloalquilo-C₁₋₆-alcoxiimino, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, C₁₋₆-alcoxi-C₁₋₆-alquiltio, C₁₋₆-alquiltio-C₁₋₆-alquilo, C₁₋₆-alquilsulfinilo, C₁₋₆-haloalquilsulfinilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfinilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfonilo, C₁₋₆-haloalquilsulfonilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfonilo, C₁₋₆-alquilsulfonilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfoniloxi, C₁₋₆-alquilcarbonilo, C₁₋₆-haloalquilcarbonilo, C₁₋₆-alquilcarboniloxi, C₁₋₆-alcoxicarbonilo, C₁₋₆-haloalcoxicarbonilo, aminocarbonilo, C₁₋₆-alquilaminocarbonilo, di-C₁₋₆-alquilaminocarbonilo, C₂₋₆-alquenilaminocarbonilo, di-C₂₋₆-alquenilaminocarbonilo, C₃₋₈-cicloalquilaminocarbonilo, C₁₋₆-alquilsulfonilamino, C₁₋₆-alquilamino, di-C₁₋₆-alquilamino, aminosulfonilo, C₁₋₆-alquilaminosulfonilo, di-C₁₋₆-alquilaminosulfonilo, C₁₋₆-alquilsulfoximino, aminotiocarbonilo, C₁₋₆-alquilaminotiocarbonilo, di-C₁₋₆-alquilaminotiocarbonilo, C₃₋₈-cicloalquilamino, C₁₋₆-alquilcarbonilamino, R² representa además un grupo seleccionado de -C(=O)-R⁸ (G1), -C(=S)-R⁸ (G2), -C(=O)-NR¹¹R¹² (G3), -C(=S)-NR¹¹R¹² (G4), -S(O)ₘ-R¹³ (G5), -S=O(=NH)-R¹³ (G6), -S=O(=N-CN)-R¹³ (G7), -S(=N-CN)-R¹³ (G8), -S(O)₂-NR¹¹R¹² (G9), -NR¹¹R¹² (G10), -NR¹¹-NR¹¹R¹² (G11), -NR¹¹-C(=O)-R⁸ (G12), -NR¹¹-C(=S)-R⁸ (G13), -NR¹¹-S(O)₂-R¹³ (G14),-N(R¹¹)-O-R¹³ (G15), -N=S(=O)ₚ-R¹⁴R¹⁵ (G16), -O-R¹³ (G17), -CR¹¹=N-OR¹³ (G18) o -CR¹¹=CR⁸R¹² G(19), en el que si R² representa G5, G6, G7, G8, G9, entonces n es 2; R³ representa hidrógeno, ciano, halógeno, nitro, acetil, hidroxi, amino, SCN, tri-C₁₋₆-alquilsililo, C₃₋₈-cicloalquilo, C₃₋₈-cicloalquilo-C₃₋₈-cicloalquilo, C₁₋₆-alquilo-C₃₋₈-cicloalquilo, halógeno-C₃₋₈-cicloalquilo, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-cianoalquilo, C₁₋₆-hidroxialquilo, hidroxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-cianoalquenilo, C₂₋₆-alquinilo, C₂₋₆-haloalquinilo, C₂₋₆-cianoalquinilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₁₋₆-cianoalcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, C₁₋₆-alquilhidroxiimino, C₁₋₆-alcoxiimino, C₁₋₆-alquilo-C₁₋₆-alcoxiimino, C₁₋₆-haloalquilo-C₁₋₆-alcoxiimino, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, C₁₋₆-alcoxi-C₁₋₆-alquiltio, C₁₋₆-alquiltio-C₁₋₆-alquilo, C₁₋₆-alquilsulfinilo, C₁₋₆-haloalquilsulfinilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfinilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfonilo, C₁₋₆-haloalquilsulfonilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfonilo, C₁₋₆-alquilsulfonilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfoniloxi, C₁₋₆-alquilcarbonilo, C₁₋₆-alquiltiocarbonilo, C₁₋₆-haloalquilcarbonilo, C₁₋₆-alquilcarboniloxi, C₁₋₆-alcoxicarbonilo, C₁₋₆-haloalcoxicarbonilo, aminocarbonilo, C₁₋₆-alquilaminocarbonilo, C₁₋₆-alquilaminotiocarbonilo, di-C₁₋₆-alquilaminocarbonilo, di-C₁₋₆-alquilaminotiocarbonilo, C₂₋₆-alquenilaminocarbonilo, di-C₂₋₆-alquenilaminocarbonilo, C₃₋₈-cicloalquilaminocarbonilo, C₁₋₆-alquilsulfonilamino, C₁₋₆-alquilamino, di-C₁₋₆-alquilamino, aminosulfonilo, C₁₋₆-alquilaminosulfonilo, di-C₁₋₆-alquilaminosulfonilo, C₁₋₆-alquilsulfoximino, aminotiocarbonilo, C₁₋₆-alquilaminotiocarbonilo, di-C₁₋₆-alquilaminotiocarbonilo, C₃₋₈-cicloalquilamino, NHCO-C₁₋₆-alquilo (C₁₋₆-alquilcarbonilamino), representa en cada caso opcionalmente en forma simple o múltiple, idéntico o distinto, en forma independiente arilo o heteroarilo sustituido, donde (en el caso de heteroarilo) opcionalmente puede contener al menos un grupo carbonilo y/o donde se consideran como sustituyentes: ciano, carboxilo, halógeno, nitro, acetil, hidroxi, amino, SCN, tri-C₁₋₆-alquilsililo, C₃₋₈-cicloalquilo, C₃₋₈-cicloalquilo-C₃₋₈-cicloalquilo, C₁₋₆-alquilo-C₃₋₈-cicloalquilo, halógeno-C₃₋₈-cicloalquilo, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-cianoalquilo, C₁₋₆-hidroxialquilo, hidroxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-cianoalquenilo, C₂₋₆-alquinilo, C₂₋₆-haloalquinilo, C₂₋₆-cianoalquinilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₁₋₆-cianoalcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, C₁₋₆-alquilhidroxiimino, C₁₋₆-alcoxiimino, C₁₋₆-alquilo-C₁₋₆-alcoxiimino, C₁₋₆-haloalquilo-C₁₋₆-alcoxiimino, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, C₁₋₆-alcoxi-C₁₋₆-alquiltio, C₁₋₆-alquiltio-C₁₋₆-alquilo, C₁₋₆-alquilsulfinilo, C₁₋₆-haloalquilsulfinilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfinilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfonilo, C₁₋₆-haloalquilsulfonilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfonilo, C₁₋₆-alquilsulfonilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfoniloxi, C₁₋₆-alquilcarbonilo, C₁₋₆-haloalquilcarbonilo, C₁₋₆-alquilcarboniloxi, C₁₋₆-alcoxicarbonilo, C₁₋₆-haloalcoxicarbonilo, aminocarbonilo, C₁₋₆-alquilaminocarbonilo, di-C₁₋₆-alquilaminocarbonilo, C₂₋₆-alquenilaminocarbonilo, di-C₂₋₆-alquenilaminocarbonilo, C₃₋₈-cicloalquilaminocarbonilo, C₁₋₆-alquilsulfonilamino, C₁₋₆-alquilamino, di-C₁₋₆-alquilamino, aminosulfonilo, C₁₋₆-alquilaminosulfonilo, di-C₁₋₆-alquilaminosulfonilo, C₁₋₆-alquilsulfoximino, aminotiocarbonilo, C₁₋₆-alquilaminotiocarbonilo, di-C₁₋₆-alquilaminotiocarbonilo, C₃₋₈-cicloalquilamino, C₁₋₆-alquilcarbonilamino; R⁴ representa hidrógeno, ciano, halógeno, nitro, acetil, hidroxi, amino, SCN, tri-C₁₋₆-alquilsililo, C₃₋₈-cicloalquilo, C₃₋₈-cicloalquilo-C₃₋₈-cicloalquilo, C₁₋₆-alquilo-C₃₋₈-cicloalquilo, halógeno C₃₋₈-cicloalquilo, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-cianoalquilo, C₁₋₆-hidroxialquilo, hidroxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-cianoalquenilo, C₂₋₆-alquinilo, C₂₋₆-haloalquinilo, C₂₋₆-cianoalquinilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₁₋₆-cianoalcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, C₁₋₆-alquilhidroxiimino, C₁₋₆-alcoxiimino, C₁₋₆-alquilo-C₁₋₆-alcoxiimino, C₁₋₆-haloalquilo-C₁₋₆-alcoxiimino, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, C₁₋₆-alcoxi-C₁₋₆-alquiltio, C₁₋₆-alquiltio-C₁₋₆-alquilo, C₁₋₆-alquilsulfinilo, C₁₋₆-haloalquilsulfinilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfinilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfonilo, C₁₋₆-haloalquilsulfonilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfonilo, C₁₋₆-alquilsulfonilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfoniloxi, C₁₋₆-alquilcarbonilo, C₁₋₆-alquiltiocarbonilo, C₁₋₆-haloalquilcarbonilo, C₁₋₆-alquilcarboniloxi, C₁₋₆-alcoxicarbonilo, C₁₋₆-haloalcoxicarbonilo, aminocarbonilo, C₁₋₆-alquilaminocarbonilo, C₁₋₆-alquilaminotiocarbonilo, di-C₁₋₆-alquilaminocarbonilo, di-C₁₋₆-alquilaminotiocarbonilo, C₂₋₆-alquenilaminocarbonilo, di-C₂₋₆-alquenilaminocarbonilo, C₃₋₈-cicloalquilaminocarbonilo, C₁₋₆-alquilsulfonilamino, C₁₋₆-alquilamino, di-C₁₋₆-alquilamino, aminosulfonilo, C₁₋₆-alquilaminosulfonilo, di-C₁₋₆-alquilaminosulfonilo, C₁₋₆-alquilsulfoximino, aminotiocarbonilo, C₁₋₆-alquilaminotiocarbonilo, di-C₁₋₆-alquilaminotiocarbonilo, C₃₋₈-cicloalquilamino, -NHCO-C₁₋₆-alquilo (C₁₋₆-alquilcarbonilamino); X representa un sistema de anillos condensados, bi- o tricíclicos, parcialmente saturado o saturado, heterocíclico o heteroaromático de 8, 9 10, 11 ó 12 miembros, que puede contener al menos un grupo carbonilo y/o donde el sistema de anillos opcionalmente pueden estar sustituidos en forma simple o múltiple, idéntico o distinto y donde los sustituyentes pueden ser seleccionados independientemente de hidrógeno, ciano, halógeno, nitro, acetil, hidroxi, amino, SCN, tri-C₁₋₆-alquilsililo, C₃₋₈-cicloalquilo, C₃₋₈-cicloalquilo-C₃₋₈-cicloalquilo, C₁₋₆-alquilo-C₃₋₈-cicloalquilo, halógeno-C₃₋₈-cicloalquilo, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-cianoalquilo, C₁₋₆-hidroxialquilo, hidroxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-haloalquenilo, C₂₋₆-cianoalquenilo, C₂₋₆-alquinilo, C₂₋₆-alquiniloxi-C₁₋₄-alquilo, C₂₋₆-haloalquinilo, C₂₋₆-cianoalquinilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi, C₁₋₆-haloalcoxi-C₁₋₆-alquilo, C₂₋₆-alqueniloxi-C₁₋₆-alquilo, C₂₋₆-haloalqueniloxi-C₁₋₆-alquilo, C₁₋₆-cianoalcoxi, C₁₋₆-alcoxicarbonilo-C₁₋₆-alcoxi, C₁₋₆-alcoxi-C₁₋₆-alcoxi, C₁₋₆-alquilhidroxiimino, C₁₋₆-alcoxiimino, C₁₋₆-alquilo-C₁₋₆-alcoxiimino, C₁₋₆-haloalquilo-C₁₋₆-alcoxiimino, C₁₋₆-alquiltio, C₁₋₆-haloalquiltio, C₁₋₆-alcoxi-C₁₋₆-alquiltio, C₁₋₆-alquiltio-C₁₋₆-alquilo, C₁₋₆-alquilsulfinilo, C₁₋₆-haloalquilsulfinilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfinilo, C₁₋₆-alquilsulfinilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfonilo, C₁₋₆-haloalquilsulfonilo, C₁₋₆-alcoxi-C₁₋₆-alquilsulfonilo, C₁₋₆-alquilsulfonilo-C₁₋₆-alquilo, C₁₋₆-alquilsulfoniloxi, C₁₋₆-alquilcarbonilo, C₁₋₆-alquilcarbonilo-C₁₋₆-alquilo, C₁₋₆-alquiltiocarbonilo, C₁₋₆-haloalquilcarbonilo, C₁₋₆-alquilcarboniloxi, C₁₋₆-alcoxicarbonilo, C₁₋₆-haloalcoxicarbonilo, aminocarbonilo, C₁₋₆-alquilaminocarbonilo, C₁₋₆-alquilaminotiocarbonilo, di-C₁₋₆-alquilaminocarbonilo, di-C₁₋₆-alquilaminotiocarbonilo, C₂₋₆-alquenilaminocarbonilo, di-C₂₋₆-alquenilaminocarbonilo, C₃₋₈-cicloalquilaminocarbonilo, C₁₋₆-alquilsulfonilamino, C₁₋₆-alquilamino, di-C₁₋₆-alquilamino, aminosulfonilo, C₁₋₆-alquilaminosulfonilo, di-C₁₋₆-alquilaminosulfonilo, C₁₋₆-alquilsulfoximino, aminotiocarbonilo, C₁₋₆-alquilaminotiocarbonilo, di-C₁₋₆-alquilaminotiocarbonilo, C₃₋₈-cicloalquilamino, NHCO-C₁₋₆-alquilo (C₁₋₆-alquilcarbonilamino), o donde los sustituyentes pueden ser seleccionados independientemente de fenilo o un anillo heteroaromático de 5 ó 6 miembros, en el que fenilo o el anillo opcionalmente pueden estar sustituidos en forma simple o múltiple, idéntico o distinto por C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₆-cicloalquilo, C₁₋₆-haloalquilo, C₂₋₆-haloalquenilo, C₂₋₆-haloalquinilo, C₃₋₆-halocicloalquilo, halógeno, CN, NO₂, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, donde X no representa el compuesto de fórmula (2); R⁸ representa hidrógeno o representa en cada caso opcionalmente sustituido en forma simple o múltiple, idéntico o distinto amino, C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₁₋₄-alcoxi, C₃₋₁₂-cicloalquilo, C₃₋₁₂-cicloalquilo-C₁₋₆-alquilo o C₄₋₁₂-bicicloalquilo, donde los sustituyentes pueden ser seleccionados independientemente de halógeno, ciano, nitro, hidroxi, C₁₋₆-alquilo, C₃₋₆-cicloalquilo, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, C₁₋₄-alquiltio, C₁₋₄-alquilsulfinilo, C₁₋₄-alquilsulfonilo, C₁₋₄-alquilsulfimino, C₁₋₄-alquilsulfimino-C₁₋₄-alquilo, C₁₋₄-alquilsulfimino-C₂₋₅-alquilcarbonilo, C₁₋₄-alquilsulfoximino, C₁₋₄-alquilsulfoximino-C₁₋₄-alquilo, C₁₋₄-alquilsulfoximino-C₂₋₅-alquilcarbonilo, C₂₋₆-alcoxicarbonilo, C₂₋₆-alquilcarbonilo, C₃₋₆-trialquilsililo, amino, C₁₋₄-alquilamino, di-(C₁₋₄-alquilo)amino, C₃₋₆-cicloalquilamino, de un anillo fenilo o un heterociclo aromático de 3 a 6 miembros parcialmente saturado o saturado, donde el anillo fenilo o el heterociclo en cada caso opcionalmente pueden estar sustituidos en forma simple o múltiple, idéntico o distinto, y los sustituyentes pueden ser seleccionados independientemente de C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₆-cicloalquilo, C₁₋₆-haloalquilo, C₂₋₆-haloalquenilo, C₂₋₆-haloalquinilo, C₃₋₆-halocicloalquilo, halógeno, CN, (C=O)OH, CONH₂, NO₂, OH, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, C₁₋₄-alquiltio, C₁₋₄-alquilsulfinilo, C₁₋₄-alquilsulfonilo, C₁₋₄-haloalquiltio, C₁₋₄-haloalquilsulfinilo, C₁₋₄-haloalquilsulfonilo, C₁₋₄-alquilamino, di-(C₁₋₄-alquilo)amino, C₃₋₆-cicloalquilamino, (C₁₋₆-alquilo)carbonilo, (C₁₋₆-alcoxi)carbonilo, (C₁₋₆-alquilo)aminocarbonilo, di-(C₁₋₄-alquilo)aminocarbonilo, tri-C₁₋₂-alquilsililo, (C₁₋₄-alquilo)(C₁₋₄-alcoxi)imino, o R⁸ representa un anillo fenilo o un heterociclo aromático de 3 a 6 miembros, parcialmente saturado o saturado, donde los heteroátomos son seleccionados de la serie N, S, O, donde el anillo fenilo o el heterociclo respectivamente pueden estar sustituidos opcionalmente en cada caso en forma simple o múltiple, idéntico o distinto y donde los sustituyentes pueden ser seleccionados independientemente de C₁₋₆-alquilo, C₂₋₆-alquenilo, C₂₋₆-alquinilo, C₃₋₆-cicloalquilo, C₁₋₆-haloalquilo, C₂₋₆-haloalquenilo, C₂₋₆-haloalquinilo, C₃₋₆-halocicloalquilo, halógeno, CN, (C=O)OH, CONH₂, NO₂, OH, C₁₋₄-alcoxi, C₁₋₄-haloalcoxi, C₁₋₄-alquiltio, C₁₋₄-alquilsulfinilo, C₁₋₄-alquilsulfonilo, C₁₋₄-haloalquiltio, C₁₋₄-haloalquilsulfinilo, C₁₋₄-haloalquilsulfonilo, C₁₋₄-alquilamino, di-(C₁₋₄-alquilo)amino, C₃₋₆-cicloalquilamino, (C₁₋₆-alquilo)carbonilo, (C₁₋₆-alcoxi)carbonilo, (C₁₋₆-alquilo)aminocarbonilo, di-(C₁₋₄-alquilo)aminocarbonilo, tri-C₁₋₂-alquilsililo, (C₁₋₄-alquilo)(C₁₋₄-alcoxi)imino; R¹³, R¹⁴, R¹⁵ representan independientemente en cada caso opcio
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