ZA200600185B - Mounting mat for a catalytic converter - Google Patents
Mounting mat for a catalytic converter Download PDFInfo
- Publication number
- ZA200600185B ZA200600185B ZA200600185A ZA200600185A ZA200600185B ZA 200600185 B ZA200600185 B ZA 200600185B ZA 200600185 A ZA200600185 A ZA 200600185A ZA 200600185 A ZA200600185 A ZA 200600185A ZA 200600185 B ZA200600185 B ZA 200600185B
- Authority
- ZA
- South Africa
- Prior art keywords
- pollution control
- mounting mat
- fibers
- layer
- mat
- Prior art date
Links
- 230000003197 catalytic effect Effects 0.000 title description 13
- 239000000835 fiber Substances 0.000 claims abstract description 109
- 239000003365 glass fiber Substances 0.000 claims abstract description 56
- 239000000919 ceramic Substances 0.000 claims abstract description 54
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 22
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 20
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 20
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011777 magnesium Substances 0.000 claims abstract description 19
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 19
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000003980 solgel method Methods 0.000 claims abstract description 18
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- 239000011521 glass Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000395 magnesium oxide Substances 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 241000206607 Porphyra umbilicalis Species 0.000 claims 1
- 210000004027 cell Anatomy 0.000 claims 1
- 210000002421 cell wall Anatomy 0.000 claims 1
- 239000010410 layer Substances 0.000 description 67
- 238000012360 testing method Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000292 calcium oxide Substances 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 4
- 238000004080 punching Methods 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 229910052878 cordierite Inorganic materials 0.000 description 2
- 229910002106 crystalline ceramic Inorganic materials 0.000 description 2
- 239000011222 crystalline ceramic Substances 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 229910052574 oxide ceramic Inorganic materials 0.000 description 2
- 239000011224 oxide ceramic Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- -1 zirconium diacetate Chemical class 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- TZONKZYJDZZXHR-UHFFFAOYSA-L [Cl-].[Cl-].CCCCCCCCCCCCc1cc(C[N+](C)(C)C)c(C)c(C[N+](C)(C)C)c1 Chemical compound [Cl-].[Cl-].CCCCCCCCCCCCc1cc(C[N+](C)(C)C)c(C)c(C[N+](C)(C)C)c1 TZONKZYJDZZXHR-UHFFFAOYSA-L 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- HZVVJJIYJKGMFL-UHFFFAOYSA-N almasilate Chemical compound O.[Mg+2].[Al+3].[Al+3].O[Si](O)=O.O[Si](O)=O HZVVJJIYJKGMFL-UHFFFAOYSA-N 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 235000004879 dioscorea Nutrition 0.000 description 1
- 239000002355 dual-layer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Chemical compound CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical class [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
- JINJMFAIGCWUDW-UHFFFAOYSA-L zirconium(2+);diacetate Chemical compound [Zr+2].CC([O-])=O.CC([O-])=O JINJMFAIGCWUDW-UHFFFAOYSA-L 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2853—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
- F01N3/2864—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing the mats or gaskets comprising two or more insulation layers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2853—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2350/00—Arrangements for fitting catalyst support or particle filter element in the housing
- F01N2350/02—Fitting ceramic monoliths in a metallic housing
- F01N2350/04—Fitting ceramic monoliths in a metallic housing with means compensating thermal expansion
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
- Catalysts (AREA)
Abstract
The present invention provides a mounting mat for mounting a pollution control monolith in a pollution control device. The mounting mat has a bulk density of 0.12 to 0.3 g/cm<3> and comprises (i) a layer of chopped magnesium aluminium silicate glass fibers and (ii) a layer of ceramic fibers obtainable from a sol-gel process. Preferably, the layer of chopped magnesium aluminium silicate glass fibers and the layer of ceramic fibers define opposite major surfaces of the mat. The present invention further provides a pollution control device comprising a pollution control monolith arranged in a metallic casing with the mounting mat disposed between the metallic casing and pollution control monolith. <IMAGE>
Description
MOUNTING MAT FOR A CATALYTIC CONVERTER
The present invention relates to a mounting mat for mounting a pollution control monolith in a pollution control device. In particular the present invention relates to a mounting mat that is comprised of a layer of glass fibers and a layer of ceramic fibers obtainable from a sol-gel process. The invention further relates to a pollution control device.
Pollution control devices are universally employed on motor vehicles to control atmospheric pollution. Two types of devices are currently in widespread use - catalytic converters and diesel particulate filters or traps. Catalytic converters contain a catalyst, which is typically coated on a monolithic structure mounted within a metallic housing.
The monolithic structures are typically ceramic, although metal monoliths have also been used. The catalyst oxidizes carbon monoxide and hydrocarbons and reduces the oxides of nitrogen in automobile exhaust gases to control atmospheric pollution.
Diesel particulate filters or traps are typically wall flow filters, which have honeycombed, monolithic structures typically made from porous crystalline ceramic materials. Alternate cells of the honeycombed structure are typically plugged such that exhaust gas enters in one cell and is forced through the porous wall to an adjacent cell where it can exit the structure. In this way, the small soot particles that are present in diesel exhaust gas are collected.
The monoliths and in particular the ceramic pollution control monoliths, used in pollution control devices are fragile and susceptible to vibration or shock damage and breakage. They have a coefficient of thermal expansion generally an order of magnitude less than the metal housing which contains them. This means that as the pollution control device is heated the gap between the inside peripheral wall of the housing and the outer wall of the monolith increases. Even though the metallic housing undergoes a smaller temperature change due to the insulating effect of the mat, the higher coefficient of thermal expansion of the metallic housing causes the housing to expand to a larger peripheral size faster than the expansion of the monolithic element. Such thermal cycling occurs hundreds of times during the life and use of the pollution control device.
To avoid damage to the ceramic monoliths from for example road shock and vibrations, to compensate for the thermal expansion difference, and to prevent exhaust gases from passing between the monolith and metal housing (thereby bypassing the catalyst), mounting mats are disposed between the ceramic monolith and the metal housing. These mats must exert sufficient pressure to hold the monolith in place over the desired temperature range but not so much pressure as to damage the ceramic monolith.
Recently, there has been a trend towards increasing the number of cells that make up the pollution control monolith per unit area and reducing the wall thickness of the cells.
Such pollution control monoliths are known as thin wall or ultra-thin wall monoliths and typically have between 400 and 1200 cells per square inch (cpsi) and a wall thickness of not more than 5 mils, i.e., 0.005 inch (0.127 mm). Because of the reduced wall thickness, these monoliths are even more susceptible to damage and accordingly, the mounting mats for mounting such monoliths are subject to more stringent requirements.
Many mounting mats have been described in the art. Known mounting mats include intumescent sheet materials comprised of ceramic fibers, intumescent materials and organic and/or inorganic binders. Intumescent sheet materials useful for mounting a catalytic converter in a housing are described in, for example, U.S. Patent Nos. 3,916,057 (Hatch et al.), 4,305,992 (Langer et al.) 5,151,253 (Merry et al.) 5,250,269 (Langer) and 5,736,109 (Howorth et al.). Intumescent mounting mats have the disadvantage that they may exert too much pressure on the pollution control monolith during use when the pollution control monolith heats up. As a result, intumescent mounting mats are less suitable for mounting thin wall and ultra-thin wall monoliths.
U.S. Patent No. 5,290,522 describes a catalytic converter having a non-woven, mounting mat comprising at least 60 % by weight shot-free high strength magnesium aluminosilicate glass fibers having a diameter greater than 5 micrometers. Such mounting mat may however not have sufficient holding strength to satisfactorily mount thin wall and ultra-thin wall monoliths at high temperature and protect them against shock and damage.
U.S. Patent No. 5,380,580 discloses a non-woven mat of physically entangled shot- free ceramic oxide fibers. The mat is taught to be useful as filter medium, mounting mat and sound or thermal insulation. In one of the examples, a non-woven mat is disclosed that comprises a layer of a polycrystalline ceramic fiber and a layer of glass fiber. The mat is apparently meant for thermal insulation and would not be readily suitable as a mounting mat for mounting a pollution control monolith in a pollution control device. Also, there is no teaching as to how such a bilayer mat is to be used as a mounting mat.
Non-intumescent mats comprised of polycrystalline ceramic fibers and binder have been proposed for mounting so-called ultra thin-wall monoliths. Examples of non- intumescent mats are described in, for example, U.S. Patent. Nos. 4,01 1,651 (Bradbury et al), 4,929,429 (Merry), 5,028,397 (Merry), 5,996,228 (Shoji et al.), and 5,580,532 (Robinson et al.). Polycrystalline fibers are typically formed through a sol-gel process as described in, for example, U.S. Patent No. 3,760,049 whereas other ceramic fibers are typically melt formed. Unfortunately, polycrystalline fibers are much more expensive than melt formed ceramic fibers such as ceramic glass fibers and as a result mounting mats of polycrystalline fibers are often prohibitively expensive.
Accordingly, it is desired to find further mounting mats suitable for mounting pollution control monoliths in a pollution control device and in particular such mounting mats that can be used to mount thin wall or ultra-thin wall monoliths. Preferably such mounting mats provide a good holding force of the monolith particularly at high temperature without exerting too much pressure that could cause damage to the monolith.
Preferably, the mounting mat can be produced at low cost and is preferably also environmentally friendly.
The present invention provides a mounting mat for mounting a pollution control monolith in a pollution control device. The mounting mat has a bulk density of 0.12 to 0.3 g/cm’ and comprises @@) a layer of chopped magnesium aluminium silicate glass fibers and (ii) a layer of ceramic fibers obtainable from a sol-gel process.
Preferably, the layer of chopped magnesium aluminium silicate glass fibers and the layer of ceramic fibers define opposite major surfaces of the mat.
The present invention further provides a pollution control device comprising a pollution control monolith arranged in a metallic casing with a mounting mat disposed between the metallic casing and pollution control monolith. The mounting mat comprises 6) a layer of chopped magnesium aluminium silicate glass fibers and (ii) alayer of ceramic fibers obtainable from a sol-gel process.
The mounting mat is arranged such that the layer of ceramic fibers faces the pollution control monolith. The term “facing” includes embodiments where there are no further layers between the monolith and the ceramic fiber layer of the mat as well as embodiments where one or more further layers are present there between. Such optional layers may or not be part of the mounting mat but when present are preferably not part of the mounting mat, and can include, for example, coatings, scrims, or films aimed at reducing possible skin irritation from the fibers. Also, any such optional layers should be selected such that they do not substantially destroy the advantages of the invention, i.c., the performance of the mounting mat with any such optional layers should be at least 90% of the performance of a similar mat without the optional layer(s).
It was found that the mounting mat according to the invention can be produced at a much lower cost than mounting mats based on a single layer of polycrystalline fibers.
Also, when mounting the pollution control monolith in the pollution control device in such a way that the layer of the ceramic fibers obtainable from a sol-gel process faces the monolith, a sufficient holding force can be maintained both at low and high temperatures and during the cycling between low and high temperature during the life time of the pollution control device that occurs when the pollution control device is used in for example a motor vehicle.
Solely for the purpose of illustration and better understanding of the invention and without the intention to limit the invention in any way thereto, the following drawings are provided:
Figure 1 is a perspective view of a catalytic converter of the present invention shown in disassembled relation.
Figure 2 schematically shows a cross-section of a mounting mat according to the invention.
Detailed Description of the Present Invention
Referring to Fig. 1, pollution control device 10 comprises metallic casing 11 with generally frusto-conical inlet and outlet ends 12 and 13, respectively. Disposed within casing 11 is a pollution control monolith 20. Surrounding pollution control monolith 20 is mounting mat 30 according to the invention and which serves to tightly but resiliently support monolithic element 20 within the casing 11. Mounting mat 30 holds pollution control monolith 20 in place in the casing and seals the gap between the pollution control monolith 20 and casing 11 to thus prevent or minimize exhaust gases from by-passing pollution control monolith 20.
The metallic casing can be made from materials known in the art for such use including stainless steel.
Pollution control monoliths that can be mounted with the mounting mat of the invention include gasoline pollution control monoliths as well as diesel pollution control monoliths. The pollution control monolith may be a catalytic converter or a particulate filter or trap. Catalytic converters contain a catalyst, which is typically coated on a monolithic structure mounted within a metallic housing. The catalyst is typically adapted to be operative and effective at the requisite temperature. For example, for use with a gasoline engine the catalytic converter should be effective at a temperature of 400°C to 950°C, whereas for a diesel engine lower temperatures, typically not more than 350°C are common. The monolithic structures are typically ceramic, although metal monoliths have also been used. The catalyst oxidizes carbon monoxide and hydrocarbons and reduces the oxides of nitrogen in exhaust gases to control atmospheric pollution. While in a gasoline engine all three of these pollutants can be reacted simultaneously in a so-called “three way converter”, most diesel engines are equipped with only a diesel oxidation catalytic converter. Catalytic converters for reducing the oxides of nitrogen, which are only in limited use today for diesel engines, generally consist of a separate catalytic converter.
Examples of pollution control monoliths for use with a gasoline engine include those made of cordierite that are commercially available from Corning Inc. (Corning, N.Y.) or NGK
Insulators, LTD. (Nagoya, Japan) or metal monoliths commercially available from Emitec (Lohmar, Germany).
Diesel particulate filters or traps arc typically wall flow filters, which have honeycombed, monolithic structures typically made from porous crystalline ceramic materials. Alternate cells of the honeycombed structure are typically plugged such that exhaust gas enters in one cell and is forced through the porous wall to an adjacent cell where it can exit the structure. In this way, the small soot particles that are present in diesel exhaust gas are collected. Suitable diesel particulate filters made of cordierite are commercially available from Corning Inc. (Corning N.Y.) and NGK Insulators, Inc. (Nagoya, Japan). Diesel particulate filters made of silicon carbide are commercially available from Ibiden Co. Ltd. (Japan) and are described in, for example,
JP 2002047070A.
The mounting mat of the present invention can be used to mount so-called thin wall or ultra-thin wall pollution control monoliths. In particular, the mounting mat can be used to mount pollution control monoliths that have from 400 to 1200 cpsi and that have wall thickness of not more than 0.005 (0.127 mm). Examples of pollution control monoliths that may be mounted with the mounting mat include thin wall monoliths 4mil/400cpsi and 4mil/600cpsi and ultra-thinwall monoliths 3mil/600cpsi, 2mil/900cpsi and 2mil/1200cpsi.
Figure 2 shows a schernatic cross-section of a mounting mat according to the invention. As can be seen, mounting mat 30 comprises a layer 31 of chopped magnesium aluminium silicate glass fibers and a layer 32 of ceramic fibers that can be obtained from a sol-gel process. When used to mount a pollution control monolith in pollution control devices, the mounting mat 30 is arranged such that layer 32 is closest to the pollution control monolith, i.e., face the pollution control monolith and layer 31 is closest to metallic housing of the pollution control device, i.e., face the latter. Thus, layer 31 defines surface 33 of mounting mat 30 in figure 1 and layer 32 defines the opposite surface (not visible in Fig. 1) of mounting mat 30. It was found that the opposite arrangement in which layer 32 would define the surface 33 of mounting mat 30 does not provide the benefits associated with the invention.
While Fig. 2 shows a configuration of a mounting mat composed of only two layers, it will be understood that the mat may contain further layers. For example, layers of different fiber composition may be included between layers 31 and 32 shown in Fig. 2.
Also, more than one layer of glass fibers can be used whereby the layers may differ for example in the chemical composition of the glass fibers making up the layers and/or the dimensions of the glass fibers making up the composition. Thus, instead of a single layer 31 of glass fibers, two or more layers of glass fibers may be used in combination with layer 32 of ceramic fibers formed from a sol-gel process. For example, the mounting mat may comprise a layer of ceramic fibers formed from a sol-gel process, a glass fiber layer made or S2-glass and a glass fiber layer made of R- or E-glass.
Mounting mat 30 generally has a bulk density, i.c., the density before mounting in the pollution control device, between 0.12 and 0.3g/cm’, preferably between 0.12 and 0.25g/cm’. When mounted the mat typically will have a mount density of 0.2 to 0.6g/cm’, preferably between 0.3 and 0.5g/cm’, i.e., the mat will be compressed when mounted.
The mounting mat will typically be designed such that when mounted, the thickness of the layer of ceramic fibers obtainable from a sol-gel process is at least 0.5mm and preferably at least 0.7mm. However, depending on the nature and type of the pollution control monolith, a smaller thickness is contemplated as well. Generally, however, the thickness of the ceramic fiber layer should be sufficient to thermally insulate the layer of the glass fibers.
The magnesium aluminium silicate glass fibers used in the non-woven mounting mat typically have an average diameter of at least Sum and a length between 0.5 and 15cm, preferably between 1 and 12cm. Preferably, the average diameter will be at least 7um and is typically in the range of 7 to 14 pm. The glass fibers are preferably individualized. To provide individualized (i.e., separate each fiber from each other) fibers, a tow or yarn of fibers can be chopped, for example, using a glass roving cutter (commercially available, for example, under the trade designation “MODEL 90 GLASS ROVING CUTTER?” from
Finn & Fram, Inc., of Pacoma, Calif.), to the desired length (typically in the range from about 0.5 to about 15 cm). The fibers typically are shot free or contain a very low amount of shot, typically less than 1% by weight based on total weight of fibers. Additionally, the fibers are typically reasonably uniform in diameter, i.e. the amount of fibers having a diameter within +/- 3pm of the average is generally at least 70% by weight, preferably at least 80% by weight and most preferably at least 90% by weight of the total weight of the magnesium aluminium silicate glass fibers.
The magnesium aluminium silicate glass fibers preferably comprise between 10 and 30% by weight of aluminium oxide, between 52 and 70% by weight of silicium oxide and between 1 and 12 % of magnesium oxide. The weight percentage of the aforementioned oxides are based on the theoretical amount of Al;Os, SiO; and MgO. It will further be understood that the magnesium aluminium silicate glass fiber may contain additional oxides. For example, additional oxides that may be present include sodium or potassium oxides, boron oxide and calcium oxide. Particular examples of magnesium aluminium silicate glass fibers include E-glass fibers which typically have a composition of about 55% of SiO,, 11% of Al,03, 6% of B,03, 18% of CaO, 5% of MgO and 5% of other oxides; S and S-2 glass fibers which typically have a composition of about 65% of
Si0,, 25% of Al,03 and 10% of MgO and R-glass fibers which typically have a composition of 60% of Si0,, 25% of Al,03, 9% of CaO and 6% of MgO. E-glass, S-glass and S-2 glass are available for example from Advanced Glassfiber Yams LLC and R-glass is available from Saint-Gobain Vetrotex.
The glass fiber layer of the mat may contain up to 10% by weight of fibers other than magnesium aluminium silicate glass fibers. Preferably however, the glass fiber layer will consist of only magnesium aluminium silicate glass fibers. If other fibers are contained in the glass fiber layer, they will typically be amorphous fibers and they should preferably also have an average diameter of at least Sum. Preferably, the glass fiber layer will be free or essentially free of fibers that have a diameter of 3pm or less, more preferably the mat will be free or essentially free of fibers that have a diameter of less than
Sum. Essentially free here means that the amount of such small diameter fibers is not more than 2% by weight, preferably not more than 1% by weight of the total weight of fibers in the glass fiber layer.
The ceramic fiber layer comprises ceramic fibers that are obtained from a sol-gel process. By the term “sol-gel” process is meant that the fibers are formed by spinning or extruding a solution or dispersion or a generally viscous concentrate of the constituting components of the fibers or precursors thereof. The sol-gel process is thus to be contrasted with a process of melt forming fibers whereby the fibers are formed by extruding a melt of the components of the fibers. A suitable sol-gel process is for example disclosed in U.S.
Patent No. 3,760,049 wherein there is taught to form the ceramic fibers by extruding a solution or dispersion of metal compounds through orifices thereby forming continuous green fibers which are then fired to obtain the ceramic fibers. The metal compounds are typically metal compounds that are calcinable to metal oxides. Often the sol-gel formed fibers are crystalline or semicrystalline, which are known in the art as polycrystalline fibers.
Examples of solutions or dispersions of metal compounds to form fibers according to the sol-gel process include aqueous solutions of an oxygen-containing zirconium compounds, such as zirconium diacetate, containing colloidal silica, such as disclosed in
U.S. Patent No. 3,709,706. A further example includes an aqueous solution of water- soluble or dispersible aluminum and boron compounds, such as aqueous basic aluminum acetate, or a two-phase system comprising an aqueous mixture of a colloidal dispersion of silica and water-soluble or dispersible aluminum and boron compounds. Other representative refractory metal oxide fibers which can be made in through a sol-gel process include zirconia, zircon, zirconia-calcia, alumina, magnesium aluminate, aluminum silicate, and the like. Such fibers additionally can contain various metal oxides, such as iron oxide, chromia, and cobalt oxide.
Ceramic fibers which are useful in the ceramic fiber layer of the mounting mat include polycrystalline oxide ceramic fibers such as mullites, alumina, high alumina aluminosilicates, aluminosilicates, zirconia, titania, chromium oxide and the like.
Preferred fibers, which are typically high alumina, crystalline fibers, comprise aluminum oxide in the range from about 67 to about 98 percent by weight and silicon oxide in the range from about 33 to about 2 percent by weight. These fibers are commercially available, for example, under the trade designation “NEXTEL 550” from the 3M
Company, SAFFIL™ available from Dyson Group PLC (Sheffield, UK), MAFTEC available from Mitsubishi Chemical Corp.(Tokyo, Japan), FIBERMAX™ from Unifrax, (Niagara Falls, N.Y), and ALTRA fibers (Rath GmbH, Germany).
Suitable polycrystalline oxide ceramic fibers further include aluminoborosilicate fibers preferably comprising aluminum oxide in the range from about 55 to about
75 percent by weight, silicon oxide in the range from less than about 45 to greater than zero (preferably, less than 44 to greater than zero) percent by weight, and boron oxide in the range from less than 25 to greater than zero (preferably, about 1 to about 5) percent by weight (calculated on a theoretical oxide basis as Al0s, SiOz, and B,0s, respectively).
The aluminoborosilicate fibers preferably are at least 50 percent by weight crystalline, more preferably, at least 75 percent, and most preferably, about 100% (i.e., crystalline fibers). Aluminoborosilicate fibers are commercially available, for example, under the trade designations “NEXTEL 312” and “NEXTEL 440” from the 3M Company.
The ceramic fibers obtainable through a sol-gel process are typically shot free or contain a very low amount of shot, typically less than 1% by weight based on total weight of the ceramic fibers. Also, the ceramic fibers will typically have an average diameter between 1 and 16 micrometers. In a preferred embodiment, the ceramic fibers have an average diameter of Spm or more and preferably the ceramic fibers are free or essentially free of fibers having a diameter of less than 3pm, more preferably the ceramic fiber layer will be free or essentially free of fibers that have a diameter of less than Sum. Essentially free here means that the amount of such small diameter fibers is not more than 2% by weight, preferably not more than 1% by weight of the total weight of fibers in the ceramic fiber layer. Accordingly, in a particularly preferred embodiment of the present invention the ceramic fiber layer and the glass fiber layer and any further optional layers are essentially free of fibers that have a diameter of less than 3pm. The ceramic fibers are generally individualized as described above for the glass fibers.
According to a method for making the nonwoven mat, chopped, individualized fibers (preferably, about 2.5 to about 5 cm in length) are fed into a conventional web- forming machine (commercially available, for example, under the trade designation “RANDO WEBBER” from Rando Machine Corp. of Macedon, N.Y; or “DAN WEB” from ScanWeb Co. of Denmark), wherein the fibers are drawn onto a wire screen or mesh belt (e.g., a metal or nylon belt). If 2 “DAN WEB" -type web-forming machine is used, the fibers are preferably individualized using a hammer mill and then a blower. To facilitate ease of handling of the mat, the mat can be formed on or placed on a scrim. Depending upon the length of the fibers, the resulting mat typically has sufficient handleability to be transferred to a needle punch machine without the need for a support (e.g., 2 scrim).
The nonwoven mat can also be made using conventional wet-forming or textile carding. For wet forming processes, the fiber length is preferably about 0.5 to about 6 cm.
The mounting mat is preferably a needle-punched nonwoven mat. A needle- punched nonwoven mat refers to a mat wherein there is physical entanglement of fibers provided by multiple full or partial (preferably, full) penetration of the mat, for example, by barbed needles. The nonwoven mat can be needle punched using a conventional needle punching apparatus (¢.g., 2 needle puncher commercially available under the trade designation *DILO” from Dilo of Germany, with barbed needles (commercially available, for example, from Foster Needle Company, Inc., of Manitowoc, Wis.)) to provide a needle-punched, nonwoven mat. Needle punching, which provides entanglement of the fibers, typically involves compressing the mat and then punching and drawing barbed needles through the mat. The optimum number of needle punches per area of mat will vary depending on the particular application. Typically, the nonwoven mat is needle punched to provide about 5 to about 60 needle punches/cm?. Preferably, the mat is needle punched to provide about 10 to about 20 needle punches/cm’.
Alternatively the mat can be stitchbonded using conventional techniques (see e.g.,
U.S. Patent No. 4,181,514 (Lefkowitz et al.), the disclosure of which is incorporated herein by reference for its teaching of stitchbonding nonwoven mats). Typically, the mat is stitchbonded with organic thread. A thin layer of an organic or inorganic sheet material can be placed on either or both sides of the mat during stitchbonding to prevent or minimize the threads from cutting through the mat. Where it is desired that the stitching thread not decompose in use, an inorganic thread, such as ceramic or metal (e.g., stainless steel) can be used. The spacing of the stitches is usually from 3 to 30 mm so that the fibers are uniformly compressed throughout the entire area of the mat.
The glass fiber layer and ceramic fiber layer may be separately formed according to the process described above and the so obtained separate needle punched or stitchbonded layers may then be bonded to each other through needle punching or stitchbonding.
Alternatively, a web of the glass fiber layer and ceramic fiber layer may be formed and this web may then be needle punched or stitchbonded to form a non-woven mounting mat.
Accordingly, in the latter configuration, the glass fiber layer and ceramic fiber layer are not separately needle punched or stitchbonded before being bonded to each other.
The invention is further described with reference to the following examples without however the intention to limit the invention thereto.
Materials Used in the Examples and Comparative Examples
A. Mats of ceramic fibers obtainable from a sol-gel process (Polycrystalline fibers)
Al Maftec™ MLS-3 needle-bonded blanket from Mitsubishi Chemical company (72%
Al,Os, 28 % SiO, without binder, bulk density 0.16 glee)
A2 Ibiden™ N4 (72 % ALO, 28 % SiO, with binder, bulk density 0. 18 g/cc)
A3 3M 1101 HT (72 % Al,03, 28 % SiO with binder, bulk density 0.14 g/cc)
A4 3M 1100 HT (96% AlL,0s, 4 % SiO, with binder, bulk density 0.16 g/cc)
AS 3M Nextel™ 312 needle-bonded mat ( 62 % ALOs, 24 % SiO2, 14 % B,0; without binder, bulk density 0.14 g/cc)
B. Glass Fiber Mat
B R Glass fibers were made into a non-woven mat as follows: 40 liters of R glass fibers (typical composition 60 % SiOz, 25 % Aly03, 9 % CaO, and 6 %
MgO) having a diameter of ca. 10 um, chopped to a length of 36 mm, were obtained from
Saint-Gobain Vetrotex Deutschland GmbH, Herzogenrath, Germany. The fibers were essentially shot free.
The glass fibers were opened in a two-zone Laroche opener. The first zone had a feed speed of 2 m/min and a Lickerin roll speed of 2,500 rev/min. The second zone had a feed speed of 4 m/min and a Lickerin roll speed of 2,500 rev/min. The output speed was 6.5 m/min.
The opened fibers were then fed into a conventional web-forming machine (commercially available under the trade designation “Rando Webber” from Rando
Machine Corp. of Macedon, N.Y, wherein the fibers were blown onto a porous metal roll to form a continuous web. The continuous web was then needle-bonded on a conventional needle tacker. The needle speed was 100 cycles/min and the output speed was 1.1 m/min.
The “weight per area” of the mounting mat could be adjusted as desired. The material had a bulk density of approximately 0.12 g/cc.
Test Method — Real Condition Fixture Test (RCFT)
This test models actual conditions found in a pollution control device with a catalyst-coated monolith or diesel particulate filter during typical use, and measures the pressure exerted by the mounting material under those modeled use conditions. The RCFT method is described in detail in Material Aspects in Automotive Pollution Control Devices, ed. Hans Bode, Wiley-VCH, 2002, pp.- 206-208.
Two 50.8 mm by 50.8 mm heated stainless steel platens, controlled independently, were heated to different temperatures to simulate the metal housing and monolith temperatures, respectively. Simultaneously, the space or gap between platens was increased by a value calculated from the temperature and the thermal expansion coefficients of a typical pollution control device of the type specified. High speed driving conditions for the pollution control device are simulated by a monolith temperature of up to 900°C and a metal housing temperature of up to 530°C.
Three cycles of the RCFT were performed on each mounting mat sample. The density of the mat when mounted in the test sample and bulk density before mounting are summarized in Table 2.
The pressure exerted by the mat is measured continuously as temperature of the first and second plates were first increased, held at peak temperature for 15 minutes and then reduced. The plate representing the monolith temperature is heated from room temperature to 900°C, held for 15 seconds, and returned to room temperature.
Simultaneously, the plate representing the shell temperature is heated from room temperature to 530°C, held for 15 seconds, and returned to room temperature. Each of these heating cycles is referred to as one RCFT cycle. After the three RCFT cycles were run, data in Table 2 were recorded..
Pressure was recorded at room temperature at the start of the test as well as pressure at peak temperature (900°C/500°C) for the 1% and 3™ cycles, respectively.
Example 1
The mounting mat of Example 1 consisted of a layer of mat of Al having a bulk density of 0.16 g/cc placed on top of a layer of mat B having a bulk density of 0.12 g/cc.
The combined mat had a bulk density of approximately 0.14 g/cc. See Table 1 below.
The real condition fixture test (RCFT) was conducted by the method described above under Test Method. The two layer mat of Example 1 was tested by placing the polycrystalline fiber layer side of the mat towards the hotter side of the RCFT test assembly and the R glass fiber layer side of the mat towards the cooler side of the RCFT test assembly and compressing the dual layer mat to a mount density of 0.35 g/cc prior to the start of the test. This resulted in a starting pressure at room temperature of 217 kPa.
RCFT results are summarized in Table 2. During the first temperature cycle, the mat showed a pressure of 55 kPa at the peak temperature. During the third temperature cycle, the mat showed a pressure of 43 kPa at the peak temperature. This pressure is such as to hold the monolith in place without crushing it.
Comparative Example 1
Comparative Example 1 comprised a mat having a single layer of needle-bonded, polycrystalline fibers having a composition of 72 % Al,O; and 28 % SiO. The bulk density before testing was approximately 0.16 g/cc. It was compressed to a mount density of 0.35 g/cc prior to the start of the test. This resulted in a starting pressure at room temperature of 257 kPa. RCFT results showed that pressure at peak temperature of the first cycle was 104 kPa. Pressure at peak temperature during the 3" cycle was 88 kPa.
Comparative Example 2
Comparative Example 2 comprised a mat having a single layer of R-Glass fibers having a bulk density of about 0.12 g/cc. It was compressed to a mount density of 0.32 g/cc prior to the start of the test. This resulted in a starting pressure at room temperature of 250 kPa. RCFT results showed that pressure at peak temperature during the first cycle was 10 kPa. Pressure at peak temperature during the 3rd cycle was 0 kPa.
Comparative Example 3
Comparative Example 3 was performed using the mat described in Example 1.
The two layer mat was placed in the test assembly with the R-glass towards the hot side of the RCFT and the polycrystalline fiber layer towards the cool side of the RCFT, an arrangement opposite to that of Example 1. The mat was compressed to a mount density of 0.35 g/cc prior to the start of the test. This resulted in starting pressure at room temperature of 281 kPa.
RCFT data showed that the pressure at peak temperature during the first cycle was 6 kPa The peak pressure at peak temperature during the 3" cycle was 5 kPa.
Comparative Examples 4-7
Comparative Examples 4-7 were conducted using single layers of polycrystalline fibers, respectively, described in detail above under “Materials used in the Examples and
Comparative Examples”.
RCFT results are summarized in Table 2.
Table 1
Mat Constructions i aH al NR 7577 density (g/cm’)
EE]
Densi Denst
EL CL EN Cl
EE EC NN I LLL
EC ON a NO
FC I cl CN Od oe fumes [| [ome we eee || owes
Gm oes || Joeee
ES CR CECT I I CLG
Table 2
RCFT Results
Example | Mat Mount | Initial Pressure at Pressure at type density, pressure, | peak temp. peak temp. (g/em” | 23°C (900/530)* for | (900/530)* (kPa) cycle 1 for cycle 3
KPa kPa
EN ca Ec CJ LAS
EI Cc cE LC CI
Ec CO CON * 900°C / 530 °C, peak temperatures of the hot side (representing monolith temperature) and cooler side (representing shell temperature) of the assembly, respectively, during the test.
Claims (19)
1. A mounting mat for mounting a pollution control element in a pollution control device, the mounting mat having a bulk density of 0.12 to 0.3 g/cm’ and comprising (1) a layer of magnesium aluminium silicate glass fibers and (ii) a layer of polycrystalline ceramic fibers.
2. A mounting mat according to claim 1 wherein said layer of magnesium aluminium silicate glass fibers and said layer of ceramic fibers define opposite major surfaces of said mat.
3. A mounting mat according to claim 1 or 2 wherein said layer of magnesium aluminium silicate glass fibers comprises said glass fibers in an amount of at least 50% by weight based on the weight of said layer.
4. A mounting mat according to any one of the previous claims wherein one or more further layers are present between said layer of magnesium aluminium silicate glass fibers and said laver of ceramic fibers.
5. A mounting mat according to any one of the previous claims wherein said glass fibers and said ceramic fibers have a number average diameter of 5m or more and a length of 0.5 to 15cm.
6. A mounting mat according to any one of the previous claims wherein said layer of magnesium aluminium silicate glass fibers and said layer of ceramic fibers are each needle bonded or stitch bonded and wherein said layers are needle bonded or stitch bonded to each other. 17 AMENDED SHEET
PY PCT/US2004/011761
7. A mounting mat according to any one of the previous claims wherein said mounting mat is free of organic binder or contains said organic binder in an amount of not more than 2% by weight based on the weight of said mat.
8. A mounting mat according to any one of the previous claims wherein said aluminium silicate glass fibers comprise aluminium oxide in an amount of 10 to 30% by weight, silicon dioxide in an amount of 52 to 70% by weight and magnesium oxide in an amount of 1 to 12% by weight based on the total weight of the glass fiber and wherein the weight percentages of aluminium oxide, silicon dioxide and magnesium oxide are calculated on a theoretical basis as Al;Os, SiO; and MgO respectively.
9. A mounting mat according to any one of the previous claims wherein said aluminium silicate glass fibers are selected from the group consisting of E-glass, S-glass, S2- glass, R-glass and a mixture thereof.
10. A mounting mat according to any one of the previous claims wherein said polycrystalline ceramic fibers are obtained by a sol-gel process.
11. A mounting mat according to any one of the previous claims wherein said glass fibers are chopped glass fibers.
12. A pollution control device comprising a pollution control element arranged in a casing with a mounting mat, according to any one of the previous claims, disposed between said casing and said pollution control element.
13. A pollution control device according to claim 12 wherein said mounting mat Is arranged such that said layer of ceramic fibers faces said pollution control element.
14. A pollution control device according to claim 12 or 15 wherein the mount density of said mounting mat is between 0.2 and 0.6 g/cm’. 18 AMENDED SHEET
PCT/US2004/011761
15. A pollution control device according to any one of claims 12 to 14 wherein said pollution control element is a monolith comprising between 400 and 1200 cells per square inch, with cell walls having a thickness of not more than 0.005"
(0.127mm).
16. A mounting mat according to claim 1, substantially as hercin described and illustrated.
17. A pollution control device according to claim 12, substantially as herein described and illustrated.
18. A new mounting mat, or a new pollution control device substantially as herein described.
19 AMENDED SHEET
Applications Claiming Priority (1)
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EP03101686A EP1486648B1 (en) | 2003-06-10 | 2003-06-10 | Mounting mat for a catalytic converter |
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JP (1) | JP4607885B2 (en) |
KR (1) | KR101036047B1 (en) |
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AT (1) | ATE317942T1 (en) |
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DK2212072T3 (en) * | 2007-10-09 | 2013-11-25 | 3M Innovative Properties Co | Method of manufacturing mounting mats for mounting emission control element |
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PL2352870T3 (en) * | 2008-11-03 | 2017-01-31 | 3M Innovative Properties Company | Mounting mat and pollution control device with the same |
KR101719006B1 (en) | 2008-11-03 | 2017-03-22 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | Mounting mat and pollution control device with the same |
KR20130056867A (en) | 2010-04-13 | 2013-05-30 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | Inorganic fiber webs and methods of making and using |
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WO2011130056A2 (en) | 2010-04-13 | 2011-10-20 | 3M Innovative Properties Company | Inorganic fiber webs and methods of making and using |
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US5290522A (en) * | 1993-01-07 | 1994-03-01 | Minnesota Mining And Manufacturing Company | Catalytic converter mounting mat |
US5569629A (en) * | 1994-08-23 | 1996-10-29 | Unifrax Corporation | High temperature stable continuous filament glass ceramic fibers |
US5686039A (en) * | 1995-06-30 | 1997-11-11 | Minnesota Mining And Manufacturing Company | Methods of making a catalytic converter or diesel particulate filter |
DE69833136T2 (en) * | 1997-02-06 | 2006-08-31 | Minnesota Mining And Mfg. Co., St. Paul | Multi-layered inflatable mat |
US6051193A (en) * | 1997-02-06 | 2000-04-18 | 3M Innovative Properties Company | Multilayer intumescent sheet |
JP3875836B2 (en) * | 1998-03-11 | 2007-01-31 | ユニフラックス コーポレイション | Support elements for brittle structures such as catalytic converters |
WO2000033946A1 (en) * | 1998-12-08 | 2000-06-15 | Unifrax Corporation | Amorphous non-intumescent inorganic fiber mat for low temperature exhaust gas treatment devices |
BR0001560B1 (en) * | 1999-04-09 | 2010-04-06 | process for producing a ceramic catalyst body and a ceramic catalyst body. | |
KR100640124B1 (en) * | 1999-06-08 | 2006-10-31 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | High Temperature Mat for a Pollution Control Device |
-
2003
- 2003-06-10 EP EP03101686A patent/EP1486648B1/en not_active Expired - Lifetime
- 2003-06-10 DE DE60303560T patent/DE60303560T2/en not_active Expired - Lifetime
- 2003-06-10 AT AT03101686T patent/ATE317942T1/en not_active IP Right Cessation
-
2004
- 2004-04-16 KR KR1020057023597A patent/KR101036047B1/en active IP Right Grant
- 2004-04-16 WO PCT/US2004/011761 patent/WO2005003530A1/en active Application Filing
- 2004-04-16 JP JP2006532419A patent/JP4607885B2/en not_active Expired - Fee Related
- 2004-04-16 CN CN2004800162867A patent/CN1806101B/en not_active Expired - Fee Related
-
2006
- 2006-01-09 ZA ZA200600185A patent/ZA200600185B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP1486648B1 (en) | 2006-02-15 |
EP1486648A1 (en) | 2004-12-15 |
DE60303560T2 (en) | 2006-12-14 |
JP4607885B2 (en) | 2011-01-05 |
JP2007504400A (en) | 2007-03-01 |
WO2005003530A1 (en) | 2005-01-13 |
KR101036047B1 (en) | 2011-05-19 |
CN1806101A (en) | 2006-07-19 |
ATE317942T1 (en) | 2006-03-15 |
DE60303560D1 (en) | 2006-04-20 |
KR20060027327A (en) | 2006-03-27 |
CN1806101B (en) | 2012-03-21 |
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