ZA201400863B - Process for the preparation of formic acid by reacting carbon dioxide with hydrogen - Google Patents

Process for the preparation of formic acid by reacting carbon dioxide with hydrogen

Info

Publication number
ZA201400863B
ZA201400863B ZA2014/00863A ZA201400863A ZA201400863B ZA 201400863 B ZA201400863 B ZA 201400863B ZA 2014/00863 A ZA2014/00863 A ZA 2014/00863A ZA 201400863 A ZA201400863 A ZA 201400863A ZA 201400863 B ZA201400863 B ZA 201400863B
Authority
ZA
South Africa
Prior art keywords
hydrogen
preparation
carbon dioxide
formic acid
reacting carbon
Prior art date
Application number
ZA2014/00863A
Inventor
Rocco Paciello
Donata Maria Fries
Martin Schäfer
Thomas Schaub
Stefan Rittinger
Peter Bassler
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of ZA201400863B publication Critical patent/ZA201400863B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
ZA2014/00863A 2011-07-07 2014-02-05 Process for the preparation of formic acid by reacting carbon dioxide with hydrogen ZA201400863B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11173130 2011-07-07
PCT/EP2012/062518 WO2013004577A1 (en) 2011-07-07 2012-06-27 Process for the preparation of formic acid by reacting carbon dioxide with hydrogen

Publications (1)

Publication Number Publication Date
ZA201400863B true ZA201400863B (en) 2015-12-23

Family

ID=46397263

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA2014/00863A ZA201400863B (en) 2011-07-07 2014-02-05 Process for the preparation of formic acid by reacting carbon dioxide with hydrogen

Country Status (9)

Country Link
EP (1) EP2729438A1 (en)
JP (1) JP2014522823A (en)
KR (1) KR20140044891A (en)
CN (1) CN103649036A (en)
BR (1) BR112013033528A2 (en)
CA (1) CA2838907A1 (en)
RU (1) RU2014104137A (en)
WO (1) WO2013004577A1 (en)
ZA (1) ZA201400863B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8946462B2 (en) 2011-11-10 2015-02-03 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US9428438B2 (en) 2012-11-27 2016-08-30 Basf Se Process for preparing formic acid
EP3710420A4 (en) * 2017-11-15 2021-08-04 Solvay SA Process for producing formic acid
EP4089177A1 (en) 2021-05-14 2022-11-16 Cebal - Centro De Biotecnologia Agrícola E Agro-Alimentar Do Alentejo Process for the production of formic acid using e. coli strains
CN117138775B (en) * 2023-07-24 2024-04-30 昆明贵金属研究所 Catalytic system for preparing formic acid by catalyzing carbon dioxide hydrogenation under alkali-free condition

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474959A (en) 1982-05-22 1984-10-02 Bp Chemicals Limited Production of formate salts from carbon dioxide, hydrogen and amines
GB8307611D0 (en) 1983-03-18 1983-04-27 Bp Chem Int Ltd Formic acid
GB8401005D0 (en) 1984-01-14 1984-02-15 Bp Chem Int Ltd Formate salts
GB8424672D0 (en) * 1984-09-29 1984-11-07 Bp Chem Int Ltd Production of formic acid
NZ227890A (en) * 1988-02-17 1992-02-25 Bp Chemical Ltd Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen
DE68920933T2 (en) * 1988-08-20 1995-05-24 Bp Chem Int Ltd Production of formate salts from nitrogen bases.
DE102004040789A1 (en) * 2004-08-23 2006-03-02 Basf Ag Process for the preparation of formic acid
BRPI0809156A2 (en) * 2007-03-23 2014-09-16 Basf Se PROCESS FOR PREPARING FORMIC ACID.
UA104324C2 (en) * 2009-06-26 2014-01-27 Басф Се Method for producing formic acid
CA2765430A1 (en) 2009-06-26 2010-12-29 Basf Se Method for producing formic acid

Also Published As

Publication number Publication date
BR112013033528A2 (en) 2017-02-07
RU2014104137A (en) 2015-08-20
EP2729438A1 (en) 2014-05-14
WO2013004577A1 (en) 2013-01-10
KR20140044891A (en) 2014-04-15
CA2838907A1 (en) 2013-01-10
CN103649036A (en) 2014-03-19
JP2014522823A (en) 2014-09-08

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