WO2023204686A1 - Aerosol medium assembly comprising porous beads and heated smoking article comprising same - Google Patents

Aerosol medium assembly comprising porous beads and heated smoking article comprising same Download PDF

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Publication number
WO2023204686A1
WO2023204686A1 PCT/KR2023/005510 KR2023005510W WO2023204686A1 WO 2023204686 A1 WO2023204686 A1 WO 2023204686A1 KR 2023005510 W KR2023005510 W KR 2023005510W WO 2023204686 A1 WO2023204686 A1 WO 2023204686A1
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WIPO (PCT)
Prior art keywords
aerosol
aerosol medium
medium
aggregate
porous
Prior art date
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PCT/KR2023/005510
Other languages
French (fr)
Korean (ko)
Inventor
정승규
권중학
임동욱
현승목
Original Assignee
주식회사 이엠텍
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Priority claimed from KR1020220153117A external-priority patent/KR20230150706A/en
Priority claimed from KR1020230017867A external-priority patent/KR20230151437A/en
Application filed by 주식회사 이엠텍 filed Critical 주식회사 이엠텍
Publication of WO2023204686A1 publication Critical patent/WO2023204686A1/en

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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/14Machines of the continuous-rod type
    • A24C5/18Forming the rod
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/04Cigars; Cigarettes with mouthpieces or filter-tips
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/20Cigarettes specially adapted for simulated smoking devices
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof

Definitions

  • the embodiments relate to an aerosol medium assembly containing porous beads and a heated smoking article including the same, and more specifically, to an aerosol medium assembly that is easy to manufacture and has improved aerosol generation efficiency and a heated smoking article including the same. .
  • slurry leaf sheets which are the main raw material of the tobacco medium, have weak tensile strength and are difficult to manufacture, and the tobacco medium contains a large amount of humectants, making its physical properties weak.
  • tobacco media containing liquids such as glycerin are sensitive to humidity in the surrounding environment due to their hydrophilic nature, making it difficult to control the manufacturing process environment. There is a limit to the amount of liquid that can be contained in the tobacco medium.
  • the liquid is stored in a separate cartomizer to generate additional aerosol, so that when the user inhales the cigarette, the aerosol derived from the liquid is inhaled through the cigarette.
  • the liquid contained in the cartomizer is There are difficulties in managing the liquid (expiration date, deterioration, etc.), and condensation may occur in the airflow path through which the aerosol generated in the cartomizer moves, causing contamination.
  • Embodiments provide an aerosol medium assembly that is simple to manufacture and has improved aerosol generation efficiency, including an aerosol medium capable of generating aerosol by heating rather than combustion, and a heated smoking article containing the same, and obtaining aerosol therefrom. It is intended for
  • the embodiments aim to provide an aerosol medium aggregate formed of a collection of porous granules, which facilitates moisture absorption and transport of liquid and can thereby increase the amount of aerosol generated, and a heated smoking article including the same.
  • the aerosol medium aggregate of one embodiment of the present invention includes an aerosol medium that generates an aerosol by heating and a plurality of porous particles with micropores formed on the surface or inside, macropores are formed between the plurality of porous particles, and the aerosol
  • the medium is characterized by being accommodated in micro-pores and macro-pores.
  • the aerosol medium aggregate is characterized in that the micro pores are formed through the Bernard Cell phenomenon.
  • the aerosol medium aggregate is characterized in that the porous particles are in the form of beads or spherical powders.
  • the aerosol medium aggregate is characterized in that the porous particles are composed of metal components and silicates.
  • the aerosol medium aggregate is characterized in that the metal component is an alkaline earth group.
  • the aerosol medium aggregate is characterized in that the porous particles include fiber glass.
  • the aerosol medium assembly is characterized in that the fiber glass includes SiO2 in a weight percent of at least 50%.
  • the aerosol medium aggregate is characterized in that the micropores fall within the range of 20 ⁇ m to 50 ⁇ m.
  • the aerosol medium aggregate is characterized in that the macro pores fall in the range of 1 ⁇ m to 20 ⁇ m.
  • the aerosol medium aggregates include porous granules selected from magnesium silicate, aluminum silicate, silicate silicate, zeolite, titanium oxide, titanium carbide, zirconia, silica, silicon carbide, silicon nitride, mullite, cordierite, tungsten carbide, and zirconium carbide. , characterized in that it contains one or more materials selected from the group containing aluminum nitride.
  • the aerosol medium aggregate is characterized in that the porous particles have a diameter of 10 ⁇ m to 300 ⁇ m.
  • the aerosol medium assembly is characterized in that the aerosol medium includes at least VG (vegetable glycerin) and PG (propylene glycol).
  • the aerosol medium aggregate is characterized in that the aerosol medium is in any one of a liquid phase, a gel phase, or a solid phase at room temperature.
  • the aerosol medium aggregate is characterized in that the aerosol medium is liquid at room temperature, is mixed with a plurality of porous particles, and is absorbed into micro-pores and macro-pores.
  • the aerosol medium aggregate exists in a gel or semi-solid phase in a first temperature range including room temperature, changes to a liquid phase in a second temperature range higher than the first temperature range, and has a second temperature range. It is characterized by vaporization into an aerosol at a third, higher temperature range.
  • the aerosol medium assembly is characterized in that the aerosol medium includes at least VG (vegetable glycerin) and carrageenan.
  • the aerosol medium assembly is characterized in that the aerosol medium includes at least VG (vegetable glycerin) and a thickener, and in the third temperature range, the thickener does not vaporize but remains in the aerosol medium assembly.
  • VG vegetable glycerin
  • the aerosol medium aggregate is characterized in that the aerosol medium is mixed with a plurality of porous particles in a liquefied state and then gelled again to be accommodated in the micro-pores and macro-pores of the plurality of porous particles.
  • the aerosol medium aggregate exists in a solid phase in a first temperature range including room temperature, changes to a liquid phase in a second temperature range higher than the first temperature range, and is higher than the second temperature range. Characterized in that it vaporizes into an aerosol in a third temperature range.
  • the aerosol medium assembly is characterized in that the aerosol medium includes at least VG (vegetable glycerin) and a thickener, and in the third temperature range, the thickener does not vaporize but remains in the aerosol medium assembly.
  • VG vegetable glycerin
  • the aerosol medium aggregate, the thickener is cellulose derivatives, dextrin derivatives, alginate derivatives, gum, pectin, hemicellulose derivatives and It is characterized in that it contains one or more substances selected from the group containing gelatin.
  • the aerosol medium aggregate is a mixture of a liquid VG (vegetable glycerin) and PG (propylene glycol) mixture, a thickener, and a solubilizing agent mixed with a plurality of porous granules to absorb moisture into the porous granules. It is formed by evaporating the solubilizer contained in the mixed solution absorbed by the grains, and the solubilizer is characterized by a lower boiling point than the liquid VG (vegetable glycerin) and PG (propylene glycol) mixture and thickener.
  • the aerosol medium rod of one embodiment of the present invention is characterized in that it includes the aerosol medium assembly of any of the above embodiments and a wrapping paper that wraps the aerosol medium assembly into a cylinder shape.
  • the heated smoking article of one embodiment of the present invention includes a filter rod, a cooling tube rod laminated on the bottom of the filter rod and hollow in the vertical direction, and an aerosol medium assembly according to any of the above embodiments laminated on the bottom of the cooling tube rod.
  • Including, the filter rod, the cooling tube rod, and the aerosol medium assembly are wrapped with wrapping paper to form a cigarette.
  • the heated smoking article is characterized in that the aerosol medium assembly is wrapped in a cylindrical shape by a separate wrapping paper.
  • the heated smoking article includes a tobacco body rod including a tobacco filler, further laminated to the top or bottom of the aerosol medium assembly, and further laminated to the aerosol medium assembly and a filter rod and cooling tube rod.
  • the tobacco body rod is wrapped to form a cigarette.
  • the heated smoking article further includes a tobacco body rod including a tobacco body, which is stacked at the bottom of the cooling tube rod, and the aerosol medium aggregate is included to be distributed inside the tobacco body rod.
  • the heated smoking article is characterized in that the tobacco rod is wrapped in a cylindrical shape by a separate wrapping paper.
  • the aerosol medium assembly is arranged to include a hollow formed to penetrate upward and downward through the center, and the hollow is provided with a tobacco body.
  • the heated smoking article is characterized in that a mesh or a breathable membrane having a plurality of through holes is formed at the interface between the hollow formed in the aerosol medium assembly and the aerosol medium assembly.
  • the method for producing an aerosol medium aggregate of an embodiment of the present invention includes the steps of preparing a liquid aerosol medium in a container, the surface or the inside of the aerosol medium. Introducing a plurality of porous particles with micropores into a container, mixing them with a liquid aerosol medium, and absorbing moisture into the porous particles, and using a filter, the porous particles that have absorbed moisture from the liquid aerosol medium and the remaining liquid aerosol. It is characterized by comprising the step of separating the medium.
  • the method for producing an aerosol medium aggregate further includes the step of drying the porous particles that have absorbed the liquid aerosol medium for a predetermined period of time to prevent the droplets from flowing.
  • the method for producing an aerosol medium aggregate further includes the step of cooling the porous particles that have absorbed the liquid aerosol medium to gel the liquid aerosol medium.
  • the method for producing an aerosol medium aggregate of an embodiment of the present invention includes a solidified aerosol medium that generates an aerosol by heating, comprising adding a mixed solution of the aerosol medium, a thickener, and a solubilizing agent to a container.
  • Preparation step (solution preparation step), introducing a plurality of porous granules with micro pores formed on the surface or inside into a container and mixing them with the mixed solution to absorb moisture into the porous granules (moisture absorption step), using a strainer , Separating the remaining mixed solution from the porous granules that absorbed the mixed solution (separation step), and evaporating the solvent contained in the mixed solution absorbed by the porous granules to obtain a solidified aerosol medium (solidification step). It is characterized by:
  • the method for producing an aerosol medium aggregate is such that the boiling point of the dissolving agent is lower than that of the aerosol medium and the thickener, and in the solidification step, the porous granules that absorb moisture from the mixed solution are placed at a boiling point higher than the boiling point of the dissolving agent and the boiling point of the aerosol medium and the thickening agent.
  • the solvent contained in the mixed solution is evaporated and a solidified aerosol medium containing the aerosol medium and the thickener is obtained.
  • the aerosol medium aggregate of the embodiment is composed of porous particles or spherical particles with an increased specific surface area, thereby increasing the moisture absorption of the aerosol medium and increasing the amount of transport of the aerosol medium due to capillary action, ultimately increasing the amount of aerosol generated. It has the effect of increasing .
  • the unit grains of the aerosol medium aggregate according to the embodiment are composed of porous grains or porous spherical grains in which the Bernard cell phenomenon occurs, so that defects are induced on the surface of the particles by the Bernard cell phenomenon, resulting in the specific surface area of the porous grains. This has the effect of increasing the moisture absorption of the liquid phase and ultimately increasing the amount of aerosol generated.
  • the porous particles can be easily absorbed by mixing them with an aerosol medium, which has the effect of facilitating manufacturing.
  • porous granules are included in the tobacco medium or tobacco body, so that the user can simultaneously inhale substances derived from the tobacco medium or tobacco body and substances derived from the aerosol medium moisture absorbed by the porous granules, and the amount of atomization is reduced. also increases, improving user experience.
  • FIG. 1 is a cross-sectional view conceptually showing an aerosol medium aggregate 30 according to an embodiment of the present invention
  • Figure 2 is a scanning microscope photograph of a plurality of porous grains (30a) according to an embodiment of the present invention
  • Figure 3 is a conceptual plan view of porous grains 30a according to an embodiment of the present invention.
  • Figure 4 is a flow chart showing a method of manufacturing an aerosol medium aggregate 30 containing a liquid or gel-like aerosol medium according to an embodiment of the present invention
  • Figure 5 is a conceptual diagram expressing the manufacturing method of Figure 4 in an easy-to-understand manner
  • Figure 6 is a flow chart showing a method of manufacturing an aerosol medium aggregate 30 including a solidified aerosol medium according to an embodiment of the present invention
  • FIG. 7 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1 according to an embodiment of the present invention
  • FIG. 8 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1a according to another embodiment of the present invention.
  • FIG. 9 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1b according to another embodiment of the present invention.
  • FIG. 10 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1c according to another embodiment of the present invention.
  • Figure 11 is a cross-sectional view conceptually showing an aerosol medium aggregate 35 according to another embodiment of the present invention.
  • expressions such as “have,” “may have,” “includes,” or “may include” refer to the existence of the corresponding feature (e.g., a numerical value, function, operation, or component such as a part). , and does not rule out the existence of additional features.
  • expressions such as “A or B,” “at least one of A or/and B,” or “one or more of A or/and B” may include all possible combinations of the items listed together.
  • “A or B”, “at least one of A and B”, or “at least one of A or B” (1) includes at least one A, (2) includes at least one B, or (3) it may refer to all cases including both at least one A and at least one B.
  • first, second, first, or second may describe various elements in any order and/or importance, and may refer to one element as another. It is only used to distinguish from components and does not limit the components.
  • a first user device and a second user device may represent different user devices regardless of order or importance.
  • a first component may be renamed a second component without departing from the scope of rights described in this document, and similarly, the second component may also be renamed to the first component.
  • Figure 1 is a cross-sectional view conceptually showing an aerosol medium aggregate 30 according to an embodiment of the present invention
  • Figure 2 is a scanning microscope photograph of a plurality of porous particles 30a according to an embodiment of the present invention
  • Figure 3 is a This is a conceptual plan view of porous grains 30a according to an embodiment of the present invention.
  • the aerosol medium aggregate 30 includes a plurality of porous particles 30a with micropores (indicated by A in FIG. 3) formed on the surface or inside. Additionally, the porous particles 30a accommodate an aerosol medium that generates an aerosol by heating.
  • the porous grains 30a are unit elements forming the aerosol medium aggregate 30, and in particular, in this embodiment, they are formed using the Bernard Cell phenomenon. Due to the Barnard cell phenomenon, defects, that is, micropores (A), are induced on the surface of the particles, which can consequently increase the specific surface area of the porous grains (30a) and thereby increase the moisture absorption or water capacity of the aerosol medium, Ultimately, the amount of aerosol generated from the aerosol medium aggregate 30 can be increased.
  • An exemplary method of manufacturing a plurality of porous grains (30a) with micropores formed on the surface or inside using the Bernard Cell phenomenon is to prepare a first dispersion solution by dispersing silicate powder bonded to a metal ion and a binder in a first solvent.
  • a step of preparing a second dispersion solution by dispersing and stirring the additive in a second solvent preparing a mixed slurry by mixing and stirring the first dispersion solution and the second dispersion solution, and spray drying the mixed slurry.
  • the metal silicate powder preferably contains one or more metal ions selected from Mg, Al, Zr, Li, Ba, MgAl, Na, and Ca, and the metal silicate powder is dispersed in an amount of 5 to 40 wt% relative to the first solvent.
  • the binder used in the preparation of the first dispersion solution is selected from polyvinyl alcohol, polyvinyl acetate, polyethylene, polyvinylbutylene, polypropylene, polyvinyl chloride, polyacrylic, polyacrylamide, guar gum, gelatin, and natural rubber. It is desirable to have more than one selected.
  • the first solvent includes one or more selected from water, ethanol, toluene, IPA, and acetone, and it is preferable that the first solvent is used in an amount of 70 to 220 wt% based on the weight of the metal silicate.
  • the additive used in the preparation of the first dispersion solution preferably includes a high boiling point solvent such as mineral spirits or xylene, and is preferably added in an amount of 0.5 to 10 wt% relative to the metal silicate. It varies depending on the additive, but in the case of organic additives, if the amount is more than 10 wt%, it may be impossible to maintain the bead shape, cause high viscosity, and reduce workability.
  • a high boiling point solvent such as mineral spirits or xylene
  • the second solution contains at least one selected from water, ethanol, toluene, IPA, and acetone, and is preferably contained in an amount of 5 to 30 wt% based on the metal silicate.
  • the first dispersion solution and the second dispersion solution are mixed and stirred to prepare a mixed slurry, and then the mixed slurry is spray dried to form porous granules with micropores.
  • spray drying uses a disk method, and the rotation speed of the disk is preferably adjusted within the range of 500 to 9000 rpm. If the rotation speed of the disk is less than 500 rpm, the effect due to centrifugal force is not significant, and the size of the spherical particles becomes excessively large.
  • the rotation speed of the rotating disk exceeds 9000 rpm, the generation rate of spherical particles of 20 ⁇ m or less increases, and these small spherical particles rather form a part of the heater or liquid hygroscopic body when manufacturing the heater or liquid hygroscopic body of the aerosol generating device. It has the disadvantage of blocking surface pores and reducing the specific surface area. Therefore, it is desirable that the rotation speed of the disk is adjusted within the range of 500 to 9000 rpm.
  • the disk on which the mixed slurry is sprayed rotates in a chamber maintaining a temperature of 220 to 300 °C, and the Bernard Cell phenomenon is induced during the spray drying stage, causing surface defects (cracks) as shown in the photo in Figure 2, increasing the ratio of porous grains. Surface area can be increased.
  • porous grains with micro pores have the advantage of being able to form micro pores without adding a separate pore-forming agent during the manufacturing process.
  • the porous granules with micropores produced in this way can increase the specific surface area.
  • the moisture absorption or capacity capable of absorbing the aerosol medium increases, and accordingly the aerosol It has the advantage of being able to increase the amount of atomization that can occur by vaporizing the medium.
  • the porous grains 30a described above are porous three-dimensional (or spherical) particles with a plurality of grooves or pores (A) formed on the surface by causing surface defects (cracks), as can be seen in the scanning microscope photo of FIG. 2. , its specific surface area has been significantly increased.
  • the porous grains 30a may be in the form of beads or spherical powder.
  • the diameter or size of the porous particles 30a is a size capable of securing a specific surface area to effectively absorb the aerosol medium, and preferably falls within the range of 10 ⁇ m to 300 ⁇ m.
  • the pores A formed on the surface or inside the porous grain 30a correspond to micro pores, and preferably have a diameter in the range of 20 ⁇ m to 50 ⁇ m to effectively accommodate the aerosol medium.
  • the pores between the plurality of porous particles 30a included in the aerosol medium aggregate 30 correspond to macro pores (indicated by B in FIG. 1) and range from 1 ⁇ m to 130 ⁇ m, more preferably 1 ⁇ m. It falls in the range of ⁇ 20 ⁇ m.
  • the aerosol medium assembly 30 may be an aggregate of a plurality of porous particles 30a charged into a predetermined space and containing the aerosol medium. At this time, the gaps formed between the plurality of porous grains 30a charged in the predetermined space may become macro pores B.
  • the porosity of the aerosol medium aggregate 30 is in the range of 30% to 70%.
  • porosity can be calculated as the total of macro pores (B) and micro pores (A).
  • Each of the porous grains 30a is composed of a metal component and silicate.
  • the metal component is an alkaline earth material such as aluminum, magnesium, and calcium.
  • the material of the porous grains 30a is magnesium silicate, aluminum silicate, silicate silicate, zeolite, titanium oxide, titanium carbide, zirconia, silica, silicon carbide, silicon nitride, mullite, cordierite, tungsten carbide, zirconium carbide, and aluminum nitride. It is composed of one or more substances selected from the group containing.
  • the porous particles 30a preferably have hydrophilic properties in order to absorb or accommodate moisture in the aerosol medium. Additionally, the porous grains 30a may additionally include fiber glass. These fiber glasses contain SiO2 in weight percent of more than 50%.
  • the plurality of porous particles 30a have the function of absorbing or receiving the aerosol medium and/or are mounted on an aerosol generating device or cartridge and have the function of transporting the liquefied aerosol medium by capillary action.
  • These moisture absorption and transport functions can be performed more smoothly in the aerosol medium aggregate 30 composed of porous particles 30a containing micro-pores and macro-pores as in the embodiment. Due to these moisture absorption and transfer functions, when applied to an aerosol generating device or cartridge, it is possible to transfer a certain amount of aerosol medium when a user puffs, thereby generating a certain amount of mist.
  • the plurality of porous particles 30a included in the aerosol medium aggregate 30 may be block into a three-dimensional shape using a predetermined binder.
  • the atomizer can be applied to an aerosol generating device or cartridge by filling a predetermined space with a plurality of porous particles 30a in the form of beads or spherical powder.
  • the porous particles 30a can be charged into an aerosol generating device or cartridge while accommodating the aerosol medium, and arranged so that a heater can heat it.
  • the shape of the heater may have various shapes such as a blade shape, a cylindrical shape, or a fin shape.
  • the aerosol medium assembly 30 does not have a specific shape, the shape or arrangement of the heater is free, and the contact area between the heater and the aerosol medium assembly 30 can be expanded.
  • the plurality of porous grains (30a) themselves are immersed in or mixed with the liquid aerosol medium to quickly and easily absorb and accommodate the aerosol medium. can do.
  • the aerosol medium can be effectively accommodated in the micro pores (A) and macro pores (B) included in the aerosol medium assembly 30, making manufacturing easier and increasing the efficiency of aerosol generation.
  • the aerosol medium assembly 30 may be wrapped by wrapping paper 31 to form a cylindrical aerosol medium rod.
  • the wrapping paper 31 substantially defines the filling space in which the porous particles 30a are filled, and wraps at least the side of the aerosol medium assembly 30 to prevent the porous particles 30a from falling off from the aerosol medium assembly 30. You can prevent it from happening.
  • the wrapping paper 31 is made of paper or membrane material with a waterproof coating to prevent leakage of the aerosol medium.
  • the wrapping paper 31 may be provided as a laminate formed by attaching aluminum foil to paper, and the aluminum foil is wrapped in a cylindrical shape so that it contacts the aerosol medium assembly 30. Accordingly, the aluminum foil can eliminate or minimize the possibility of the aerosol medium being liquefied from the aerosol medium assembly 30 and flowing out through the side of the aerosol medium rod.
  • a predetermined binder may be applied, or when forming the aerosol medium rod, only the side of the aerosol medium assembly 30 is covered with the wrapping paper 31. No, it can cover the entire direction. However, in this case, it is preferable that the wrapping paper 31 has pores large enough to allow aerosol particles to pass through.
  • an aerosol medium assembly 30 in the form of an aerosol medium rod is inserted into an aerosol generating device and heated by a heater, especially its side, i.e. the part surrounded by the wrapping paper 31, This heat heats the aerosol medium contained in the porous particles 30a, ultimately producing an aerosol.
  • the aerosol medium aggregate 30 is surrounded on its side by the wrapping paper 31 to form an aerosol medium rod, the user creates an air flow from the bottom to the top, as shown by the arrow, through the act of inhalation. It is possible to inhale aerosols originating from an aerosol medium.
  • the bottom side can be referred to as “upstream” and the top side can be referred to as “downstream.”
  • the aerosol medium may include any one or more of materials that can be converted to an aerosol by heating, such as flavoring, nicotine, VG (vegetable glycerin), PG (propylene glycol), medicine, clove, etc. You can.
  • VG vegetable glycerin
  • PG propylene glycol
  • the aerosol medium included in the aerosol medium aggregate may be liquid, gel, or solid at room temperature.
  • a liquid aerosol medium can be created by mixing liquid VG and PG at room temperature.
  • the aerosol medium is liquid at room temperature, if its moisture absorption amount is controlled, it can be maintained without leakage while being absorbed into the micro pores (A) and macro pores (B) included in the aerosol medium assembly 30.
  • a gel-like aerosol medium can be formed by mixing at least glycerin and a thickener.
  • glycerin PG Proplylene Glycol
  • VG Veetable Glycerine
  • a thickener carbrageenan, etc.
  • the mixture maintains a gel or semi-solid state in a first temperature range that includes room temperature (e.g., a temperature range of less than 50° C.), and is heated to a second temperature range that is higher than the first temperature range (e.g., 50-100° C. temperature range), it changes from a liquid phase to a sol phase and exists in the liquid phase, and when further heated, it vaporizes into an aerosol in a third temperature range higher than the second temperature range (for example, a temperature range of 150 °C or higher). You can.
  • the gel-like aerosol medium may additionally include one or more of agar, thickener, starch powder, cellulose, carboxymethyl ether, natural food flavoring, or fruit extract.
  • the content of glycerin in the gel-like aerosol medium is preferably 50% by weight or more.
  • the mixture may additionally contain agar, in which case it serves advantageously to form a gel-like aerosol medium mixture.
  • the gel-like aerosol medium mixture may include thickeners, starch powder, cellulose, and carboxymethyl ether as additives.
  • the gel-like aerosol medium contains carrageenan, which is widely known to act as a thickener
  • phase changes can be expected depending on the temperature range as described above.
  • the aerosol medium in a gel state in a first temperature range including room temperature may change into a liquid or sol state as the colloidal particles are disconnected in a second temperature range, and may be further heated to vaporize into an aerosol in a third temperature range. there is.
  • the gel-like aerosol medium may contain 0.1 to 5% of a gelling agent, 5 to 100% of an aerosol generator including glycerin, 0.1 to 20% of an acidity regulator, and optionally 0.1 to 15% of a flavoring agent and additives. Or it may contain an active substance.
  • the gel-like aerosol medium may additionally include one or more of kappa carrageenan, iota carrageenan, agar, pectin, guar gum, calcium lactate, potassium chloride, glucose, starch powder, natural food additives, or fruit extracts or compounds. You can.
  • the gel-like aerosol medium is vaporized and aerosolized at a temperature range (third temperature range) higher than the second temperature range, for example, about 150 to 300° C., and is aerosolized after heating into a liquid phase that is not inhaled.
  • a temperature range higher than the second temperature range, for example, about 150 to 300° C.
  • the aerosol medium is cooled to room temperature, it can change back into a gel state inside the aerosol medium assembly 30.
  • the aerosol medium includes a thickener so that the aerosol medium maintains a gel or semi-solid state in the first temperature range, and according to a preferred embodiment, the thickener is added at a temperature of about 150 to about 150° C. at which the aerosol medium containing glycerin is vaporized and aerosolized. It does not vaporize in the temperature range of 300°C (third temperature range) and remains in the porous particles 30a or the aerosol medium aggregate 30. That is, when glycerin, the main aerosol medium, vaporizes into an aerosol, the thickener does not vaporize but remains in the micropores (A) within the porous grains (30a) or the macropores (B) between the porous grains (30a).
  • This thickener is composed of one or more substances selected from the group including monosaccharides, disaccharides, sugar alcohols, and oligosaccharides.
  • Methods such as using gelatin extracted from fish, meat, etc. or vegetable gelatin as a thickener to gelatinize glycerin, or mixing such gelatin thickener and water with glycerin and cooling while stirring were considered.
  • the vaporization point of glycerin in the gel-like aerosol medium obtained in this way is It is approximately 200 to 300 ° C. under atmospheric pressure, and the vaporization point of water is approximately 100 ° C. under atmospheric pressure, so this gelatin or water thickener is in the temperature range of about 150 to 300 ° C.
  • the thickener includes one or more substances selected from the group including monosaccharides, disaccharides, sugar alcohols, and oligosaccharides.
  • the monosaccharide is a plant extract and includes one or more substances selected from the group comprising glucose, fructose, and galactose.
  • the vaporization point of glucose is 527.1 ⁇ 50.0 °C under atmospheric pressure
  • the vaporization point of fructose is 697.1 ⁇ 50.0 °C under atmospheric pressure
  • the vaporization point of galactose is 527.1 ⁇ 50.0 °C under atmospheric pressure, so the aerosol medium containing glycerin vaporizes and becomes an aerosol. It does not vaporize in the temperature range of about 150 to 300°C (third temperature range) and remains in the moisture absorbent.
  • the disaccharide includes components derived from sugar, etc. Since the vaporization point of sugar is 697.1 ⁇ 50.0 ° C. under atmospheric pressure, it does not vaporize in the temperature range of about 150 to 300 ° C. (third temperature range), at which the aerosol medium containing glycerin vaporizes and becomes aerosol, but remains in the absorbent.
  • the sugar alcohol includes one or more substances selected from the group including isomalt, maltitol, xylitol, and sorbitol.
  • the vaporization point of isomalt is 788.5 °C
  • the vaporization point of maltitol is 788.5 ⁇ 60.0 °C under atmospheric pressure, so in the temperature range of about 150 to 300 °C (third temperature range) where the aerosol medium containing glycerin vaporizes and becomes aerosol. It does not evaporate and remains in the absorbent.
  • the monosaccharide is a disaccharide or higher saccharide and includes maltodextrin. Since the vaporization point of erase textrin is 527.1°C, it does not vaporize in the temperature range of about 150 to 300°C (third temperature range), where the aerosol medium containing glycerin vaporizes and becomes aerosol, but remains in the absorbent.
  • the solid aerosol medium may also be a mixture of glycerin and a thickener, similar to the gel aerosol medium.
  • a mixed solution can be made by adding a thickener, an additive for solidification, and a solubilizer, an additive to temporarily prevent solidification, to glycerin PG (Proplylene Glycol) or VG (Vegetable Glycerine), or a mixture of PG and VG.
  • glycerin PG Proplylene Glycol
  • VG Veetable Glycerine
  • the thickeners used for solidification include cellulose derivatives, dextrin derivatives, alginate derivatives, gum, pectin, hemicellulose derivatives, and gelatin ( It is preferable to include one or more substances selected from the group containing gelatin.
  • the solubilizing agent may also be, for example, distilled water or ethanol; it is particularly preferred that it is a substance with a lower boiling point than the aerosol medium to be used (e.g. PG and VG) and the thickening agent.
  • a mixed solution of a liquid aerosol medium for example, PG or VG
  • a thickener for example, PG or VG
  • a solubilizer is prepared, and then mixed with the plurality of porous granules 30a described above to form porous granules ( After moisture absorption in 30a), it is heated to evaporate only the solvent with a relatively low boiling point contained in the mixed solution absorbed in the porous grains (30a), and the aerosol medium and thickener can remain in the porous grains (30a).
  • PG and VG are trapped in the thickener, forming a solid aerosol medium, and ultimately, an aerosol medium aggregate 30 containing the solid aerosol medium can be produced.
  • the solid image aerosol medium of the aerosol medium assembly 30 can be expected to change phase according to temperature changes, similar to the gel-like aerosol medium described above. That is, the solid image aerosol medium exists in a solid image due to the action of the thickener in a predetermined temperature range including room temperature to room temperature (for example, a temperature range below 50° C., a first temperature range). Also, in a typical use of the aerosol medium assembly 30, the aerosol medium assembly 30 is heated by a heater in the aerosol generating device to a second temperature range higher than the first temperature range (e.g., 50 - 100° C.
  • the thickener gradually loses its properties, and the solid phase aerosol medium can change to a liquid phase, and in a third temperature range higher than the second temperature range (e.g., a temperature range of 150° C. to 300° C.), Aerosol media (eg PG and VG) can be vaporized.
  • a third temperature range higher than the second temperature range e.g., a temperature range of 150° C. to 300° C.
  • Aerosol media eg PG and VG
  • the aerosol medium is still absorbed or contained within the micropores (A) and macropores (B) included in the aerosol medium assembly 30, so leakage may occur. Very unlikely.
  • the thickener does not vaporize in the temperature range of about 150 ° C to 300 ° C (third temperature range), where the aerosol medium containing glycerin is vaporized and aerosolized, but is formed in the porous particles 30a to the aerosol medium. It remains in the aggregate 30. That is, when glycerin, the main aerosol medium, vaporizes into an aerosol, the thickener does not vaporize but remains in the micropores (A) within the porous grains (30a) or the macropores (B) between the porous grains (30a). Therefore, in general usage, the user may inhale only the vaporized aerosol medium, such as PG or VG, and not the thickener.
  • the vaporized aerosol medium such as PG or VG
  • the aerosol medium may additionally contain natural food flavors or fruit extracts. In this case, it becomes possible to add various flavors to the user through the generated aerosol. In any case, it is preferable that the glycerin content in the aerosol medium mixture is 50% by weight or more, thereby minimizing the burnt taste in the generated aerosol. Additionally, the aerosol medium mixture may or may not contain nicotine.
  • the aerosol medium may further include flavoring agents, for example, licorice, sucrose, fructose syrup, iso-sweeteners, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, Bergamot, geranium, honey essence, rose oil, vanilla, lemon oil, orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang ylang, sage, spearmint, ginger, coriander or coffee. It can be included.
  • flavoring agents for example, licorice, sucrose, fructose syrup, iso-sweeteners, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, Bergamot, geranium, honey essence, rose oil, vanilla, lemon oil, orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang
  • Figure 4 is a flowchart showing a method of manufacturing an aerosol medium aggregate 30 containing a liquid or gel-like aerosol medium according to an embodiment of the present invention
  • Figure 5 is a conceptual diagram expressing the manufacturing method of Figure 4 in an easy-to-understand manner.
  • a liquid aerosol medium e.g., PG and VG mixture
  • M mixed solution
  • the mixed solution (M) may further include a thickener, and in order to prevent gelation, the mixed solution (M) is heated to a predetermined temperature (for example, the second temperature range described above). It may be a state.
  • the porous granules (30a) are introduced into the container (K) and soaked in the mixed solution (M) (FIG. 5 (b), (c)). For example, at this time, stirring may be performed to ensure that the porous grains 30a are well wetted. As a result, the porous grains (30a) and the mixed solution (M) are mixed, and the mixed solution (M) can absorb moisture or be accommodated in the micropores and surfaces of the porous grains (30a).
  • the remaining mixed solution (M) and the porous grains (30a) can be separated using, for example, a fine strainer (FIG. 5(d)).
  • a fine strainer FOG. 5(d)
  • a drying step may be additionally included.
  • the porous particles 30a that have absorbed the mixed solution (M) can be cooled to gel the moisture-absorbed liquid aerosol medium.
  • FIG. 6 is a flowchart showing a method of manufacturing an aerosol medium assembly 30 including a solidified aerosol medium according to an embodiment of the present invention.
  • a solution preparation step s210
  • a mixed solution (M) of a liquid aerosol medium for example, a mixture of PG and VG
  • a thickener for example, a thickener
  • a solubilizing agent is prepared in the container (K) (FIG. 5(a)).
  • the porous granules (30a) are introduced into the container (K) and soaked in the mixed solution (M) (FIG. 5 (b), (c)).
  • stirring may be performed to ensure that the porous grains 30a are well wetted.
  • the porous grains (30a) and the mixed solution (M) of the aerosol medium, thickener, and solubilizer are mixed, and the mixed solution (M) may be absorbed or accommodated in the micropores and surfaces of the porous grains (30a).
  • the separation step (s230) the remaining mixed solution (M) and the porous grains (30a) can be separated using, for example, a fine strainer (FIG. 5(d)).
  • the solidification step (s240) is a step of obtaining a solidified aerosol medium by evaporating the solvent contained in the mixed solution (M) moisture absorbed by the porous grains (30a).
  • the porous grains (30a) that have absorbed the mixed solution (M) are heated to a temperature higher than the boiling point of the included solvent and lower than the boiling points of the included aerosol medium and thickener, and added to the mixed solution (M).
  • a solidified aerosol medium can be obtained by evaporating the contained solvent, leaving the aerosol medium and thickener as is.
  • the aerosol medium may be solidified while being accommodated in micro pores (A) within the porous grains (30a) or macro pores (B) between the porous grains (30a).
  • porous particles 30a containing the liquid, gel, or solid aerosol medium prepared in this way are wrapped by the wrapping paper 31 in the form of an aerosol medium rod as shown in FIG. 1 or inserted into a predetermined space to form an aerosol medium.
  • an aggregate 30 By forming an aggregate 30, it can function as an atomizer that generates an aerosol.
  • FIG. 7 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1 according to an embodiment of the present invention.
  • the heated smoking article (1) includes a filter rod (10) that is a mouth filter on the upper side, a cooling tube rod (20) stacked at the bottom of the filter rod (10), and a bottom of the cooling tube rod (20).
  • An aerosol medium assembly (30) within the scope of an embodiment of the present invention, which is laminated on an aerosol medium assembly (30), and a wrapping that surrounds the filter rod (10), the cooling tube rod (20), and the aerosol medium assembly (30) to maintain the layered structure. It is composed of paper 50. That is, in the heated smoking article 1, the filter rod 10, the cooling tube rod 20, and the aerosol medium assembly 30 are sequentially stacked in the vertical direction, and the wrapping paper 50 surrounds them to form a cigarette as a whole. .
  • the filter rod 10 is a filter that functions as a mouthpiece, allowing aerosols to pass through and preventing liquid from entering.
  • the filter rod 10 may be made of pulp and may be made in a cylindrical or tube shape.
  • the filter rod 10 may be made of materials such as cellulose acetate, paper, PP, and PLA. Meanwhile, the filter rod 10 can improve user satisfaction by including flavoring ingredients.
  • Flavoring ingredients include, for example, licorice, sucrose, fructose syrup, iso-sweeteners, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, bergamot, geranium, honey essence, rose oil, vanilla, lemon.
  • Oils may include orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang ylang, sage, spearmint, ginger, coriander or coffee.
  • the cooling tube rod 20 has a hollow 22 extending in the vertical direction formed therein to provide a passage for the aerosol. It contains PLA and lowers the temperature of the aerosol to prevent the user from getting burned when inhaling the aerosol. You may.
  • the cooling tube rod 20 may be made of cellulose acetate, and the cooling tube rod 20 serving as the cooling structure may be made of pure polylactic acid or by combining polylactic acid with other degradable polymers.
  • the wrapping paper 50 may be made of, for example, plain paper or porous paper.
  • the aerosol medium assembly 30 included in the heated smoking article 1 may be in the form of an aerosol medium rod wrapped by a separate wrapping paper as described in FIG. 1.
  • the heated smoking article 1 of the embodiments can be inserted into a predetermined aerosol generating device to heat the aerosol medium aggregate 30, thereby forming micropores in the porous particles 30a. Aerosols originating from a liquid, gel, or solid aerosol medium contained in (A) or in the macro pores (B) between the porous particles 30a may be generated.
  • FIG. 8 is a vertical cross-sectional view conceptually showing the inside of a heated smoking article 1a according to another embodiment of the present invention.
  • the heated smoking article 1a according to this embodiment additionally includes a tobacco body rod 40 containing a tobacco body as another aerosol medium at the top or bottom of the aerosol medium assembly 30. That is, the tobacco rod 40 may be provided as another aerosol medium at the top or bottom of the aerosol medium assembly 30.
  • the user can puff by mixing the aerosol derived from the aerosol medium assembly 30 and the aerosol derived from the tobacco rod 40.
  • the tobacco rod 40 and the aerosol medium assembly 30 As shown in FIG.
  • the tobacco rod 40 when the tobacco rod 40 is located below (if located upstream), the tobacco rod 40 As the aerosol derived from passes through the aerosol medium assembly 30, it will be mixed with the aerosol derived from the aerosol medium assembly 30 and the user will puff, and if the aerosol medium assembly 30 is located below (located upstream) In this case), the aerosol derived from the aerosol medium assembly 30 passes through the tobacco rod 40 and is mixed with the aerosol derived from the tobacco rod 40, so that the user puffs.
  • the tobacco body rod 40 may include a tobacco body, that is, a solid material based on tobacco raw materials such as leaf tobacco, cut tobacco, reconstituted tobacco, etc.
  • the tobacco body rod 40 may be filled with corrugated leaf sheets.
  • the lamellar sheet may be wrinkled by being rolled, folded, compressed, or contracted substantially transversely to the axis of the cylinder. Porosity can be determined by controlling the valley spacing of the wrinkled plate-like sheet.
  • the tobacco body rod 40 may be filled with tobacco cut fillers.
  • tobacco cut fillers can be produced by cutting tobacco sheets (or slurry leaf sheets) into small pieces.
  • the tobacco body rod 40 may be formed by combining a plurality of tobacco strands in the same direction (parallel) or randomly.
  • the tobacco body rod 40 is formed by combining a plurality of tobacco strands, and a plurality of longitudinal channels through which aerosol can pass may be formed. At this time, depending on the size and arrangement of the tobacco strands, the longitudinal channels may be uniform or non-uniform.
  • the tobacco rod 40 may further include at least one of ethylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and oleyl alcohol. Additionally, the tobacco rod 40 may further include glycerin and propylene glycol.
  • the tobacco body rod 40 may contain other added substances such as flavoring agents and/or organic acids.
  • flavoring agents include licorice, sucrose, fructose syrup, isosweet, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, bergamot, geranium, honey essence, rose oil, It may contain vanilla, lemon oil, orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang ylang, sage, spearmint, ginger, coriander or coffee. Meanwhile, the tobacco rod 40 may contain some glycerin or propylene glycol.
  • FIG. 9 is a vertical cross-sectional view conceptually showing the inside of a heated smoking article 1b according to another embodiment of the present invention.
  • the heated smoking article (1b) includes a filter rod (10) that is a mouth filter on the upper side, a cooling tube rod (20) stacked at the bottom of the filter rod (10), and a bottom of the cooling tube rod (20).
  • the filter rod 10, the cooling tube rod 20, and the wrapping paper 50 have the same names and reference numerals, and the contents previously described above can be applied as is.
  • the tobacco body rod 40a may include at least a tobacco body 41, and as shown in FIG. 9, it preferably further includes a plurality of porous granules 30a with micropores formed on the surface or inside. .
  • the sizes of certain components, particularly the porous grains 30a, are exaggerated for visibility, and the sizes of the components are not limited by their relative sizes in the drawings.
  • the tobacco body rod 40a may be formed by agglomerating the tobacco body 41 itself, or may be formed by agglomerating the tobacco body 41 and wrapping it with separate wrapping paper (not shown). That is, the tobacco body rod 40a may be a structure in which the tobacco body 41 is bundled into a rod or cylinder shape, or for structural rigidity and ease of manufacture, at least one side of the structure may be wrapped with separate wrapping paper. It can be wrapped and formed.
  • the wrapping paper (not shown) surrounding the tobacco body 41 is preferably made of paper or membrane material with a waterproof coating to prevent leakage of the aerosol medium that may occur.
  • the wrapping paper may be provided as a laminate formed by attaching aluminum foil to paper, and the aluminum foil is wrapped in a cylinder shape so that it contacts the tobacco body 41. Accordingly, the aluminum foil can eliminate or minimize the possibility of the aerosol medium being liquefied from the tobacco body 41 or the plurality of porous particles 30a and flowing out through the side of the tobacco body rod 40a.
  • the tobacco body 41 may include solid materials based on tobacco raw materials, such as leaf tobacco, cut tobacco, and reconstituted tobacco.
  • the tobacco body 41 may be a cigarette in the form of a wrinkled leaf sheet.
  • the lamellar sheet may be wrinkled by being rolled, folded, compressed, or contracted substantially transversely to the axis of the cylinder. Porosity can be determined by controlling the valley spacing of the wrinkled plate-like sheet.
  • the tobacco body 41 may be a tobacco cut filler.
  • tobacco cut fillers can be produced by cutting tobacco sheets (or slurry leaf sheets) into small pieces.
  • the tobacco body 41 may be formed by combining a plurality of tobacco strands in the same direction (parallel) or randomly.
  • the tobacco body 41 is formed by combining a plurality of tobacco strands, and a plurality of longitudinal channels through which aerosol can pass may be formed. At this time, depending on the size and arrangement of the tobacco strands, the longitudinal channels may be uniform or non-uniform.
  • the tobacco body 41 may further include at least one of ethylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and oleyl alcohol. Additionally, the tobacco body 41 may further contain glycerin and propylene glycol.
  • the tobacco body 41 may contain other added substances such as flavoring agents and/or organic acids.
  • flavoring agents include licorice, sucrose, fructose syrup, isosweet, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, bergamot, geranium, honey essence, rose oil, It may contain vanilla, lemon oil, orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang ylang, sage, spearmint, ginger, coriander or coffee. Meanwhile, the tobacco body 41 may contain some glycerin or propylene glycol.
  • the tobacco body 41 may be aggregated into a cylinder or rod shape to form the tobacco body rod 40a.
  • the tobacco rod 40a further includes a plurality of porous granules 30a containing at least one aerosol medium.
  • the porous grains 30a can be evenly distributed within the tobacco body 41.
  • the tobacco body 41 is solid, and a large number are aggregated to substantially form the tobacco body rod 40a, so the porous grains 30a are distributed in large numbers between the tobacco bodies 41 within the tobacco body rod 40a, and the tobacco body 41 is distributed in large numbers. The position can be fixed by the sieve 41.
  • a plurality of porous granules (30a) may be blocked into a three-dimensional shape using a predetermined binder and included in the tobacco rod (40a).
  • the porous particles 30a in the form of a plurality of beads or spherical powder can be mixed with the tobacco body 41 and applied to an aerosol generating device or cartridge as an atomizer.
  • porous grains 30a can be applied as described above with the same names and reference numerals.
  • the heated smoking article 1b of the embodiment can be inserted into a predetermined aerosol generating device so that the tobacco body rod 40a is heated, thereby producing aerosol and aerosol derived from the tobacco body 41. Aerosols originating from liquid, gel, or solid aerosol media contained in the micropores (A) or on the surface of the porous grains (30a) may be generated. Accordingly, the user can inhale a mixture of aerosol components derived from different sources, thereby simultaneously feeling more diverse flavors and a richer sense of smoke compared to conventional smoking articles.
  • Figure 10 is a vertical cross-sectional view conceptually showing the inside of a heated smoking article 1c according to another embodiment of the present invention.
  • the aerosol medium aggregate 35 is arranged to include a hollow formed to penetrate upward and downward through the center, and the hollow contains a tobacco body. (41) is provided differently.
  • a hollow having the same diameter and sharing the same central axis as the hollow 22 of the cooling tube rod 20 may be formed in the aerosol medium assembly 35, and the tobacco body 41 may be filled into the hollow.
  • the hollow filled with the tobacco body 41 may serve as an airflow path connected to the hollow 22 of the cooling tube rod 20.
  • the aerosol medium aggregate 35 may also be wrapped in a separate, preferably waterproof, wrapping paper to form a rod.
  • the heated smoking article (1c) when the heated smoking article (1c) is inserted into an aerosol generating device and the exterior of the aerosol medium assembly (35) is heated by the heater included therein, the heated smoking article (1c) is included in the porous particles (30a) of the aerosol medium assembly (35).
  • the aerosol medium may be converted into an aerosol and introduced into the hollow of the aerosol medium assembly 35.
  • this hot aerosol heats the tobacco body 41, so that aerosol can also be generated from the tobacco body 41, and the aerosols from the above two sources are mixed, and the cooling tube rod 20 and the filter rod 10 It can be inhaled by the user.
  • the aerosol medium aggregate 35 can be manufactured by first agglomerating the tobacco body 41 into a cylindrical shape, inserting the tobacco body 41, and then filling the outside with porous particles 30a.
  • the tobacco body 41 is first lumped into a cylindrical shape, then wrapped with mesh or a separate wrapping paper having a plurality of holes, and the aerosol medium aggregate 35 is formed by inserting the tobacco body 41 and filling the outside with the porous granules 30a.
  • the mesh or a separate wrapping paper having multiple holes substantially defines the boundary between the hollow formed in the aerosol medium assembly 35 and the aerosol medium assembly 35 and serves as a breathable membrane.
  • the inside and outside of the hollow aerosol medium assembly 35 are wrapped with mesh or a separate wrapping paper having a plurality of holes so that the cross section has a donut shape, and then the tobacco body 41 is filled into the formed hollow to produce aerosol.
  • a medium assembly 35 may also be manufactured.
  • FIG 11 is a cross-sectional view conceptually showing an aerosol medium aggregate 35 according to another embodiment of the present invention.
  • the aerosol medium aggregate 35 is wrapped by a separate wrapping paper 31, so that the outermost shape is cylindrical.
  • a hollow 32 is formed in the center of the aerosol medium aggregate 35 to penetrate upward and downward.
  • the hollow 32 must be filled with the tobacco body 41, but the tobacco body 41 is omitted in this drawing.
  • the inside and outside of the aerosol medium assembly 35 where the hollow 32 is formed is wrapped with a mesh or a breathable membrane 32a having a plurality of holes so that the cross-section of the aerosol medium assembly 35 is donut-shaped.
  • it is possible to manufacture an aerosol medium aggregate 35 including a cavity 32 by substantially filling both boundaries of the air permeable membrane 32a with porous particles 30a.
  • the gas permeable membrane 32a is shown as surrounding both the inside and the outside of the aerosol medium assembly 35 in which the hollow 32 is formed.
  • the gas permeable membrane 32a is wrapped around the aerosol medium assembly 35. ) may be formed only at the interface between the hollow 32 formed in and the aerosol medium aggregate 35.
  • Heated smoking articles (1, 1a, 1b, 1c) may be heated by being inserted into a heating space in a heating device to which a resistance heating method such as a film heater is applied, and in another embodiment, a heating device to which an induction heating method is applied. It may also be inserted into the heating space within.
  • the heating device has a heating space (cavity) into which the heated smoking articles (1, 1a, 1b, 1c) can be inserted and heated, and the glycerin of the heated smoking articles (1, 1a, 1b, 1c) inserted into the heating space.
  • a heating space cavity
  • It refers to an aerosol-generating device of a grippable and portable size, which forms an aerosol by heating an aerosol medium such as an aerosol medium, a tobacco body, and/or an aerosol-forming substrate such as nicotine by a heater.
  • the heater may be provided as a resistance heating type or an induction heating type as described above.
  • the heated smoking article (1, 1a, 1b, 1c) The aerosol medium or forming substrate provided inside is heated to generate an aerosol.
  • the target temperature may be in the range of 200 to 350 °C, and according to a more preferred example, the target temperature may be in the range of 250 to 320 °C (for example, 280 °C as the target). may be determined). In some cases, the target temperature may be in the range of 150 to 250 °C (for example, 180 °C may be set as the target temperature), which means that the object to generate aerosol is glycerin, cigarette change, or a liquid such as glycerin. It may vary depending on whether the composition is a moisture-absorbed cigarette change or nicotine liquid.
  • the aerosol generated within the heated smoking articles (1, 1a, 1b, 1c) is inhaled into the user's mouth through the cooling tube rod (20) and the filter rod (10) when the user puffs, so during the puffing process
  • the target temperature of the heating element must be set in advance. It must be decided. Additionally, for the above reasons, the upper limit of the target temperature of the heating element is limited as above.
  • the temperature at which the generated aerosol passes through the cooling tube rod 20 and the filter rod 10 can be measured as the mouth end temperature.
  • the temperature of the aerosol may be measured.
  • the temperature should be below 50°C, preferably below 45°C.
  • the mouth end temperature of a preferred aerosol is in the temperature range of 25 to 45° C., and the more preferred mouth end temperature of the aerosol is in the temperature range of 30 to 40° C.
  • an aerosol medium assembly (30) and a tobacco body rod (40, 40a) are provided along the longitudinal direction of the smoking article (in some cases, aerosol The medium assembly 30 may be located upstream or downstream).
  • the target temperature of the aerosol medium assembly 30 and the target temperature of the tobacco rods 40 and 40a are different, so that the heating device It is preferable that the heating space is provided with an independent heater capable of heating the aerosol medium assembly 30 and the tobacco rods 40 and 40a in response to each target temperature.
  • the target temperature of the aerosol medium assembly for example, 300 ° C.
  • the heater that heats the aerosol medium aggregate e.g., a resistance heating heater
  • the heater that heats the tobacco rod e.g., a resistance heating heater

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Abstract

Embodiments relate to an aerosol medium assembly comprising porous beads and a heated smoking article comprising same and, more specifically, to an aerosol medium assembly which is easy to manufacture and has improved aerosol generation efficiency, and a heated smoking article comprising same. The aerosol medium assembly of any embodiment comprises: an aerosol medium which generates an aerosol by heating; and a plurality of porous grains having micropores formed on the surface or inside thereof, macropores are formed between the plurality of porous grains, and the aerosol medium is accommodated in the micropores and the macropores.

Description

다공성 비드를 포함하는 에어로졸 매질 집합체 및 이를 포함하는 가열식 흡연 물품Aerosol medium aggregate containing porous beads and heated smoking article containing the same
실시예들은 다공성 비드를 포함하는 에어로졸 매질 집합체 및 이를 포함하는 가열식 흡연 물품에 관한 것으로, 더욱 상세하게는, 제조가 용이하고 에어로졸 발생 효율이 개선된 에어로졸 매질 집합체 및 이를 포함하는 가열식 흡연 물품에 관한 것이다.The embodiments relate to an aerosol medium assembly containing porous beads and a heated smoking article including the same, and more specifically, to an aerosol medium assembly that is easy to manufacture and has improved aerosol generation efficiency and a heated smoking article including the same. .
근래에 일반적인 궐련의 단점들을 극복하는 대체 방법에 관한 수요가 증가하고 있다. 예를 들어, 궐련을 연소시켜 에어로졸을 생성시키는 방법이 아닌 궐련 내의 에어로졸 발생 물질이 가열됨에 따라 에어로졸이 생성되는 방법에 관한 수요가 증가하고 있다.In recent years, there has been an increasing demand for alternative methods to overcome the disadvantages of regular cigarettes. For example, there is an increasing demand for a method in which aerosol is generated by heating the aerosol-generating material in the cigarette, rather than a method of generating aerosol by burning a cigarette.
일반적으로 담배 매질의 주원료인 슬러리 판상엽 시트의 경우 인장력이 약하여 제조적성이 어려우며, 담배 매질에 보습제도 다량 함유되어 있어 물리성이 취약하다. 또한, 글리세린 등과 같은 액상을 함유한 담배 매질은 친수성으로 인하여 주위 환경의 습도에도 민감하여 제조 공정 환경을 제어하는데 어려움이 있다. 담배 매질 내 함유시킬 수 있는 액상의 양도 한계가 있다.In general, slurry leaf sheets, which are the main raw material of the tobacco medium, have weak tensile strength and are difficult to manufacture, and the tobacco medium contains a large amount of humectants, making its physical properties weak. In addition, tobacco media containing liquids such as glycerin are sensitive to humidity in the surrounding environment due to their hydrophilic nature, making it difficult to control the manufacturing process environment. There is a limit to the amount of liquid that can be contained in the tobacco medium.
담배 매질을 포함하는 궐련 이외에 별도의 카토마이저에 액상을 보관하여 에어로졸을 추가로 발생시켜서 사용자가 궐련을 흡입할 때 액상으로부터 유래하는 에어로졸을 궐련을 통해 흡입하는 경우도 제안되고 있으나, 카토마이저에 함유된 액상을 관리하는데 어려움(유통기한, 변질 등)이 있으며, 카토마이저에서 생성된 에어로졸이 이동하는 기류 패스에 응축물이 발생하여 오염이 발생할 수 있다. In addition to cigarettes containing tobacco media, it has been proposed that the liquid is stored in a separate cartomizer to generate additional aerosol, so that when the user inhales the cigarette, the aerosol derived from the liquid is inhaled through the cigarette. However, it has been proposed that the liquid contained in the cartomizer is There are difficulties in managing the liquid (expiration date, deterioration, etc.), and condensation may occur in the airflow path through which the aerosol generated in the cartomizer moves, causing contamination.
이에 따라, 한 번 사용하고 버리게 되는 가열식 흡연 물품 내에 에어로졸 매질을 제공하고 이로부터 에어로졸을 얻기 위한 니즈가 존재한다.Accordingly, there is a need to provide an aerosol medium and obtain aerosol from a heated smoking article that is discarded after one use.
실시예들은 연소 방식이 아닌 가열 방식으로 에어로졸을 발생시킬 수 있는 에어로졸 매질을 포함하면서, 제조가 간편하고 에어로졸 발생 효율이 개선된 에어로졸 매질 집합체 및 이를 포함하는 가열식 흡연 물품을 제공하고 이로부터 에어로졸을 얻기 위한 것을 목적으로 한다.Embodiments provide an aerosol medium assembly that is simple to manufacture and has improved aerosol generation efficiency, including an aerosol medium capable of generating aerosol by heating rather than combustion, and a heated smoking article containing the same, and obtaining aerosol therefrom. It is intended for
또한 실시예들은 다공성 알갱이들의 집합으로 형성되어, 액상의 흡습과 이송이 원활하고 그에 따라 에어로졸 발생량이 증가할 수 있는 에어로졸 매질 집합체 및 이를 포함하는 가열식 흡연 물품을 제공하는 것을 목적으로 한다.Additionally, the embodiments aim to provide an aerosol medium aggregate formed of a collection of porous granules, which facilitates moisture absorption and transport of liquid and can thereby increase the amount of aerosol generated, and a heated smoking article including the same.
본 발명의 일 실시예의 에어로졸 매질 집합체는, 가열에 의해 에어로졸을 생성하는 에어로졸 매질 및 표면이나 내부에 마이크로 기공이 형성된 복수의 다공성 알갱이를 포함하고, 복수의 다공성 알갱이 사이에는 매크로 기공이 형성되고, 에어로졸 매질은 마이크로 기공과 매크로 기공에 수용된 것을 특징으로 한다.The aerosol medium aggregate of one embodiment of the present invention includes an aerosol medium that generates an aerosol by heating and a plurality of porous particles with micropores formed on the surface or inside, macropores are formed between the plurality of porous particles, and the aerosol The medium is characterized by being accommodated in micro-pores and macro-pores.
또한 어느 실시예에서 에어로졸 매질 집합체는, 마이크로 기공은 버나드셀 현상을 통하여 형성된 것을 특징으로 한다. Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the micro pores are formed through the Bernard Cell phenomenon.
또한 어느 실시예에서 에어로졸 매질 집합체는, 다공성 알갱이는 비드 형태나 구형 분말 형태인 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the porous particles are in the form of beads or spherical powders.
또한 어느 실시예에서 에어로졸 매질 집합체는, 다공성 알갱이는 금속 성분과 실리케이트로 구성된 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the porous particles are composed of metal components and silicates.
또한 어느 실시예에서 에어로졸 매질 집합체는, 금속 성분은 알칼리토류족인 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the metal component is an alkaline earth group.
또한 어느 실시예에서 에어로졸 매질 집합체는, 다공성 알갱이는 섬유 글라스를 포함하는 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the porous particles include fiber glass.
또한 어느 실시예에서 에어로졸 매질 집합체는, 섬유 글라스는 50% 이상의 중량 퍼센트로 SiO2를 포함하는 것을 특징으로 한다.Additionally, in some embodiments, the aerosol medium assembly is characterized in that the fiber glass includes SiO2 in a weight percent of at least 50%.
또한 어느 실시예에서 에어로졸 매질 집합체는, 마이크로 기공은 20 ㎛ ~ 50 ㎛ 범위에 속하는 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the micropores fall within the range of 20 ㎛ to 50 ㎛.
또한 어느 실시예에서 에어로졸 매질 집합체는, 매크로 기공은 1 ㎛ ~ 20 ㎛ 범위에 속하는 것을 특징으로 한다.In addition, in one embodiment, the aerosol medium aggregate is characterized in that the macro pores fall in the range of 1 μm to 20 μm.
또한 어느 실시예에서 에어로졸 매질 집합체는, 다공성 알갱이는 마그네슘 실리케이트, 알루미늄 실리케이트, 규산 실리케이트, 제올라이트, 산화 티탄, 탄화 티탄, 지르코니아, 실리카, 탄화규소, 질화규소, 뮬라이트, 코디어라이트, 탄화 텅스텐, 탄화 지르코늄, 질화 알루미늄을 포함하는 군에서 선택된 하나 이상의 물질을 포함하여 구성된 것을 특징으로 한다.Also in some embodiments, the aerosol medium aggregates include porous granules selected from magnesium silicate, aluminum silicate, silicate silicate, zeolite, titanium oxide, titanium carbide, zirconia, silica, silicon carbide, silicon nitride, mullite, cordierite, tungsten carbide, and zirconium carbide. , characterized in that it contains one or more materials selected from the group containing aluminum nitride.
또한 어느 실시예에서 에어로졸 매질 집합체는, 다공성 알갱이는 10 ㎛ 내지 300 ㎛의 직경을 갖는 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the porous particles have a diameter of 10 μm to 300 μm.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 적어도 VG(식물성 글리세린)와 PG(프로필렌 글리콜)를 포함하는 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium assembly is characterized in that the aerosol medium includes at least VG (vegetable glycerin) and PG (propylene glycol).
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 상온에서 액상, 겔상 또는 고형화상 중 어느 하나인 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the aerosol medium is in any one of a liquid phase, a gel phase, or a solid phase at room temperature.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 상온에서 액상이고, 복수의 다공성 알갱이와 혼합되며 마이크로 기공과 매크로 기공에 흡습되는 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium aggregate is characterized in that the aerosol medium is liquid at room temperature, is mixed with a plurality of porous particles, and is absorbed into micro-pores and macro-pores.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 상온을 포함하는 제1 온도 범위에서 겔상 또는 반고상으로 존재하고, 제1 온도 범위보다 높은 제2 온도 범위에서 액상으로 변화하며, 제2 온도 범위보다 높은 제3 온도 범위에서 에어로졸로 기화하는 것을 특징으로 한다.In addition, in some embodiments, the aerosol medium aggregate exists in a gel or semi-solid phase in a first temperature range including room temperature, changes to a liquid phase in a second temperature range higher than the first temperature range, and has a second temperature range. It is characterized by vaporization into an aerosol at a third, higher temperature range.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 적어도 VG(식물성 글리세린)와 카라기난을 포함하는 것을 특징으로 한다.Additionally, in one embodiment, the aerosol medium assembly is characterized in that the aerosol medium includes at least VG (vegetable glycerin) and carrageenan.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 적어도 VG(식물성 글리세린)와 증점제를 포함하고, 제3 온도 범위에서 증점제는 기화하지 않고 에어로졸 매질 집합체에 잔류하는 것을 특징으로 한다.Also, in one embodiment, the aerosol medium assembly is characterized in that the aerosol medium includes at least VG (vegetable glycerin) and a thickener, and in the third temperature range, the thickener does not vaporize but remains in the aerosol medium assembly.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 액상화된 상태로 복수의 다공성 알갱이와 혼합된 후 다시 겔상화되어 복수의 다공성 알갱이의 마이크로 기공과 매크로 기공에 수용되는 것을 특징으로 한다.In addition, in one embodiment, the aerosol medium aggregate is characterized in that the aerosol medium is mixed with a plurality of porous particles in a liquefied state and then gelled again to be accommodated in the micro-pores and macro-pores of the plurality of porous particles.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 상온을 포함하는 제1 온도 범위에서 고형화상으로 존재하고, 제1 온도 범위보다 높은 제2 온도 범위에서 액상으로 변화하며, 제2 온도 범위보다 높은 제3 온도 범위에서 에어로졸로 기화하는 것을 특징으로 한다.In addition, in one embodiment, the aerosol medium aggregate exists in a solid phase in a first temperature range including room temperature, changes to a liquid phase in a second temperature range higher than the first temperature range, and is higher than the second temperature range. Characterized in that it vaporizes into an aerosol in a third temperature range.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은 적어도 VG(식물성 글리세린)와 증점제를 포함하고, 제3 온도 범위에서 증점제는 기화하지 않고 에어로졸 매질 집합체에 잔류하는 것을 특징으로 한다.Also, in one embodiment, the aerosol medium assembly is characterized in that the aerosol medium includes at least VG (vegetable glycerin) and a thickener, and in the third temperature range, the thickener does not vaporize but remains in the aerosol medium assembly.
또한 어느 실시예에서 에어로졸 매질 집합체는, 증점제는 셀룰로오스 유도체(Cellulose derivatives), 덱스트린 유도체(Dextrin derivatives), 알지네이트 유도체(Alginate derivatives), 검(Gum), 펙틴(Pectin), 헤미셀룰로오스 유도체(Hemicellulose derivatices) 및 젤라틴(Gelatin)을 포함하는 군에서 선택된 하나 이상의 물질을 포함하는 것을 특징으로 한다.In addition, in some embodiments, the aerosol medium aggregate, the thickener is cellulose derivatives, dextrin derivatives, alginate derivatives, gum, pectin, hemicellulose derivatives and It is characterized in that it contains one or more substances selected from the group containing gelatin.
또한 어느 실시예에서 에어로졸 매질 집합체는, 에어로졸 매질은, 액상의 VG(식물성 글리세린)와 PG(프로필렌 글리콜) 혼합물, 증점제 및 용해제의 혼합 용액을 복수의 다공성 알갱이와 혼합하여 다공성 알갱이에 흡습시키고, 다공성 알갱이에 흡습된 혼합 용액에 포함된 용해제를 증발시켜 형성되며, 용해제는 액상의 VG(식물성 글리세린)와 PG(프로필렌 글리콜) 혼합물 및 증점제보다 끓는 점이 낮은 것을 특징으로 한다.In addition, in one embodiment, the aerosol medium aggregate is a mixture of a liquid VG (vegetable glycerin) and PG (propylene glycol) mixture, a thickener, and a solubilizing agent mixed with a plurality of porous granules to absorb moisture into the porous granules. It is formed by evaporating the solubilizer contained in the mixed solution absorbed by the grains, and the solubilizer is characterized by a lower boiling point than the liquid VG (vegetable glycerin) and PG (propylene glycol) mixture and thickener.
또한 본 발명의 일 실시예의 에어로졸 매질 로드는, 상기 어느 실시예의 에어로졸 매질 집합체 및 에어로졸 매질 집합체를 실린더 형상으로 랩핑하는 랩핑 페이퍼를 포함하는 것을 특징으로 한다.Additionally, the aerosol medium rod of one embodiment of the present invention is characterized in that it includes the aerosol medium assembly of any of the above embodiments and a wrapping paper that wraps the aerosol medium assembly into a cylinder shape.
또한 본 발명의 일 실시예의 가열식 흡연 물품은, 필터 로드, 필터 로드의 하단에 적층되며 상하 방향으로 중공이 형성된 냉각 튜브 로드 및 냉각 튜브 로드의 하단에 적층되는 상기 어느 실시예에 따른 에어로졸 매질 집합체를 포함하고, 필터 로드와 냉각 튜브 로드와 에어로졸 매질 집합체는 랩핑 페이퍼로 랩핑되어 궐련을 형성하는 것을 특징으로 한다.In addition, the heated smoking article of one embodiment of the present invention includes a filter rod, a cooling tube rod laminated on the bottom of the filter rod and hollow in the vertical direction, and an aerosol medium assembly according to any of the above embodiments laminated on the bottom of the cooling tube rod. Including, the filter rod, the cooling tube rod, and the aerosol medium assembly are wrapped with wrapping paper to form a cigarette.
또한 어느 실시예에서 가열식 흡연 물품은, 에어로졸 매질 집합체는 별도의 랩핑 페이퍼에 의해 실린더 형상으로 랩핑되어 있는 것을 특징으로 한다.Additionally, in one embodiment, the heated smoking article is characterized in that the aerosol medium assembly is wrapped in a cylindrical shape by a separate wrapping paper.
또한 어느 실시예에서 가열식 흡연 물품은, 에어로졸 매질 집합체의 상단 또는 하단에 추가로 적층되는, 담배 각초를 포함하는 담배체 로드를 포함하며, 필터 로드와 냉각 튜브 로드와 에어로졸 매질 집합체와 추가로 적층되는 담배체 로드가 랩핑되어 궐련을 형성하는 것을 특징으로 한다.Additionally, in some embodiments, the heated smoking article includes a tobacco body rod including a tobacco filler, further laminated to the top or bottom of the aerosol medium assembly, and further laminated to the aerosol medium assembly and a filter rod and cooling tube rod. The tobacco body rod is wrapped to form a cigarette.
또한 어느 실시예에서 가열식 흡연 물품은, 냉각 튜브 로드의 하단에 적층되는, 담배체를 포함하는 담배체 로드를 더 포함하고, 에어로졸 매질 집합체는 담배체 로드 내측에 분포하도록 포함되는 것을 특징으로 한다.In addition, in one embodiment, the heated smoking article further includes a tobacco body rod including a tobacco body, which is stacked at the bottom of the cooling tube rod, and the aerosol medium aggregate is included to be distributed inside the tobacco body rod.
또한 어느 실시예에서 가열식 흡연 물품은, 담배체 로드는 별도의 랩핑 페이퍼에 의해 실린더 형상으로 랩핑되어 있는 것을 특징으로 한다.In addition, in one embodiment, the heated smoking article is characterized in that the tobacco rod is wrapped in a cylindrical shape by a separate wrapping paper.
또한 어느 실시예에서 가열식 흡연 물품은, 에어로졸 매질 집합체는 그 중심부를 상하로 관통하도록 형성된 중공을 포함하도록 배치되고, 상기 중공에는 담배체가 구비되는 것을 특징으로 한다.In addition, in one embodiment of the heated smoking article, the aerosol medium assembly is arranged to include a hollow formed to penetrate upward and downward through the center, and the hollow is provided with a tobacco body.
또한 어느 실시예에서 가열식 흡연 물품은, 에어로졸 매질 집합체에 형성된 중공과 에어로졸 매질 집합체의 경계면에는 메쉬 또는 다수의 통공을 갖는 통기막이 형성된 것을 특징으로 한다.In addition, in one embodiment, the heated smoking article is characterized in that a mesh or a breathable membrane having a plurality of through holes is formed at the interface between the hollow formed in the aerosol medium assembly and the aerosol medium assembly.
또한 본 발명의 일 실시예의 에어로졸 매질 집합체의 제조 방법은, 가열에 의해 에어로졸을 생성하는 에어로졸 매질을 포함하는 에어로졸 매질 집합체의 제조 방법에 있어서, 용기에 액상의 에어로졸 매질을 준비하는 단계, 표면이나 내부에 마이크로 기공이 형성된 복수의 다공성 알갱이를 용기에 도입하여 액상의 에어로졸 매질과 혼합하고 다공성 알갱이에 흡습시키는 단계, 및 거름망을 이용하여, 액상의 에어로졸 매질을 흡습한 다공성 알갱이들과 잔존하는 액상의 에어로졸 매질을 분리하는 단계를 포함하는 것을 특징으로 한다.In addition, the method for producing an aerosol medium aggregate of an embodiment of the present invention includes the steps of preparing a liquid aerosol medium in a container, the surface or the inside of the aerosol medium. Introducing a plurality of porous particles with micropores into a container, mixing them with a liquid aerosol medium, and absorbing moisture into the porous particles, and using a filter, the porous particles that have absorbed moisture from the liquid aerosol medium and the remaining liquid aerosol. It is characterized by comprising the step of separating the medium.
또한 어느 실시예에서 에어로졸 매질 집합체의 제조 방법은, 액적이 흐르지 않도록, 액상의 에어로졸 매질을 흡습한 다공성 알갱이들을 소정 시간 건조하는 단계를 추가로 포함하는 것을 특징으로 한다.In addition, in one embodiment, the method for producing an aerosol medium aggregate further includes the step of drying the porous particles that have absorbed the liquid aerosol medium for a predetermined period of time to prevent the droplets from flowing.
또한 어느 실시예에서 에어로졸 매질 집합체의 제조 방법은, 액상의 에어로졸 매질을 흡습한 다공성 알갱이들을 냉각하여, 액상의 에어로졸 매질을 겔상화 하는 단계를 추가로 포함하는 것을 특징으로 한다.In addition, in one embodiment, the method for producing an aerosol medium aggregate further includes the step of cooling the porous particles that have absorbed the liquid aerosol medium to gel the liquid aerosol medium.
또한 본 발명의 일 실시예의 에어로졸 매질 집합체의 제조 방법은, 가열에 의해 에어로졸을 생성하는 고형화된 에어로졸 매질을 포함하는 에어로졸 매질 집합체의 제조 방법에 있어서, 용기에 에어로졸 매질, 증점제 및 용해제의 혼합 용액을 준비하는 단계(용액 준비 단계), 표면이나 내부에 마이크로 기공이 형성된 복수의 다공성 알갱이를 용기에 도입하여 상기 혼합 용액과 혼합하여 혼합 용액을 다공성 알갱이에 흡습시키는 단계(흡습 단계), 거름망을 이용하여, 혼합 용액을 흡습한 다공성 알갱이들과 잔존하는 혼합 용액을 분리하는 단계(분리 단계) 및 다공성 알갱이에 흡습된 혼합 용액에 포함된 용해제를 증발시켜 고형화된 에어로졸 매질을 얻는 단계(고형화 단계)를 포함하는 것을 특징으로 한다.In addition, the method for producing an aerosol medium aggregate of an embodiment of the present invention includes a solidified aerosol medium that generates an aerosol by heating, comprising adding a mixed solution of the aerosol medium, a thickener, and a solubilizing agent to a container. Preparation step (solution preparation step), introducing a plurality of porous granules with micro pores formed on the surface or inside into a container and mixing them with the mixed solution to absorb moisture into the porous granules (moisture absorption step), using a strainer , Separating the remaining mixed solution from the porous granules that absorbed the mixed solution (separation step), and evaporating the solvent contained in the mixed solution absorbed by the porous granules to obtain a solidified aerosol medium (solidification step). It is characterized by:
또한 어느 실시예에서 에어로졸 매질 집합체의 제조 방법은, 용해제는 에어로졸 매질 및 증점제보다 끓는 점이 낮고, 고형화 단계에서, 혼합 용액을 흡습한 다공성 알갱이를, 용해제의 끓는 점보다 높고 에어로졸 매질 및 증점제의 끓는 점보다 낮은 온도로 가열하여, 혼합 용액에 포함된 용해제를 증발시키고, 에어로졸 매질 및 증점제를 포함하는 고형화된 에어로졸 매질을 얻는 것을 특징으로 한다.In addition, in one embodiment, the method for producing an aerosol medium aggregate is such that the boiling point of the dissolving agent is lower than that of the aerosol medium and the thickener, and in the solidification step, the porous granules that absorb moisture from the mixed solution are placed at a boiling point higher than the boiling point of the dissolving agent and the boiling point of the aerosol medium and the thickening agent. By heating to a lower temperature, the solvent contained in the mixed solution is evaporated and a solidified aerosol medium containing the aerosol medium and the thickener is obtained.
실시예인 에어로졸 매질 집합체는 비표면적이 증가된 다공성 알갱이 또는 구형 알갱이들을 포함하여 구성됨으로써, 그에 따라 에어로졸 매질의 흡습량을 증가시킬 수 있으며 모세관 현상에 따른 에어로졸 매질의 이송량도 증가시킴으로써, 최종적으로 에어로졸 발생량을 증가시킬 수 있는 효과가 있다.The aerosol medium aggregate of the embodiment is composed of porous particles or spherical particles with an increased specific surface area, thereby increasing the moisture absorption of the aerosol medium and increasing the amount of transport of the aerosol medium due to capillary action, ultimately increasing the amount of aerosol generated. It has the effect of increasing .
또한, 실시예에 따른 에어로졸 매질 집합체의 단위 알갱이들은 버나드셀 현상이 이루어지는 다공성 알갱이들 또는 다공성 구형 알갱이들로 이루어짐으로써, 버나드 셀 현상에 의해 입자의 표면에 결함이 유도되어 결과적으로 다공성 알갱이의 비표면적을 증가시킬 수 있고 그에 따라 액상의 흡습량을 증가시킬 수 있으며 최종적으로 에어로졸 발생량을 증가시킬 수 있다는 효과가 있다.In addition, the unit grains of the aerosol medium aggregate according to the embodiment are composed of porous grains or porous spherical grains in which the Bernard cell phenomenon occurs, so that defects are induced on the surface of the particles by the Bernard cell phenomenon, resulting in the specific surface area of the porous grains. This has the effect of increasing the moisture absorption of the liquid phase and ultimately increasing the amount of aerosol generated.
또한 실시예에 따르면, 다공성 알갱이를 에어로졸 매질과 혼합하는 방식으로 용이하게 흡습시킬 수 있어, 제조가 용이해지는 효과가 있다.In addition, according to the example, the porous particles can be easily absorbed by mixing them with an aerosol medium, which has the effect of facilitating manufacturing.
또한 실시예에 따르면, 다공성 알갱이를 담배 매질 내지 담배체에 포함시켜, 사용자는 담배 매질 내지 담배체로부터 유래하는 물질과 다공성 알갱이에 흡습된 에어로졸 매질로부터 유래하는 물질을 동시에 흡입할 수 있으며, 무화량도 증가하여 사용자 경험이 개선된다.In addition, according to an embodiment, porous granules are included in the tobacco medium or tobacco body, so that the user can simultaneously inhale substances derived from the tobacco medium or tobacco body and substances derived from the aerosol medium moisture absorbed by the porous granules, and the amount of atomization is reduced. also increases, improving user experience.
도 1은 본 발명의 일 실시예에 따른 에어로졸 매질 집합체(30)를 개념적으로 도시한 단면도,1 is a cross-sectional view conceptually showing an aerosol medium aggregate 30 according to an embodiment of the present invention;
도 2는 본 발명의 일 실시예에 따른 복수의 다공성 알갱이(30a)의 주사현미경 사진,Figure 2 is a scanning microscope photograph of a plurality of porous grains (30a) according to an embodiment of the present invention;
도 3은 본 발명의 일 실시예에 따른 다공성 알갱이(30a)의 개념적인 평면도,Figure 3 is a conceptual plan view of porous grains 30a according to an embodiment of the present invention;
도 4는 본 발명의 일 실시예에 따른, 액상 또는 겔상의 에어로졸 매질을 포함하는 에어로졸 매질 집합체(30)의 제조 방법을 나타낸 순서도,Figure 4 is a flow chart showing a method of manufacturing an aerosol medium aggregate 30 containing a liquid or gel-like aerosol medium according to an embodiment of the present invention;
도 5는 도 4의 제조 방법을 이해하기 쉽게 표현한 개념도,Figure 5 is a conceptual diagram expressing the manufacturing method of Figure 4 in an easy-to-understand manner;
도 6은 본 발명의 일 실시예에 따른, 고형화된 에어로졸 매질을 포함하는 에어로졸 매질 집합체(30)의 제조 방법을 나타낸 순서도,Figure 6 is a flow chart showing a method of manufacturing an aerosol medium aggregate 30 including a solidified aerosol medium according to an embodiment of the present invention;
도 7은 본 발명의 일 실시예에 따른 가열식 흡연 물품(1)의 내부를 개념적으로 나타낸 수직 단면도,7 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1 according to an embodiment of the present invention;
도 8은 본 발명의 또 다른 실시예에 따른 가열식 흡연 물품(1a)의 내부를 개념적으로 나타낸 수직 단면도,8 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1a according to another embodiment of the present invention;
도 9는 본 발명의 또 다른 실시예에 따른 가열식 흡연 물품(1b)의 내부를 개념적으로 나타낸 수직 단면도,9 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1b according to another embodiment of the present invention;
도 10은 본 발명의 또 다른 실시예에 따른 가열식 흡연 물품(1c)의 내부를 개념적으로 나타낸 수직 단면도,10 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1c according to another embodiment of the present invention;
도 11은 본 발명의 또 다른 실시예에 따른 에어로졸 매질 집합체(35)를 개념적으로 도시한 단면도이다.Figure 11 is a cross-sectional view conceptually showing an aerosol medium aggregate 35 according to another embodiment of the present invention.
이하에서, 실시예들은 도면을 통하여 상세하게 설명된다. 그러나, 이는 특정한 실시 형태에 대해 한정하려는 것이 아니며, 설명되는 실시예들은 그 실시예들의 다양한 변경(modification), 균등물(equivalent), 및/또는 대체물(alternative)을 포함하는 것으로 이해되어야 한다. 도면의 설명과 관련하여, 유사한 구성요소에 대해서는 유사한 참조 부호가 사용될 수 있다.Hereinafter, embodiments are described in detail through the drawings. However, this is not intended to be limiting to specific embodiments, and the described embodiments should be understood to include various modifications, equivalents, and/or alternatives of the embodiments. In connection with the description of the drawings, similar reference numbers may be used for similar components.
본 문서에서, "가진다", "가질 수 있다", "포함한다", 또는 "포함할 수 있다" 등의 표현은 해당 특징(예: 수치, 기능, 동작, 또는 부품 등의 구성요소)의 존재를 가리키며, 추가적인 특징의 존재를 배제하지 않는다.In this document, expressions such as “have,” “may have,” “includes,” or “may include” refer to the existence of the corresponding feature (e.g., a numerical value, function, operation, or component such as a part). , and does not rule out the existence of additional features.
본 문서에서, "A 또는 B", "A 또는/및 B 중 적어도 하나", 또는 "A 또는/및 B 중 하나 또는 그 이상" 등의 표현은 함께 나열된 항목들의 모든 가능한 조합을 포함할 수 있다. 예를 들면, "A 또는 B", "A 및 B 중 적어도 하나", 또는 "A 또는 B 중 적어도 하나"는, (1) 적어도 하나의 A를 포함, (2) 적어도 하나의 B를 포함, 또는 (3) 적어도 하나의 A 및 적어도 하나의 B 모두를 포함하는 경우를 모두 지칭할 수 있다.In this document, expressions such as “A or B,” “at least one of A or/and B,” or “one or more of A or/and B” may include all possible combinations of the items listed together. . For example, “A or B”, “at least one of A and B”, or “at least one of A or B” (1) includes at least one A, (2) includes at least one B, or (3) it may refer to all cases including both at least one A and at least one B.
본 문서에서 사용된 "제1", "제2", "첫째", 또는 "둘째" 등의 표현들은 다양한 구성요소들을, 순서 및/또는 중요도에 상관없이 수식할 수 있고, 한 구성요소를 다른 구성요소와 구분하기 위해 사용될 뿐 해당 구성요소들을 한정하지 않는다. 예를 들면, 제1 사용자 기기와 제2 사용자 기기는, 순서 또는 중요도와 무관하게, 서로 다른 사용자 기기를 나타낼 수 있다. 예를 들면, 본 문서에 기재된 권리 범위를 벗어나지 않으면서 제1 구성요소는 제2 구성요소로 명명될 수 있고, 유사하게 제2 구성요소도 제1 구성요소로 바꾸어 명명될 수 있다. As used herein, expressions such as "first", "second", "first", or "second" may describe various elements in any order and/or importance, and may refer to one element as another. It is only used to distinguish from components and does not limit the components. For example, a first user device and a second user device may represent different user devices regardless of order or importance. For example, a first component may be renamed a second component without departing from the scope of rights described in this document, and similarly, the second component may also be renamed to the first component.
본 문서에서 사용된 용어들은 단지 특정한 실시 예를 설명하기 위해 사용된 것으로, 다른 실시 예의 범위를 한정하려는 의도가 아닐 수 있다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함할 수 있다. 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 용어들은 본 문서에 기재된 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가질 수 있다. 본 문서에 사용된 용어들 중 일반적인 사전에 정의된 용어들은 관련 기술의 문맥 상 가지는 의미와 동일 또는 유사한 의미로 해석될 수 있으며, 본 문서에서 명백하게 정의되지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다. 경우에 따라서, 본 문서에서 정의된 용어일지라도 본 문서의 실시 예들을 배제하도록 해석될 수 없다.Terms used in this document are merely used to describe specific embodiments and may not be intended to limit the scope of other embodiments. Singular expressions may include plural expressions, unless the context clearly indicates otherwise. Terms used herein, including technical or scientific terms, may have the same meaning as commonly understood by a person of ordinary skill in the technical field described in this document. Among the terms used in this document, terms defined in general dictionaries may be interpreted to have the same or similar meaning as the meaning they have in the context of related technology, and unless clearly defined in this document, they may be interpreted in an ideal or excessively formal sense. It is not interpreted. In some cases, even terms defined in this document cannot be interpreted to exclude embodiments of this document.
도 1은 본 발명의 일 실시예에 따른 에어로졸 매질 집합체(30)를 개념적으로 도시한 단면도, 도 2는 본 발명의 일 실시예에 따른 복수의 다공성 알갱이(30a)의 주사현미경 사진, 도 3은 본 발명의 일 실시예에 따른 다공성 알갱이(30a)의 개념적인 평면도이다. 본 개시의 도면들에 있어서 어느 구성요소, 특히 다공성 알갱이(30a)의 도시에 있어서 크기는 가시성을 위하여 과장되어 표현되었으며, 도면상의 상대적인 크기에 의해 구성요소들의 크기가 한정되는 것은 아니다. 본 실시예에서 에어로졸 매질 집합체(30)는 표면이나 내부에 마이크로 기공(도 3에서 A로 지시됨)이 형성된 복수의 다공성 알갱이(30a)를 포함한다. 또한 상기 다공성 알갱이(30a)는 가열에 의해 에어로졸을 생성하는 에어로졸 매질을 수용하고 있다.Figure 1 is a cross-sectional view conceptually showing an aerosol medium aggregate 30 according to an embodiment of the present invention, Figure 2 is a scanning microscope photograph of a plurality of porous particles 30a according to an embodiment of the present invention, and Figure 3 is a This is a conceptual plan view of porous grains 30a according to an embodiment of the present invention. In the drawings of the present disclosure, the sizes of certain components, particularly the porous grains 30a, are exaggerated for visibility, and the sizes of the components are not limited by their relative sizes in the drawings. In this embodiment, the aerosol medium aggregate 30 includes a plurality of porous particles 30a with micropores (indicated by A in FIG. 3) formed on the surface or inside. Additionally, the porous particles 30a accommodate an aerosol medium that generates an aerosol by heating.
다공성 알갱이(30a)는 에어로졸 매질 집합체(30)를 형성하는 단위 요소로서 특히 본 실시예에서는 버나드셀 현상을 이용하여 형성된다. 버나드 셀 현상에 의해 입자의 표면에 결함, 즉 마이크로 기공(A)이 유도되어 결과적으로 다공성 알갱이(30a)의 비표면적을 증가시킬 수 있고 그에 따라 에어로졸 매질의 흡습량 내지 수용량을 증가시킬 수 있으며, 최종적으로 에어로졸 매질 집합체(30)로부터 기인하는 에어로졸 발생량을 증가시킬 수 있다. The porous grains 30a are unit elements forming the aerosol medium aggregate 30, and in particular, in this embodiment, they are formed using the Bernard Cell phenomenon. Due to the Barnard cell phenomenon, defects, that is, micropores (A), are induced on the surface of the particles, which can consequently increase the specific surface area of the porous grains (30a) and thereby increase the moisture absorption or water capacity of the aerosol medium, Ultimately, the amount of aerosol generated from the aerosol medium aggregate 30 can be increased.
버나드셀 현상을 이용한, 표면이나 내부에 마이크로 기공이 형성된 복수의 다공성 알갱이(30a)의 예시적인 제조방법은, 금속 이온과 결합된 실리케이트 분말과 결합제를 제1 용매에 분산하여 제1 분산 용액을 제조하는 단계, 첨가제를 제2 용매에 분산시켜 교반하여 제2 분산 용액을 제조하는 단계, 제1 분산 용액과 제2 분산 용액을 혼합하고 교반하여 혼합 슬러리를 제조하는 단계 및 혼합 슬러리를 분무 건조하는 단계를 포함한다.An exemplary method of manufacturing a plurality of porous grains (30a) with micropores formed on the surface or inside using the Bernard Cell phenomenon is to prepare a first dispersion solution by dispersing silicate powder bonded to a metal ion and a binder in a first solvent. a step of preparing a second dispersion solution by dispersing and stirring the additive in a second solvent, preparing a mixed slurry by mixing and stirring the first dispersion solution and the second dispersion solution, and spray drying the mixed slurry. Includes.
이때, 금속 실리케이트 분말은 Mg, Al, Zr, Li, Ba, MgAl, Na 및 Ca 중에서 선택된 하나 이상의 금속 이온을 포함하는 것이 바람직하며, 금속 실리케이트 분말은 제1 용매 대비 5 내지 40 wt% 분산된다. At this time, the metal silicate powder preferably contains one or more metal ions selected from Mg, Al, Zr, Li, Ba, MgAl, Na, and Ca, and the metal silicate powder is dispersed in an amount of 5 to 40 wt% relative to the first solvent.
한편, 제1 분산 용액의 제조에 사용되는 결합제는 폴리비닐알콜, 폴리비닐 아세테이트, 폴리에틸렌, 폴리비닐부티렌, 폴리프로필렌, 폴리염화비닐, 폴리 아크릴, 폴리 아크릴 아미드, 구아 검, 젤라틴, 천연고무 중에서 선택된 하나 이상인 것이 바람직하다. Meanwhile, the binder used in the preparation of the first dispersion solution is selected from polyvinyl alcohol, polyvinyl acetate, polyethylene, polyvinylbutylene, polypropylene, polyvinyl chloride, polyacrylic, polyacrylamide, guar gum, gelatin, and natural rubber. It is desirable to have more than one selected.
또한 제1 용매는 물, 에탄올, 톨루엔, IPA, 아세톤 중에서 선택된 하나 이상을 포함하며, 제1 용매는 금속 실리케이트 중량 대비 70~220 wt% 사용되는 것이 바람직하다. In addition, the first solvent includes one or more selected from water, ethanol, toluene, IPA, and acetone, and it is preferable that the first solvent is used in an amount of 70 to 220 wt% based on the weight of the metal silicate.
이때, 제1 분산 용액의 제조에 사용되는 첨가제는 미네랄 스프릿 또는 자일렌과 같은 고비점 용제를 포함하는 것이 바람직하며, 금속 실리케이트 대비 0.5~10 wt% 첨가되는 것이 바람직하다. 첨가제에 따라 다르나 유기물 첨가제의 경우 10 wt% 이상이 될 경우 비드 형태를 유지하기 불가하고, 고점성을 유발하며, 작업성 저하될 수 있다. At this time, the additive used in the preparation of the first dispersion solution preferably includes a high boiling point solvent such as mineral spirits or xylene, and is preferably added in an amount of 0.5 to 10 wt% relative to the metal silicate. It varies depending on the additive, but in the case of organic additives, if the amount is more than 10 wt%, it may be impossible to maintain the bead shape, cause high viscosity, and reduce workability.
또한 제2 용액은 물, 에탄올, 톨루엔, IPA, 아세톤 중에서 선택된 하나 이상을 포함하며, 금속 실리케이트 대비 5 내지 30 wt% 포함되는 것이 바람직하다. Additionally, the second solution contains at least one selected from water, ethanol, toluene, IPA, and acetone, and is preferably contained in an amount of 5 to 30 wt% based on the metal silicate.
제1 분산 용액과 제2 분산 용액을 혼합하고 교반하여 혼합 슬러리를 제조한 다음 혼합 슬러리를 분무 건조하여 마이크로 기공이 형성된 다공성 알갱이를 형성한다. 이때, 분무 건조는 디스크 방식을 사용하며, 디스크의 회전 속도는 500 내지 9000 rpm의 범위 내에서 조절되는 것이 바람직하다. 디스크의 회전 속도는 500 rpm보다 작으면 원심력으로 인한 효과가 크지 않아 구형 입자의 크기가 지나치게 커진다. 반면, 회전 디스크의 회전 속도가 9000 rpm이 넘어가면 20㎛ 이하의 구형 입자들의 생성 비율이 높아지고, 이러한 소형 구형 입자들이 에어로졸 발생 장치의 히터 또는 액상 흡습체의 제조 시에 오히려 히터 또는 액상 흡습체의 표면 기공을 막아버려 오히려 비표면적을 감소시키는 단점이 있다. 따라서 디스크의 회전 속도는 500 내지 9000 rpm의 범위 내에서 조절되는 것이 바람직하다.The first dispersion solution and the second dispersion solution are mixed and stirred to prepare a mixed slurry, and then the mixed slurry is spray dried to form porous granules with micropores. At this time, spray drying uses a disk method, and the rotation speed of the disk is preferably adjusted within the range of 500 to 9000 rpm. If the rotation speed of the disk is less than 500 rpm, the effect due to centrifugal force is not significant, and the size of the spherical particles becomes excessively large. On the other hand, when the rotation speed of the rotating disk exceeds 9000 rpm, the generation rate of spherical particles of 20㎛ or less increases, and these small spherical particles rather form a part of the heater or liquid hygroscopic body when manufacturing the heater or liquid hygroscopic body of the aerosol generating device. It has the disadvantage of blocking surface pores and reducing the specific surface area. Therefore, it is desirable that the rotation speed of the disk is adjusted within the range of 500 to 9000 rpm.
혼합 슬러리가 분무되는 디스크는 220~300 ℃ 온도를 유지하는 챔버 내에서 회전하며, 분무 건조 단계에서 버나드셀 현상이 유발되어, 도 2의 사진과 같이 표면 결함(크랙)을 유발하여 다공성 알갱이의 비표면적을 증가시킬 수 있다. 이때, 마이크로 기공이 형성된 다공성 알갱이는 제조 과정에서 조공제를 별도로 첨가하지 않고도 마이크로 기공을 형성할 수 있다는 장점이 있다. 이렇게 제조된 마이크로 기공이 형성된 다공성 알갱이는 비표면적을 증가시킬 수 있다. 따라서 실시예에 따른 버나드 셀 현상을 이용한 마이크로 기공이 형성된 다공성 알갱이로 에어로졸 발생장치의 히터 또는 에어로졸 매질 흡습체를 제조할 경우, 에어로졸 매질을 흡습할 수 있는 흡습량 내지 수용량이 증가하고, 그에 따라 에어로졸 매질을 기화시켜 발생할 수 있는 무화량을 증가시킬 수 있다는 장점이 있다. The disk on which the mixed slurry is sprayed rotates in a chamber maintaining a temperature of 220 to 300 ℃, and the Bernard Cell phenomenon is induced during the spray drying stage, causing surface defects (cracks) as shown in the photo in Figure 2, increasing the ratio of porous grains. Surface area can be increased. At this time, porous grains with micro pores have the advantage of being able to form micro pores without adding a separate pore-forming agent during the manufacturing process. The porous granules with micropores produced in this way can increase the specific surface area. Therefore, when a heater of an aerosol generating device or an aerosol medium moisture absorber is manufactured from porous granules in which micropores are formed using the Barnard cell phenomenon according to the embodiment, the moisture absorption or capacity capable of absorbing the aerosol medium increases, and accordingly the aerosol It has the advantage of being able to increase the amount of atomization that can occur by vaporizing the medium.
이상에서 설명한 다공성 알갱이들(30a)은 도 2의 주사현미경 사진으로 확인할 수 있듯이 표면 결함(크랙)의 유발에 의해 그 표면에 다수의 홈이나 기공(A)이 형성된 다공성 입체(또는 구형) 입자로서, 그 비표면적이 현저하게 증가된 상태이다. 다공성 알갱이(30a)는 비드 형태이거나 구형 분말 형태일 수 있다. 다공성 알갱이(30a)의 직경이나 사이즈는, 에어로졸 매질을 효과적으로 흡수할 비표면적을 확보할 수 있는 크기로서, 바람직하게 10 ㎛ ~ 300 ㎛의 범위에 속한다. 다공성 알갱이(30a)의 표면이나 내부에 형성된 기공(A)은 마이크로 기공에 해당되며, 에어로졸 매질을 효과적으로 수용할 수 있도록 바람직하게는 그 직경이 20 ㎛ ~ 50 ㎛ 범위에 속한다.The porous grains 30a described above are porous three-dimensional (or spherical) particles with a plurality of grooves or pores (A) formed on the surface by causing surface defects (cracks), as can be seen in the scanning microscope photo of FIG. 2. , its specific surface area has been significantly increased. The porous grains 30a may be in the form of beads or spherical powder. The diameter or size of the porous particles 30a is a size capable of securing a specific surface area to effectively absorb the aerosol medium, and preferably falls within the range of 10 ㎛ to 300 ㎛. The pores A formed on the surface or inside the porous grain 30a correspond to micro pores, and preferably have a diameter in the range of 20 ㎛ to 50 ㎛ to effectively accommodate the aerosol medium.
에어로졸 매질 집합체(30)가 포함하는 복수의 다공성 알갱이(30a) 사이의 기공은 매크로 기공(도 1에서 B로 지시됨)에 해당되며, 1 ㎛ ~ 130 ㎛ 범위에 속하며, 더욱 바람직하게는 1 ㎛ ~ 20 ㎛ 범위에 속한다. 예를 들어 에어로졸 매질 집합체(30)는 소정의 공간에 장입된, 에어로졸 매질을 수용한, 복수의 다공성 알갱이(30a)들의 집합체일 수 있다. 이 때 상기 소정의 공간 내에 장입된 복수의 다공성 알갱이(30a)들 사이에 형성되는 간격들이 매크로 기공(B)이 될 수 있다. 바람직하게 에어로졸 매질 집합체(30)의 기공율은 30 % ~ 70 % 범위에 속한다. 여기에서 기공율은 매크로 기공(B)과 마이크로 기공(A)의 총합으로 계산될 수 있다. The pores between the plurality of porous particles 30a included in the aerosol medium aggregate 30 correspond to macro pores (indicated by B in FIG. 1) and range from 1 ㎛ to 130 ㎛, more preferably 1 ㎛. It falls in the range of ~20 ㎛. For example, the aerosol medium assembly 30 may be an aggregate of a plurality of porous particles 30a charged into a predetermined space and containing the aerosol medium. At this time, the gaps formed between the plurality of porous grains 30a charged in the predetermined space may become macro pores B. Preferably, the porosity of the aerosol medium aggregate 30 is in the range of 30% to 70%. Here, porosity can be calculated as the total of macro pores (B) and micro pores (A).
다공성 알갱이(30a)들 각각은 금속 성분과 실리케이트로 구성된다. 금속 성분은 알루미늄, 마그네슘, 칼슘 등의 알칼리토류족의 소재이다. 특히, 다공성 알갱이(30a)의 재질은 마그네슘 실리케이트, 알루미늄 실리케이트, 규산 실리케이트, 제올라이트, 산화 티탄, 탄화 티탄, 지르코니아, 실리카, 탄화규소, 질화규소, 뮬라이트, 코디어라이트, 탄화 텅스텐, 탄화 지르코늄, 질화 알루미늄을 포함하는 군에서 선택된 하나 이상의 물질을 포함하여 구성된다. Each of the porous grains 30a is composed of a metal component and silicate. The metal component is an alkaline earth material such as aluminum, magnesium, and calcium. In particular, the material of the porous grains 30a is magnesium silicate, aluminum silicate, silicate silicate, zeolite, titanium oxide, titanium carbide, zirconia, silica, silicon carbide, silicon nitride, mullite, cordierite, tungsten carbide, zirconium carbide, and aluminum nitride. It is composed of one or more substances selected from the group containing.
다공성 알갱이(30a)는 에어로졸 매질의 흡습 내지 수용을 위해 친수성 성질을 지니는 것이 바람직하다. 또한, 다공성 알갱이(30a)는 추가적으로 섬유 글라스(glass)를 포함할 수 있다. 이러한 섬유 글라스에 SiO2가 50 % 이상의 중량 퍼센트로 포함된다.The porous particles 30a preferably have hydrophilic properties in order to absorb or accommodate moisture in the aerosol medium. Additionally, the porous grains 30a may additionally include fiber glass. These fiber glasses contain SiO2 in weight percent of more than 50%.
실시예에서 복수의 다공성 알갱이(30a)는 에어로졸 매질을 흡습 내지 수용하는 기능 및/또는, 에어로졸 발생 장치나 카트리지에 장착되어, 액상화된 에어로졸 매질을 모세관 현상에 의해 이송시키는 기능을 지닌다. 이러한 흡습 기능과 이송 기능은 실시예와 같은 마이크로 기공과 매크로 기공을 포함하는 다공성 알갱이들(30a)로 구성된 에어로졸 매질 집합체(30)에서 보다 원활하게 수행될 수 있다. 이러한 흡습 기능과 이송 기능에 의해서, 에어로졸 발생 장치나 카트리지에 적용될 경우, 사용자에 의한 퍼프 시에 일정한 에어로졸 매질의 이송이 가능함으로써 일정한 양의 연무가 발생되도록 할 수 있다.In the embodiment, the plurality of porous particles 30a have the function of absorbing or receiving the aerosol medium and/or are mounted on an aerosol generating device or cartridge and have the function of transporting the liquefied aerosol medium by capillary action. These moisture absorption and transport functions can be performed more smoothly in the aerosol medium aggregate 30 composed of porous particles 30a containing micro-pores and macro-pores as in the embodiment. Due to these moisture absorption and transfer functions, when applied to an aerosol generating device or cartridge, it is possible to transfer a certain amount of aerosol medium when a user puffs, thereby generating a certain amount of mist.
실시예들에 있어서, 에어로졸 매질 집합체(30)가 포함하는 복수의 다공성 알갱이(30a)는 소정의 바인더를 이용하여 입체 형상으로 블록화될 수 있다. 또는 이러한 블록화 과정 없이, 복수의 비드 형태나 구형 분말 형태의 다공성 알갱이(30a)를 소정 공간에 충진시키는 방법으로 에어로졸 발생 장치나 카트리지에 무화기로 적용할 수 있다. 다공성 알갱이(30a)를 에어로졸 매질을 수용한 상태로 에어로졸 발생 장치나 카트리지에 장입하고, 히터가 이를 가열할 수 있도록 배치할 수 있다. 이 때 히터의 형태는 블레이드 형태나 원통형, 핀형 등 다양한 형태를 가질 수 있다. 에어로졸 매질 집합체(30)는 특정한 형상을 가지지 않기 때문에, 히터의 형태나 배치가 자유롭고, 히터와 에어로졸 매질 집합체(30)의 접촉면적을 넓힐 수 있다는 장점이 있다. 또한 제조 단계에 있어서, 에어로졸 매질을 다공성 알갱이(30a)에 수용시킬 때, 복수의 다공성 알갱이(30a) 자체를 액상의 에어로졸 매질에 담그거나 그와 혼합시키는 방법으로 빠르고 용이하게 에어로졸 매질을 흡습시켜 수용할 수 있다.In embodiments, the plurality of porous particles 30a included in the aerosol medium aggregate 30 may be block into a three-dimensional shape using a predetermined binder. Alternatively, without this blocking process, the atomizer can be applied to an aerosol generating device or cartridge by filling a predetermined space with a plurality of porous particles 30a in the form of beads or spherical powder. The porous particles 30a can be charged into an aerosol generating device or cartridge while accommodating the aerosol medium, and arranged so that a heater can heat it. At this time, the shape of the heater may have various shapes such as a blade shape, a cylindrical shape, or a fin shape. Since the aerosol medium assembly 30 does not have a specific shape, the shape or arrangement of the heater is free, and the contact area between the heater and the aerosol medium assembly 30 can be expanded. In addition, in the manufacturing step, when the aerosol medium is accommodated in the porous grains (30a), the plurality of porous grains (30a) themselves are immersed in or mixed with the liquid aerosol medium to quickly and easily absorb and accommodate the aerosol medium. can do.
결국 에어로졸 매질 집합체(30)가 포함하는 마이크로 기공(A)과 매크로 기공(B)에 에어로졸 매질이 효과적으로 수용될 수 있어, 제조가 용이해짐과 동시에 에어로졸 발생의 효율이 증가할 수 있다.Ultimately, the aerosol medium can be effectively accommodated in the micro pores (A) and macro pores (B) included in the aerosol medium assembly 30, making manufacturing easier and increasing the efficiency of aerosol generation.
실시예에 따라 에어로졸 매질 집합체(30)는 랩핑 페이퍼(31)에 의해 랩핑되어 실린더 형상의 에어로졸 매질 로드로 형성될 수 있다. 이 때 랩핑 페이퍼(31)는 다공성 알갱이(30a)가 충진되는 충진 공간을 실질적으로 정의하며, 적어도 에어로졸 매질 집합체(30)의 측면을 랩핑하여 다공성 알갱이(30a)가 에어로졸 매질 집합체(30)로부터 탈락하는 것을 방지할 수 있다. 바람직하게 랩핑 페이퍼(31)는 에어로졸 매질의 누액을 방지하기 위해 방수 코팅이 되어 있는 페이퍼나 멤브레인 재질로 이루어진다. 예를 들어, 랩핑 페이퍼(31)는 알루미늄 포일이 종이에 부착되어 형성된 합지로 제공될 수 있으며, 알루미늄 포일이 에어로졸 매질 집합체(30)에 접촉하도록 실린더 형상으로 랩핑된다. 이에 따라 알루미늄 포일은 에어로졸 매질 집합체(30)로부터 에어로졸 매질이 액화되어 에어로졸 매질 로드의 측면을 통해 흘러나올 가능성을 없애거나 최소화할 수 있다.Depending on the embodiment, the aerosol medium assembly 30 may be wrapped by wrapping paper 31 to form a cylindrical aerosol medium rod. At this time, the wrapping paper 31 substantially defines the filling space in which the porous particles 30a are filled, and wraps at least the side of the aerosol medium assembly 30 to prevent the porous particles 30a from falling off from the aerosol medium assembly 30. You can prevent it from happening. Preferably, the wrapping paper 31 is made of paper or membrane material with a waterproof coating to prevent leakage of the aerosol medium. For example, the wrapping paper 31 may be provided as a laminate formed by attaching aluminum foil to paper, and the aluminum foil is wrapped in a cylindrical shape so that it contacts the aerosol medium assembly 30. Accordingly, the aluminum foil can eliminate or minimize the possibility of the aerosol medium being liquefied from the aerosol medium assembly 30 and flowing out through the side of the aerosol medium rod.
에어로졸 매질 집합체(30)로부터 다공성 알갱이(30a)의 이탈을 방지하기 위하여, 소정의 바인더가 적용될 수 있으며, 또는 에어로졸 매질 로드의 형성 시, 랩핑 페이퍼(31)로 에어로졸 매질 집합체(30)의 측면뿐만이 아닌, 전체 방향을 감쌀 수도 있다. 다만 이 경우의 랩핑 페이퍼(31)는 에어로졸 입자는 통과시킬 수 있을 정도의 기공을 갖고 있는 것이 바람직하다.In order to prevent the porous particles 30a from leaving the aerosol medium assembly 30, a predetermined binder may be applied, or when forming the aerosol medium rod, only the side of the aerosol medium assembly 30 is covered with the wrapping paper 31. No, it can cover the entire direction. However, in this case, it is preferable that the wrapping paper 31 has pores large enough to allow aerosol particles to pass through.
도 1을 참조하면, 예를 들어, 에어로졸 매질 로드 형태의 에어로졸 매질 집합체(30)가 에어로졸 발생 장치 내에 삽입되어, 히터에 의해 특히 그 측면, 즉 랩핑 페이퍼(31)로 둘러쌓인 부분이 가열되면, 이 열은 다공성 알갱이(30a)에 수용되어 있는 에어로졸 매질을 가열하여, 궁극적으로는 에어로졸이 생성될 수 있다. 도 1과 같이 에어로졸 매질 집합체(30)가 랩핑 페이퍼(31)에 의해 그 측면이 둘러쌓여 에어로졸 매질 로드를 형성하는 경우, 사용자는 흡입 행위를 통하여, 화살표로 도시한, 하단에서 상단으로 향하는 공기 흐름을 발생시켜 에어로졸 매질로부터 기인하는 에어로졸을 흡입할 수 있다. 이와 같은 에어로졸 매질 집합체(30)의 사용에 있어 하단에서 상단으로 향하는 공기 흐름을 가정하면, 편의상 하단쪽을 “상류”로 참조할 수 있으며 상단쪽을 “하류”로 참조할 수 있다.Referring to Figure 1, for example, when an aerosol medium assembly 30 in the form of an aerosol medium rod is inserted into an aerosol generating device and heated by a heater, especially its side, i.e. the part surrounded by the wrapping paper 31, This heat heats the aerosol medium contained in the porous particles 30a, ultimately producing an aerosol. As shown in FIG. 1, when the aerosol medium aggregate 30 is surrounded on its side by the wrapping paper 31 to form an aerosol medium rod, the user creates an air flow from the bottom to the top, as shown by the arrow, through the act of inhalation. It is possible to inhale aerosols originating from an aerosol medium. In the use of such aerosol medium aggregate 30, assuming an air flow from the bottom to the top, for convenience, the bottom side can be referred to as “upstream” and the top side can be referred to as “downstream.”
실시예에서, 에어로졸 매질은 가열에 의해 에어로졸로 변환될 수 있는 소재, 예를 들어, 향료, 니코틴, VG(식물성 글리세린), PG(프로필렌 글리콜), 약품, 정향 등 중의 어느 하나 이상의 물질을 포함할 수 있다. 특히 에어로졸 매질에 VG(식물성 글리세린), PG(프로필렌 글리콜)이 포함될 경우, 풍부한 에어로졸 및 시각 효과(연기)가 발생할 수 있다는 점에서 바람직하다.In an embodiment, the aerosol medium may include any one or more of materials that can be converted to an aerosol by heating, such as flavoring, nicotine, VG (vegetable glycerin), PG (propylene glycol), medicine, clove, etc. You can. In particular, when VG (vegetable glycerin) and PG (propylene glycol) are included in the aerosol medium, it is desirable because abundant aerosol and visual effects (smoke) can be generated.
에어로졸 매질 집합체에 포함되는 에어로졸 매질은 상온에서 액상이거나 겔상이거나 또는 고형화상일 수 있다. 예를 들어, 상온에서 액상인 VG와 PG를 혼합하여 액상 에어로졸 매질을 만들 수 있다. 에어로졸 매질은 상온에서 액상임에도 불구하고, 그 흡습량을 조절하면, 에어로졸 매질 집합체(30)에 포함된 마이크로 기공(A)과 매크로 기공(B)에 흡습된 채로 누액의 발생 없이 유지될 수 있다.The aerosol medium included in the aerosol medium aggregate may be liquid, gel, or solid at room temperature. For example, a liquid aerosol medium can be created by mixing liquid VG and PG at room temperature. Although the aerosol medium is liquid at room temperature, if its moisture absorption amount is controlled, it can be maintained without leakage while being absorbed into the micro pores (A) and macro pores (B) included in the aerosol medium assembly 30.
또한 예를 들어, 겔상 에어로졸 매질은 적어도 글리세린과 증점제를 혼합하여 형성할 수 있다. 일례로 글리세린 PG(Proplylene Glycol) 혹은 VG(Vegetable Glycerine), 혹은 PG 및 VG 혼합물을 열을 주며 30분간 교반하여 점도를 낮추고, 여기에 겔화할 수 있는 첨가물인 증점제(카라기난 등)를 10 ~ 50 중량%를 첨가하여 첨가물이 글리세린에 녹을 때까지 교반하고 글리세린과 증점제 혼합물을 얻을 수 있게 된다. 혼합물은 상온을 포함하는 제1 온도 범위(예를 들어 50 ℃ 미만의 온도 범위)에서는 겔상 혹은 반고상을 유지하며, 가열되어 제1 온도 범위보다 높은 제2 온도 범위(예를 들어 50 - 100 ℃의 온도 범위)에서는 액상 내지 졸(sol)상으로 변화하여 액상으로 존재하고 추가로 가열되는 경우, 제2 온도 범위보다 높은 제3 온도 범위(예를 들어 150 ℃ 이상의 온도 범위)에서 에어로졸로 기화할 수 있다.Also, for example, a gel-like aerosol medium can be formed by mixing at least glycerin and a thickener. For example, glycerin PG (Proplylene Glycol) or VG (Vegetable Glycerine), or a mixture of PG and VG, is heated and stirred for 30 minutes to lower the viscosity, and then 10 to 50 weight of a thickener (carrageenan, etc.) that can gel is added. Add % and stir until the additive is dissolved in glycerin to obtain a glycerin and thickener mixture. The mixture maintains a gel or semi-solid state in a first temperature range that includes room temperature (e.g., a temperature range of less than 50° C.), and is heated to a second temperature range that is higher than the first temperature range (e.g., 50-100° C. temperature range), it changes from a liquid phase to a sol phase and exists in the liquid phase, and when further heated, it vaporizes into an aerosol in a third temperature range higher than the second temperature range (for example, a temperature range of 150 ℃ or higher). You can.
이상과 같이, 겔상 에어로졸 매질은, 한천(agar), 증점제, 전분 분말, 셀룰로오스류, 카르복시메틸에테르류, 천연 식품 향료 또는 과일 추출물 중 하나 이상을 추가적으로 포함할 수 있다. 아울러, 겔상 에어로졸 매질에서 글리세린의 함량은 50 중량% 이상인 것이 바람직하다. 또한, 혼합물은 추가로 한천(agar)를 포함할 수 있으며, 이 경우에 겔상 에어로졸 매질 혼합물을 형성하는데 유리하게 작용한다. 이에 부가하여, 겔상 에어로졸 매질 혼합물은 첨가물로 증점제, 전분 분말, 셀룰로오스류, 카르복시메틸에테르류를 포함할 수 있다.As described above, the gel-like aerosol medium may additionally include one or more of agar, thickener, starch powder, cellulose, carboxymethyl ether, natural food flavoring, or fruit extract. In addition, the content of glycerin in the gel-like aerosol medium is preferably 50% by weight or more. Additionally, the mixture may additionally contain agar, in which case it serves advantageously to form a gel-like aerosol medium mixture. In addition, the gel-like aerosol medium mixture may include thickeners, starch powder, cellulose, and carboxymethyl ether as additives.
예를 들어, 겔상 에어로졸 매질이 증점제 역할을 하는 것으로 널리 알려진 카라기난을 포함하는 것으로 상기와 같은 온도 범위에 따른 상 변화를 기대할 수 있다. 상온을 포함하는 제1 온도 범위에서 겔 상태의 에어로졸 매질은 제2 온도 범위에서 콜로이드 입자들의 연결이 해제되며 액상 내지 졸 상태로 변화할 수 있으며, 더욱 가열되어 제3 온도 범위에서 에어로졸로 기화될 수 있다.For example, since the gel-like aerosol medium contains carrageenan, which is widely known to act as a thickener, phase changes can be expected depending on the temperature range as described above. The aerosol medium in a gel state in a first temperature range including room temperature may change into a liquid or sol state as the colloidal particles are disconnected in a second temperature range, and may be further heated to vaporize into an aerosol in a third temperature range. there is.
실시예에 따라 겔상 에어로졸 매질은 0.1 내지 5 % 겔화제와, 글리세린을 포함하는 5 내지 100 %의 에어로졸 생성제와, 0.1 내지 20 %의 산미조절제와, 선택적으로 0.1 내지 15 %의 향미제, 첨가제 또는 활성 물질을 포함할 수 있다. 또한, 실시예에 따라 겔상 에어로졸 매질은 카파 카라기난, 아이오타 카라기난, 한천, 펙틴, 구아검, 젖산 칼슘, 염화 칼륨, 포도당, 전분 분말, 천연 식품 첨가제 또는 과일 추출물 또는 화합물 중 하나 이상을 추가적으로 포함할 수 있다. Depending on the embodiment, the gel-like aerosol medium may contain 0.1 to 5% of a gelling agent, 5 to 100% of an aerosol generator including glycerin, 0.1 to 20% of an acidity regulator, and optionally 0.1 to 15% of a flavoring agent and additives. Or it may contain an active substance. In addition, depending on the embodiment, the gel-like aerosol medium may additionally include one or more of kappa carrageenan, iota carrageenan, agar, pectin, guar gum, calcium lactate, potassium chloride, glucose, starch powder, natural food additives, or fruit extracts or compounds. You can.
앞서 설명한 바와 같이, 겔상의 에어로졸 매질은 제2 온도 범위보다 높은 예를 들어, 약 150 내지 300 ℃의 온도범위(제3 온도 범위)에서 기화하여 에어로졸화되는데, 가열 후 에어로졸화되어 흡입되지 않은 액상 상태의 에어로졸 매질은 상온으로 냉각되면 에어로졸 매질 집합체(30) 내부에서 다시 겔상으로 변할 수 있다.As described above, the gel-like aerosol medium is vaporized and aerosolized at a temperature range (third temperature range) higher than the second temperature range, for example, about 150 to 300° C., and is aerosolized after heating into a liquid phase that is not inhaled. When the aerosol medium is cooled to room temperature, it can change back into a gel state inside the aerosol medium assembly 30.
전술한 대로, 제 1 온도 범위에서 에어로졸 매질이 겔상 또는 반고상을 유지하도록, 에어로졸 매질은 증점제를 포함하는데, 바람직한 실시예에 따라 증점제는 글리세린을 포함하는 에어로졸 매질이 기화하여 에어로졸화되는 약 150 내지 300 ℃의 온도범위(제3 온도 범위)에서 기화하지 않고 다공성 알갱이(30a) 내지 에어로졸 매질 집합체(30)에 잔류한다. 즉 증점제는 주된 에어로졸 매질인 글리세린이 에어로졸로 기화할 때, 기화하지 않고 다공성 알갱이(30a) 내의 마이크로 기공(A)이나 다공성 알갱이(30a)들 사이의 매크로 기공(B)에 그대로 잔류한다. As described above, the aerosol medium includes a thickener so that the aerosol medium maintains a gel or semi-solid state in the first temperature range, and according to a preferred embodiment, the thickener is added at a temperature of about 150 to about 150° C. at which the aerosol medium containing glycerin is vaporized and aerosolized. It does not vaporize in the temperature range of 300°C (third temperature range) and remains in the porous particles 30a or the aerosol medium aggregate 30. That is, when glycerin, the main aerosol medium, vaporizes into an aerosol, the thickener does not vaporize but remains in the micropores (A) within the porous grains (30a) or the macropores (B) between the porous grains (30a).
이러한 증점제로서, 단당류, 이당류, 당알코올, 소당류를 포함하는 군으로부터 선택된 하나 이상의 물질을 포함하여 구성된다. 글리세린을 겔화시키는 증점제로 어류, 육류 등으로부터 추출된 젤라틴이나 식물성 젤라틴을 이용하거나 이러한 젤라틴 증점제와 물을 글리세린과 섞어서 교반하면서 냉각시키는 방법 등이 고려되었으나, 이렇게 얻어진 겔상 에어로졸 매질에서 글리세린의 기화점은 대기압하에서 대략 200 ~ 300 ℃이고, 물의 기화점도 대기압하에서 대략 100 ℃이어서, 이러한 젤라틴 또는 물 증점제는 글리세린을 포함하는 에어로졸이 기화하여 에어로졸화되는 약 150 내지 300 ℃의 온도범위(제3 온도 범위)에서 글리세린과 함께 기화하여 에어로졸화될 수 있다. 따라서 발명자들은 다른 증점제를 고려하게 되었으며, 실시예에서는 증점제로, 단당류, 이당류, 당알코올, 소당류를 포함하는 군으로부터 선택된 하나 이상의 물질을 포함한다. This thickener is composed of one or more substances selected from the group including monosaccharides, disaccharides, sugar alcohols, and oligosaccharides. Methods such as using gelatin extracted from fish, meat, etc. or vegetable gelatin as a thickener to gelatinize glycerin, or mixing such gelatin thickener and water with glycerin and cooling while stirring were considered. However, the vaporization point of glycerin in the gel-like aerosol medium obtained in this way is It is approximately 200 to 300 ° C. under atmospheric pressure, and the vaporization point of water is approximately 100 ° C. under atmospheric pressure, so this gelatin or water thickener is in the temperature range of about 150 to 300 ° C. (third temperature range) at which the aerosol containing glycerin vaporizes and becomes aerosol. It can be vaporized with glycerin and aerosolized. Accordingly, the inventors considered other thickeners, and in the examples, the thickener includes one or more substances selected from the group including monosaccharides, disaccharides, sugar alcohols, and oligosaccharides.
바람직한 일 실시예에서, 단당류는 식물 추출물로 글루코스, 과당, 갈락토스를 포함하는 군으로부터 선택된 하나 이상의 물질을 포함한다. 글루코스의 기화점은 대기압하에서 527.1 ± 50.0 ℃이고, 과당의 기화점은 대기압하에서 697.1 ± 50.0 ℃이고, 갈락토스의 기화점은 대기압하에서 527.1 ± 50.0 ℃이므로, 글리세린을 포함하는 에어로졸 매질이 기화하여 에어로졸화되는 약 150 내지 300℃의 온도범위(제3 온도 범위)에서 기화하지 않고 흡습체 내에 그대로 잔류한다.In a preferred embodiment, the monosaccharide is a plant extract and includes one or more substances selected from the group comprising glucose, fructose, and galactose. The vaporization point of glucose is 527.1 ± 50.0 ℃ under atmospheric pressure, the vaporization point of fructose is 697.1 ± 50.0 ℃ under atmospheric pressure, and the vaporization point of galactose is 527.1 ± 50.0 ℃ under atmospheric pressure, so the aerosol medium containing glycerin vaporizes and becomes an aerosol. It does not vaporize in the temperature range of about 150 to 300°C (third temperature range) and remains in the moisture absorbent.
바람직한 다른 실시예에서, 이당류는 설탕 등에서 추출한 성분을 포함한다. 설탕의 기화점은 대기압하에서 697.1 ± 50.0 ℃이므로, 글리세린을 포함하는 에어로졸 매질이 기화하여 에어로졸화되는 약 150 내지 300℃의 온도범위(제3 온도 범위)에서 기화하지 않고 흡습체 내에 그대로 잔류한다.In another preferred embodiment, the disaccharide includes components derived from sugar, etc. Since the vaporization point of sugar is 697.1 ± 50.0 ° C. under atmospheric pressure, it does not vaporize in the temperature range of about 150 to 300 ° C. (third temperature range), at which the aerosol medium containing glycerin vaporizes and becomes aerosol, but remains in the absorbent.
바람직한 다른 실시예에서, 당알코올은 이소말트, 말티톨, 자일리톨, 소르비톨을 포함하는 군에서 선택된 하나 이상의 물질을 포함한다. 이소말트의 기화점은 788.5 ℃이고, 말티톨의 기화점은 대기압하에서 788.5 ± 60.0 ℃이므로, 글리세린을 포함하는 에어로졸 매질이 기화하여 에어로졸화되는 약 150 내지 300℃의 온도범위(제3 온도 범위)에서 기화하지 않고 흡습체 내에 그대로 잔류한다.In another preferred embodiment, the sugar alcohol includes one or more substances selected from the group including isomalt, maltitol, xylitol, and sorbitol. The vaporization point of isomalt is 788.5 ℃, and the vaporization point of maltitol is 788.5 ± 60.0 ℃ under atmospheric pressure, so in the temperature range of about 150 to 300 ℃ (third temperature range) where the aerosol medium containing glycerin vaporizes and becomes aerosol. It does not evaporate and remains in the absorbent.
바람직한 다른 실시예에서, 소당류는 이당류 이상의 당류로서, 말토덱스트린을 포함한다. 말소텍스트린의 기화점은 527.1 ℃이므로, 글리세린을 포함하는 에어로졸 매질이 기화하여 에어로졸화되는 약 150 내지 300℃의 온도범위(제3 온도 범위)에서 기화하지 않고 흡습체 내에 그대로 잔류한다.In another preferred embodiment, the monosaccharide is a disaccharide or higher saccharide and includes maltodextrin. Since the vaporization point of erase textrin is 527.1°C, it does not vaporize in the temperature range of about 150 to 300°C (third temperature range), where the aerosol medium containing glycerin vaporizes and becomes aerosol, but remains in the absorbent.
다음으로, 고형화상 에어로졸 매질 역시 겔상 에어로졸 매질과 유사하게, 글리세린과 증점제의 혼합물일 수 있다. 일례로 글리세린 PG(Proplylene Glycol) 혹은 VG(Vegetable Glycerine), 혹은 PG 및 VG 혼합물에, 고형화를 위한 첨가물인 증점제와, 고형화를 임시적으로 막기 위한 첨가물인 용해제를 넣은 혼합 용액을 만들 수 있다. 다음으로 이 혼합 용액을 가열하여 용해제만을 증발시키면 PG 및 VG는 증점제에 갇히며 고형화된 에어로졸 매질이 형성될 수 있다.Next, the solid aerosol medium may also be a mixture of glycerin and a thickener, similar to the gel aerosol medium. For example, a mixed solution can be made by adding a thickener, an additive for solidification, and a solubilizer, an additive to temporarily prevent solidification, to glycerin PG (Proplylene Glycol) or VG (Vegetable Glycerine), or a mixture of PG and VG. Next, when this mixed solution is heated to evaporate only the solvent, PG and VG are trapped in the thickener and a solidified aerosol medium can be formed.
이 때, 고형화를 위해 사용되는 증점제는 셀룰로오스 유도체(Cellulose derivatives), 덱스트린 유도체(Dextrin derivatives), 알지네이트 유도체(Alginate derivatives), 검(Gum), 펙틴(Pectin), 헤미셀룰로오스 유도체(Hemicellulose derivatices) 및 젤라틴(Gelatin)을 포함하는 군에서 선택된 하나 이상의 물질을 포함하는 것이 바람직하다. 또한 용해제는 예를 들어 증류수이거나 에탄올일 수 있는데, 특히 사용될 에어로졸 매질(예를 들어 PG와 VG) 및 증점제보다 끓는 점이 낮은 물질인 것이 바람직하다.At this time, the thickeners used for solidification include cellulose derivatives, dextrin derivatives, alginate derivatives, gum, pectin, hemicellulose derivatives, and gelatin ( It is preferable to include one or more substances selected from the group containing gelatin. The solubilizing agent may also be, for example, distilled water or ethanol; it is particularly preferred that it is a substance with a lower boiling point than the aerosol medium to be used (e.g. PG and VG) and the thickening agent.
상기와 같은 바람직한 실시예를 따를 경우, 액상의 에어로졸 매질(예를 들어 PG 또는 VG), 증점제 및 용해제의 혼합 용액을 제조한 뒤, 이를 전술한 복수의 다공성 알갱이(30a)와 혼합하여 다공성 알갱이(30a)에 흡습시킨 후, 가열하여 다공성 알갱이(30a)에 흡습된 혼합 용액에 포함된, 끓는 점이 상대적으로 낮은, 용해제만을 증발시키고, 에어로졸 매질과 증점제는 다공성 알갱이(30a)에 잔존시킬 수 있다. 이 때 PG 및 VG는 증점제에 갇히며 고형화상의 에어로졸 매질이 형성되고, 궁극적으로는 고형화상 에어로졸 매질을 포함하는 에어로졸 매질 집합체(30)가 제조될 수 있다.When following the preferred embodiment as described above, a mixed solution of a liquid aerosol medium (for example, PG or VG), a thickener, and a solubilizer is prepared, and then mixed with the plurality of porous granules 30a described above to form porous granules ( After moisture absorption in 30a), it is heated to evaporate only the solvent with a relatively low boiling point contained in the mixed solution absorbed in the porous grains (30a), and the aerosol medium and thickener can remain in the porous grains (30a). At this time, PG and VG are trapped in the thickener, forming a solid aerosol medium, and ultimately, an aerosol medium aggregate 30 containing the solid aerosol medium can be produced.
또한 상기 바람직한 실시예에 따른 에어로졸 매질 집합체(30)의 고형화상 에어로졸 매질은, 전술한 겔상 에어로졸 매질과 마찬가지로 온도 변화에 따른 상 변화를 기대할 수 있다. 즉 고형화상 에어로졸 매질은 상온 내지 상온을 포함하는 소정의 온도 범위(예를 들어 50 ℃ 미만의 온도 범위, 제1 온도 범위)에서 증점제의 작용에 의하여 고형화상으로 존재한다. 또한 에어로졸 매질 집합체(30)의 통상적인 사용 양태에 있어서, 에어로졸 매질 집합체(30)는 에어로졸 발생 장치 내의 히터에 의해 가열되어, 제1 온도 범위보다 높은 제2 온도 범위(예를 들어 50 - 100 ℃의 온도 범위)에서 증점제는 점점 그 성질을 잃어, 고형화상 에어로졸 매질은 액상으로 변화할 수 있으며, 제2 온도 범위보다 높은 제3 온도 범위(예를 들어 150 ℃ 내지 300 ℃의 온도 범위)에서, 에어로졸 매질(예를 들어 PG 및 VG)은 기화될 수 있다. 이 때 예를 들어, 제2 온도 범위에서 에어로졸 매질은 액상화에도 불구하고, 에어로졸 매질 집합체(30)가 포함하는 마이크로 기공(A)과 매크로 기공(B) 내에 여전히 흡습 내지 수용되어 있으므로, 누액이 발생할 가능성은 거의 없다.In addition, the solid image aerosol medium of the aerosol medium assembly 30 according to the preferred embodiment can be expected to change phase according to temperature changes, similar to the gel-like aerosol medium described above. That is, the solid image aerosol medium exists in a solid image due to the action of the thickener in a predetermined temperature range including room temperature to room temperature (for example, a temperature range below 50° C., a first temperature range). Also, in a typical use of the aerosol medium assembly 30, the aerosol medium assembly 30 is heated by a heater in the aerosol generating device to a second temperature range higher than the first temperature range (e.g., 50 - 100° C. temperature range), the thickener gradually loses its properties, and the solid phase aerosol medium can change to a liquid phase, and in a third temperature range higher than the second temperature range (e.g., a temperature range of 150° C. to 300° C.), Aerosol media (eg PG and VG) can be vaporized. At this time, for example, in the second temperature range, despite being liquefied, the aerosol medium is still absorbed or contained within the micropores (A) and macropores (B) included in the aerosol medium assembly 30, so leakage may occur. Very unlikely.
또한 상기 바람직한 실시예에 따를 경우, 증점제는 글리세린을 포함하는 에어로졸 매질이 기화하여 에어로졸화되는 약 150 ℃ 내지 300 ℃의 온도범위(제3 온도 범위)에서 기화하지 않고 다공성 알갱이(30a) 내지 에어로졸 매질 집합체(30)에 잔류한다. 즉 증점제는 주된 에어로졸 매질인 글리세린이 에어로졸로 기화할 때, 기화하지 않고 다공성 알갱이(30a) 내의 마이크로 기공(A)이나 다공성 알갱이(30a)들 사이의 매크로 기공(B)에 그대로 잔류한다. 따라서 사용자는 일반적인 사용 양태에 있어서 예를 들어 PG나 VG와 같은 기화된 에어로졸 매질만을 흡입하며, 증점제는 흡입하지 않을 수 있다.In addition, according to the preferred embodiment, the thickener does not vaporize in the temperature range of about 150 ° C to 300 ° C (third temperature range), where the aerosol medium containing glycerin is vaporized and aerosolized, but is formed in the porous particles 30a to the aerosol medium. It remains in the aggregate 30. That is, when glycerin, the main aerosol medium, vaporizes into an aerosol, the thickener does not vaporize but remains in the micropores (A) within the porous grains (30a) or the macropores (B) between the porous grains (30a). Therefore, in general usage, the user may inhale only the vaporized aerosol medium, such as PG or VG, and not the thickener.
에어로졸 매질은 추가로 천연 식품 향료 또는 과일 추출물을 포함할 수 있다. 이 경우 발생한 에어로졸을 통해 사용자에게 다양한 맛을 가미하는 것이 가능해진다. 어느 경우든 에어로졸 매질 혼합물에서 글리세린의 함량은 50 중량% 이상인 것이 바람직한데, 이렇게 함으로써 발생한 에어로졸에서 탄맛을 최소화할 수 있게 된다. 추가적으로 에어로졸 매질 혼합물은 니코틴을 포함할 수도 있고, 포함하지 않을 수도 있다.The aerosol medium may additionally contain natural food flavors or fruit extracts. In this case, it becomes possible to add various flavors to the user through the generated aerosol. In any case, it is preferable that the glycerin content in the aerosol medium mixture is 50% by weight or more, thereby minimizing the burnt taste in the generated aerosol. Additionally, the aerosol medium mixture may or may not contain nicotine.
에어로졸 매질은 추가로 향미제를 포함할 수 있으며, 예를 들어, 향미제는 감초, 자당, 과당 시럽, 이소감미제, 코코아, 라벤더, 시나몬, 카르다몸, 셀러리, 호로파, 카스카릴라, 백단, 베르가못, 제라늄, 벌꿀 에센스, 장미 오일, 바닐라, 레몬 오일, 오렌지 오일, 민트 오일, 계피, 캐러웨이, 코냑, 자스민, 카모마일, 멘톨, 계피, 일랑일랑, 샐비어, 스피어민트, 생강, 고수 또는 커피 등을 포함할 수 있다.The aerosol medium may further include flavoring agents, for example, licorice, sucrose, fructose syrup, iso-sweeteners, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, Bergamot, geranium, honey essence, rose oil, vanilla, lemon oil, orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang ylang, sage, spearmint, ginger, coriander or coffee. It can be included.
도 4는 본 발명의 일 실시예에 따른, 액상 또는 겔상의 에어로졸 매질을 포함하는 에어로졸 매질 집합체(30)의 제조 방법을 나타낸 순서도, 도 5는 도 4의 제조 방법을 이해하기 쉽게 표현한 개념도이다. 먼저, 용액 준비 단계(s110)로서 용기(K)에 액상의 에어로졸 매질(예를 들어, PG와 VG 혼합물) 혼합 용액(M)을 준비한다(도 5의 (a)). 겔상 에어로졸 매질의 경우, 상기 혼합 용액(M)은 증점제를 더욱 포함할 수 있으며, 겔상화를 방지하기 위하여 상기 혼합 용액(M)은 소정 온도(예를 들어 전술한 제2 온도 범위)로 가열된 상태일 수 있다.Figure 4 is a flowchart showing a method of manufacturing an aerosol medium aggregate 30 containing a liquid or gel-like aerosol medium according to an embodiment of the present invention, and Figure 5 is a conceptual diagram expressing the manufacturing method of Figure 4 in an easy-to-understand manner. First, as a solution preparation step (s110), a liquid aerosol medium (e.g., PG and VG mixture) mixed solution (M) is prepared in the container (K) (FIG. 5(a)). In the case of a gel-like aerosol medium, the mixed solution (M) may further include a thickener, and in order to prevent gelation, the mixed solution (M) is heated to a predetermined temperature (for example, the second temperature range described above). It may be a state.
다음으로 흡습 단계(s120)로서, 다공성 알갱이(30a)들을 용기(K)로 도입하여 상기 혼합 용액(M)에 적신다(도 5의 (b), (c)). 예를 들어 이 때 다공성 알갱이(30a)가 잘 적셔지도록 교반 작업이 수행될 수 있다. 그로 인하여, 다공성 알갱이(30a)와 혼합 용액(M)이 혼합되며 다공성 알갱이(30a)의 마이크로 기공 및 표면에 상기 혼합 용액(M)이 흡습 내지 수용될 수 있다. Next, in the moisture absorption step (s120), the porous granules (30a) are introduced into the container (K) and soaked in the mixed solution (M) (FIG. 5 (b), (c)). For example, at this time, stirring may be performed to ensure that the porous grains 30a are well wetted. As a result, the porous grains (30a) and the mixed solution (M) are mixed, and the mixed solution (M) can absorb moisture or be accommodated in the micropores and surfaces of the porous grains (30a).
다음으로 분리 단계(s130)로서, 예를 들어 미세 거름망을 이용하여 잔존하는 혼합 용액(M)과 다공성 알갱이(30a)를 분리할 수 있다(도 5의 (d)). 이후 실시예에 따라, 향후 혹시라도 누액이 발생할 가능성을 없애기 위하여, 다공성 알갱이(30a)에 흡수되지는 않았으나 표면장력 등의 현상으로 여전히 다공성 알갱이(30a)에 과도하게 묻어 있는 혼합 용액(M)을 건조시키는 건조 단계가 추가로 포함될 수 있다.Next, in the separation step (s130), the remaining mixed solution (M) and the porous grains (30a) can be separated using, for example, a fine strainer (FIG. 5(d)). According to the following embodiments, in order to eliminate the possibility of liquid leakage occurring in the future, the mixed solution (M), which has not been absorbed into the porous grains (30a) but is still excessively embedded in the porous grains (30a) due to phenomena such as surface tension, is A drying step may be additionally included.
다음으로, 혼합 용액(M)이 증점제를 포함하는 경우에는, 혼합 용액(M)을 흡습한 다공성 알갱이(30a)들을 냉각시켜 흡습된 액상 에어로졸 매질을 겔상화할 수 있다.Next, when the mixed solution (M) includes a thickener, the porous particles 30a that have absorbed the mixed solution (M) can be cooled to gel the moisture-absorbed liquid aerosol medium.
도 6은 본 발명의 일 실시예에 따른, 고형화된 에어로졸 매질을 포함하는 에어로졸 매질 집합체(30)의 제조 방법을 나타낸 순서도이다. 본 실시예 역시 이해를 돕기 위하여 도 5 및 그에 포함된 동일한 참조부호를 이용하여 설명한다. 먼저, 용액 준비 단계(s210)로서 용기(K)에 액상의 에어로졸 매질(예를 들어, PG와 VG 혼합물)과 증점제와 용해제의 혼합 용액(M)을 준비한다(도 5의 (a)). 다음으로 흡습 단계(s220)로서, 다공성 알갱이(30a)들을 용기(K)로 도입하여 상기 혼합 용액(M)에 적신다(도 5의 (b), (c)). 예를 들어 이 때 다공성 알갱이(30a)가 잘 적셔지도록 교반 작업이 수행될 수 있다. 그로 인하여, 다공성 알갱이(30a)와 에어로졸 매질과 증점제와 용해제의 혼합 용액(M)이 혼합되며 다공성 알갱이(30a)의 마이크로 기공 및 표면에 상기 혼합 용액(M)이 흡습 내지 수용될 수 있다. 다음으로 분리 단계(s230)로서, 예를 들어 미세 거름망을 이용하여 잔존하는 혼합 용액(M)과 다공성 알갱이(30a)를 분리할 수 있다(도 5의 (d)). 다음으로 고형화 단계(s240)로서, 다공성 알갱이(30a)에 흡습된 혼합 용액(M)에 포함된 용해제를 증발시켜 고형화된 에어로졸 매질을 얻는 단계이다. 예를 들어, 혼합 용액(M)을 흡습한 다공성 알갱이(30a)를, 포함된 용해제의 끓는 점보다는 높고, 포함된 에어로졸 매질 및 증점제의 끓는 점보다 낮은 온도로 가열하여, 혼합 용액(M)에 포함된 용해제를 증발시키고, 에어로졸 매질 및 증점제는 그대로 남도록 하여 고형화된 에어로졸 매질을 얻을 수 있다. 이 과정에서 에어로졸 매질은 다공성 알갱이(30a) 내의 마이크로 기공(A)이나 다공성 알갱이(30a)들 사이의 매크로 기공(B)에 수용된 채 고형화될 수 있다.Figure 6 is a flowchart showing a method of manufacturing an aerosol medium assembly 30 including a solidified aerosol medium according to an embodiment of the present invention. To facilitate understanding, this embodiment will also be described using FIG. 5 and the same reference numerals included therein. First, as a solution preparation step (s210), a mixed solution (M) of a liquid aerosol medium (for example, a mixture of PG and VG), a thickener, and a solubilizing agent is prepared in the container (K) (FIG. 5(a)). Next, in the moisture absorption step (s220), the porous granules (30a) are introduced into the container (K) and soaked in the mixed solution (M) (FIG. 5 (b), (c)). For example, at this time, stirring may be performed to ensure that the porous grains 30a are well wetted. As a result, the porous grains (30a) and the mixed solution (M) of the aerosol medium, thickener, and solubilizer are mixed, and the mixed solution (M) may be absorbed or accommodated in the micropores and surfaces of the porous grains (30a). Next, in the separation step (s230), the remaining mixed solution (M) and the porous grains (30a) can be separated using, for example, a fine strainer (FIG. 5(d)). Next is the solidification step (s240), which is a step of obtaining a solidified aerosol medium by evaporating the solvent contained in the mixed solution (M) moisture absorbed by the porous grains (30a). For example, the porous grains (30a) that have absorbed the mixed solution (M) are heated to a temperature higher than the boiling point of the included solvent and lower than the boiling points of the included aerosol medium and thickener, and added to the mixed solution (M). A solidified aerosol medium can be obtained by evaporating the contained solvent, leaving the aerosol medium and thickener as is. In this process, the aerosol medium may be solidified while being accommodated in micro pores (A) within the porous grains (30a) or macro pores (B) between the porous grains (30a).
이렇게 제조한, 액상의 또는 겔상의 또는 고형화상의 에어로졸 매질을 수용한 다공성 알갱이(30a)들은 도 1에서와 같이 에어로졸 매질 로드의 형태로 랩핑 페이퍼(31)에 의해 랩핑 되거나 소정 공간 내에 장입되어 에어로졸 매질 집합체(30)를 형성하여, 에어로졸을 발생시키는 무화기로서 기능할 수 있다.The porous particles 30a containing the liquid, gel, or solid aerosol medium prepared in this way are wrapped by the wrapping paper 31 in the form of an aerosol medium rod as shown in FIG. 1 or inserted into a predetermined space to form an aerosol medium. By forming an aggregate 30, it can function as an atomizer that generates an aerosol.
도 7은 본 발명의 일 실시예에 따른 가열식 흡연 물품(1)의 내부를 개념적으로 나타낸 수직 단면도이다. 본 실시예에 따른 가열식 흡연 물품(1)은 상측에 마우스 필터인 필터 로드(10)와, 필터 로드(10)의 하단에 적층되는 냉각 튜브 로드(20)와, 냉각 튜브 로드(20)의 하단에 적층되는, 본 발명의 어느 실시예의 범주 내에 있는 에어로졸 매질 집합체(30)와, 필터 로드(10)와 냉각 튜브 로드(20) 및 에어로졸 매질 집합체(30)을 둘러 감싸서 그 적층 구조를 유지시키는 랩핑 페이퍼(50)를 포함하여 구성된다. 즉 가열식 흡연 물품(1)은 필터 로드(10)와 냉각 튜브 로드(20) 및 에어로졸 매질 집합체(30)가 상하 방향으로 순차적으로 적층되고, 랩핑 페이퍼(50)가 이를 감싸, 전체적으로 궐련을 형성한다.Figure 7 is a vertical cross-sectional view conceptually showing the interior of a heated smoking article 1 according to an embodiment of the present invention. The heated smoking article (1) according to this embodiment includes a filter rod (10) that is a mouth filter on the upper side, a cooling tube rod (20) stacked at the bottom of the filter rod (10), and a bottom of the cooling tube rod (20). An aerosol medium assembly (30) within the scope of an embodiment of the present invention, which is laminated on an aerosol medium assembly (30), and a wrapping that surrounds the filter rod (10), the cooling tube rod (20), and the aerosol medium assembly (30) to maintain the layered structure. It is composed of paper 50. That is, in the heated smoking article 1, the filter rod 10, the cooling tube rod 20, and the aerosol medium assembly 30 are sequentially stacked in the vertical direction, and the wrapping paper 50 surrounds them to form a cigarette as a whole. .
필터 로드(10)는 마우스피스 역할을 하는 필터로, 에어로졸은 통과하고 액 유입은 막아주는 역할을 한다. 필터 로드(10)는 펄프로 제작될 수 있으며, 원통형 또는 튜브 형태로 제작될 수 있다. 필터 로드(10)는 셀룰로오스 아세테이트, 종이, PP, PLA 등의 재질로 제조될 수 있다. 한편, 필터 로드(10)는 가향 성분을 포함하여 사용자의 만족감을 향상시킬 수 있다. 가향 성분은 예를 들어, 감초, 자당, 과당 시럽, 이소감미제, 코코아, 라벤더, 시나몬, 카르다몸, 셀러리, 호로파, 카스카릴라, 백단, 베르가못, 제라늄, 벌꿀 에센스, 장미 오일, 바닐라, 레몬 오일, 오렌지 오일, 민트 오일, 계피, 케러웨이, 코냑, 자스민, 카모마일, 멘톨, 계피, 일랑일랑, 샐비어, 스피어민트, 생강, 고수 또는 커피 등을 포함할 수 있다.The filter rod 10 is a filter that functions as a mouthpiece, allowing aerosols to pass through and preventing liquid from entering. The filter rod 10 may be made of pulp and may be made in a cylindrical or tube shape. The filter rod 10 may be made of materials such as cellulose acetate, paper, PP, and PLA. Meanwhile, the filter rod 10 can improve user satisfaction by including flavoring ingredients. Flavoring ingredients include, for example, licorice, sucrose, fructose syrup, iso-sweeteners, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, bergamot, geranium, honey essence, rose oil, vanilla, lemon. Oils may include orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang ylang, sage, spearmint, ginger, coriander or coffee.
냉각 튜브 로드(20)는 상하 방향으로 연장되는 중공(22)이 내부에 형성되어, 에어로졸의 이동 통로를 제공하는데, PLA를 포함하여 에어로졸의 온도를 낮추어 사용자가 에어로졸 흡입 시에 화상을 입는 것을 방지할 수도 있다. 냉각 튜브 로드(20)는 셀룰로오스 아세테이트로 제작될 수 있으며, 냉각 구조물로 기능하는 냉각 튜브 로드(20)은 순수한 폴리락트산으로 제작되거나, 다른 분해성 폴리머와 폴리락트산을 조합하여 제작될 수 있다. 랩핑 페이퍼(50)는 예를 들어 일반지나 다공지 등으로 구성될 수 있다.The cooling tube rod 20 has a hollow 22 extending in the vertical direction formed therein to provide a passage for the aerosol. It contains PLA and lowers the temperature of the aerosol to prevent the user from getting burned when inhaling the aerosol. You may. The cooling tube rod 20 may be made of cellulose acetate, and the cooling tube rod 20 serving as the cooling structure may be made of pure polylactic acid or by combining polylactic acid with other degradable polymers. The wrapping paper 50 may be made of, for example, plain paper or porous paper.
실시예에 따라 가열식 흡연 물품(1)에 포함되는 에어로졸 매질 집합체(30)는 도 1에서 설명한 바와 같이 별도의 랩핑 페이퍼에 의해 랩핑된 에어로졸 매질 로드의 형태일 수 있다.According to the embodiment, the aerosol medium assembly 30 included in the heated smoking article 1 may be in the form of an aerosol medium rod wrapped by a separate wrapping paper as described in FIG. 1.
이상 설명한 실시예들에 근거하면, 실시예들의 가열식 흡연 물품(1)은 소정의 에어로졸 발생 장치에 삽입되어 에어로졸 매질 집합체(30)가 가열될 수 있으며, 그에 따라, 다공성 알갱이(30a) 내의 마이크로 기공(A)이나 다공성 알갱이(30a)들 사이의 매크로 기공(B)에 수용된 액상이나 겔상이나 고형화상의 에어로졸 매질로부터 유래하는 에어로졸이 발생할 수 있다.Based on the above-described embodiments, the heated smoking article 1 of the embodiments can be inserted into a predetermined aerosol generating device to heat the aerosol medium aggregate 30, thereby forming micropores in the porous particles 30a. Aerosols originating from a liquid, gel, or solid aerosol medium contained in (A) or in the macro pores (B) between the porous particles 30a may be generated.
도 8은 본 발명의 또 다른 실시예에 따른 가열식 흡연 물품(1a)의 내부를 개념적으로 나타낸 수직 단면도이다. 본 실시예에 따른 가열식 흡연 물품(1a)은, 에어로졸 매질 집합체(30)의 상단 또는 하단에 또 다른 에어로졸 매질로서 담배체를 포함하는 담배체 로드(40)를 추가적으로 포함한다. 즉 이와 같이 에어로졸 매질 집합체(30)의 상단 혹은 하단에 또 다른 에어로졸 매질로서 담배체 로드(40)가 제공될 수도 있다. 이 경우 사용자는 에어로졸 매질 집합체(30)로부터 유래하는 에어로졸과, 담배체 로드(40)로부터 유래하는 에어로졸을 혼합하여 퍼핑할 수 있게 된다. 담배체 로드(40)와 에어로졸 매질 집합체(30)의 상대적 위치에 따라, 도 7과 같이, 담배체 로드(40)가 아래에 위치하는 경우(상류에 위치하는 경우)에는 담배체 로드(40)에서 유래하는 에어로졸이 에어로졸 매질 집합체(30)를 지나면서 에어로졸 매질 집합체(30)로부터 유래하는 에어로졸과 혼합되어 사용자가 퍼핑하게 될 것이고, 에어로졸 매질 집합체(30)가 아래에 위치하는 경우(상류에 위치하는 경우)에는 에어로졸 매질 집합체(30)에서 유래하는 에어로졸이 담배체 로드(40)를 지나면서 담배체 로드(40)로부터 유래하는 에어로졸과 혼합되어 사용자가 퍼핑하게 될 것이다.Figure 8 is a vertical cross-sectional view conceptually showing the inside of a heated smoking article 1a according to another embodiment of the present invention. The heated smoking article 1a according to this embodiment additionally includes a tobacco body rod 40 containing a tobacco body as another aerosol medium at the top or bottom of the aerosol medium assembly 30. That is, the tobacco rod 40 may be provided as another aerosol medium at the top or bottom of the aerosol medium assembly 30. In this case, the user can puff by mixing the aerosol derived from the aerosol medium assembly 30 and the aerosol derived from the tobacco rod 40. Depending on the relative positions of the tobacco rod 40 and the aerosol medium assembly 30, as shown in FIG. 7, when the tobacco rod 40 is located below (if located upstream), the tobacco rod 40 As the aerosol derived from passes through the aerosol medium assembly 30, it will be mixed with the aerosol derived from the aerosol medium assembly 30 and the user will puff, and if the aerosol medium assembly 30 is located below (located upstream) In this case), the aerosol derived from the aerosol medium assembly 30 passes through the tobacco rod 40 and is mixed with the aerosol derived from the tobacco rod 40, so that the user puffs.
담배체 로드(40)는 담배체, 즉 판상엽 담배, 각초, 재구성 담배 등 담배 원료를 기초로 하는 고체 물질을 포함할 수 있다. 일 실시예에서 담배체 로드(40)는 주름진 판상엽 시트로 충진될 수 있다. 판상엽 시트는 실린더 축에 실질적으로 가로방향으로 둘둘 말리거나, 접히거나, 압축되거나, 수축됨으로써 주름이 형성될 수 있다. 주름진 판상엽 시트의 골 간격 등을 조절함으로써 다공도를 결정할 수 있다.The tobacco body rod 40 may include a tobacco body, that is, a solid material based on tobacco raw materials such as leaf tobacco, cut tobacco, reconstituted tobacco, etc. In one embodiment, the tobacco body rod 40 may be filled with corrugated leaf sheets. The lamellar sheet may be wrinkled by being rolled, folded, compressed, or contracted substantially transversely to the axis of the cylinder. Porosity can be determined by controlling the valley spacing of the wrinkled plate-like sheet.
다른 실시예에서 담배체 로드(40)는 담배 각초들로 충진될 수 있다. 여기에서, 담배 각초들은 담배 시트(또는 슬러리 판상엽 시트)를 잘게 절단함으로써 생성될 수 있다. 또한, 담배체 로드(40)는 복수의 담배 가닥들이 서로 같은 방향(평행)으로 또는 무작위로 합쳐져서 형성될 수 있다. 구체적으로, 담배체 로드(40)는 복수의 담배 가닥들이 합쳐져서 형성되고, 에어로졸이 통과할 수 있는 종방향의 복수의 채널들이 형성될 수 있다. 이때, 담배 가닥들의 크기 및 배열에 의하여, 종방향의 채널들은 균일하거나 불균일할 수 있다.In another embodiment, the tobacco body rod 40 may be filled with tobacco cut fillers. Here, tobacco cut fillers can be produced by cutting tobacco sheets (or slurry leaf sheets) into small pieces. Additionally, the tobacco body rod 40 may be formed by combining a plurality of tobacco strands in the same direction (parallel) or randomly. Specifically, the tobacco body rod 40 is formed by combining a plurality of tobacco strands, and a plurality of longitudinal channels through which aerosol can pass may be formed. At this time, depending on the size and arrangement of the tobacco strands, the longitudinal channels may be uniform or non-uniform.
담배체 로드(40)는 추가로 에틸렌 글리콜, 디프로필렌 글리콜, 디에틸렌 글리콜, 트리에틸렌글리콜, 테트라에틸렌 글리콜 및 올레일 알코올 중 적어도 하나를 포함할 수 있다. 또한, 담배체 로드(40)는 글리세린 및 프로필렌 글리콜을 더 포함할 수도 있다.The tobacco rod 40 may further include at least one of ethylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and oleyl alcohol. Additionally, the tobacco rod 40 may further include glycerin and propylene glycol.
또한, 담배체 로드(40)는 풍미제 및/또는 유기산(organic acid)과 같은 다른 첨가 물질을 함유할 수 있다. 예를 들어, 풍미제는 감초, 자당, 과당 시럽, 이소감미제(isosweet), 코코아, 라벤더, 시나몬, 카르다몸, 셀러리, 호로파, 카스카릴라, 백단, 베르가못, 제라늄, 벌꿀 에센스, 장미 오일, 바닐라, 레몬 오일, 오렌지 오일, 민트 오일, 계피, 케러웨이, 코냑, 자스민, 카모마일, 멘톨, 계피, 일랑일랑, 샐비어, 스피어민트, 생강, 고수 또는 커피 등을 포함할 수 있다. 한편, 담배체 로드(40)는 글리세린 또는 프로필렌 글리콜을 일부 포함할 수도 있다.Additionally, the tobacco body rod 40 may contain other added substances such as flavoring agents and/or organic acids. For example, flavoring agents include licorice, sucrose, fructose syrup, isosweet, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, bergamot, geranium, honey essence, rose oil, It may contain vanilla, lemon oil, orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang ylang, sage, spearmint, ginger, coriander or coffee. Meanwhile, the tobacco rod 40 may contain some glycerin or propylene glycol.
도 9는 본 발명의 또 다른 실시예에 따른 가열식 흡연 물품(1b)의 내부를 개념적으로 나타낸 수직 단면도이다. 본 실시예에 따른 가열식 흡연 물품(1b)은 상측에 마우스 필터인 필터 로드(10)와, 필터 로드(10)의 하단에 적층되는 냉각 튜브 로드(20)와, 냉각 튜브 로드(20)의 하단에 적층되는, 담배체(41)를 포함하는 담배체 로드(40a)와, 필터 로드(10)와 냉각 튜브 로드(20) 및 담배체 로드(30)을 둘러 감싸서 그 적층 구조를 유지시키는 랩핑 페이퍼(50)를 포함하여 구성된다. 즉 가열식 흡연 물품(1b)은 필터 로드(10)와 냉각 튜브 로드(20) 및 담배체 로드(40a)가 상하 방향으로 순차적으로 적층되고, 랩핑 페이퍼(50)가 이를 감싸, 전체적으로 궐련을 형성한다.Figure 9 is a vertical cross-sectional view conceptually showing the inside of a heated smoking article 1b according to another embodiment of the present invention. The heated smoking article (1b) according to this embodiment includes a filter rod (10) that is a mouth filter on the upper side, a cooling tube rod (20) stacked at the bottom of the filter rod (10), and a bottom of the cooling tube rod (20). A wrapping paper that surrounds the tobacco rod 40a including the tobacco body 41, the filter rod 10, the cooling tube rod 20, and the tobacco rod 30 and maintains the stacked structure. It is composed including (50). That is, in the heated smoking article 1b, the filter rod 10, the cooling tube rod 20, and the tobacco body rod 40a are sequentially stacked in the vertical direction, and the wrapping paper 50 surrounds them to form a cigarette as a whole. .
자명하게도, 필터 로드(10)와 냉각 튜브 로드(20)와 랩핑 페이퍼(50)는 위에서 동일한 명칭과 참조부호로서 기 설명한 내용을 그대로 적용할 수 있다.Obviously, the filter rod 10, the cooling tube rod 20, and the wrapping paper 50 have the same names and reference numerals, and the contents previously described above can be applied as is.
담배체 로드(40a)는 적어도 담배체(41)를 포함할 수 있으며, 도 9에서 도시된 바와 같이, 바람직하게는 표면이나 내부에 마이크로 기공이 형성된 복수의 다공성 알갱이(30a)를 추가로 포함한다. 본 개시의 도면들에 있어서 어느 구성요소, 특히 다공성 알갱이(30a)의 도시에 있어서 크기는 가시성을 위하여 과장되어 표현되었으며, 도면상의 상대적인 크기에 의해 구성요소들의 크기가 한정되는 것은 아니다.The tobacco body rod 40a may include at least a tobacco body 41, and as shown in FIG. 9, it preferably further includes a plurality of porous granules 30a with micropores formed on the surface or inside. . In the drawings of the present disclosure, the sizes of certain components, particularly the porous grains 30a, are exaggerated for visibility, and the sizes of the components are not limited by their relative sizes in the drawings.
담배체 로드(40a)는 담배체(41) 자체가 뭉쳐져 형성되거나 또는 담배체(41)를 뭉쳐 별도의 랩핑 페이퍼(미도시)로 감싸 형성될 수 있다. 즉 담배체 로드(40a)는 담배체(41)를 로드(rod) 내지 실린더 형태로 뭉친 구조체일 수 있으며, 또는 구조의 견고성과 제조의 용이성을 위하여, 별도의 랩핑 페이퍼로 상기 구조체의 적어도 측면을 감싸 형성할 수 있다.The tobacco body rod 40a may be formed by agglomerating the tobacco body 41 itself, or may be formed by agglomerating the tobacco body 41 and wrapping it with separate wrapping paper (not shown). That is, the tobacco body rod 40a may be a structure in which the tobacco body 41 is bundled into a rod or cylinder shape, or for structural rigidity and ease of manufacture, at least one side of the structure may be wrapped with separate wrapping paper. It can be wrapped and formed.
담배체(41)를 감싸는 랩핑 페이퍼(미도시)는 바람직하게, 혹시라도 발생할 에어로졸 매질의 누액을 방지하기 위해 방수 코팅이 되어 있는 페이퍼나 멤브레인 재질로 이루어진다. 예를 들어, 랩핑 페이퍼는 알루미늄 포일이 종이에 부착되어 형성된 합지로 제공될 수 있으며, 알루미늄 포일이 담배체(41)에 접촉하도록 실린더 형상으로 랩핑된다. 이에 따라 알루미늄 포일은 담배체(41)나 다수의 다공성 알갱이(30a)로부터 에어로졸 매질이 액화되어 담배체 로드(40a)의 측면을 통해 흘러나올 가능성을 없애거나 최소화할 수 있다.The wrapping paper (not shown) surrounding the tobacco body 41 is preferably made of paper or membrane material with a waterproof coating to prevent leakage of the aerosol medium that may occur. For example, the wrapping paper may be provided as a laminate formed by attaching aluminum foil to paper, and the aluminum foil is wrapped in a cylinder shape so that it contacts the tobacco body 41. Accordingly, the aluminum foil can eliminate or minimize the possibility of the aerosol medium being liquefied from the tobacco body 41 or the plurality of porous particles 30a and flowing out through the side of the tobacco body rod 40a.
담배체(41)는 판상엽 담배, 각초, 재구성 담배 등 담배 원료를 기초로 하는 고체 물질을 포함할 수 있다. 일 실시예에서 담배체(41)는 주름진 판상엽 시트 형태의 담배일 수 있다. 판상엽 시트는 실린더 축에 실질적으로 가로방향으로 둘둘 말리거나, 접히거나, 압축되거나, 수축됨으로써 주름이 형성될 수 있다. 주름진 판상엽 시트의 골 간격 등을 조절함으로써 다공도를 결정할 수 있다.The tobacco body 41 may include solid materials based on tobacco raw materials, such as leaf tobacco, cut tobacco, and reconstituted tobacco. In one embodiment, the tobacco body 41 may be a cigarette in the form of a wrinkled leaf sheet. The lamellar sheet may be wrinkled by being rolled, folded, compressed, or contracted substantially transversely to the axis of the cylinder. Porosity can be determined by controlling the valley spacing of the wrinkled plate-like sheet.
다른 실시예에서 담배체(41)는 담배 각초일 수 있다. 여기에서, 담배 각초들은 담배 시트(또는 슬러리 판상엽 시트)를 잘게 절단함으로써 생성될 수 있다. 또한, 담배체(41)는 복수의 담배 가닥들이 서로 같은 방향(평행)으로 또는 무작위로 합쳐져서 형성될 수 있다. 구체적으로, 담배체(41)는 복수의 담배 가닥들이 합쳐져서 형성되고, 에어로졸이 통과할 수 있는 종방향의 복수의 채널들이 형성될 수 있다. 이때, 담배 가닥들의 크기 및 배열에 의하여, 종방향의 채널들은 균일하거나 불균일할 수 있다.In another embodiment, the tobacco body 41 may be a tobacco cut filler. Here, tobacco cut fillers can be produced by cutting tobacco sheets (or slurry leaf sheets) into small pieces. Additionally, the tobacco body 41 may be formed by combining a plurality of tobacco strands in the same direction (parallel) or randomly. Specifically, the tobacco body 41 is formed by combining a plurality of tobacco strands, and a plurality of longitudinal channels through which aerosol can pass may be formed. At this time, depending on the size and arrangement of the tobacco strands, the longitudinal channels may be uniform or non-uniform.
담배체(41)는 추가로 에틸렌 글리콜, 디프로필렌 글리콜, 디에틸렌 글리콜, 트리에틸렌글리콜, 테트라에틸렌 글리콜 및 올레일 알코올 중 적어도 하나를 포함할 수 있다. 또한, 담배체(41)는 글리세린 및 프로필렌 글리콜을 더 포함할 수도 있다.The tobacco body 41 may further include at least one of ethylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and oleyl alcohol. Additionally, the tobacco body 41 may further contain glycerin and propylene glycol.
또한, 담배체(41)는 풍미제 및/또는 유기산(organic acid)과 같은 다른 첨가 물질을 함유할 수 있다. 예를 들어, 풍미제는 감초, 자당, 과당 시럽, 이소감미제(isosweet), 코코아, 라벤더, 시나몬, 카르다몸, 셀러리, 호로파, 카스카릴라, 백단, 베르가못, 제라늄, 벌꿀 에센스, 장미 오일, 바닐라, 레몬 오일, 오렌지 오일, 민트 오일, 계피, 케러웨이, 코냑, 자스민, 카모마일, 멘톨, 계피, 일랑일랑, 샐비어, 스피어민트, 생강, 고수 또는 커피 등을 포함할 수 있다. 한편, 담배체(41)는 글리세린 또는 프로필렌 글리콜을 일부 포함할 수도 있다.Additionally, the tobacco body 41 may contain other added substances such as flavoring agents and/or organic acids. For example, flavoring agents include licorice, sucrose, fructose syrup, isosweet, cocoa, lavender, cinnamon, cardamom, celery, fenugreek, cascarilla, sandalwood, bergamot, geranium, honey essence, rose oil, It may contain vanilla, lemon oil, orange oil, mint oil, cinnamon, caraway, cognac, jasmine, chamomile, menthol, cinnamon, ylang ylang, sage, spearmint, ginger, coriander or coffee. Meanwhile, the tobacco body 41 may contain some glycerin or propylene glycol.
전술한 대로 담배체(41)가 실린더 내지 로드 형태로 뭉쳐지며 담배체 로드(40a)가 형성될 수 있다. 또한 바람직하게 담배체 로드(40a)에는 적어도 하나의 에어로졸 매질을 포함하는 복수의 다공성 알갱이(30a)를 추가로 포함한다. 이 때 다공성 알갱이(30a)는 담배체(41) 내에 고르게 분포할 수 있다. 담배체(41)는 고체이며, 다수가 뭉쳐져 실질적으로 담배체 로드(40a)를 형성하므로 다공성 알갱이(30a)는 담배체 로드(40a) 내에서 담배체(41) 사이 사이에 다수가 분포하며 담배체(41)에 의해 위치가 고정될 수 있다.As described above, the tobacco body 41 may be aggregated into a cylinder or rod shape to form the tobacco body rod 40a. Also preferably, the tobacco rod 40a further includes a plurality of porous granules 30a containing at least one aerosol medium. At this time, the porous grains 30a can be evenly distributed within the tobacco body 41. The tobacco body 41 is solid, and a large number are aggregated to substantially form the tobacco body rod 40a, so the porous grains 30a are distributed in large numbers between the tobacco bodies 41 within the tobacco body rod 40a, and the tobacco body 41 is distributed in large numbers. The position can be fixed by the sieve 41.
실시예들에 있어서, 복수의 다공성 알갱이(30a)는 소정의 바인더를 이용하여 입체 형상으로 블록화되어 담배체 로드(40a)에 포함될 수 있다. 또는 이러한 블록화 과정 없이, 복수의 비드 형태나 구형 분말 형태의 다공성 알갱이(30a)를 담배체(41)와 섞어 혼합하여 에어로졸 발생 장치나 카트리지에 무화기로 적용할 수 있다.In embodiments, a plurality of porous granules (30a) may be blocked into a three-dimensional shape using a predetermined binder and included in the tobacco rod (40a). Alternatively, without this blocking process, the porous particles 30a in the form of a plurality of beads or spherical powder can be mixed with the tobacco body 41 and applied to an aerosol generating device or cartridge as an atomizer.
역시 자명하게도, 다공성 알갱이(30a)는 위에서 동일한 명칭과 참조부호로서 기 설명한 내용을 그대로 적용할 수 있다.As is also evident, the porous grains 30a can be applied as described above with the same names and reference numerals.
이상 설명한 실시예에 근거하면, 실시예의 가열식 흡연 물품(1b)은 소정의 에어로졸 발생 장치에 삽입되어 담배체 로드(40a)가 가열될 수 있으며, 그에 따라, 담배체(41)로부터 유래하는 에어로졸과 다공성 알갱이(30a) 내의 마이크로 기공(A)이나 표면에 수용된 액상이나 겔상이나 고형화상의 에어로졸 매질로부터 유래하는 에어로졸이 발생할 수 있다. 그에 따라 사용자는 서로 다른 출처로부터 유래하는 에어로졸 성분을 혼합하여 흡입할 수 있어, 종래 기술의 흡연 물품과 비교하여, 더욱 다양해진 풍미와 풍성한 연무감을 동시에 느낄 수 있다.Based on the above-described embodiments, the heated smoking article 1b of the embodiment can be inserted into a predetermined aerosol generating device so that the tobacco body rod 40a is heated, thereby producing aerosol and aerosol derived from the tobacco body 41. Aerosols originating from liquid, gel, or solid aerosol media contained in the micropores (A) or on the surface of the porous grains (30a) may be generated. Accordingly, the user can inhale a mixture of aerosol components derived from different sources, thereby simultaneously feeling more diverse flavors and a richer sense of smoke compared to conventional smoking articles.
도 10은 본 발명의 또 다른 실시예에 따른 가열식 흡연 물품(1c)의 내부를 개념적으로 나타낸 수직 단면도이다. 본 실시예의 가열식 흡연 물품(1c)은 도 7의 가열식 흡연 물품(1)과 비교하여, 에어로졸 매질 집합체(35)는 그 중심부를 상하로 관통하도록 형성된 중공을 포함하도록 배치되고, 상기 중공에는 담배체(41)가 구비되는 점을 달리한다.Figure 10 is a vertical cross-sectional view conceptually showing the inside of a heated smoking article 1c according to another embodiment of the present invention. In the heated smoking article 1c of the present embodiment, compared to the heated smoking article 1 of FIG. 7, the aerosol medium aggregate 35 is arranged to include a hollow formed to penetrate upward and downward through the center, and the hollow contains a tobacco body. (41) is provided differently.
예를 들어 에어로졸 매질 집합체(35)에 냉각 튜브 로드(20)의 중공(22)과 동일한 직경의, 또한 동일한 중심축을 공유하는 중공을 형성하고, 그 중공에 담배체(41)를 채워 넣을 수 있다. 이 때 담배체(41)가 채워진 중공은 냉각 튜브 로드(20)의 중공(22)과 연결되는 기류 패스의 역할을 할 수 있다. 본 실시예의 에어로졸 매질 집합체(35) 역시 실시예에 따라, 로드(rod)를 형성하기 위하여 별도의, 바람직하게는 방수 기능을 갖는, 랩핑 페이퍼에 랩핑될 수 있다.For example, a hollow having the same diameter and sharing the same central axis as the hollow 22 of the cooling tube rod 20 may be formed in the aerosol medium assembly 35, and the tobacco body 41 may be filled into the hollow. . At this time, the hollow filled with the tobacco body 41 may serve as an airflow path connected to the hollow 22 of the cooling tube rod 20. Depending on the embodiment, the aerosol medium aggregate 35 may also be wrapped in a separate, preferably waterproof, wrapping paper to form a rod.
예를 들어 가열식 흡연 물품(1c)이 어느 에어로졸 발생 장치 내에 삽입되고, 그에 포함된 히터에 의해 에어로졸 매질 집합체(35)의 외곽이 가열되면, 에어로졸 매질 집합체(35)의 다공성 알갱이(30a)에 포함된 에어로졸 매질이 에어로졸로 변환되어 상기 에어로졸 매질 집합체(35)의 중공으로 도입될 수 있다. 이 때, 이 뜨거운 에어로졸이 담배체(41)를 가열하여 담배체(41)로부터 역시 에어로졸이 발생할 수 있으며, 상기의 두 출처의 에어로졸이 혼합되어, 냉각 튜브 로드(20) 및 필터 로드(10)를 거쳐 사용자에게 흡입될 수 있다.For example, when the heated smoking article (1c) is inserted into an aerosol generating device and the exterior of the aerosol medium assembly (35) is heated by the heater included therein, the heated smoking article (1c) is included in the porous particles (30a) of the aerosol medium assembly (35). The aerosol medium may be converted into an aerosol and introduced into the hollow of the aerosol medium assembly 35. At this time, this hot aerosol heats the tobacco body 41, so that aerosol can also be generated from the tobacco body 41, and the aerosols from the above two sources are mixed, and the cooling tube rod 20 and the filter rod 10 It can be inhaled by the user.
예를 들어 담배체(41)를 원통 형태로 먼저 뭉친 후, 그것을 인서트한 채 다공성 알갱이(30a)를 외곽에 채우는 방법으로 에어로졸 매질 집합체(35)를 제조할 수 있다. 또는 담배체(41)를 원통 형태로 먼저 뭉친 후, 그것을 메쉬 또는 다수의 통공을 갖는 별도의 랩핑 페이퍼로 랩핑하여, 그것을 인서트한 채 다공성 알갱이(30a)를 외곽에 채우는 방법으로 에어로졸 매질 집합체(35)를 제조할 수 있다. 이 경우, 상기 메쉬 또는 다수의 통공을 갖는 별도의 랩핑 페이퍼는 에어로졸 매질 집합체(35)에 형성된 중공과 에어로졸 매질 집합체(35)의 경계를 실질적으로 정의하며 통기막의 역할을 한다. 또는 그 횡단면이 도넛 형상이 되도록, 중공이 형성된 에어로졸 매질 집합체(35)의 내측과 외측을 메쉬 또는 다수의 통공을 갖는 별도의 랩핑 페이퍼로 감싼 후, 형성된 중공에 담배체(41)를 채워 넣어 에어로졸 매질 집합체(35)를 제조할 수도 있다.For example, the aerosol medium aggregate 35 can be manufactured by first agglomerating the tobacco body 41 into a cylindrical shape, inserting the tobacco body 41, and then filling the outside with porous particles 30a. Alternatively, the tobacco body 41 is first lumped into a cylindrical shape, then wrapped with mesh or a separate wrapping paper having a plurality of holes, and the aerosol medium aggregate 35 is formed by inserting the tobacco body 41 and filling the outside with the porous granules 30a. ) can be manufactured. In this case, the mesh or a separate wrapping paper having multiple holes substantially defines the boundary between the hollow formed in the aerosol medium assembly 35 and the aerosol medium assembly 35 and serves as a breathable membrane. Alternatively, the inside and outside of the hollow aerosol medium assembly 35 are wrapped with mesh or a separate wrapping paper having a plurality of holes so that the cross section has a donut shape, and then the tobacco body 41 is filled into the formed hollow to produce aerosol. A medium assembly 35 may also be manufactured.
도 11은 본 발명의 또 다른 실시예에 따른 에어로졸 매질 집합체(35)를 개념적으로 도시한 단면도이다. 에어로졸 매질 집합체(35)는 별도의 랩핑 페이퍼(31)에 의해 랩핑되어 최외곽의 형상은 원통 형상을 갖는다. 에어로졸 매질 집합체(35)의 중심부에는 상하로 관통하도록 중공(32)이 형성되어 있다. 상기 중공(32)에는 담배체(41)가 채워져야 하지만, 본 도면에서는 담배체(41)의 도시를 생략하였다. 에어로졸 매질 집합체(35)의 횡단면이 도넛 형상이 되도록, 중공(32)이 형성된 에어로졸 매질 집합체(35)의 내측과 외측은 메쉬 또는 다수의 통공을 갖는 통기막(32a)으로 감싸여져 있다. 결국 실질적으로 통기막(32a)의 양 경계에 다공성 알갱이(30a)를 채워넣어, 중공(32)을 포함하는 에어로졸 매질 집합체(35)를 제조할 수 있는 것이다.Figure 11 is a cross-sectional view conceptually showing an aerosol medium aggregate 35 according to another embodiment of the present invention. The aerosol medium aggregate 35 is wrapped by a separate wrapping paper 31, so that the outermost shape is cylindrical. A hollow 32 is formed in the center of the aerosol medium aggregate 35 to penetrate upward and downward. The hollow 32 must be filled with the tobacco body 41, but the tobacco body 41 is omitted in this drawing. The inside and outside of the aerosol medium assembly 35 where the hollow 32 is formed is wrapped with a mesh or a breathable membrane 32a having a plurality of holes so that the cross-section of the aerosol medium assembly 35 is donut-shaped. In the end, it is possible to manufacture an aerosol medium aggregate 35 including a cavity 32 by substantially filling both boundaries of the air permeable membrane 32a with porous particles 30a.
본 실시예에서 통기막(32a)은 중공(32)이 형성된 에어로졸 매질 집합체(35)의 내측과 외측을 모두 감싸는 것으로 도시되었지만, 실시예를 달리하여, 통기막(32a)은 에어로졸 매질 집합체(35)에 형성된 중공(32)과 에어로졸 매질 집합체(35)의 경계면에만 형성될 수도 있다.In this embodiment, the gas permeable membrane 32a is shown as surrounding both the inside and the outside of the aerosol medium assembly 35 in which the hollow 32 is formed. However, in a different embodiment, the gas permeable membrane 32a is wrapped around the aerosol medium assembly 35. ) may be formed only at the interface between the hollow 32 formed in and the aerosol medium aggregate 35.
실시예에 따른 가열식 흡연 물품(1, 1a, 1b, 1c)은 필름 히터와 같은 저항 가열 방식이 적용된 가열 디바이스 내의 가열 공간에 삽입되어 가열될 수도 있으며, 다른 실시예로 유도 가열 방식이 적용된 가열 디바이스 내에 가열 공간에 삽입될 수도 있다. Heated smoking articles (1, 1a, 1b, 1c) according to an embodiment may be heated by being inserted into a heating space in a heating device to which a resistance heating method such as a film heater is applied, and in another embodiment, a heating device to which an induction heating method is applied. It may also be inserted into the heating space within.
가열 디바이스는, 가열식 흡연 물품(1, 1a, 1b, 1c)이 삽입되어 가열될 수 있는 가열 공간(공동)을 갖고, 가열 공간에 삽입된 가열식 흡연 물품(1, 1a, 1b, 1c)의 글리세린과 같은 에어로졸 매질, 담배체 및/또는 니코틴과 같은 에어로졸 형성 기질을 히터에 의해 가열하여 에어로졸을 형성시키는, 파지 가능하고 휴대 가능한 크기의 에어로졸 발생 장치를 가리킨다. 히터는 전술한 바와 같이 저항 가열 방식 혹은 유도 가열 방식으로 제공될 수 있는데, 일 예로 100 - 400 ℃의 온도까지 가열되어, 가열 디바이스의 가열 공간(공동) 내에 삽입되는 가열식 흡연 물품(1, 1a, 1b, 1c) 내부에 제공되는 에어로졸 매질 내지 형성 기질을 가열시켜 에어로졸을 발생시킨다. 바람직한 일 실시예에 따르면, 그 타켓 온도는 200 내지 350 ℃의 범위가 될 수 있으며, 더욱 바람직한 일 예에 따르면 그 타겟 온도는 250 내지 320 ℃의 범위가 될 수 있다 (일 예로 280 ℃를 타겟으로 정할 수도 있음). 경우에 따라서는 그 타겟 온도가 150 내지 250 ℃의 범위일 수 있는데(일 예로 180 ℃를 타겟 온도로 정할 수도 있음), 이것은 에어로졸을 발생시키고자 하는 대상이 글리세린인지 혹은 담배체인지 혹은 글리세린과 같은 액상 조성물이 흡습된 담배체인지 혹은 니코틴액인지에 따라 달라질 수 있다. 어느 경우든 가열식 흡연 물품(1, 1a, 1b, 1c) 내에서 발생된 에어로졸은 사용자의 퍼핑 시에 냉각 튜브 로드(20) 및 필터 로드(10)를 통해 사용자의 입안으로 흡입되므로, 퍼핑 과정에서 냉각되는 것을 고려하더라도 발생된 에어로졸의 온도가 과도하게 높으면 사용자에게 불쾌감을 주거나 화상의 위험이 있고 너무 과도하게 에어로졸이 발생할 수 있어서 여러 번의 퍼프가 힘들 수 있기에 이러한 점을 감안하여 발열체의 타겟 온도가 미리 정해져야 한다. 또한 이상의 이유 때문에 발열체의 타겟 온도의 상한이 위와 같이 제한된다. The heating device has a heating space (cavity) into which the heated smoking articles (1, 1a, 1b, 1c) can be inserted and heated, and the glycerin of the heated smoking articles (1, 1a, 1b, 1c) inserted into the heating space. It refers to an aerosol-generating device of a grippable and portable size, which forms an aerosol by heating an aerosol medium such as an aerosol medium, a tobacco body, and/or an aerosol-forming substrate such as nicotine by a heater. The heater may be provided as a resistance heating type or an induction heating type as described above. For example, the heated smoking article (1, 1a, 1b, 1c) The aerosol medium or forming substrate provided inside is heated to generate an aerosol. According to a preferred embodiment, the target temperature may be in the range of 200 to 350 °C, and according to a more preferred example, the target temperature may be in the range of 250 to 320 °C (for example, 280 °C as the target). may be determined). In some cases, the target temperature may be in the range of 150 to 250 ℃ (for example, 180 ℃ may be set as the target temperature), which means that the object to generate aerosol is glycerin, cigarette change, or a liquid such as glycerin. It may vary depending on whether the composition is a moisture-absorbed cigarette change or nicotine liquid. In any case, the aerosol generated within the heated smoking articles (1, 1a, 1b, 1c) is inhaled into the user's mouth through the cooling tube rod (20) and the filter rod (10) when the user puffs, so during the puffing process Even considering cooling, if the temperature of the generated aerosol is excessively high, there is a risk of discomfort or burns to the user, and excessive aerosol may be generated, making multiple puffs difficult. Taking this into account, the target temperature of the heating element must be set in advance. It must be decided. Additionally, for the above reasons, the upper limit of the target temperature of the heating element is limited as above.
바람직한 일 실시예에 따르면 발생된 에어로졸이 냉각 튜브 로드(20) 및 필터 로드(10)를 거쳐 나오는 온도가 마우스 엔드 온도(mouth end temperature)로 측정될 수 있는데, 사용자에게 불쾌감을 주지 않기 위해서 에어로졸의 온도는 50 ℃ 미만, 바람직하게는 45 ℃ 이하의 온도로 되어야 한다. 바람직한 에어로졸의 마우스 엔드 온도는 25 내지 45 ℃의 온도 범위를 갖고, 더욱 바람직한 에어로졸의 마우스 엔드 온도는 30 내지 40 ℃의 온도 범위를 갖는다.According to a preferred embodiment, the temperature at which the generated aerosol passes through the cooling tube rod 20 and the filter rod 10 can be measured as the mouth end temperature. In order to avoid causing discomfort to the user, the temperature of the aerosol may be measured. The temperature should be below 50°C, preferably below 45°C. The mouth end temperature of a preferred aerosol is in the temperature range of 25 to 45° C., and the more preferred mouth end temperature of the aerosol is in the temperature range of 30 to 40° C.
바람직한 일 실시예에 따른 가열식 흡연 물품(1, 1a, 1b, 1c)에서 에어로졸 매질 집합체(30)와, 담배체 로드(40, 40a)가 흡연 물품의 길이 방향을 따라 제공되는데(경우에 따라 에어로졸 매질 집합체(30)가 상류에 혹은 하류에 위치할 수 있음), 전술한 바와 같이 에어로졸 매질 집합체(30)의 타겟 온도와, 담배체 로드(40, 40a)의 타겟 온도가 다르므로, 가열 디바이스의 가열 공간에는 각각의 타겟 온도에 대응해서 에어로졸 매질 집합체(30)와, 담배체 로드(40, 40a)를 가열시킬 수 있는 독립적인 히터가 제공되는 것이 바람직하다. In a heated smoking article (1, 1a, 1b, 1c) according to a preferred embodiment, an aerosol medium assembly (30) and a tobacco body rod (40, 40a) are provided along the longitudinal direction of the smoking article (in some cases, aerosol The medium assembly 30 may be located upstream or downstream). As described above, the target temperature of the aerosol medium assembly 30 and the target temperature of the tobacco rods 40 and 40a are different, so that the heating device It is preferable that the heating space is provided with an independent heater capable of heating the aerosol medium assembly 30 and the tobacco rods 40 and 40a in response to each target temperature.
일 실시예로 필터 로드 - 냉각 튜브 로드 - 에어로졸 매질 집합체 - 담배체 로드의 순서로 형성된 가열식 흡연 물품(1, 1a, 1b, 1c)의 경우, 에어로졸 매질 집합체의 타겟 온도(일 예로 300 ℃)가 담배체 로드의 타겟 온도(일 예로 200 ℃)와 다르므로, 에어로졸 매질 집합체를 가열하는 히터(일 예로 저항 가열 히터)와, 담배체 로드를 가열하는 히터(일 예로 저항 가열 히터)가 서로 이격되어 다른 온도 범위로 에어로졸 매질 집합체와 담배체 로드를 가열시켜, 각각의 로드로부터 유래하는 에어로졸을 유효하게 발생시키는 것이 좋다. In one embodiment, in the case of heated smoking articles (1, 1a, 1b, 1c) formed in the following order: filter rod - cooling tube rod - aerosol medium assembly - tobacco body rod, the target temperature of the aerosol medium assembly (for example, 300 ° C.) Since it is different from the target temperature of the tobacco rod (e.g., 200° C.), the heater that heats the aerosol medium aggregate (e.g., a resistance heating heater) and the heater that heats the tobacco rod (e.g., a resistance heating heater) are spaced apart from each other. It is advisable to heat the aerosol medium aggregate and the tobacco rod to different temperature ranges to effectively generate aerosol from each rod.
물론 이상의 예를 일 예를 든 것이고, 가열 방식에 따라, 에어로졸 형성 기재의 배열 순서에 따라 이상과 같은 설명을 고려하여 배열과 배치를 바꾸는 것이 이 분야의 통상의 지식을 가진 자에게 당연한 사항이 될 것이다.Of course, the above example is just an example, and it will be natural for those skilled in the field to change the arrangement and arrangement according to the heating method and the order of arrangement of the aerosol-forming substrate, taking the above explanation into consideration. will be.
본 발명은 상술한 특정의 바람직한 실시예에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변형실시가 가능한 것은 물론이고, 그와 같은 변경은 청구범위 기재의 범위 내에 있게 된다.The present invention is not limited to the specific preferred embodiments described above, and various modifications can be made by anyone skilled in the art without departing from the gist of the invention as claimed in the claims. Of course, such changes are within the scope of the claims.

Claims (35)

  1. 가열에 의해 에어로졸을 생성하는 에어로졸 매질; 및an aerosol medium that generates an aerosol by heating; and
    표면이나 내부에 마이크로 기공이 형성된 복수의 다공성 알갱이;를 포함하고,It includes a plurality of porous grains with micropores formed on the surface or inside,
    복수의 다공성 알갱이 사이에는 매크로 기공이 형성되고, 에어로졸 매질은 마이크로 기공과 매크로 기공에 수용된 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium aggregate characterized in that macro pores are formed between a plurality of porous particles, and the aerosol medium is accommodated in the micro pores and macro pores.
  2. 제1항에 있어서,According to paragraph 1,
    마이크로 기공은 버나드셀 현상을 통하여 형성된 것을 특징으로 하는 에어로졸 매질 집합체.Micro pores are an aerosol medium aggregate characterized by being formed through the Bernard Cell phenomenon.
  3. 제1항에 있어서,According to paragraph 1,
    다공성 알갱이는 비드 형태나 구형 분말 형태인 것을 특징으로 하는 에어로졸 매질 집합체.The porous particles are an aerosol medium aggregate characterized in that they are in the form of beads or spherical powders.
  4. 제1항에 있어서, According to paragraph 1,
    다공성 알갱이는 금속 성분과 실리케이트로 구성된 것을 특징으로 하는 에어로졸 매질 집합체.The porous granules are an aerosol medium aggregate characterized in that they are composed of metal components and silicates.
  5. 제4항에 있어서, According to paragraph 4,
    금속 성분은 알칼리토류족인 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium aggregate characterized in that the metal component is an alkaline earth group.
  6. 제4항에 있어서, According to paragraph 4,
    다공성 알갱이는 섬유 글라스를 포함하는 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium aggregate characterized in that the porous particles contain fiber glass.
  7. 제6항에 있어서, According to clause 6,
    섬유 글라스는 50 % 이상의 중량 퍼센트로 SiO2를 포함하는 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium aggregate characterized in that the fiber glass comprises SiO2 in a weight percent of at least 50%.
  8. 제1항에 있어서,According to paragraph 1,
    마이크로 기공은 20 ㎛ ~ 50 ㎛ 범위에 속하는 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium aggregate characterized in that the micro pores fall within the range of 20 ㎛ to 50 ㎛.
  9. 제1항에 있어서,According to paragraph 1,
    매크로 기공은 1 ㎛ ~ 20 ㎛ 범위에 속하는 것을 특징으로 하는 에어로졸 매질 집합체.Macro pores are an aerosol medium aggregate characterized in that they fall in the range of 1 ㎛ to 20 ㎛.
  10. 제1항에 있어서, According to paragraph 1,
    다공성 알갱이는 마그네슘 실리케이트, 알루미늄 실리케이트, 규산 실리케이트, 제올라이트, 산화 티탄, 탄화 티탄, 지르코니아, 실리카, 탄화규소, 질화규소, 뮬라이트, 코디어라이트, 탄화 텅스텐, 탄화 지르코늄, 질화 알루미늄을 포함하는 군에서 선택된 하나 이상의 물질을 포함하여 구성된 것을 특징으로 하는 에어로졸 매질 집합체.The porous grains are one selected from the group comprising magnesium silicate, aluminum silicate, silicate silicate, zeolite, titanium oxide, titanium carbide, zirconia, silica, silicon carbide, silicon nitride, mullite, cordierite, tungsten carbide, zirconium carbide, aluminum nitride. An aerosol medium aggregate comprising the above substances.
  11. 제1항에 있어서, According to paragraph 1,
    다공성 알갱이는 10 ㎛ 내지 300 ㎛의 직경을 갖는 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium aggregate, characterized in that the porous particles have a diameter of 10 ㎛ to 300 ㎛.
  12. 제1항에 있어서,According to paragraph 1,
    에어로졸 매질은 적어도 VG(식물성 글리세린)와 PG(프로필렌 글리콜)를 포함하는 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium assembly characterized in that the aerosol medium contains at least VG (vegetable glycerin) and PG (propylene glycol).
  13. 제1항에 있어서,According to paragraph 1,
    에어로졸 매질은 상온에서 액상, 겔상 또는 고형화상 중 어느 하나인 것을 특징으로 하는 에어로졸 매질 집합체.The aerosol medium is a collection of aerosol media characterized in that it is either a liquid, gel, or solid phase at room temperature.
  14. 제13항에 있어서,According to clause 13,
    에어로졸 매질은 상온에서 액상이고, 복수의 다공성 알갱이와 혼합되며 마이크로 기공과 매크로 기공에 흡습되는 것을 특징으로 하는 에어로졸 매질 집합체.The aerosol medium is an aerosol medium aggregate characterized in that it is liquid at room temperature, is mixed with a plurality of porous particles, and is absorbed into micro-pores and macro-pores.
  15. 제13항에 있어서,According to clause 13,
    에어로졸 매질은 상온을 포함하는 제1 온도 범위에서 겔상 또는 반고상으로 존재하고, 제1 온도 범위보다 높은 제2 온도 범위에서 액상으로 변화하며, 제2 온도 범위보다 높은 제3 온도 범위에서 에어로졸로 기화하는 것을 특징으로 하는 에어로졸 매질 집합체.The aerosol medium exists in a gel or semi-solid phase in a first temperature range including room temperature, changes to a liquid phase in a second temperature range higher than the first temperature range, and vaporizes into an aerosol in a third temperature range higher than the second temperature range. An aerosol medium aggregate characterized in that.
  16. 제15항에 있어서,According to clause 15,
    에어로졸 매질은 적어도 VG(식물성 글리세린)와 카라기난을 포함하는 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium aggregate characterized in that the aerosol medium contains at least VG (vegetable glycerin) and carrageenan.
  17. 제15항에 있어서,According to clause 15,
    에어로졸 매질은 적어도 VG(식물성 글리세린)와 증점제를 포함하고, 제3 온도 범위에서 증점제는 기화하지 않고 에어로졸 매질 집합체에 잔류하는 것을 특징으로 하는 에어로졸 매질 집합체.The aerosol medium includes at least VG (vegetable glycerin) and a thickener, and wherein the thickener does not vaporize and remains in the aerosol medium assembly in the third temperature range.
  18. 제15항에 있어서,According to clause 15,
    에어로졸 매질은 액상화된 상태로 복수의 다공성 알갱이와 혼합된 후 다시 겔상화되어 복수의 다공성 알갱이의 마이크로 기공과 매크로 기공에 수용되는 것을 특징으로 하는 에어로졸 매질 집합체.An aerosol medium aggregate characterized in that the aerosol medium is mixed with a plurality of porous particles in a liquefied state, then gelled again and accommodated in the micro-pores and macro-pores of the plurality of porous particles.
  19. 제13항에 있어서,According to clause 13,
    에어로졸 매질은 상온을 포함하는 제1 온도 범위에서 고형화상으로 존재하고, 제1 온도 범위보다 높은 제2 온도 범위에서 액상으로 변화하며, 제2 온도 범위보다 높은 제3 온도 범위에서 에어로졸로 기화하는 것을 특징으로 하는 에어로졸 매질 집합체.The aerosol medium exists in a solid phase in a first temperature range including room temperature, changes to a liquid phase in a second temperature range higher than the first temperature range, and vaporizes into an aerosol in a third temperature range higher than the second temperature range. Characterized by an aerosol medium aggregate.
  20. 제19항에 있어서,According to clause 19,
    에어로졸 매질은 적어도 VG(식물성 글리세린)와 증점제를 포함하고, 제3 온도 범위에서 증점제는 기화하지 않고 에어로졸 매질 집합체에 잔류하는 것을 특징으로 하는 에어로졸 매질 집합체.The aerosol medium includes at least VG (vegetable glycerin) and a thickener, and wherein the thickener does not vaporize and remains in the aerosol medium assembly in the third temperature range.
  21. 제20항에 있어서,According to clause 20,
    증점제는 셀룰로오스 유도체(Cellulose derivatives), 덱스트린 유도체(Dextrin derivatives), 알지네이트 유도체(Alginate derivatives), 검(Gum), 펙틴(Pectin), 헤미셀룰로오스 유도체(Hemicellulose derivatices) 및 젤라틴(Gelatin)을 포함하는 군에서 선택된 하나 이상의 물질을 포함하는 것을 특징으로 하는 에어로졸 매질 집합체.The thickener is selected from the group comprising cellulose derivatives, dextrin derivatives, alginate derivatives, gum, pectin, hemicellulose derivatices and gelatin. An aerosol medium aggregate comprising one or more substances.
  22. 제19항에 있어서,According to clause 19,
    에어로졸 매질은, 액상의 VG(식물성 글리세린)와 PG(프로필렌 글리콜) 혼합물, 증점제 및 용해제의 혼합 용액을 복수의 다공성 알갱이와 혼합하여 다공성 알갱이에 흡습시키고, 다공성 알갱이에 흡습된 혼합 용액에 포함된 용해제를 증발시켜 형성되며, 용해제는 액상의 VG(식물성 글리세린)와 PG(프로필렌 글리콜) 혼합물 및 증점제보다 끓는 점이 낮은 것을 특징으로 하는 에어로졸 매질 집합체.The aerosol medium is a mixed solution of liquid VG (vegetable glycerin) and PG (propylene glycol) mixture, thickener, and solubilizer mixed with a plurality of porous granules, moisture is absorbed into the porous granules, and the solubilizer contained in the mixed solution absorbed by the porous granules is mixed. An aerosol medium aggregate that is formed by evaporating and the dissolving agent has a lower boiling point than the liquid VG (vegetable glycerin) and PG (propylene glycol) mixture and thickener.
  23. 제1항 내지 제22항 중 어느 한 항에 따른 에어로졸 매질 집합체; 및An aerosol medium assembly according to any one of claims 1 to 22; and
    에어로졸 매질 집합체를 실린더 형상으로 랩핑하는 랩핑 페이퍼;를 포함하는 것을 특징으로 하는 에어로졸 매질 로드.An aerosol medium rod comprising a wrapping paper that wraps the aerosol medium assembly into a cylinder shape.
  24. 필터 로드;filter load;
    필터 로드의 하단에 적층되며 상하 방향으로 중공이 형성된 냉각 튜브 로드; 및A cooling tube rod laminated at the bottom of the filter rod and formed with a hollow top and bottom; and
    냉각 튜브 로드의 하단에 적층되는 제1항 내지 제22항 중 어느 한 항에 따른 에어로졸 매질 집합체;를 포함하고, 필터 로드와 냉각 튜브 로드와 에어로졸 매질 집합체는 랩핑 페이퍼로 랩핑되어 궐련을 형성하는 것을 특징으로 하는 가열식 흡연 물품.An aerosol medium assembly according to any one of claims 1 to 22 stacked at the bottom of the cooling tube rod, wherein the filter rod, the cooling tube rod, and the aerosol medium assembly are wrapped with wrapping paper to form a cigarette. A heated smoking article characterized by:
  25. 제24항에 있어서,According to clause 24,
    에어로졸 매질 집합체는 별도의 랩핑 페이퍼에 의해 실린더 형상으로 랩핑되어 있는 것을 특징으로 하는 가열식 흡연 물품.A heated smoking article, characterized in that the aerosol medium aggregate is wrapped in a cylindrical shape by separate wrapping paper.
  26. 제24항에 있어서,According to clause 24,
    에어로졸 매질 집합체의 상단 또는 하단에 추가로 적층되는, 담배 각초를 포함하는 담배체 로드를 포함하며, 필터 로드와 냉각 튜브 로드와 에어로졸 매질 집합체와 추가로 적층되는 담배체 로드가 랩핑되어 궐련을 형성하는 것을 특징으로 하는 가열식 흡연 물품.It includes a tobacco body rod including a tobacco cut filler, which is further laminated on the top or bottom of the aerosol medium assembly, and the filter rod, the cooling tube rod, and the aerosol medium assembly and the tobacco body rod further laminated are wrapped to form a cigarette. A heated smoking article characterized in that.
  27. 제24항에 있어서,According to clause 24,
    냉각 튜브 로드의 하단에 적층되는, 담배체를 포함하는 담배체 로드;를 더 포함하고,It further includes a tobacco body rod including a tobacco body, which is stacked on the lower end of the cooling tube rod,
    에어로졸 매질 집합체는 담배체 로드 내측에 분포하도록 포함되는 것을 특징으로 하는 가열식 흡연 물품.A heated smoking article, characterized in that the aerosol medium aggregate is included to be distributed inside the tobacco rod.
  28. 제27항에 있어서,According to clause 27,
    담배체 로드는 별도의 랩핑 페이퍼에 의해 실린더 형상으로 랩핑되어 있는 것을 특징으로 하는 가열식 흡연 물품.A heated smoking article characterized in that the tobacco rod is wrapped in a cylindrical shape by separate wrapping paper.
  29. 제24항에 있어서,According to clause 24,
    에어로졸 매질 집합체는 그 중심부를 상하로 관통하도록 형성된 중공을 포함하도록 배치되고,The aerosol medium aggregate is arranged to include a hollow formed to penetrate upward and downward through its center,
    상기 중공에는 담배체가 구비되는 것을 특징으로 하는 가열식 흡연 물품.A heated smoking article, characterized in that the hollow is provided with a tobacco body.
  30. 제29항에 있어서,According to clause 29,
    에어로졸 매질 집합체에 형성된 중공과 에어로졸 매질 집합체의 경계면에는 메쉬 또는 다수의 통공을 갖는 통기막이 형성된 것을 특징으로 하는 가열식 흡연 물품.A heated smoking article, characterized in that a mesh or a breathable membrane having a plurality of through holes is formed at the interface of the hollow formed in the aerosol medium assembly and the aerosol medium assembly.
  31. 가열에 의해 에어로졸을 생성하는 에어로졸 매질을 포함하는 에어로졸 매질 집합체의 제조 방법에 있어서,In the method of producing an aerosol medium aggregate comprising an aerosol medium that generates an aerosol by heating,
    용기에 액상의 에어로졸 매질을 준비하는 단계;Preparing a liquid aerosol medium in a container;
    표면이나 내부에 마이크로 기공이 형성된 복수의 다공성 알갱이를 용기에 도입하여 액상의 에어로졸 매질과 혼합하고 다공성 알갱이에 흡습시키는 단계; 및Introducing a plurality of porous granules with micropores formed on the surface or inside into a container, mixing them with a liquid aerosol medium, and allowing moisture to be absorbed into the porous granules; and
    거름망을 이용하여, 액상의 에어로졸 매질을 흡습한 다공성 알갱이들과 잔존하는 액상의 에어로졸 매질을 분리하는 단계;를 포함하는 것을 특징으로 하는 에어로졸 매질 집합체의 제조 방법.A method for producing an aerosol medium aggregate, comprising the step of separating the remaining liquid aerosol medium from the porous particles that have absorbed the liquid aerosol medium using a filter.
  32. 제31항에 있어서,According to clause 31,
    액적이 흐르지 않도록, 액상의 에어로졸 매질을 흡습한 다공성 알갱이들을 소정 시간 건조하는 단계;를 추가로 포함하는 것을 특징으로 하는 에어로졸 매질 집합체의 제조 방법.A method for producing an aerosol medium aggregate, further comprising drying the porous particles that have absorbed moisture from the liquid aerosol medium for a predetermined period of time to prevent the droplets from flowing.
  33. 제31항에 있어서,According to clause 31,
    액상의 에어로졸 매질을 흡습한 다공성 알갱이들을 냉각하여, 액상의 에어로졸 매질을 겔상화 하는 단계;를 추가로 포함하는 것을 특징으로 하는 에어로졸 매질 집합체의 제조 방법.A method for producing an aerosol medium aggregate, comprising the step of cooling the porous particles that have absorbed the liquid aerosol medium to gel the liquid aerosol medium.
  34. 가열에 의해 에어로졸을 생성하는 고형화된 에어로졸 매질을 포함하는 에어로졸 매질 집합체의 제조 방법에 있어서,In the method of producing an aerosol medium aggregate comprising a solidified aerosol medium that generates an aerosol by heating,
    용기에 에어로졸 매질, 증점제 및 용해제의 혼합 용액을 준비하는 단계(용액 준비 단계);Preparing a mixed solution of aerosol medium, thickener, and solubilizer in a container (solution preparation step);
    표면이나 내부에 마이크로 기공이 형성된 복수의 다공성 알갱이를 용기에 도입하여 상기 혼합 용액과 혼합하여 혼합 용액을 다공성 알갱이에 흡습시키는 단계(흡습 단계);A step of introducing a plurality of porous granules with micropores formed on the surface or inside into a container, mixing them with the mixed solution, and causing the mixed solution to absorb moisture into the porous granules (moisture absorption step);
    거름망을 이용하여, 혼합 용액을 흡습한 다공성 알갱이들과 잔존하는 혼합 용액을 분리하는 단계(분리 단계); 및Separating the remaining mixed solution from the porous particles that have absorbed moisture from the mixed solution using a strainer (separation step); and
    다공성 알갱이에 흡습된 혼합 용액에 포함된 용해제를 증발시켜 고형화된 에어로졸 매질을 얻는 단계(고형화 단계);를 포함하는 것을 특징으로 하는 에어로졸 매질 집합체의 제조 방법.A method for producing an aerosol medium aggregate comprising a step of obtaining a solidified aerosol medium by evaporating the solvent contained in the mixed solution moisture absorbed by the porous particles (solidification step).
  35. 제34항에 있어서,According to clause 34,
    용해제는 에어로졸 매질 및 증점제보다 끓는 점이 낮고,The solubilizer has a lower boiling point than the aerosol medium and thickener,
    고형화 단계에서, 혼합 용액을 흡습한 다공성 알갱이를, 용해제의 끓는 점보다 높고 에어로졸 매질 및 증점제의 끓는 점보다 낮은 온도로 가열하여, 혼합 용액에 포함된 용해제를 증발시키고, 에어로졸 매질 및 증점제를 포함하는 고형화된 에어로졸 매질을 얻는 것을 특징으로 하는 에어로졸 매질 집합체의 제조 방법.In the solidification step, the porous granules that have absorbed the mixed solution are heated to a temperature higher than the boiling point of the dissolving agent and lower than the boiling point of the aerosol medium and the thickener to evaporate the dissolving agent contained in the mixed solution, and A method for producing an aerosol medium aggregate, characterized in that obtaining a solidified aerosol medium.
PCT/KR2023/005510 2022-04-22 2023-04-21 Aerosol medium assembly comprising porous beads and heated smoking article comprising same WO2023204686A1 (en)

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KR20220049898 2022-04-22
KR10-2022-0049898 2022-04-22
KR1020220153117A KR20230150706A (en) 2022-04-22 2022-11-15 Porous absorbent
KR10-2022-0153117 2022-11-15
KR10-2023-0017867 2023-02-10
KR1020230017867A KR20230151437A (en) 2022-04-22 2023-02-10 Aerosol medium aggregates comprising porous beads and heating type smoking article comprising the same
KR1020230021511A KR20230151439A (en) 2022-04-22 2023-02-17 Aerosol medium aggregates comprising porous beads and heating type smoking article comprising the same
KR10-2023-0021513 2023-02-17
KR1020230021513A KR20230151441A (en) 2022-04-22 2023-02-17 Aerosol medium aggregates comprising porous beads and heating type smoking article comprising the same
KR10-2023-0021511 2023-02-17
KR1020230021512A KR20230151440A (en) 2022-04-22 2023-02-17 Aerosol medium aggregates comprising porous beads and heating type smoking article comprising the same
KR10-2023-0021512 2023-02-17
KR1020230023593A KR20230151445A (en) 2022-04-22 2023-02-22 Electrically-heating type smoking articles
KR10-2023-0023593 2023-02-22
KR10-2023-0024785 2023-02-24
KR1020230024785A KR20230151450A (en) 2022-04-22 2023-02-24 Heating type smoking article comprising porous beads and tobacco body

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0978057A (en) * 1995-09-18 1997-03-25 Suzuki Yushi Kogyo Kk Aerosol composition and its production, and aerosol product using the same
US20080110470A1 (en) * 2006-08-03 2008-05-15 Philip Morris Usa Inc. Immobilized diluents for smoking articles
JP2012525137A (en) * 2009-04-29 2012-10-22 ブリティッシュ アメリカン タバコ (インヴェストメンツ) リミテッド Aerosol generator for smoking products
JP2017099287A (en) * 2014-04-02 2017-06-08 日本たばこ産業株式会社 Filter for smoking article
KR20200092268A (en) * 2019-01-24 2020-08-03 주식회사 이엠텍 Gel state aerosol generating medium cartridge insertable into electrically-heating type smoking article, electrically-heating type smoking article including the above and aerosol generating apparatus and its system therefor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0978057A (en) * 1995-09-18 1997-03-25 Suzuki Yushi Kogyo Kk Aerosol composition and its production, and aerosol product using the same
US20080110470A1 (en) * 2006-08-03 2008-05-15 Philip Morris Usa Inc. Immobilized diluents for smoking articles
JP2012525137A (en) * 2009-04-29 2012-10-22 ブリティッシュ アメリカン タバコ (インヴェストメンツ) リミテッド Aerosol generator for smoking products
JP2017099287A (en) * 2014-04-02 2017-06-08 日本たばこ産業株式会社 Filter for smoking article
KR20200092268A (en) * 2019-01-24 2020-08-03 주식회사 이엠텍 Gel state aerosol generating medium cartridge insertable into electrically-heating type smoking article, electrically-heating type smoking article including the above and aerosol generating apparatus and its system therefor

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