AR045964A1 - Procedimiento para producir 1,3-propanodiol mediante hidrogenacion catalitica de 3-hidroxipropanal en presencia de un co-catalizador de hidratacion - Google Patents

Procedimiento para producir 1,3-propanodiol mediante hidrogenacion catalitica de 3-hidroxipropanal en presencia de un co-catalizador de hidratacion

Info

Publication number
AR045964A1
AR045964A1 ARP040103605A ARP040103605A AR045964A1 AR 045964 A1 AR045964 A1 AR 045964A1 AR P040103605 A ARP040103605 A AR P040103605A AR P040103605 A ARP040103605 A AR P040103605A AR 045964 A1 AR045964 A1 AR 045964A1
Authority
AR
Argentina
Prior art keywords
hydrogenation
propanediol
catalyst
hydroxypropanal
stages
Prior art date
Application number
ARP040103605A
Other languages
English (en)
Inventor
Glenn Charles Komplin
Joseph Broun Powell
Paul Richard Weider
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of AR045964A1 publication Critical patent/AR045964A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un procedimiento para preparar 1,3-propanodiol que comprende las etapas de : (a) preparar una mezcla acuosa de 3-hidroxipropanal y derivados de reacción, (b) pasar dicha mezcla acuosa de 3-hidroxipropanal a una zona de hidrogenación, en donde la zona de hidrogenación comprende al menos dos etapas en las cuales en la primer etapa la hidrogenación se lleva a cabo en condiciones de hidrogenación a una temperatura en la gama de 50 a 130sC en presencia de un catalizador de hidrogenación de lecho fijo o lechada, y en donde se agrega o está presente un co-catalizador ácido en al menos una de las últimas etapas, y la hidrogenación en dichas últimas etapas se lleva a cabo en condiciones de hidrogenación a una temperatura más alta que la de la primera etapa de hidrogenación y en la gama de 70 a 155sC, lo que forma una solución acuosa de 1,3- propanodiol; y (c) recuperar tal 1,3-propanodiol. Reivindicación 1: Un procedimiento para preparar 1,3-propanodiol mediante la hidrogenación de 3- hidroxipropanal que comprende las etapas de: (a) preparar una mezcla acuosa de 3-hidroxipropanal; (b) pasar la mezcla acuosa de 3-hidroxipropanal a una zona de hidrogenación, en donde la zona de hidrogenación comprende al menos dos etapas en las cuales en la primer etapa la hidrogenación se lleva a cabo en condiciones de hidrogenación a una temperatura en la gama de 50 a 130sC en presencia de un catalizador de hidrogenación de lecho fijo o lechada, y en donde se agrega o está presente un co- catalizador ácido, que se selecciona del grupo consistente en zeolitas ácidas, resinas de intercambio catiónico en forma ácida, óxidos de metal ácidos o anfóteros, heteropoliácidos, y ácidos solubles, en al menos una de las últimas etapas, y la hidrogenación en dichas últimas etapas se lleva a cabo en condiciones de hidrogenación a una temperatura más alta que la de la primera etapa de hidrogenación y en la gama de 70 a 155sC, lo que forma una solución acuosa de 1,3-propanodiol; y (c) recuperar tal 1,3-propanodiol.
ARP040103605A 2003-10-07 2004-10-05 Procedimiento para producir 1,3-propanodiol mediante hidrogenacion catalitica de 3-hidroxipropanal en presencia de un co-catalizador de hidratacion AR045964A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US50976603P 2003-10-07 2003-10-07

Publications (1)

Publication Number Publication Date
AR045964A1 true AR045964A1 (es) 2005-11-16

Family

ID=34465113

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP040103605A AR045964A1 (es) 2003-10-07 2004-10-05 Procedimiento para producir 1,3-propanodiol mediante hidrogenacion catalitica de 3-hidroxipropanal en presencia de un co-catalizador de hidratacion

Country Status (14)

Country Link
US (1) US7329785B2 (es)
EP (1) EP1682472A1 (es)
JP (1) JP2007507545A (es)
KR (1) KR20060103504A (es)
CN (1) CN100448825C (es)
AR (1) AR045964A1 (es)
BR (1) BRPI0415104A (es)
CA (1) CA2542950A1 (es)
MX (1) MXPA06003819A (es)
MY (1) MY138726A (es)
RU (1) RU2351581C2 (es)
SA (1) SA04250328B1 (es)
TW (1) TW200523236A (es)
WO (1) WO2005037749A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200700152A (en) * 2005-04-21 2007-01-01 Shell Int Research Hydrogenation catalyst and hydrogenation method
KR20080112373A (ko) * 2006-04-13 2008-12-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 알데하이드의 수소화 방법
WO2008122029A1 (en) * 2007-04-02 2008-10-09 Inventure Chemical, Inc. Simultaneous esterification and alcohol ysis/hydrolysis of oil-containing materials with cellulosic and peptidic content
US7943792B2 (en) * 2007-04-02 2011-05-17 Inventure Chemical Inc. Production of biodiesel, cellulosic sugars, and peptides from the simultaneous esterification and alcoholysis/hydrolysis of materials with oil-containing substituents including phospholipids and peptidic content
US20090054702A1 (en) * 2007-06-04 2009-02-26 Joseph Broun Powell Hydrogenation process
US7777085B2 (en) * 2008-10-01 2010-08-17 Inventure Chemical, Inc. Method for conversion of oil-containing algae to 1,3-propanediol
CN103333055B (zh) 2013-06-09 2015-03-18 北京东方红升新能源应用技术研究院有限公司 一种浆态床催化加氢精制聚甲醛二烷基醚的方法
RU2737159C2 (ru) 2016-01-07 2020-11-25 Хальдор Топсёэ А/С Способ получения этиленгликоля из сахаров
AU2017205691B2 (en) * 2016-01-07 2021-06-17 Haldor Topsøe A/S Process for the preparation of ethylene glycol from sugars
CN112920016B (zh) * 2021-01-27 2022-07-08 浙江恒逸石化研究院有限公司 一种1,3-丙二醇粗产品溶液的制备装置及方法

Family Cites Families (20)

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US4401834A (en) 1982-06-01 1983-08-30 Exxon Research & Engineering Co. Process for producing alcohols
US4876402A (en) 1986-11-03 1989-10-24 Union Carbide Chemicals And Plastics Company Inc. Improved aldehyde hydrogenation process
DE3926136A1 (de) 1989-08-08 1991-02-14 Degussa Verfahren zur herstellung von 1,3-propandiol
US5093537A (en) 1991-07-24 1992-03-03 Hoechst Celanese Corporation Method for the manufacture of 1,3-propanediol
DE4132663C2 (de) 1991-10-01 1993-10-14 Degussa Verfahren zum Herstellen von 1,3-Propandiol durch Hydrieren von Hydroxypropionaldehyd
DE4138982A1 (de) * 1991-11-27 1993-06-03 Degussa Verfahren zur herstellung von 3-hydroxyalkanalen
DE4218282A1 (de) 1992-06-03 1993-12-09 Degussa Verfahren zur Herstellung von 1,3-Propandiol
DE4222708A1 (de) * 1992-07-10 1994-01-13 Degussa Verfahren zur Herstellung von 1,3-Propandiol
US5304691A (en) 1993-07-13 1994-04-19 Shell Oil Company Process for making 1,3-propanediol and 3-hydroxypropanal
US5256827A (en) 1993-02-05 1993-10-26 Shell Oil Company Process for making 3-hydroxypropanal and 1,3-propanediol
US5344993A (en) 1993-10-01 1994-09-06 Shell Oil Company Process or making 3-hydroxyaldehydes
US5585528A (en) 1994-09-30 1996-12-17 Shell Oil Company Cobalt-catalyzed process for preparing 1,3-propanediol using a lipophilic tertiary amine promoter
EP0906258B1 (en) 1996-05-30 2002-03-13 Shell Internationale Researchmaatschappij B.V. Process for preparing 1,3-alkanediols
US5786524A (en) 1996-05-30 1998-07-28 Shell Oil Company Process for preparation of 1,3-propanediol via hydrogenation of 3-hydroxypropanal
CA2291037A1 (en) 1997-06-18 1998-12-23 E.I. Du Pont De Nemours And Company Process for the production of 1,3-propanediol by hydrogenating 3 -hydroxypropionaldehyde
KR20010073116A (ko) * 1998-09-04 2001-07-31 메리 이. 보울러 3-히드록시프로판알의 촉매적 수소 첨가 반응에 의한1,3-프로판디올의 2-단계 제조 방법
US5945570A (en) 1998-10-29 1999-08-31 Arhancet; Juan Pedro Catalyst and process for preparing 1,3-propanediol
US6693222B2 (en) * 2002-02-12 2004-02-17 E. I. Du Pont De Nemours And Company Process for splitting water-soluble ethers
US6972346B2 (en) * 2002-11-01 2005-12-06 Shell Oil Company Solid acid catalyzed reactive stripping of impurities formed during the production of 1, 3-propanediol
US6969779B2 (en) * 2002-11-01 2005-11-29 Shell Oil Company Method for removal of MW176 cyclic acetal formed during the production of 1,3-propanediol

Also Published As

Publication number Publication date
US7329785B2 (en) 2008-02-12
KR20060103504A (ko) 2006-10-02
CA2542950A1 (en) 2005-04-28
EP1682472A1 (en) 2006-07-26
US20050080300A1 (en) 2005-04-14
SA04250328B1 (ar) 2009-02-01
RU2351581C2 (ru) 2009-04-10
TW200523236A (en) 2005-07-16
CN1874980A (zh) 2006-12-06
JP2007507545A (ja) 2007-03-29
RU2006115593A (ru) 2007-11-20
CN100448825C (zh) 2009-01-07
WO2005037749A1 (en) 2005-04-28
BRPI0415104A (pt) 2006-11-28
MXPA06003819A (es) 2006-08-11
MY138726A (en) 2009-07-31

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