WO2023026956A1 - 光硬化性材料及び画像表示装置 - Google Patents
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- WO2023026956A1 WO2023026956A1 PCT/JP2022/031233 JP2022031233W WO2023026956A1 WO 2023026956 A1 WO2023026956 A1 WO 2023026956A1 JP 2022031233 W JP2022031233 W JP 2022031233W WO 2023026956 A1 WO2023026956 A1 WO 2023026956A1
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
Definitions
- the present invention relates to photocurable materials and image display devices.
- a typical image display device has a structure in which a front panel and an image display panel are laminated via a transparent resin layer, which is a cured product of a photocurable resin composition.
- a photocurable resin composition that functions as a damming agent is usually applied to the outer edge of the image display panel to form a photocurable dam portion, and then a region surrounded by the photocurable dam portion is formed.
- the image display panel and the front panel are bonded together, and the photocurable dam portion and the photocurable It is produced by a construction method (so-called dam-fill construction method) in which a transparent resin layer is formed by irradiating the fill portion with ultraviolet rays for photocuring (Patent Document 1).
- dam part and the fill part of the transparent resin layer of the image display device created by such a dam fill method due to the difference in the type and blending ratio of the components of the photocurable resin composition used, or the dam Due to migration of low-molecular-weight substances between the dam portion and the fill portion, a refractive index difference occurs between the dam portion and the fill portion, and the boundary line between them is visually recognized as a so-called knit line. are concerned.
- Patent Document 1 a curable resin composition that functions as a damming agent and a curable resin composition that functions as a filling agent are used in order to make the knit line invisible between the dam portion and the filling portion. , respectively, it is recommended to adjust the 400 nm transmittance difference between them to 5% or less, the refractive index difference to 0.01% or less, and the haze difference to 0.2% or less.
- Patent Document 1 the problem is the visibility of the boundary line when the curable resin composition used as a damming agent before curing and the curable resin composition used as a filling agent before curing come into contact with each other. However, it cannot be said that the knit line in the transparent resin layer after curing was examined. Moreover, in Patent Document 1, the "400 nm transmittance difference" and “refractive index difference” between the curable resin composition used as a damming agent before curing and the curable resin composition used as a filling agent before curing and the "haze difference" do not exceed predetermined values, but no specific index is given as to how the constituent components should be selected.
- An object of the present invention is to solve the conventional problems described above. To make it difficult to visually recognize a knit line between a dam portion and a fill portion of a cured transparent resin layer when a photocurable material for forming is used as a dam agent or a fill agent.
- the present inventors have developed a photocurable material for forming a dam portion and/or a fill portion of the transparent resin layer of an image display device in which an image display panel and a front panel are laminated via a transparent resin layer.
- a photocurable material for forming a dam portion and/or a fill portion of the transparent resin layer of an image display device in which an image display panel and a front panel are laminated via a transparent resin layer.
- the inventors have found that the above object can be achieved by doing the following, and have completed the present invention.
- the present invention provides a photocurable material for forming the transparent resin layer of an image display device in which an image display panel and a front panel are laminated via a transparent resin layer, the photocurable material comprising the following components ( a) to component (c): Component (a) (meth)acrylic acid ester component; component (b) a plasticizer component; and component (c) a photoinitiator component, Provided is a photocurable material in which the difference between the refractive index of the photocured product of the (meth)acrylic acid ester component of component (a) and the refractive index of the plasticizer component of component (b) is 0.02 or less.
- the present invention also provides an image display device in which an image display panel and a front panel are laminated via a transparent resin layer, wherein the transparent resin layer is a photocurable material of the above-described photocurable material of the present invention.
- An object image display device is provided.
- the photocurable material of the present invention contains component (a) (meth)acrylic acid ester component, component (b) plasticizer component, and component (c) photopolymerization initiator component, and component (a) (The difference between the refractive index of the photocured product of the meth)acrylic acid ester component and the refractive index of the plasticizer component (b) is 0.02 or less.
- component (a) (meth)acrylic acid ester component that easily migrates migrates from one of the dam portion and the fill portion of the transparent resin layer to the other, There is a concern that the boundary line will be visually recognized as a knit line.
- the difference between the refractive index of the photocured product of the component (a) (meth)acrylic acid ester component and the refractive index of the component (b) the plasticizer component is 0.5. 02 or less, which is very small. Therefore, it can be expected that the boundary line between the dam portion and the fill portion of the transparent resin layer is made difficult to be visually recognized as a knit line.
- FIG. 1 is a schematic cross-sectional view of one mode of an image display device.
- the photocurable material of the present invention is preferably used for forming the transparent resin layer 5 of the image display device 10 of FIG.
- the image display device 10 has a structure in which the image display panel 1 and the front panel 2 are laminated via a transparent resin layer 5 composed of a dam portion 3 and a fill portion 4 surrounded by the dam portion 3.
- a polarizing plate 6 is usually arranged on the surface of the image display panel 1 on the transparent resin layer 5 side.
- the photocurable material of the present invention may be applied to form both the dam portion 3 and the fill portion 4 of the transparent resin layer 5 in the image display device 10. may apply.
- the image display device to which the photocurable material of the present invention can be applied is not limited to the embodiment shown in FIG.
- the photocurable material of the present invention contains component (a) (meth)acrylic acid ester component, component (b) plasticizer component, and component (c) photopolymerization initiator component, which are photopolymerizable components.
- the difference between the refractive index of the photocured product of component (a) (meth)acrylic acid ester component and the refractive index of component (b) plasticizer component is 0.02 or less, preferably It is a material adjusted to 0.015 or less.
- the viscosity of the photocurable material of the present invention is too low, it tends to spread beyond the intended area when the material is applied, and it tends to be difficult to control the application area.
- the (a) (meth)acrylic ester component Since the difference between the refractive index of the photocured product of the acid ester component and the refractive index of the plasticizer component of component (b) is as small as 0.02 or less, the dam portion and the fill portion of the transparent resin layer after photocuring It becomes difficult to visually recognize the boundary line as a knit line.
- the photocured product of the component (a) (meth)acrylic acid ester component whose refractive index is to be measured is obtained by adding the component (c) the photopolymerization initiator component to 100 parts by mass of the component (a) (meth)acrylic acid ester component. It is obtained by mixing 0.5 to 1.0 parts by mass and photocuring by irradiation with light such as ultraviolet rays.
- the refractive index of the other component (b), which is the object of refractive index measurement, can be measured without any special pretreatment such as curing treatment.
- the refractive index can be measured using a commercially available Abbe refractive index measuring device.
- the measurement can be performed using a digital refractometer that detects the photorefractive critical angle.
- the photo-curing conditions for the component (a) (meth)acrylic acid ester component conditions can be appropriately selected such that the curing rate calculated by the FT-IR method is 90% or more, preferably 95% or more.
- a curing condition of 5000 mJ/cm 2 or more using a metal halide lamp can be mentioned.
- Specific measurement of the refractive index of the photocured product of the component (a) (meth)acrylic acid ester component can be performed as follows.
- a photocured product of a mixture of the plurality of components is measured.
- the adjustment of the refractive index of the photocured product of the component (a) (meth) acrylic acid ester component is the type and number of (meth) acrylic acid esters used as the (meth) acrylic acid ester component, and the mixing ratio of each can be done by changing
- the photo-curing of the component (a) (meth)acrylic acid ester component can be appropriately carried out according to a known technique depending on the type of polymerization initiator and the type of polymerization initiator. Photocuring is performed by irradiating the component (a) (meth)acrylic acid ester component having a thickness of 0.3 mm with ultraviolet rays normally emitted by a metal halide lamp so that the integrated light amount becomes 3000 to 5000 mJ/cm 2 . It can be carried out.
- the photocured product is one cured so that the overall average reaction rate (hardening rate) is 90% or more (preferably 95% or more).
- the reaction rate of the entire photocured product means the reaction rate measured for a cured product formed into a film having a thickness of 0.3 mm, for example.
- the reaction rate is the ratio of the amount of (meth)acryloyl groups present after photocuring to the amount of (meth)acryloyl groups present in the component (a) (meth)acrylic acid ester component before photocuring ( consumption ratio).
- a larger value of the reaction rate indicates more progress of the reaction.
- the reaction rate is the absorption peak height (X) of 1640 to 1620 cm -1 from the baseline in the FT-IR measurement chart of the photocurable material before photocuring, and the photocurability after photocuring. It can be calculated by substituting the absorption peak height (Y) at 1640 to 1620 cm ⁇ 1 from the baseline in the FT-IR measurement chart of the material (photocured layer) into the following formula.
- the plasticizer component is usually a high-viscosity liquid
- the refractive index of the plasticizer component is measured at the prism portion of a commercially available digital refractometer that detects the critical angle of light refraction (for example, RX-5000 ⁇ manufactured by Atago Co., Ltd.).
- the plasticizer component can be set and measured.
- the refractive index R of each of a plurality of plasticizers is measured.
- the refractive index R of each plasticizer is multiplied by its abundance (parts by mass) M to obtain a numerical value A, and the numerical value B obtained by adding all the numerical values A obtained for each plasticizer is Let the numerical value obtained by dividing by the total abundance C be the refractive index.
- the plasticizer component of component (b) contains two kinds of plasticizers (first plasticizer and second plasticizer)
- the calculation is performed as follows.
- the plasticizer component of component (b) contains a first plasticizer with a refractive index RIa and a second plasticizer with a refractive index RIb, the amount of the first plasticizer is W1 parts by mass, and the second When the existing amount of the plasticizer is W2 parts by mass, the refractive index of the plasticizer component of component (b) is calculated according to the following formula.
- the photocurable material of the present invention contains a (meth)acrylate component as component (a).
- (meth)acrylic acid ester includes acrylic acid ester and methacrylic acid ester in the present invention.
- the component (a) (meth)acrylate ester component preferably contains one or more polyfunctional (meth)acrylate oligomers and one or more monofunctional (meth)acrylate monomers.
- the reason for containing the polyfunctional (meth)acrylate oligomer is to maintain the film-forming properties of the photocurable material when forming a transparent resin layer from the photocurable material, and the monofunctional (meth)acrylate monomer is used.
- the reason for containing is to adjust the applicability and viscosity of the photocurable material and to impart good adhesiveness to the transparent resin layer containing the oligomer.
- a polyfunctional (meth)acrylate oligomer having a dielectric constant of 4.0 or more at 100 kHz can be preferably used. If the dielectric constant is less than 4.0, the moisture permeability of the cured product of the photocurable material tends to be too low. In addition, the dielectric constant can be measured by a general LCR meter.
- polyfunctional (meth)acrylate oligomer having a dielectric constant of 4.0 or more at 100 kHz a polyfunctional polyether-based urethane (meth)acrylate oligomer, a polyfunctional polyester-based urethane oligomer, a polyfunctional hydroxy group-containing oligomer, etc. are preferred. can be mentioned. Among them, a bifunctional polyether-based urethane (meth)acrylate oligomer is preferable because it can impart good moisture permeability to the cured product of the photocurable material.
- the weight-average molecular weight of the polyfunctional (meth)acrylate oligomer is too small, the cured product of the photo-curing material will be too hard, resulting in display unevenness when applied to a display device. It is preferably from 20,000 to 50,000, and more preferably from 30,000 to 40,000, because there is a concern that it will not be possible to impart an appropriate viscosity during handling. This weight average molecular weight can be measured using a general gel permeation chromatography device (GPC device).
- GPC device general gel permeation chromatography device
- the viscosity of the polyfunctional (meth)acrylate oligomer is too low, the cured product of the photocurable material becomes too hard, causing display unevenness when applied to a display device.
- the viscosity is preferably 20,000 to 60,000 mPa ⁇ s, and more preferably 30,000 to 50,000 mPa ⁇ s, since there is a tendency that an appropriate viscosity cannot be imparted. Viscosity can be measured using a general Brookfield viscometer.
- the glass transition temperature of the polyfunctional (meth)acrylate oligomer is too low, it will not be possible to impart good adhesiveness to the photocurable material.
- the temperature is preferably -30 to 10.degree. C., more preferably -20 to 0.degree.
- the glass transition temperature can be measured using a common differential scanning calorimeter.
- the content of the polyfunctional (meth)acrylate oligomer having a dielectric constant of 4.0 or more at 100 kHz in the (meth)acrylic ester component (a) is determined from the viewpoint of the adhesiveness and reactivity of the photocurable material. , preferably 20% to 40% by mass, more preferably 20% to 30% by mass.
- Component (a) (meth)acrylic acid ester component is a polyfunctional (meth)acrylate oligomer other than a polyfunctional (meth)acrylate oligomer having a dielectric constant of 4.0 or more at 100 kHz as long as it does not impair the effects of the present invention. , for example, a polyether-modified polyfunctional (meth)acrylate oligomer or the like.
- the monofunctional (meth)acrylate monomer contained in the component (a) (meth)acrylic acid ester component imparts high polarity to the photocurable material, improves the moisture permeability of the cured product of the photocurable material, and provides polarized light.
- a hydroxy group-containing (meth)acrylate monomer is preferably exemplified in order to release moisture generated from the plate to the outside of the image display device.
- the hydroxy group-containing (meth)acrylate monomer may contain two or more hydroxy groups, but from the viewpoint of avoiding a decrease in water resistance and adhesive strength of the photocured product, it is preferred that the hydroxy group is one. preferable.
- hydroxy group-containing (meth)acrylate monomers examples include hydroxyalkyl (meth)acrylate monomers, and although the number of carbon atoms in the alkyl is not limited, it is usually C1 to 12, preferably C1 to 6, Specific examples include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, hexyl, 2-ethylbutyl and the like.
- hydroxyalkyl (meth)acrylate monomers include 2-hydroxyethyl (meth)acrylate, 1-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate, 1 -hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, phenylglycidyl ether (meth)acrylate and the like.
- 2-hydroxyethyl (meth)acrylate and particularly 4-hydroxybutyl (meth)acrylate are preferable from the viewpoint of efficiently increasing the moisture permeability of the photocured product of the photocurable material.
- the component (a) (meth)acrylic acid ester component can contain a (meth)acrylate monomer that does not contain a hydroxy group as long as the effects of the invention are not impaired.
- (meth)acrylate monomers containing no hydroxy group include chain hydrocarbon group-containing types and cyclic hydrocarbon group-containing types. Examples include alkyl (meth)acrylate monomers, cycloalkyl or bicycloalkyl (meth)acrylate monomers, or heterocycloalkyl or heterobicycloalkyl (meth)acrylate monomers.
- Preferred alkyl (meth)acrylate monomers include isostearyl acrylate monomers and lauryl acrylate monomers.
- Cycloalkyl or bicycloalkyl (meth)acrylate monomers preferably include isobornyl acrylate monomers.
- Heterocycloalkyl or heterobicycloalkyl (meth)acrylate monomers preferably include morpholyl acrylate monomers.
- the content of monofunctional (meth)acrylate monomers such as hydroxyl group-containing (meth)acrylate monomers in the component (a) (meth)acrylic acid ester component is the moisture permeability of the cured product of the photocurable material. is preferably 25% by mass or more, more preferably 50% by mass or more, in order to improve the
- the content of the component (a) (meth)acrylic acid ester component in the photocurable material is too small, it will be difficult to impart an appropriate viscosity during handling of the photocurable material. Since there is a concern that the shrinkage rate during curing may become too large, the content is preferably 20% by mass to 40% by mass, more preferably 25% by mass to 35% by mass.
- the difference in refractive index between the photocured products of one or more polyfunctional (meth)acrylate oligomers and one or more monofunctional (meth)acrylate monomers contained in the component (a) (meth)acrylic acid ester component is preferably 0.02 or less, more preferably 0.015 or less from the viewpoint of migration from one of the dam portion and the fill portion to the other.
- the photocured product of each polyfunctional (meth)acrylate oligomer and each monofunctional (meth)acrylate monomer contains 0.5 parts by mass to 1.0 part by mass of the photopolymerization initiator component (c) to 100 parts by mass of each oligomer or monomer. 0 parts by mass were mixed and photocured.
- the photocuring conditions conditions can be appropriately selected so that the curing rate calculated by the FT-IR method is 90% or more, preferably 95% or more.
- a curing condition of 5000 mJ/cm 2 or more using a metal halide lamp can be mentioned.
- the refractive index can be measured using a commercially available Abbe refractive index measuring device.
- the photocurable material of the present invention contains a plasticizer component as component (b).
- the plasticizer itself does not undergo photocuring upon irradiation with light, and imparts flexibility to the photocured product after photocuring.
- a plasticizer preferably contains one of polyether-based polyols and polyester-based polyols. It is more preferable to contain a polyether-based polyol.
- general polymers that are miscible with these plasticizer components can also be used as plasticizers.
- a polymer that can be used as a plasticizer a polymer having a small refractive index difference with respect to the plasticizer component (b) used in combination can be preferably used.
- polymers containing hydroxyl groups can be exemplified.
- polyether-based polyols for example, general polyether polyols obtained by addition polymerization of alkylene oxide to polyols such as ethylene glycol, propylene glycol, glycerin, and trimethylolpropane can be used.
- Alkylene oxide is not particularly limited, and examples thereof include ethylene oxide, propylene oxide, butylene oxide and the like.
- polyether-based polyols include, for example, "ADEKA Polyether” manufactured by ADEKA Corporation. More specifically, the "P series” are propylene oxide (PO) adducts of propylene glycol, the “BPX series” are PO adducts of bisphenol A, the “G series” are PO adducts of glycerin, and trimethylol.
- PO propylene oxide
- BPX series propylene oxide
- G series are PO adducts of glycerin
- trimethylol trimethylol
- the number average molecular weight of the polyether-based polyol is preferably 500 to 8000, more preferably 1000 to 5000.
- the number average molecular weight can be measured using a general gel permeation chromatography device (GPC device).
- polyester-based polyol for example, a general polyester polyol obtained by subjecting a dicarboxylic acid and a diol to a polycondensation reaction can be used.
- dicarboxylic acids include aliphatic carboxylic acids such as adipic acid, azelaic acid, sebacic acid and dodecanedioic acid; aromatic carboxylic acids such as terephthalic acid and isophthalic acid.
- diols examples include straight-chain diols such as ethylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,9-nonanediol, and diethylene glycol; 1,2-propylene glycol, 1,3- butylene glycol, 2-methyl-1,3-propanediol, neopentyl glycol, 3-methyl-1,5-pentadiol, 2,2-dimethyl-1,3-propanediol, 2-methyl-1,8- octanediol and the like.
- straight-chain diols such as ethylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,9-nonanediol, and diethylene glycol
- 1,2-propylene glycol 1,3- butylene glycol, 2-methyl-1,3-propanediol, neopentyl glycol, 3-methyl-1
- polyester polyols include “P-1010”, “P-2010”, “P-3010”, “P-2050” (manufactured by Kuraray Co., Ltd.), “OD-X-102”, “OD -X-668”, “OD-X-2068” (manufactured by DIC), “NS-2400”, “YT-101”, “F7-67”, “#50”, “F1212-29”, “YG-108”, “V14-90”, “Y65-55" (manufactured by ADEKA) and the like.
- the number average molecular weight of the polyester-based polyol is too small, exudation may occur from the cured product of the photocurable material. is concerned, it is preferably 500 to 8000, more preferably 1000 to 5000.
- the content of the plasticizer component of component (b) in the photocurable material is too small, sufficient flexibility required when applying the cured product of the photocurable material as a laminating agent for an image display device will not be obtained. If it is too large, there is a concern that sufficient adhesive strength cannot be imparted to the photocurable material.
- the difference in refractive index between them is one of the dam portion and the fill portion From the viewpoint of suppressing migration from one to the other, it is preferably 0.03 or less, more preferably 0.02 or less.
- the preferable upper limit (0.03 or less) of the refractive index difference in component (b) is higher than the preferable upper limit (preferably 0.02 or less) of the refractive index difference in component (a) because the component ( This is because the plasticizer component b) has a higher viscosity than the component (a) and is difficult to flow in the first place.
- the photocurable material of the present invention contains a photopolymerization initiator as component (c) depending on the type of polymerization. Among them, it is preferable to contain a photoradical polymerization initiator from the viewpoint of imparting high reactivity to the photocurable material. As the radical photopolymerization initiator, it is more preferable to contain at least one of an alkylphenone-based photopolymerization initiator and an acylphosphine oxide-based photopolymerization initiator.
- alkylphenone-based photopolymerization initiators examples include 1-hydroxycyclohexylphenyl ketone (Omnirad 184, manufactured by IGM Resins B.V.), 2-hydroxy-1- ⁇ 4-[4-(2-hydroxy-2- Methyl-propyronyl)benzyl]phenyl ⁇ -2-methylpropan-1-one (Omnirad 127, manufactured by IGM Resins B.V.) and the like can be used.
- acylphosphine oxide-based photopolymerization initiator 2,4,6-trimethylbenzoyldiphenylphosphine oxide (SPEEDCURE TPO, manufactured by Ransom) and the like can be used.
- benzophenone, acetophenone, etc. can also be used as a photopolymerization initiator.
- the content of the photopolymerization initiator as the component (c) in the photocurable material of the present invention is 0.2 to 2 parts by mass is preferable, and 0.5 to 1 part by mass is more preferable. By setting it to such a range, it is possible to more effectively prevent insufficient curing at the time of light irradiation, and more effectively prevent an increase in outgassing due to the polymerization reaction.
- a photoinitiator may be used individually by 1 type, and may use 2 or more types together. When two or more photopolymerization initiators are used in combination, the total amount preferably satisfies the above range.
- the photocurable material of the present invention can contain a known filler as component (d) depending on the application of the photocurable material.
- a known filler as component (d) depending on the application of the photocurable material.
- silica as a filler. This is because the inclusion of silica can impart a thixotropic ratio of preferably 2 to 5, more preferably 2.5 to 3.5 to the photocurable material, making it useful as a damming agent. Specifically, if it is too small, it becomes difficult to maintain the shape of the photocurable material, and if it is too large, the dischargeability of the photocurable material from a dispenser or the like decreases.
- the thixotropic ratio is calculated from the viscosity measured using a general rotational viscometer (cone plate rheometer, 25° C., cone C35/2, number of revolutions 10 rpm). It is defined as a numerical value obtained by dividing the viscosity at a rotational speed of 1 rpm by the viscosity at a rotational speed of 10 rpm.
- the average particle size of such silica is 7 nm or more and 40 nm or less, more preferably 10 nm or more and 20 nm or less.
- the average particle size can be measured using a general laser diffraction particle size distribution meter.
- silica as component (d) is preferably hydrophobized on its surface.
- a photocurable material containing hydrophobized silica can exhibit good thixotropy without impairing the moisture permeability and transparency of the cured product.
- a known alkylsilylation treatment of silica can be preferably mentioned.
- a higher alkyl silylation treatment having 12 to 18 carbon atoms, particularly a hexadecyl silylation treatment as described below is preferred.
- Hexadecylsilylation treatment of silica can be carried out according to a conventional method. For example, it can be carried out by subjecting hydroxyl groups present on the surface of silica filler having an untreated surface to a polycondensation reaction with silanol having a hexadecyl group.
- the BET specific surface area of the filler (especially silica) of component (d) is too small, it may not be possible to impart sufficient thixotropy to the photocurable material, and if it is too large, secondary aggregation in the photocurable material It is preferably 100 m 2 /g or more and 300 m 2 /g or less, more preferably 130 m 2 /g or more and 200 m 2 /g or less.
- the BET specific surface area can be measured by the so-called BET method.
- the content of the component (d) filler (especially silica) in the photocurable material is too low, sufficient thixotropic properties cannot be obtained, and if it is too high, there is concern that the transparency of the cured product cannot be maintained. , preferably 5% by mass or more and 15% by mass or less, more preferably 5% by mass or more and 10% by mass or less.
- the photocurable material of the present invention contains antioxidants, solvents, ultraviolet absorbers, colorants, organic or inorganic fillers, etc., as long as the effects of the present invention are not impaired. of known resin additives.
- the photocurable material of the present invention can be prepared by uniformly mixing the components described above according to a known mixing method.
- the photocurable material of the present invention is such that the image display panel 1 and the front panel 2, as shown in FIG. It can be preferably used as a material for forming the dam portion 3 or the fill portion 4 or both the dam portion 3 and the fill portion 4 of the laminated image display device 10 .
- a polarizing plate 6 may be arranged on the surface of the image display panel in contact with the transparent resin layer 5 .
- Such an image display device is also one aspect of the present invention, but the image display device of the present invention is not limited to the aspect of FIG.
- the component (a) in the dam portion 3 The difference between the refractive index of the photocured product of the (meth)acrylic acid ester component and the refractive index of the plasticizer component of component (b) is set to 0.02 or less, preferably 0.015 or less.
- the difference between the refractive index of the photocured product of the (meth)acrylic acid ester component of component (a) and the refractive index of the plasticizer component of component (b) in 4 is 0.02 or less, preferably 0.015 or less. .
- the refractive index of the photocured product of the (meth)acrylic acid ester component of component (a) in the dam portion 3 and the (meth) of component (a) in the fill portion 4 is preferably 0.02 or less, more preferably 0.015 or less, and the refractive index of the plasticizer component (b) in the dam portion 3 is The difference in refractive index from the plasticizer component of component (b) in 4 is also preferably 0.02 or less, more preferably 0.015 or less.
- Image display panel 1 Examples of the image display panel 1 constituting the image display device 10 of the present invention include a liquid crystal display panel, an organic EL display panel, a touch panel, and the like.
- the touch panel means an image display/input panel in which a display element such as a liquid crystal display panel and a position input device such as a touch pad are combined.
- the front panel 2 that constitutes the image display device 10 of the present invention functions as a protective panel for the image display panel 1 .
- the front panel 2 include plate-like materials and sheet-like materials such as glass, acrylic resin, polyethylene terephthalate, polyethylene naphthalate, and polycarbonate. These materials may be subjected to hard coating treatment, antireflection treatment, or the like on one or both sides thereof. Physical properties such as the thickness and elastic modulus of the front panel 2 can be appropriately determined according to the purpose of use.
- the front panel 2 includes not only the member having a relatively simple structure as described above, but also a laminate of various sheets or film materials such as a touch panel module.
- a light shielding layer may be provided on the periphery of the front panel 2 to improve the image contrast (not shown).
- the light shielding layer can be formed, for example, by applying a paint colored black or the like by a screen printing method or the like, followed by drying and curing.
- the thickness of the light-shielding layer is usually 5-100 ⁇ m.
- the transparent resin layer 5 of the image display device 10 of the present invention is composed of the dam portion 3 and the fill portion 4 .
- the dam portion 3 is provided on the outer periphery of the image display panel, and the inside of the dam portion 3 is filled with the filling portion 4 .
- the dam portion 3 is generally a continuous structure with a width of 0.3 mm to 3 mm and a height of 0.1 mm to 2 mm.
- a metal bezel not shown
- the boundary between the metal bezel and the image display panel usually has a width of 0.3 mm to 3 mm and a height of 0.1 mm to 0.1 mm.
- a continuous further dam with a size of 2 mm may be provided.
- the polarizing plate 6 has a polarizer (not shown) sandwiched between a pair of protective layers (not shown). An adhesive may be used when sandwiching. Moreover, the polarizing plate 6 may further include an optical layer (for example, a retardation plate) other than the polarizer and the protective layer. The thickness of the polarizing plate 6 is usually 0.1 mm to 0.3 mm.
- polarizer for example, a polarizer having a well-known structure obtained by subjecting a polyvinyl alcohol-based resin to a dyeing treatment with a dichroic substance (eg, an iodine compound) and a stretching treatment can be used.
- a dichroic substance eg, an iodine compound
- thermoplastic resins such as triacetyl cellulose (TAC), polyester resins such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN), polyethersulfone resins, polysulfone resins, polycarbonate resins, Polyamide resins, polyimide resins, polyolefin resins, (meth)acrylic resins, cyclic polyolefin resins, polyarylate resins, polystyrene resins, polyvinyl alcohol resins, and mixtures thereof.
- TAC triacetyl cellulose
- PET polyethylene terephthalate
- PEN polyethylene naphthalate
- polyethersulfone resins polysulfone resins
- polysulfone resins polycarbonate resins
- Polyamide resins polyimide resins
- polyolefin resins polyolefin resins
- (meth)acrylic resins cyclic polyolefin resins
- polyarylate resins polyst
- the image display device of the present invention shown in FIG. 1 can be manufactured as described below, but is not limited thereto.
- a polarizing plate is placed on one side of an image display panel according to a conventional method, and the photocurable material of the present invention is applied around it in a dam shape using a dispenser or the like, and a photocurable dam portion is formed by irradiating with ultraviolet rays.
- a photocurable resin composition for forming the fill portion is applied to the area surrounded by the photocurable dam portion using a dispenser or the like and dried to form the photocurable fill portion.
- a photocurable resin layer composed of a photocurable dam portion and a photocurable fill portion is formed.
- the front panel is laminated on the photocurable resin layer.
- the photocurable resin layer is irradiated with ultraviolet light through the front panel to be photocured, thereby forming a photocured transparent resin layer, and the image display device shown in FIG. 1 is obtained.
- Plasticizer component Polyether plasticizer: ADEKA POLYETHER P-3000 (PO adduct of propylene glycol, manufactured by ADEKA Co., Ltd.); Hydroxyl group-containing polymer: Elfort 3122L (polymer of 2-ethylhexyl acrylate and hydroxyethyl acrylate, manufactured by Showa Denko Materials Co., Ltd.).
- ⁇ Component (c) photoinitiator component Phosphine oxide-based photopolymerization initiator: SPEEDCURE TPO (2,4,6-trimethylbenzoyldiphenylphosphine oxide, manufactured by Ransome).
- ⁇ Component (d) filler> Surface-untreated silica: Aerosil 200 (fumed silica, manufactured by Nippon Aerosil Co., Ltd.); Hydrophobized surface-treated silica: VP NKC130 (fumed silica surface-treated with hexadecyl group-containing silane (alkyl group-containing silane compound having 16 carbon atoms), manufactured by Nippon Aerosil Co., Ltd.).
- Examples 1-3, Comparative Examples 1-2 Components (a) to (d) shown in Table 1 were uniformly mixed according to a conventional method to prepare photocurable materials for the dam portion and the fill portion.
- Table 1 shows the visibility evaluation results of the knit line at the boundary between the dam portion and the fill portion of the transparent resin layer of the image display device having the structure of FIG. 1 obtained in each example and comparative example.
- the photocurable material of the present invention contains component (a) (meth)acrylic acid ester component, component (b) plasticizer component, and component (c) photopolymerization initiator component, and component (a) (The difference between the refractive index of the photocured product of the meth)acrylate component and the refractive index of the plasticizer component (b) is 0.02 or less. Therefore, when the photocurable material of the present invention is applied to form the transparent resin layer of an image display device in which an image display panel and a front panel are laminated via a transparent resin layer, the dam of the transparent resin layer It can be expected that the boundary line between the part and the fill part is made difficult to be visually recognized as a knit line. Therefore, the photocurable material of the present invention is useful for manufacturing various types of image display devices.
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Abstract
Description
成分(a)(メタ)アクリル酸エステル成分;
成分(b)可塑剤成分;及び
成分(c)光重合開始剤成分
を含有し、
成分(a)の(メタ)アクリル酸エステル成分の光硬化物の屈折率と、成分(b)の可塑剤成分の屈折率との差が0.02以下である光硬化性材料を提供する。
本発明の光硬化性材料は、光重合成分である成分(a)(メタ)アクリル酸エステル成分と、成分(b)可塑剤成分と、成分(c)光重合開始剤成分とを含有する。本発明の光硬化性材料は、成分(a)(メタ)アクリル酸エステル成分の光硬化物の屈折率と、成分(b)可塑剤成分の屈折率との差が0.02以下、好ましくは0.015以下に調整されている材料である。
屈折率の測定対象である成分(a)(メタ)アクリル酸エステル成分の光硬化物は、成分(a)(メタ)アクリル酸エステル成分100質量部に、成分(c)光重合開始剤成分を0.5~1.0質量部で混合し、紫外線などの光照射により光硬化させたものである。なお、もう一方の屈折率の測定対象である成分(b)可塑剤成分については、硬化処理などの特別な前処理を施すことなく、そのまま屈折率を測定すればよい。なお、屈折率の測定対象の光硬化物が固体である場合、その屈折率の測定は、市販のアッベ式屈折率測定装置を用いて行うことができる。なお、屈折率の測定対象の光硬化物が高粘度液体である場合には、光屈折臨界角検出方式のデジタル屈折計を用いて行うことができる。
可塑剤成分が単一成分である場合と、複数の可塑剤を含有している場合(合算屈折率)に分けて説明する。
可塑剤成分の屈折率は、可塑剤成分が、通常、高粘度液体なので、光屈折臨界角検出方式の市販のデジタル屈折計(例えば、(株)アタゴのRX-5000α)のプリズム部に測定対象である可塑剤成分をセットして測定することができる。
上述したように、複数の可塑剤のそれぞれの屈折率Rを測定する。各可塑剤の屈折率Rにその存在量(質量部)Mを乗じて数値Aを求め、各可塑剤で求められた数値Aをすべて足し合わせて得られた数値Bを、複数の可塑剤の合計の存在量Cで除することにより得られる数値を屈折率とする。具体例として、成分(b)の可塑剤成分が2種類の可塑剤(第1可塑剤と第2可塑剤)を含有している場合、以下のように算出される。
本発明の光硬化性材料は、成分(a)として(メタ)アクリル酸エステル成分を含有する。ここで、“(メタ)アクリル酸エステル”という用語は、本発明においてはアクリル酸エステルとメタクリル酸エステルとを包含する。
本発明の光硬化性材料は、成分(b)として可塑剤成分を含有する。可塑剤は、光照射によりそれ自身が光硬化をせず、光硬化後の光硬化物に柔軟性を付与するものである。このような可塑剤は、他の成分との相溶性の観点から、好ましくはポリエーテル系ポリオール及びポリエステル系ポリオールの1種を含有することが好ましい。ポリエーテル系ポリオールを含有することがより好ましい。また、これらの可塑剤成分と混和する一般的なポリマーも可塑剤として使用可能である。このような可塑剤として使用可能なポリマーとしては、併用される成分(b)の可塑剤成分に対して屈折率差が小さいポリマーを好ましく使用できる。例えば、水酸基を含有するポリマーを例示することができる。
本発明の光硬化性材料は、成分(c)として重合形式に応じた光重合開始剤を含有する。中でも、光硬化性材料に高反応性を付与する点から、光ラジカル重合開始剤を含有することが好ましい。光ラジカル重合開始剤としては、アルキルフェノン系光重合開始剤及びアシルフォスフィンオキサイド系光重合開始剤の少なくとも1種を含有することがより好ましい。アルキルフェノン系光重合開始剤としては、1-ヒドロキシシクロへキシルフェニルケトン(Omnirad184、IGM Resins B.V.社製)、2-ヒドロキシ-1-{4-[4-(2一ヒドロキシ-2-メチル-プロピロニル)ベンジル]フェニル}-2-メチルプロパン-1-オン(Omnirad127、IGM Resins B.V.社製)等を用いることができる。アシルフォスフィンオキサイド系光重合開始剤としては、2,4,6-トリメチルベンゾイルジフェニルホスフィンオキサイド(SPEEDCURE TPO、ランサム社製)等を用いることができる。その他、光重合開始剤としては、ベンゾフェノン、アセトフェノン等を用いることもできる。
本発明の光硬化性材料は、光硬化性材料の用途等に応じ、成分(d)として公知のフィラーを含有することができる。特に、フィラーとしてシリカを含有することが好ましい。シリカを含有することにより、光硬化性材料に好ましくは2~5、より好ましくは2.5~3.5のチキソ比を付与することができ、ダム剤として有用となるからである。具体的には、小さすぎると光硬化性材料の形状保持が困難となり、大きすぎると光硬化性材料のディスペンサー等からの吐出性が低下するからである。ここで、チキソ比は、一般的な回転粘度計(コーンプレートレオメータ、25℃、コーンC35/2、回転数10rpm)を用いて測定した粘度から計算されるものであり、具体的には、25℃で回転速度1rpm時の粘度を回転速度10rpm時の粘度で除して得られる数値として定義される。
本発明の光硬化性材料は、上述した成分(a)~(d)の他、本発明の効果を損なわない範囲で、酸化防止剤、溶剤、紫外線吸収剤、着色剤、有機または無機フィラー等の公知の樹脂用添加剤を含有することができる。
本発明の光硬化性材料は、上述した各成分を、公知の混合手法に従って均一に混合することにより調製することができる。
本発明の光硬化性材料は、図1に示すような、画像表示パネル1と前面パネル2とが、フィル部4とその外周を囲むダム部3とから構成された透明樹脂層5を介して積層されてなる画像表示装置10の当該ダム部3又はフィル部4もしくはダム部3とフィル部4の双方を形成するための材料として、好ましく使用することができる。このように、本発明の光硬化性材料を透明樹脂層に適用することにより、ダム部3とフィル部4との境界線においてニットラインを視認され難くすることができる。なお、透明樹脂層5に接する画像表示パネル表面には偏光板6が配置されていてもよい。このような画像表示装置も本発明の一態様であるが、本発明の画像表示装置は、図1の態様に限定されるものではない。
本発明の画像表示装置10を構成する画像表示パネル1としては、液晶表示パネル、有機EL表示パネル、タッチパネル等が挙げられる。ここで、タッチパネルとは、液晶表示パネルのような表示素子とタッチパッドのような位置入力装置を組み合わせた画像表示・入力パネルを意味する。
本発明の画像表示装置10を構成する前面パネル2は、画像表示パネル1の保護パネルとして機能するものである。前面パネル2としては、ガラス、アクリル樹脂、ポリエチレンテレフタレート、ポリエチレンナフタレート、ポリカーボネート等の板状材料やシート状材料が挙げられる。これらの材料には、片面又は両面にハードコート処理、反射防止処理などが施されていてもよい。前面パネル2の厚さや弾性率などの物性は、使用目的に応じて適宜決定することができる。なお、前面パネル2には、上記のような比較的構成の簡単な部材だけでなく、タッチパネルモジュールのような各種シート又はフィルム材が積層されたものも含まれる。
本発明の画像表示装置10の透明樹脂層5は、ダム部3とフィル部4とから構成される。ダム部3は、画像表示パネルの外周に設けられ、その内側にフィル部4が充填されるものである。ダム部3は、通常、幅0.3mm~3mmで高さ0.1mm~2mmの大きさの連続した構造物である。また、金属ベゼル(図示せず)が画像表示パネル1の外縁に設けられている場合には、金属ベゼルと画像表示パネルの境界に、通常、幅0.3mm~3mmで高さ0.1mm~2mmの大きさの連続した別のダム部が設けられていてもよい。
偏光板6は、偏光子(図示せず)を一対の保護層(図示せず)で挟持したものである。挟持する際、接着剤を用いてもよい。また、偏光板6は、偏光子と保護層以外の他の光学層(例えば位相差板)をさらに備えていてもよい。偏光板6の厚みは、通常0.1mm~0.3mmである。
図1に示す本発明の画像表示装置は、以下に説明するように製造することができるが、限定されるものではない。
(オリゴマー)
ポリエーテル系オリゴマー:UV-3700B(ウレタンアクリレートオリゴマー、三菱ケミカル(株)製)。
(モノマー)
水酸基含有モノマー:4-HBA(4-ヒドロキシブチルアクリレート、大阪有機化学工業(株)製);
環状基含有モノマー:ビスコート200(環状トリメチロールプロパンホルマールアクリレ―ト、大阪有機化学工業(株)製);
エーテル基含有モノマー:ビスコート190(エトキシエトキシエチルアクリレート、大阪有機化学工業(株)製);
アルキル基含有モノマー:IDAA(イソデシルアクリレート、大阪有機化学工業(株)製)。
ポリエーテル系可塑剤:アデカポリエーテルP-3000(プロピレングリコールのPO付加物、(株)ADEKA製);
水酸基含有ポリマー:エルフォート3122L(2-エチルヘキシルアクリレートとヒドロキシエチルアクリレートの重合体、昭和電工マテリアルズ(株)製)。
ホスフィンオキサイド系光重合開始剤:SPEEDCURE TPO(2,4,6-トリメチルベンゾイルジフェニルホスフィンオキシド、ランサム社製)。
表面未処理シリカ:アエロジル200(ヒュームドシリカ、日本アエロジル(株)製);
疎水化表面処理シリカ:VP NKC130(ヘキサデシル基含有シラン(炭素数16のアルキル基含有シラン化合物)で表面処理されたヒュームドシリカ、日本アエロジル(株)製)。
表1に示す成分(a)~(d)を、常法に従って均一に混合することによりダム部用並びにフィル部用の光硬化性材料を調整した。
各実施例、比較例で得られた図1の構造を有する画像表示装置の透明樹脂層のダム部とフィル部との境界線のニットラインの目視による視認性評価結果を表1に示す。
表1からわかるように、成分(a)の全体の光硬化物の屈折率と成分(b)の屈折率差に関し、実施例1~3の光硬化性材料は0.02未満となっていたため、ニットラインは視認されなかった。特に、実施例1及び2の光硬化性材料は0.02を大きく下回っていたため、実施例3の光硬化性材料よりもニットラインの視認性が低下していると期待される。
2 前面パネル
3 ダム部
4 フィル部
5 透明樹脂層
6 偏光板
10 画像表示装置
Claims (12)
- 画像表示パネルと前面パネルとが、透明樹脂層を介して積層されてなる画像表示装置の当該透明樹脂層を形成するための光硬化性材料であって、以下の成分(a)~成分(c):
成分(a)(メタ)アクリル酸エステル成分;
成分(b)可塑剤成分;及び
成分(c)光重合開始剤成分
を含有し、
成分(a)の(メタ)アクリル酸エステル成分の光硬化物の屈折率と、成分(b)の可塑剤成分の屈折率との差が0.02以下である光硬化性材料。 - 成分(a)の(メタ)アクリル酸エステル成分の光硬化物は、(メタ)アクリル酸エステル成分100質量部に、成分(c)の光重合開始剤成分0.5質量部~1.0質量部を混合し、光硬化させたものである請求項1記載の光硬化性材料。
- 成分(a)の(メタ)アクリル酸エステル成分が、1種以上の多官能(メタ)アクリレートオリゴマーと1種以上の単官能(メタ)アクリレートモノマーとを含有する請求項1又は2記載の光硬化性材料。
- 多官能(メタ)アクリレートオリゴマーが、2官能ポリエーテル系ウレタン(メタ)アクリレートオリゴマーであり、単官能(メタ)アクリレートモノマーがヒドロキシ基含有(メタ)アクリレートモノマーである請求項3記載の光硬化性材料。
- 成分(a)の(メタ)アクリル酸エステル成分が含有する各オリゴマー及び各モノマーの光硬化物相互間の屈折率の差が0.02以下である請求項1~4のいずれかに記載の光硬化性材料。
- 成分(b)の可塑剤成分が複数の可塑剤を含有している場合、成分(b)の可塑剤成分の屈折率は、複数の可塑剤の各可塑剤について、屈折率にその存在量(質量部)を乗じて数値を求め、各可塑剤で求められた数値をすべて足し合わせて得られた数値を、複数の可塑剤の合計の存在量で除することにより得られる数値である請求項1~5のいずれかに記載の光硬化性材料。
- 成分(b)の可塑剤成分が複数の可塑剤を含有している場合、複数の可塑剤の相互間の屈折率差が、0.03以下である請求項1~7のいずれかに記載の光硬化性材料。
- 該透明樹脂層が、画像表示パネルの表示部に対応した位置に存在するフィル部とその外周を囲むダム部とから構成されている場合に当該ダム部を形成するための請求項1~8のいずれかに記載の光硬化性材料は、更に成分(d)としてフィラーを含有する光硬化性材料。
- 画像表示パネルと前面パネルとが、透明樹脂層を介して積層されてなる画像表示装置であって、当該透明樹脂層が、請求項1~9のいずれかに記載の光硬化性材料の光硬化物である画像表示装置。
- 該透明樹脂層が、画像表示パネルの表示部に対応した位置に存在するフィル部とその外周を囲むダム部とから構成されている場合に、当該ダム部を形成するための請求項1~9のいずれかに記載の光硬化性材料における成分(a)の(メタ)アクリル酸エステル成分の光硬化物の屈折率と成分(b)の可塑剤成分の屈折率との差が0.02以下であり、当該フィル部を形成するための請求項1~9のいずれかに記載の光硬化性材料における成分(a)の(メタ)アクリル酸エステル成分の光硬化物の屈折率と成分(b)の可塑剤成分の屈折率との差が0.02以下である画像表示装置。
- ダム部における成分(a)の(メタ)アクリル酸エステル成分の光硬化物の屈折率と、フィル部における成分(a)の(メタ)アクリル酸エステル成分の光硬化物の屈折率との差、及びダム部における成分(b)の可塑剤成分の屈折率と、フィル部における成分(b)の可塑剤成分の屈折率との差が、それぞれ0.02以下である請求項11記載の画像表示装置。
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KR1020247005422A KR20240035576A (ko) | 2021-08-26 | 2022-08-18 | 광경화성 재료 및 화상 표시 장치 |
EP22861244.6A EP4393971A1 (en) | 2021-08-26 | 2022-08-18 | Photocurable material and image display device |
CN202280056872.2A CN117836834A (zh) | 2021-08-26 | 2022-08-18 | 光固化性材料和图像显示装置 |
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US20100302641A1 (en) * | 2006-07-20 | 2010-12-02 | Zhijian Lu | Optical Diffusers, Photomasks and Their Methods of Fabrication |
WO2014046182A1 (ja) * | 2012-09-20 | 2014-03-27 | 三菱レイヨン株式会社 | 光硬化型粘着剤組成物及び表示パネル |
JP2014148606A (ja) * | 2013-01-31 | 2014-08-21 | Denki Kagaku Kogyo Kk | 硬化性樹脂組成物 |
WO2014168173A1 (ja) * | 2013-04-10 | 2014-10-16 | 電気化学工業株式会社 | 硬化性樹脂組成物 |
WO2016039289A1 (ja) * | 2014-09-08 | 2016-03-17 | 電気化学工業株式会社 | 組成物 |
WO2018110666A1 (ja) * | 2016-12-14 | 2018-06-21 | デンカ株式会社 | 組成物 |
JP2018140601A (ja) * | 2017-02-28 | 2018-09-13 | デクセリアルズ株式会社 | 積層体の製造方法、及び光硬化性樹脂組成物 |
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2022
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- 2022-08-18 EP EP22861244.6A patent/EP4393971A1/en active Pending
- 2022-08-18 CN CN202280056872.2A patent/CN117836834A/zh active Pending
- 2022-08-18 WO PCT/JP2022/031233 patent/WO2023026956A1/ja active Application Filing
- 2022-08-25 TW TW111132055A patent/TW202323045A/zh unknown
Patent Citations (7)
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US20100302641A1 (en) * | 2006-07-20 | 2010-12-02 | Zhijian Lu | Optical Diffusers, Photomasks and Their Methods of Fabrication |
WO2014046182A1 (ja) * | 2012-09-20 | 2014-03-27 | 三菱レイヨン株式会社 | 光硬化型粘着剤組成物及び表示パネル |
JP2014148606A (ja) * | 2013-01-31 | 2014-08-21 | Denki Kagaku Kogyo Kk | 硬化性樹脂組成物 |
WO2014168173A1 (ja) * | 2013-04-10 | 2014-10-16 | 電気化学工業株式会社 | 硬化性樹脂組成物 |
WO2016039289A1 (ja) * | 2014-09-08 | 2016-03-17 | 電気化学工業株式会社 | 組成物 |
WO2018110666A1 (ja) * | 2016-12-14 | 2018-06-21 | デンカ株式会社 | 組成物 |
JP2018140601A (ja) * | 2017-02-28 | 2018-09-13 | デクセリアルズ株式会社 | 積層体の製造方法、及び光硬化性樹脂組成物 |
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JP2023031994A (ja) | 2023-03-09 |
TW202323045A (zh) | 2023-06-16 |
CN117836834A (zh) | 2024-04-05 |
WO2023026956A9 (ja) | 2023-04-13 |
EP4393971A1 (en) | 2024-07-03 |
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