AR015979A1 - Catalizador de acetato de vinilo que comprende paladio, oro y cualquiera de ciertos metales terciarios. - Google Patents
Catalizador de acetato de vinilo que comprende paladio, oro y cualquiera de ciertos metales terciarios.Info
- Publication number
- AR015979A1 AR015979A1 ARP980105282A ARP980105282A AR015979A1 AR 015979 A1 AR015979 A1 AR 015979A1 AR P980105282 A ARP980105282 A AR P980105282A AR P980105282 A ARP980105282 A AR P980105282A AR 015979 A1 AR015979 A1 AR 015979A1
- Authority
- AR
- Argentina
- Prior art keywords
- gold
- metal
- palladium
- oxide
- solution
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un catalizador que comprende un soporte poroso sobre cuyas superficies porosas se depositan cantidades catalíticamente efectivas de paladio metálico y oroy un metal terciario seleccionado del grupo que consiste en magnesio, calcio, bario zirconio yc erio, como su oxido o mezcla de oxido y metal habiendo sidopreparado dicho catalizador por ya sea el método (A) que comprende impregnar un soporte poroso con una solucion acuosa de sales solubles en agua de paladio ydicho metal terciario, fijardicho paladio y metal terciario como compuestos insolubles en agua mediante la reaccion con un compuesto alcalino apropiado,posteriormente impregnar el catalizador con una solucion de una sal de oro soluble en agua, fijar el oro en la solucionpresente en la ultima impregnacion comoun compuesto insoluble en agua mediante la reaccion con un compuesto alcalino apropiado, y reducir el oro y el paladio fijados a su estado metálico y el metalterciario fijado a su oxido o mezcla de oxido y sumetal; o el m étodo (B) que comprende los pasos de impregnar el soporte con una solucion de sales solubles enagua de paladio, oro y dicho metal terciario, fijar el paladio, el oro y el metal terciario en la ultima solucion como compuestos insolublesen agua por me diosque incluyen el paso de rotar y/o revolver en tambor el soporte impregnado mientras que se sumerge en una solucion de un compuesto alcalino apropiado, yreducir el paladio y el oro fijos a su estado metálico y el metal terciario asu oxido o mezcl a de oxido y su metal.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/960,888 US5859287A (en) | 1997-10-30 | 1997-10-30 | Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals |
Publications (1)
Publication Number | Publication Date |
---|---|
AR015979A1 true AR015979A1 (es) | 2001-05-30 |
Family
ID=25503765
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP980105282A AR015979A1 (es) | 1997-10-30 | 1998-10-22 | Catalizador de acetato de vinilo que comprende paladio, oro y cualquiera de ciertos metales terciarios. |
ARP990103312A AR019907A2 (es) | 1997-10-30 | 1999-07-07 | Proceso para la produccion de acetato de vinilo mediante la reaccion de etileno, oxigeno y acido acetico como reactivos. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP990103312A AR019907A2 (es) | 1997-10-30 | 1999-07-07 | Proceso para la produccion de acetato de vinilo mediante la reaccion de etileno, oxigeno y acido acetico como reactivos. |
Country Status (30)
Country | Link |
---|---|
US (1) | US5859287A (es) |
EP (2) | EP1044067B1 (es) |
JP (2) | JP4906187B2 (es) |
KR (2) | KR100579351B1 (es) |
CN (1) | CN1104952C (es) |
AR (2) | AR015979A1 (es) |
AT (1) | ATE275000T1 (es) |
AU (1) | AU734360B2 (es) |
BR (1) | BR9813299B1 (es) |
CA (1) | CA2306788C (es) |
CZ (1) | CZ300008B6 (es) |
DE (1) | DE69826031T2 (es) |
ES (1) | ES2227889T3 (es) |
HU (1) | HUP0004382A2 (es) |
ID (1) | ID24489A (es) |
MY (1) | MY127878A (es) |
NO (1) | NO321475B1 (es) |
NZ (1) | NZ504032A (es) |
PE (1) | PE56399A1 (es) |
PL (2) | PL209621B1 (es) |
RU (1) | RU2216402C2 (es) |
SA (1) | SA98190674B1 (es) |
SG (1) | SG106071A1 (es) |
SK (1) | SK5902000A3 (es) |
TR (2) | TR200103086T2 (es) |
TW (1) | TWI239949B (es) |
UA (1) | UA66814C2 (es) |
WO (1) | WO1999022863A2 (es) |
YU (1) | YU49186B (es) |
ZA (1) | ZA989630B (es) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5859287A (en) * | 1997-10-30 | 1999-01-12 | Celanese International Corporation | Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals |
GB9817365D0 (en) * | 1998-08-11 | 1998-10-07 | Bp Chem Int Ltd | Process for the production of vinyl acetate |
US6358882B1 (en) | 1998-12-08 | 2002-03-19 | The Standard Oil Company | Fluid bed vinyl acetate catalyst |
US6013834A (en) * | 1999-03-04 | 2000-01-11 | Celanese International Corporation | Production of vinyl acetate in a catalytic reactor equipped with filter and distribution bed |
US20030039659A1 (en) * | 1999-09-24 | 2003-02-27 | Mccormick Alison A. | Self antigen vaccines for treating B cell lymphomas and other cancers |
US6303537B1 (en) * | 1999-11-17 | 2001-10-16 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication |
TW201236754A (en) * | 2003-12-19 | 2012-09-16 | Celanese Int Corp | Zirconia containing support materials for catalysts |
BRPI0518825A2 (pt) * | 2004-12-20 | 2008-12-09 | Celanese Int Corp | materias de suporte modificados para catalisadores |
US8227369B2 (en) * | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
JP4964170B2 (ja) * | 2007-04-09 | 2012-06-27 | 昭和電工株式会社 | 酢酸アルケニル製造用触媒の製造方法 |
DE102007047430A1 (de) * | 2007-10-04 | 2009-04-09 | Evonik Degussa Gmbh | Katalysator |
DE102008059342A1 (de) * | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung |
JP2011121048A (ja) * | 2009-12-09 | 2011-06-23 | Rohm & Haas Co | 固体触媒物質をブレンドし、管状構造物に装填する方法 |
US8273682B2 (en) * | 2009-12-16 | 2012-09-25 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalyst |
US8329611B2 (en) | 2009-12-16 | 2012-12-11 | Lyondell Chemical Technology, L,P. | Titania-containing extrudate |
US8507720B2 (en) * | 2010-01-29 | 2013-08-13 | Lyondell Chemical Technology, L.P. | Titania-alumina supported palladium catalyst |
CN117567273A (zh) * | 2018-07-27 | 2024-02-20 | 株式会社可乐丽 | 1,3-双酰氧基-2-亚甲基丙烷的制造方法 |
KR20200116730A (ko) | 2019-04-02 | 2020-10-13 | 최미순 | 미량의 과산화수소수의 농도를 측정하는 장치 및 방법 |
US11607656B2 (en) * | 2019-12-16 | 2023-03-21 | Showa Denko K.K. | Fixed-bed multi-tubular reactor for producing alkenyl acetate |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH534005A (de) * | 1968-02-01 | 1973-02-28 | Bayer Ag | Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators |
DE4120492A1 (de) * | 1991-06-21 | 1992-12-24 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
TW213869B (es) * | 1991-06-21 | 1993-10-01 | Hoechst Ag | |
US5332710A (en) * | 1992-10-14 | 1994-07-26 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
US5314858A (en) * | 1992-10-14 | 1994-05-24 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
CA2135021A1 (en) * | 1993-11-19 | 1995-05-20 | David J. Gulliver | Process for the preparation of catalysts for use in the production of vinyl acetate |
US5466652A (en) * | 1994-02-22 | 1995-11-14 | The Standard Oil Co. | Process for the preparation of vinyl acetate catalyst |
DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
IN188013B (es) * | 1995-05-23 | 2002-08-10 | Hoechst Celanese Corp | |
WO1997038790A1 (en) * | 1996-04-16 | 1997-10-23 | Hoechst Celanese Corporation | A two step gold addition method for preparing a vinyl acetate catalyst |
US5859287A (en) * | 1997-10-30 | 1999-01-12 | Celanese International Corporation | Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals |
-
1997
- 1997-10-30 US US08/960,888 patent/US5859287A/en not_active Expired - Lifetime
-
1998
- 1998-10-12 CA CA002306788A patent/CA2306788C/en not_active Expired - Fee Related
- 1998-10-12 EP EP98954958A patent/EP1044067B1/en not_active Expired - Lifetime
- 1998-10-12 HU HU0004382A patent/HUP0004382A2/hu unknown
- 1998-10-12 UA UA2000042450A patent/UA66814C2/uk unknown
- 1998-10-12 RU RU2000113735/04A patent/RU2216402C2/ru not_active IP Right Cessation
- 1998-10-12 KR KR1020057015041A patent/KR100579351B1/ko not_active IP Right Cessation
- 1998-10-12 PL PL377992A patent/PL209621B1/pl not_active IP Right Cessation
- 1998-10-12 JP JP2000518784A patent/JP4906187B2/ja not_active Expired - Fee Related
- 1998-10-12 AU AU11874/99A patent/AU734360B2/en not_active Ceased
- 1998-10-12 TR TR2001/03086T patent/TR200103086T2/xx unknown
- 1998-10-12 NZ NZ504032A patent/NZ504032A/xx not_active IP Right Cessation
- 1998-10-12 AT AT98954958T patent/ATE275000T1/de active
- 1998-10-12 BR BRPI9813299-7A patent/BR9813299B1/pt not_active IP Right Cessation
- 1998-10-12 TR TR2000/01181T patent/TR200001181T2/xx unknown
- 1998-10-12 PL PL340627A patent/PL194845B1/pl not_active IP Right Cessation
- 1998-10-12 CN CN98810744A patent/CN1104952C/zh not_active Expired - Fee Related
- 1998-10-12 CZ CZ20001580A patent/CZ300008B6/cs not_active IP Right Cessation
- 1998-10-12 EP EP02076572A patent/EP1230977A3/en not_active Ceased
- 1998-10-12 SK SK590-2000A patent/SK5902000A3/sk unknown
- 1998-10-12 SG SG200202564A patent/SG106071A1/en unknown
- 1998-10-12 KR KR1020007004701A patent/KR100577508B1/ko not_active IP Right Cessation
- 1998-10-12 ES ES98954958T patent/ES2227889T3/es not_active Expired - Lifetime
- 1998-10-12 WO PCT/US1998/021546 patent/WO1999022863A2/en active Application Filing
- 1998-10-12 ID IDW20000678A patent/ID24489A/id unknown
- 1998-10-12 DE DE69826031T patent/DE69826031T2/de not_active Expired - Lifetime
- 1998-10-14 TW TW087117072A patent/TWI239949B/zh not_active IP Right Cessation
- 1998-10-22 AR ARP980105282A patent/AR015979A1/es active IP Right Grant
- 1998-10-22 ZA ZA9809630A patent/ZA989630B/xx unknown
- 1998-10-28 SA SA98190674A patent/SA98190674B1/ar unknown
- 1998-10-29 MY MYPI98004940A patent/MY127878A/en unknown
- 1998-10-30 PE PE1998001026A patent/PE56399A1/es not_active Application Discontinuation
- 1998-10-30 YU YU48098A patent/YU49186B/sh unknown
-
1999
- 1999-07-07 AR ARP990103312A patent/AR019907A2/es active IP Right Grant
-
2000
- 2000-04-28 NO NO20002233A patent/NO321475B1/no not_active IP Right Cessation
-
2008
- 2008-12-18 JP JP2008322989A patent/JP4975721B2/ja not_active Expired - Fee Related
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Legal Events
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