AR105360A1 - Hidrazidas de ácido carboxílico heteroarilo sustituidas o sus sales y su uso para aumentar la tolerancia al estrés en plantas - Google Patents
Hidrazidas de ácido carboxílico heteroarilo sustituidas o sus sales y su uso para aumentar la tolerancia al estrés en plantasInfo
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- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
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- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
- C07D285/06—1,2,3-Thiadiazoles; Hydrogenated 1,2,3-thiadiazoles
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- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
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- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
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Abstract
Para aumentar la tolerancia al estrés abiótico, así como para aumentar el crecimiento de las plantas y/o para aumentar el rendimiento de la planta. Reivindicación 1: Hidrazidas de ácido carboxílico heteroarilo sustituidas de la formula general (1) o sales de los mismos, donde R¹, R² y R⁷ son independientemente hidrógeno, halógeno, ciano, nitro, NR²¹R²², OR²³, S(O)ₙR²⁴, tiocianato, isotiocianato, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, pentafluortio, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, C₁₋₈-haloalcoxi-C₁₋₈-haloalquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, C₁₋₈-alquilcarbonilo-C₁₋₈-alquilo, COOR²³, CONR²¹R²², COR²³, -C=NOR²³, R²¹R²²N-C₁₋₈-alquilo, R²³OOC-C₁₋₈-alquilo, arilo-C₁₋₈-alquinilo, heteroarilo-C₁₋₈-alquinilo, heterociclilo-C₁₋₈-alquinilo, tris-[C₁₋₈-alquilo]sililC₂₋₈-alquinilo, bis-[C₁₋₈-alquilo](aril)sililC₂₋₈-alquinilo, bis-aril[C₁₋₈-alquilo]sililC₂₋₈-alquinilo, C₃₋₈-cicloalquilo-C₂₋₈-alquinilo, arilo-C₂₋₈-alquenilo, heteroarilo-C₂₋₈-alquenilo, heterociclilo-C₂₋₈-alquenilo, C₃₋₈-cicloalquilo-C₂₋₈-alquenilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquilaminosulfonilamino, C₃₋₈-cicloalquilamino sulfonilamino, diazo, diazo arilo, tris-[C₁₋₈-alquilo]sililo, bis-[C₁₋₈-alquilo](aril)silil, bis-aril[C₁₋₈-alquilo]silil; X¹, X² y X³ son iguales o diferentes y representan independientemente O (oxígeno), S (azufre), N (nitrógeno), la agrupación C-R² o la agrupación N-R²⁰, sin embargo en ningún caso un átomo O y un átomo S son adyacentes y en ningún caso uno o mas átomos O ó átomos S está contenido en el anillo formado de 5 miembros y donde R² en la agrupación C-R² y R²⁰ en la agrupación N-R²⁰ tienen significados idénticos o diferentes según se define anteriormente o a continuación; W es O (oxígeno) o S (azufre); A¹, A², A³, A⁴ y A⁵ son iguales o diferentes y representan independientemente N (nitrógeno) o la agrupación C-R⁷, sin embargo en ningún caso más de dos átomos N son adyacentes, y en el que R⁷ en la agrupación C-R⁷ tiene los mismos o diferentes significados respectivamente según la definición anterior; R³ representa C₁₋₈-alquilo, ciano-C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, R²¹R²²N-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo; R⁴ representa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, C₁₋₈-alquilamino-C₁₋₈-alquilo, bis-[C₁₋₈-alquilo]amino-C₁₋₈-alquilo, C₃₋₈-cicloalquilamino-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, COR²³, C₁₋₈-alcoxicarbonilo, C₂₋₈-alqueniloxicarbonilo, C₂₋₈-alquiniloxicarbonilo, arilo-C₁₋₈-alcoxicarbonilo, heteroarilo-C₁₋₈-alcoxicarbonilo, C₃₋₈-cicloalquilo-C₁₋₈-alcoxicarbonilo, CONR²¹R²², SO₂R²⁴, hidroxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alqueniloxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alquiniloxicarbonilo-C₁₋₈-alquilo, arilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, heteroarilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, heterociclilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alquilcarbonilo-C₁₋₈-alquilo, C₁₋₈-alquilsulfonilo-C₁₋₈-alquilo, C₁₋₈-alquilsulfinilo-C₁₋₈-alquilo; R⁵ y R⁶ representan independientemente hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, COOR²³, CONR²¹R²², hidroxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alqueniloxicarbonilo-C₁₋₈-alquilo, C₂₋₈-alquiniloxicarbonilo-C₁₋₈-alquilo, arilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, heteroarilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, heterociclilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo; R³ y R⁴ junto con el átomo de nitrógeno al que están unidos forman un anillo de 3 a 7 miembros totalmente saturado, parcialmente saturado o totalmente insaturado, opcionalmente interrumpido por heteroátomos y opcionalmente adicionalmente sustituido; R¹ y X¹, si X¹ representa un grupo C-R², forman un anillo de 5 - 7 miembros opcionalmente sustituido, totalmente saturado, parcialmente saturado o totalmente insaturado, opcionalmente interrumpido por heteroátomos, con los átomos a los que están unidos; X¹ y X², si ambos representan un grupo C-R², forman un anillo de 5 - 7 miembros opcionalmente sustituido, totalmente saturado, parcialmente saturado o totalmente insaturado, opcionalmente interrumpido por heteroátomos, con los átomos a los que están unidos; A¹ y A², si ambos representan un grupo C-R⁷, forman un anillo de 5 - 7 miembros opcionalmente sustituido, totalmente saturado, parcialmente saturado o totalmente insaturado, opcionalmente interrumpido por heteroátomos, con los átomos a los que están unidos; A² y A³, si ambos representan un grupo C-R⁷, forman un anillo de 5 - 7 miembros opcionalmente sustituido, totalmente saturado, parcialmente saturado o totalmente insaturado, opcionalmente interrumpido por heteroátomos, con los átomos a los que están unidos; y A³ y A⁴, si ambos representan un grupo C-R⁷, forman un anillo de 5 - 7 miembros opcionalmente sustituido, totalmente saturado, parcialmente saturado o totalmente insaturado, opcionalmente interrumpido por heteroátomos, con los átomos a los que están unidos; Y es un enlace o representa los grupos Y-1 a Y-7 del grupo de fórmulas (2), en el que R⁸, R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷, R¹⁸ y R¹⁹ tiene cada uno el significado que se define a continuación y en el que la flecha representa un enlace del anillo de 6 miembros con los grupos A¹, A², A³, A⁴ y A⁵; R⁸ R⁹, R¹⁰, R¹¹, R¹², R¹³, R¹⁴, R¹⁵ R¹⁶, R¹⁷ R¹⁸ y R¹⁹ representan independientemente hidrógeno, halógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, COOR²³; R⁵ y R⁶ junto con el átomo al que están unidos forman un anillo de 5 a 7 miembros totalmente saturado o parcialmente saturado, opcionalmente interrumpido por heteroátomos y opcionalmente adicionalmente sustituido; R²⁰ representa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₄₋₁₀-cicloalquenilo, C₁₋₈-alcoxi, arilo, heteroarilo, heterociclilo, C₁₋₈-alquilcarbonilo, arilo-C₁₋₈-alquilcarbonilo, C₃₋₈-cicloalquilcarbonilo, arilcarbonilo, heteroarilcarbonilo, C₁₋₈-alcoxicarbonilo, C₂₋₈-alqueniloxicarbonilo, arilo-C₁₋₈-alcoxicarbonilo, heteroarilo-C₁₋₈-alcoxicarbonilo, C₃₋₈-cicloalquilo-C₁₋₈-alcoxicarbonilo, C₁₋₈-alquilsulfonilo, C₁₋₈-haloalquilsulfonilo, arilsulfonilo, heteroarilsulfonilo, C₃₋₈-cicloalquilsulfonilo, C₁₋₈-alquilsulfinilo, arilsulfinilo, heteroarilsulfinilo, C₃₋₈-cicloalquilsulfinilo; n es 0, 1 ó 2; R²¹ y R²² son iguales o diferentes y representan independientemente hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenilo-C₁₋₈-alquilo, COR²³, SO₂-R²⁴, C₁₋₈-alquilo-HNO₂S-, C₃₋₈-cicloalquilo-HNO₂S-, heterociclilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo, arilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, arilo-C₁₋₈-alcoxicarbonilo, heteroarilo-C₁₋₈-alcoxicarbonilo, C₂₋₈-alqueniloxicarbonilo, C₂₋₈-alquiniloxicarbonilo, heterociclilo-C₁₋₈-alquilo; R²³ representa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenilo-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo,C₂₋₈-alqueniloxicarbonilo-C₁₋₈-alquilo, arilo-C₁₋₈-alcoxicarbonilo-C₁₋₈-alquilo, hidroxicarbonilo-C₁₋₈-alquilo, heterociclilo, heterociclilo-C₁₋₈-alquilo; y R²⁴ representa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₂₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, arilo-C₁₋₈-alquilo, heteroarilo, heteroarilo-C₁₋₈-alquilo, heterociclilo-C₁₋₈-alquilo, C₃₋₈-cicloalquilo-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenilo-C₁₋₈-alquilo, NR²¹R²².
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