ZA200503358B - Method for the production of at least one partial propylene oxidation and/or ammoxidation product - Google Patents

Method for the production of at least one partial propylene oxidation and/or ammoxidation product Download PDF

Info

Publication number: ZA200503358B
Authority: ZA; South Africa
Prior art keywords: volume; gas mixture; propane; propylene; hydrocarbons
Prior art date: 2002-09-27

Application number

ZA200503358A

Other languages

English (en)

Inventor

Christoph Adami

Claus Hechler

Goetz-Peter Schindler

Jochen Petzoldt

Otto Machhammer

Klaus J Mueller-Engel

Hans Martan

Original Assignee

Basf Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-09-27

Filing date

2005-04-26

Publication date

2006-07-26

2005-04-26 Application filed by Basf Ag filed Critical Basf Ag

2006-07-26 Publication of ZA200503358B publication Critical patent/ZA200503358B/en

Links

238000000034 method Methods 0.000 title claims description 98
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims description 92
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims description 90
230000003647 oxidation Effects 0.000 title claims description 45
238000007254 oxidation reaction Methods 0.000 title claims description 45
238000004519 manufacturing process Methods 0.000 title claims description 4
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 206
239000007789 gas Substances 0.000 claims description 157
239000000203 mixture Substances 0.000 claims description 146
239000001294 propane Substances 0.000 claims description 99
230000008569 process Effects 0.000 claims description 83
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 64
239000000470 constituent Substances 0.000 claims description 39
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 31
239000001301 oxygen Substances 0.000 claims description 31
229910052760 oxygen Inorganic materials 0.000 claims description 31
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 29
239000003054 catalyst Substances 0.000 claims description 23
150000001875 compounds Chemical class 0.000 claims description 23
238000006356 dehydrogenation reaction Methods 0.000 claims description 22
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 20
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 14
238000006243 chemical reaction Methods 0.000 claims description 14
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
229930195733 hydrocarbon Natural products 0.000 claims description 13
229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
150000002430 hydrocarbons Chemical class 0.000 claims description 10
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 10
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 8
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 8
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
239000005977 Ethylene Substances 0.000 claims description 7
229910052742 iron Inorganic materials 0.000 claims description 7
229910052759 nickel Inorganic materials 0.000 claims description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 6
229910052782 aluminium Inorganic materials 0.000 claims description 6
229910021529 ammonia Inorganic materials 0.000 claims description 6
229910052804 chromium Inorganic materials 0.000 claims description 6
230000007717 exclusion Effects 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
229910052758 niobium Inorganic materials 0.000 claims description 6
229910052719 titanium Inorganic materials 0.000 claims description 6
229910052721 tungsten Inorganic materials 0.000 claims description 6
239000004215 Carbon black (E152) Substances 0.000 claims description 5
239000001282 iso-butane Substances 0.000 claims description 5
229910052748 manganese Inorganic materials 0.000 claims description 5
229910052715 tantalum Inorganic materials 0.000 claims description 5
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
LVZWSLJZHVFIQJ-UHFFFAOYSA-N Cyclopropane Chemical compound C1CC1 LVZWSLJZHVFIQJ-UHFFFAOYSA-N 0.000 claims description 4
229910052733 gallium Inorganic materials 0.000 claims description 4
229910052750 molybdenum Inorganic materials 0.000 claims description 4
229910052697 platinum Inorganic materials 0.000 claims description 4
MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 claims description 4
229910052703 rhodium Inorganic materials 0.000 claims description 4
229910052707 ruthenium Inorganic materials 0.000 claims description 4
229910052720 vanadium Inorganic materials 0.000 claims description 4
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
229910052787 antimony Inorganic materials 0.000 claims description 3
229910052796 boron Inorganic materials 0.000 claims description 3
KDKYADYSIPSCCQ-UHFFFAOYSA-N but-1-yne Chemical compound CCC#C KDKYADYSIPSCCQ-UHFFFAOYSA-N 0.000 claims description 3
229910052757 nitrogen Inorganic materials 0.000 claims description 3
229910052763 palladium Inorganic materials 0.000 claims description 3
JTXAHXNXKFGXIT-UHFFFAOYSA-N propane;prop-1-ene Chemical group CCC.CC=C JTXAHXNXKFGXIT-UHFFFAOYSA-N 0.000 claims description 3
229910052714 tellurium Inorganic materials 0.000 claims description 3
IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical compound C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 claims description 2
238000009833 condensation Methods 0.000 claims description 2
230000005494 condensation Effects 0.000 claims description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 5
239000010936 titanium Substances 0.000 claims 5
229910052710 silicon Inorganic materials 0.000 claims 4
239000011701 zinc Substances 0.000 claims 3
229910052726 zirconium Inorganic materials 0.000 claims 3
229910052783 alkali metal Inorganic materials 0.000 claims 2
150000001340 alkali metals Chemical class 0.000 claims 2
229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
150000001342 alkaline earth metals Chemical class 0.000 claims 2
229910052737 gold Inorganic materials 0.000 claims 2
229910052738 indium Inorganic materials 0.000 claims 2
229910052744 lithium Inorganic materials 0.000 claims 2
229910052749 magnesium Inorganic materials 0.000 claims 2
229910052700 potassium Inorganic materials 0.000 claims 2
229910052709 silver Inorganic materials 0.000 claims 2
229910052708 sodium Inorganic materials 0.000 claims 2
229910052725 zinc Inorganic materials 0.000 claims 2
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
229910052684 Cerium Inorganic materials 0.000 claims 1
229910052692 Dysprosium Inorganic materials 0.000 claims 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
229910052785 arsenic Inorganic materials 0.000 claims 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical group [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical group [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
229910017052 cobalt Chemical group 0.000 claims 1
239000010941 cobalt Chemical group 0.000 claims 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
229910052802 copper Inorganic materials 0.000 claims 1
229910052698 phosphorus Inorganic materials 0.000 claims 1
239000011574 phosphorus Chemical group 0.000 claims 1
239000010703 silicon Substances 0.000 claims 1
229910052716 thallium Inorganic materials 0.000 claims 1
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims 1
229910052718 tin Inorganic materials 0.000 claims 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
239000010937 tungsten Chemical group 0.000 claims 1
235000013849 propane Nutrition 0.000 description 72
239000000047 product Substances 0.000 description 14
150000001335 aliphatic alkanes Chemical class 0.000 description 7
239000006227 byproduct Substances 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 6
238000010521 absorption reaction Methods 0.000 description 5
230000000694 effects Effects 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
235000013844 butane Nutrition 0.000 description 4
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
238000003795 desorption Methods 0.000 description 4
-1 generally oxidic Substances 0.000 description 4
239000000543 intermediate Substances 0.000 description 4
235000013847 iso-butane Nutrition 0.000 description 4
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
239000002994 raw material Substances 0.000 description 4
238000000926 separation method Methods 0.000 description 4
QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
239000002250 absorbent Substances 0.000 description 3
230000002745 absorbent Effects 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 3
229910001882 dioxygen Inorganic materials 0.000 description 3
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 3
238000000746 purification Methods 0.000 description 3
239000012495 reaction gas Substances 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
239000001273 butane Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
230000001627 detrimental effect Effects 0.000 description 2
XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
238000004817 gas chromatography Methods 0.000 description 2
239000012535 impurity Substances 0.000 description 2
150000002825 nitriles Chemical class 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
230000005855 radiation Effects 0.000 description 2
238000004064 recycling Methods 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
238000002336 sorption--desorption measurement Methods 0.000 description 2
239000007858 starting material Substances 0.000 description 2
230000035899 viability Effects 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
229910002483 Cu Ka Inorganic materials 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
230000035508 accumulation Effects 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
230000009471 action Effects 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001361 allenes Chemical class 0.000 description 1
238000001479 atomic absorption spectroscopy Methods 0.000 description 1
230000008901 benefit Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
230000008859 change Effects 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
NPUACKRELIJTFM-UHFFFAOYSA-N cr gas Chemical compound C1=NC2=CC=CC=C2OC2=CC=CC=C21 NPUACKRELIJTFM-UHFFFAOYSA-N 0.000 description 1
238000005336 cracking Methods 0.000 description 1
238000007323 disproportionation reaction Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000005611 electricity Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000010574 gas phase reaction Methods 0.000 description 1
238000007210 heterogeneous catalysis Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
239000003701 inert diluent Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000011835 investigation Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000012528 membrane Substances 0.000 description 1
238000005649 metathesis reaction Methods 0.000 description 1
229910000069 nitrogen hydride Inorganic materials 0.000 description 1
229910052756 noble gas Inorganic materials 0.000 description 1
150000002835 noble gases Chemical class 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
238000010926 purge Methods 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000003134 recirculating effect Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
238000003345 scintillation counting Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/18—Preparation of carboxylic acid nitriles by reaction of ammonia or amines with compounds containing carbon-to-carbon multiple bonds other than in six-membered aromatic rings
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

ZA200503358A 2002-09-27 2005-04-26 Method for the production of at least one partial propylene oxidation and/or ammoxidation product ZA200503358B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE10245585A DE10245585A1 (de)	2002-09-27	2002-09-27	Verfahren zur Herstellung von wenigstens einem partiellen Oxidations- und/oder Ammoxidationsprodukt des Propylens

Publications (1)

Publication Number	Publication Date
ZA200503358B true ZA200503358B (en)	2006-07-26

Family

ID=31984280

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ZA200503358A ZA200503358B (en)	2002-09-27	2005-04-26	Method for the production of at least one partial propylene oxidation and/or ammoxidation product

Country Status (3)

Country	Link
CN (2)	CN1305817C (zh)
DE (1)	DE10245585A1 (zh)
ZA (1)	ZA200503358B (zh)

Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8431743B2 (en)	2004-07-01	2013-04-30	Basf Aktiengesellschaft	Preparation of acrylic acid by heterogeneously catalyzed partial gas phase oxidation of propylene
JP5156375B2 (ja)	2004-07-01	2013-03-06	ビーエーエスエフソシエタス・ヨーロピア	プロパンからのアクロレインもしくはアクリル酸またはそれらの混合物の製造
DE102004061772A1 (de) *	2004-12-22	2006-07-06	Basf Ag	Verfahren zur Herstellung von Propen aus Propan
US7601866B2 (en)	2005-03-01	2009-10-13	Basf Aktiengesellschaft	Process for removing methacrolein from liquid phase comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component
US7705181B2 (en)	2005-03-01	2010-04-27	Basf Akiengesellschaft	Process for removing methacrylic acid from liquid phase comprising acrylic acid as a main constituent and target product, and methacrylic acid as a secondary component
DE102005019911A1 (de)	2005-04-27	2006-11-02	Basf Ag	Verfahren der rektifikativen Auftrennung einer Acrylsäure und/oder Methacrylsäure enthaltenden Flüssigkeit
DE102005022798A1 (de)	2005-05-12	2006-11-16	Basf Ag	Verfahren zur Herstellung wenigstens eines Zielproduktes durch partielle Oxidation und/oder Ammoxidation von Propylen
EP1881952B1 (de)	2005-05-12	2015-08-19	Basf Se	Verfahren zur herstellung wenigstens eines zielproduktes durch partielle oxidation und/oder ammoxidation von propylen
US7388106B2 (en)	2005-10-14	2008-06-17	Basf Aktiengesellschaft	Process for preparing acrolein or acrylic acid or a mixture thereof from propane
KR101278795B1 (ko)	2005-11-03	2013-06-25	바스프 에스이	프로판으로부터 아크롤레인 또는 아크릴산 또는 그의혼합물을 수득하기 위한 안정한 연속 제조 방법
DE102005052923A1 (de) *	2005-11-03	2007-05-10	Basf Ag	Verfahren zum stabilen Betreiben eines kontinuierlich ausgeübten Herstellprozesses zur Erzeugung von Acrolein, oder Acrylsäure oder deren Gemisch aus Propan
KR101370749B1 (ko)	2005-11-24	2014-03-06	바스프 에스이	프로판으로부터 아크롤레인 또는 아크릴산, 또는 그의혼합물의 제조 방법
WO2007060036A1 (de) *	2005-11-24	2007-05-31	Basf Se	Verfahren zur herstellung von acrolein, oder acrylsäure, oder deren gemisch aus propan
DE102005061626A1 (de)	2005-12-21	2007-06-28	Basf Ag	Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung wenigstens eines zu dehydrierenden Kohlenwasserstoffs
DE102005062010A1 (de)	2005-12-22	2007-06-28	Basf Ag	Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
DE102005062026A1 (de)	2005-12-22	2007-06-28	Basf Ag	Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
CN101405079A (zh)	2006-03-20	2009-04-08	旭化成化学株式会社	氧化或氨氧化用催化剂及其制造方法
DE102006024901A1 (de) *	2006-05-24	2007-11-29	Basf Ag	Verfahren zur Herstellung von Acrolein, oder Acrylsäure oder deren Gemisch aus Propan
DE102006029790A1 (de)	2006-06-27	2008-01-03	Basf Ag	Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung wenigstens eines zu dehydrierenden Kohlenwasserstoffs
JP2009543845A (ja)	2006-07-20	2009-12-10	ビーエーエスエフソシエタス・ヨーロピア	対応するアルカンからのイソプロパノール及び２ブタノールの製造方法
DE102006049939A1 (de)	2006-10-19	2008-04-24	Basf Ag	Verfahren zur Trennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure enthaltener Acrylsäure und Benzoesäure
DE102007004961A1 (de)	2007-01-26	2008-07-31	Basf Se	Verfahren zur Herstellung von Katalysatorformkörpern, deren Aktivmasse ein Multielementoxid ist
DE102007004960A1 (de)	2007-01-26	2008-07-31	Basf Se	Verfahren zur Herstellung von Acrylsäure
DE102007055086A1 (de)	2007-11-16	2009-05-20	Basf Se	Verfahren zur Herstellung von Acrylsäure
DE102007006647A1 (de)	2007-02-06	2008-08-07	Basf Se	Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts
DE102007029053A1 (de)	2007-06-21	2008-01-03	Basf Ag	Verfahren der heterogen katalysierten partiellen Direktoxidation von n-Propan zu Acrylsäure
BE1018537A3 (fr)	2007-09-13	2011-03-01	Basf Se	Procede d'exploitation d'une separation en continu d'un produit cible x sous la forme d'un cristallisat finement divise.
DE102007043759A1 (de)	2007-09-13	2008-09-11	Basf Se	Verfahren zum Betreiben einer kontinuierlichen Abtrennung eines Zielproduktes X in Form von feinteiligem Kristallisat
DE102007043758A1 (de)	2007-09-13	2008-10-23	Basf Se	Verfahren zum Betreiben einer kontinuierlichen Abtrennung eines Zielproduktes X in Form von feinteiligem Kristallisat des Zielproduktes X
DE102007043748A1 (de)	2007-09-13	2008-09-11	Basf Se	Verfahren zur kontinuierlichen Abtrennung eines Zielproduktes X in Form von feinteiligem Kristallisat
DE102008040799A1 (de)	2008-07-28	2008-12-11	Basf Se	Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enthaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal
JP2011529094A (ja)	2008-07-28	2011-12-01	ビーエーエスエフソシエタス・ヨーロピア	アクリル酸のｃ３前駆体化合物のガス状生成混合物から主生成物として含有されるアクリル酸および副生成物として含有されるグリオキサールを分離する方法
DE102008041573A1 (de)	2008-08-26	2010-03-04	Basf Se	Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enhaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal
DE102008044946B4 (de)	2008-08-29	2022-06-15	Evonik Superabsorber Gmbh	Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren
DE102008042060A1 (de)	2008-09-12	2009-06-18	Basf Se	Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008042064A1 (de)	2008-09-12	2010-03-18	Basf Se	Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008042061A1 (de)	2008-09-12	2010-03-18	Basf Se	Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102009027401A1 (de)	2009-07-01	2010-02-18	Basf Se	Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung
DE102010001228A1 (de)	2010-01-26	2011-02-17	Basf Se	Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung
WO2011000808A2 (de)	2009-07-01	2011-01-06	Basf Se	Verfahren der abtrennung von acrylsäure aus dem produktgasgemisch einer heterogen katalysierten partiellen gasphasenoxidation wenigstens einer c3-vorläuferverbindung
DE102011001587B4 (de) *	2010-08-05	2016-12-29	Flagsol Gmbh	Verfahren zum Aufbereiten eines Wärmeträgermediums eines solarthermischen Kraftwerks
DE102010042216A1 (de)	2010-10-08	2011-06-09	Basf Se	Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure
DE102011076931A1 (de)	2011-06-03	2012-12-06	Basf Se	Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base
DE102011079035A1 (de)	2011-07-12	2013-01-17	Basf Se	Mo, Bi und Fe enthaltende Multimetalloxidmassen
EP2731715B1 (de)	2011-07-12	2019-12-11	Basf Se	Mo, bi und fe enthaltende multimetalloxidmassen
DE102011084040A1 (de)	2011-10-05	2012-01-05	Basf Se	Mo, Bi und Fe enthaltende Multimetalloxidmasse
US11111193B2 (en)	2014-06-30	2021-09-07	Shell Oil Company	Treatment of a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium
US20170137348A1 (en) *	2014-06-30	2017-05-18	Shell Oil Company	Alkane oxidative dehydrogenation and/or alkene oxidation
WO2017025391A1 (en)	2015-08-07	2017-02-16	Basf Se	Process for production of acrylic acid
DE102018200841A1 (de)	2018-01-19	2019-07-25	Basf Se	Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen
EP3826987A1 (de)	2018-07-26	2021-06-02	Basf Se	Verfahren zur hemmung der unerwünschten radikalischen polymerisation von in einer flüssigen phase p befindlicher acrylsäure
JP2023519280A (ja)	2020-03-26	2023-05-10	ベーアーエスエフ・エスエー	液相ｐに存在するアクリル酸の望ましくないフリーラジカル重合を抑制する方法
CN114763316B (zh) *	2021-01-15	2023-10-20	中国科学院大学	一种介孔尖晶石高效催化丙烷直接脱氢制丙烯方法
WO2023006503A1 (de)	2021-07-28	2023-02-02	Basf Se	Verfahren zur herstellung von acrylsäure
WO2024037905A1 (de)	2022-08-16	2024-02-22	Basf Se	Verfahren zur herstellung von vollkatalysatorformkörpern zur gasphasenoxidation eines alkens und/oder eines alkohols zu einem α,β-ungesättigtem aldehyd und/oder einer α,β-ungesättigten carbonsäure

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5268497A (en) *	1992-02-24	1993-12-07	The Boc Group, Inc.	Process for the production of nitriles
DE10028582A1 (de) *	2000-06-14	2001-12-20	Basf Ag	Verfahren zur Herstellung von Acrolein oder Acrylsäure oder deren Gemischen aus Propan

2002
- 2002-09-27 DE DE10245585A patent/DE10245585A1/de not_active Withdrawn
2003
- 2003-09-18 CN CNB038254107A patent/CN1305817C/zh not_active Expired - Fee Related
- 2003-09-18 CN CNB038254093A patent/CN1310855C/zh not_active Expired - Fee Related
2005
- 2005-04-26 ZA ZA200503358A patent/ZA200503358B/en unknown

Also Published As

Publication number	Publication date
CN1310855C (zh)	2007-04-18
CN1305817C (zh)	2007-03-21
CN1703387A (zh)	2005-11-30
DE10245585A1 (de)	2004-04-08
CN1701054A (zh)	2005-11-23

Publication	Publication Date	Title
ZA200503358B (en)	2006-07-26	Method for the production of at least one partial propylene oxidation and/or ammoxidation product
US7326802B2 (en)	2008-02-05	Preparation of at least one partial oxidation and/or ammoxidation product of propylene
US4547615A (en)	1985-10-15	Process for producing conjugated diolefins
EP0573713B1 (en)	1997-01-02	Catalyst composition and process for oxidation or ammoxidation of olefines
US4423281A (en)	1983-12-27	Process for producing conjugated diolefins
JP3488471B2 (ja)	2004-01-19	アルカンの酸化法
US4309361A (en)	1982-01-05	Ammoxidation of olefins with novel antimonate catalysts
JP2006500430A5 (zh)	2011-02-24
CA1037060A (en)	1978-08-22	CATALYTIC OXIDATION OF .alpha.-OLEFINS
Viparelli et al.	1999	Oxidative dehydrogenation of propane over vanadium and niobium oxides supported catalysts
JP2004536149A (ja)	2004-12-02	少なくとも１種のオレフィン系炭化水素の部分酸化生成物および／または部分アンモ酸化生成物の製造方法
WO2000029105A1 (en)	2000-05-25	Catalytic oxidation of alkanes to corresponding acids
US4777319A (en)	1988-10-11	Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons
KR20060136425A (ko)	2007-01-02	ｎ-부탄으로부터 펜텐니트릴의 제조 방법
TW200538426A (en)	2005-12-01	Preparation of pentene nitriles from n-butane
US4316855A (en)	1982-02-23	Multiply promoted Sn-Sb oxide catalysts
TW546283B (en)	2003-08-11	Method for production of acrolein and acrylic acid
Solsona et al.	2007	Selective oxidation of n-butane over MoV-containing oxidic bronze catalysts
US6933407B2 (en)	2005-08-23	Method for producing methacrylic acid from isobutane
US4939286A (en)	1990-07-03	Promoted bismuth cerium molybdate catalysts
US4413155A (en)	1983-11-01	Ammoxidation of olefins with novel antimonate catalysts
US4339394A (en)	1982-07-13	Process of ammoxidation of olefins in the presence of multiply promoted Sn-Sb oxide catalysts
EP0428413B1 (en)	1994-09-07	Method for preparing unsaturated compounds
EP0557790B1 (en)	1998-08-19	Process for producing isobutylene by oxidative dehydrogenation of isobutane
EP0002626A2 (en)	1979-06-27	Ammoxidation of olefins with novel antimonate catalysts