AR084143A1 - Procesos para preparar composiciones de polimeros a base de etileno - Google Patents
Procesos para preparar composiciones de polimeros a base de etilenoInfo
- Publication number
- AR084143A1 AR084143A1 ARP110104523A ARP110104523A AR084143A1 AR 084143 A1 AR084143 A1 AR 084143A1 AR P110104523 A ARP110104523 A AR P110104523A AR P110104523 A ARP110104523 A AR P110104523A AR 084143 A1 AR084143 A1 AR 084143A1
- Authority
- AR
- Argentina
- Prior art keywords
- ethylene
- based polymers
- processes
- prepare compositions
- polymerize
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/34—Per-compounds with one peroxy-radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/60003—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/60168—Tetra- or multi-dentate ligand
- C08F4/60186—Dianionic ligand
- C08F4/60193—OOOO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/62003—Refractory metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/62168—Tetra- or multi-dentate ligand
- C08F4/62186—Dianionic ligand
- C08F4/62193—OOOO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/04—Philipps catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Abstract
La presente provee un proceso para formar una composición de polímeros basados en etileno, comprendiendo el proceso por lo menos lo siguiente: paso 1: polimerizar un primer polímero basado en etileno en la presencia de por lo menos un catalizador molecular y de un agente de transferencia de cadenas de hidrocarburos, y bajo una presión de polimerización de por lo menos 14.000 psi; paso 2: polimerizar un segundo polímero basado en etileno.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41956010P | 2010-12-03 | 2010-12-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR084143A1 true AR084143A1 (es) | 2013-04-24 |
Family
ID=45218882
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP110104523A AR084143A1 (es) | 2010-12-03 | 2011-12-02 | Procesos para preparar composiciones de polimeros a base de etileno |
Country Status (11)
Country | Link |
---|---|
US (1) | US9045628B2 (es) |
EP (2) | EP2813545A1 (es) |
JP (1) | JP6031042B2 (es) |
KR (1) | KR101869997B1 (es) |
CN (1) | CN103339186B (es) |
AR (1) | AR084143A1 (es) |
BR (1) | BR112013013634B1 (es) |
CA (1) | CA2819467C (es) |
ES (1) | ES2524430T3 (es) |
SG (1) | SG190985A1 (es) |
WO (1) | WO2012074812A1 (es) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL2576690T3 (pl) * | 2010-05-28 | 2019-01-31 | Basell Polyolefine Gmbh | Kompozycja polietylenowa |
CN103781806B (zh) | 2011-07-05 | 2017-06-23 | 陶氏环球技术有限责任公司 | 基于乙烯的聚合物和制备它的方法 |
WO2013169359A1 (en) * | 2012-05-09 | 2013-11-14 | Dow Global Technologies Llc | Polyolefin polymerization process, semi-crystalline ethylene-based polymer made therefrom, and articles made from the polymer |
EP2855541B1 (en) * | 2012-06-01 | 2016-04-27 | Dow Global Technologies LLC | Free-radical processes to make ethylene-based polymers using alklyated phenols |
US9751998B2 (en) | 2012-12-27 | 2017-09-05 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
BR112015015550B1 (pt) * | 2012-12-27 | 2021-05-11 | Dow Global Technologies Llc | processo de polimerização para a produção de polímeros a base de etileno |
EP2938648B1 (en) * | 2012-12-27 | 2019-01-30 | Dow Global Technologies LLC | A polymerization process for producing ethylene based polymers |
CN113201084A (zh) | 2013-06-28 | 2021-08-03 | 陶氏环球技术有限责任公司 | 使用卤化双苯基苯氧基催化剂控制聚烯烃的分子量 |
CN105793296A (zh) | 2013-12-19 | 2016-07-20 | 陶氏环球技术有限责任公司 | 用c-c引发剂减黏裂化丙烯类聚合物的方法 |
CN106459258B (zh) | 2014-05-09 | 2020-07-24 | 陶氏环球技术有限责任公司 | 利用烃引发剂制备乙烯类聚合物的方法 |
SG11201705082YA (en) | 2014-12-23 | 2017-07-28 | Dow Global Technologies Llc | Process for preparing a modified ethylene-based polymer using a hydrocarbon initiator |
KR101679515B1 (ko) * | 2015-02-12 | 2016-11-24 | 주식회사 엘지화학 | 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계 |
CN107735414A (zh) * | 2015-06-22 | 2018-02-23 | 陶氏环球技术有限责任公司 | 使用碳‑碳自由基引发剂制备基于乙烯的聚合物的方法 |
EP3317312B1 (en) | 2015-06-30 | 2020-06-10 | Dow Global Technologies LLC | A polymerization process for producing ethylene based polymers |
ES2785628T3 (es) | 2015-06-30 | 2020-10-07 | Dow Global Technologies Llc | Un proceso de polimerización para producir polímeros basados en etileno |
CN108350121B (zh) | 2015-09-30 | 2021-10-01 | 陶氏环球技术有限责任公司 | 主催化剂和使用其的聚合方法 |
US10647797B2 (en) | 2015-09-30 | 2020-05-12 | Dow Global Technologies Llc | Polymerization process for producing ethylene based polymers |
EP3408307A1 (en) | 2016-01-28 | 2018-12-05 | Dow Global Technologies, LLC | Process for producing functionalized ethylene-based polymers with a low gel content |
ES2970349T3 (es) | 2016-10-18 | 2024-05-28 | Dow Global Technologies Llc | Composiciones y estructuras de fundas extensibles multicapa |
CN111164110A (zh) | 2017-09-29 | 2020-05-15 | 陶氏环球技术有限责任公司 | 在金属上具有烷氧基或酰胺基配体的用于改进溶解度的双-苯基-苯氧基聚烯烃催化剂 |
ES2911503T3 (es) | 2017-09-29 | 2022-05-19 | Dow Global Technologies Llc | Catalizadores de bis-fenil-fenoxi-poliolefina que tienen un ligando de metilentrialquilsilicio en el metal para mejorar la solubilidad |
ES2967951T3 (es) | 2017-09-29 | 2024-05-06 | Dow Global Technologies Llc | Catalizadores de bis-fenil fenoxi poliolefina que tienen dos ligandos de metilentrialquilsilicio en el metal para mejorar la solubilidad |
US20230132152A1 (en) * | 2020-05-29 | 2023-04-27 | Dow Global Technologies Llc | Attenuated post-metallocene catalysts |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1205635A (en) * | 1967-05-12 | 1970-09-16 | Ici Ltd | Polymerisation of ethylene |
FR2519007B1 (fr) * | 1981-12-24 | 1985-12-27 | Charbonnages Ste Chimique | Copolymeres modifies de l'ethylene et d'au moins une a-olefine et procede pour leur preparation |
JPS5922910A (ja) * | 1982-07-29 | 1984-02-06 | Sumitomo Chem Co Ltd | エチレン重合体またはエチレン共重合体の製造方法 |
US5084534A (en) | 1987-06-04 | 1992-01-28 | Exxon Chemical Patents, Inc. | High pressure, high temperature polymerization of ethylene |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
GB9103527D0 (en) * | 1991-02-20 | 1991-04-10 | Exxon Chemical Patents Inc | Hp catalyst killer |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
KR100253826B1 (ko) | 1991-12-30 | 2000-04-15 | 그레이스 스티븐 에스. | 에틸렌 공중합체의 중합방법 |
US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
ZA94612B (en) | 1993-01-29 | 1995-07-28 | Dow Chemical Co | Ethylene interpolymerization |
GB9319340D0 (en) * | 1993-09-17 | 1993-11-03 | Exxon Chemical Patents Inc | Olefin polymersisation process |
US5616664A (en) * | 1994-08-02 | 1997-04-01 | The Dow Chemical Company | Polymerization process with biscyclopentadienyl diene complex containing catalysts |
IT1275777B1 (it) | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
ES2237911T3 (es) * | 1998-03-04 | 2005-08-01 | Exxonmobil Chemical Patents Inc. | Aniones no coordinantes para polimerizacion de olefinas. |
US6869904B2 (en) | 2002-04-24 | 2005-03-22 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
JP4158424B2 (ja) * | 2002-06-04 | 2008-10-01 | 東ソー株式会社 | エチレン系重合体およびその製造方法 |
JP5507048B2 (ja) * | 2004-11-02 | 2014-05-28 | ダウ グローバル テクノロジーズ エルエルシー | 低密度ポリエチレン組成物の生成方法およびこれから生成されたポリマー |
WO2007075299A2 (en) * | 2005-12-16 | 2007-07-05 | Dow Global Technologies Inc. | Polydentate heteroatom ligand containing metal complexes, catalysts and methods of making and using the same |
KR101401785B1 (ko) * | 2006-05-17 | 2014-05-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/α-올레핀/디엔 용액 중합 방법 |
KR101141494B1 (ko) * | 2007-09-05 | 2012-05-03 | 에스케이이노베이션 주식회사 | 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법 |
US8202958B2 (en) | 2008-03-13 | 2012-06-19 | Dow Global Technologies Llc | Long chain branched (LCB), block or interconnected copolymers of ethylene in combination with one other polymer |
WO2010141557A1 (en) | 2009-06-05 | 2010-12-09 | Dow Global Technologies Inc. | Process to make long chain branched (lcb), block, or interconnected copolymers of ethylene |
US8722817B2 (en) * | 2009-06-05 | 2014-05-13 | Dow Global Technologies Llc | Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene |
WO2011032174A1 (en) | 2009-09-14 | 2011-03-17 | Dow Global Technologies Inc. | Polymers comprising units derived from ethylene and poly(alkoxide) |
WO2011032172A1 (en) | 2009-09-14 | 2011-03-17 | Dow Global Technologies Inc. | Polymers comprising units derived from ethylene and siloxane |
BR112012005109A2 (pt) | 2009-09-14 | 2023-04-25 | Dow Global Technologies Llc | Polímero compreendendo unidades derivadas de etileno e polialquileno, composição e artigo |
US8440772B2 (en) * | 2011-04-28 | 2013-05-14 | Chevron Phillips Chemical Company Lp | Methods for terminating olefin polymerizations |
-
2011
- 2011-11-21 WO PCT/US2011/061622 patent/WO2012074812A1/en active Application Filing
- 2011-11-21 CN CN201180066451.XA patent/CN103339186B/zh not_active Expired - Fee Related
- 2011-11-21 CA CA2819467A patent/CA2819467C/en active Active
- 2011-11-21 SG SG2013042882A patent/SG190985A1/en unknown
- 2011-11-21 BR BR112013013634-0A patent/BR112013013634B1/pt not_active IP Right Cessation
- 2011-11-21 EP EP14180705.7A patent/EP2813545A1/en not_active Withdrawn
- 2011-11-21 KR KR1020137017253A patent/KR101869997B1/ko active IP Right Grant
- 2011-11-21 US US13/990,061 patent/US9045628B2/en active Active
- 2011-11-21 JP JP2013542049A patent/JP6031042B2/ja not_active Expired - Fee Related
- 2011-11-21 ES ES11793922.3T patent/ES2524430T3/es active Active
- 2011-11-21 EP EP11793922.3A patent/EP2646508B1/en active Active
- 2011-12-02 AR ARP110104523A patent/AR084143A1/es not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
BR112013013634A2 (pt) | 2016-09-13 |
EP2646508B1 (en) | 2014-10-01 |
CN103339186A (zh) | 2013-10-02 |
EP2646508A1 (en) | 2013-10-09 |
CN103339186B (zh) | 2016-03-30 |
US9045628B2 (en) | 2015-06-02 |
EP2813545A1 (en) | 2014-12-17 |
SG190985A1 (en) | 2013-07-31 |
KR101869997B1 (ko) | 2018-06-22 |
CA2819467C (en) | 2019-06-18 |
US20130253126A1 (en) | 2013-09-26 |
CA2819467A1 (en) | 2012-06-07 |
JP2013544940A (ja) | 2013-12-19 |
JP6031042B2 (ja) | 2016-11-24 |
ES2524430T3 (es) | 2014-12-09 |
KR20130122960A (ko) | 2013-11-11 |
BR112013013634B1 (pt) | 2020-11-10 |
WO2012074812A1 (en) | 2012-06-07 |
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